PL414234A1 - Sposób wytwarzania kompleksów rutenu i związków pośrednich oraz ich zastosowanie w metatezie olefin - Google Patents

Sposób wytwarzania kompleksów rutenu i związków pośrednich oraz ich zastosowanie w metatezie olefin

Info

Publication number
PL414234A1
PL414234A1 PL414234A PL41423415A PL414234A1 PL 414234 A1 PL414234 A1 PL 414234A1 PL 414234 A PL414234 A PL 414234A PL 41423415 A PL41423415 A PL 41423415A PL 414234 A1 PL414234 A1 PL 414234A1
Authority
PL
Poland
Prior art keywords
application
ruthenium
metathesis
olefins
intermediate compounds
Prior art date
Application number
PL414234A
Other languages
English (en)
Other versions
PL238806B1 (pl
Inventor
Krzysztof Skowerski
Rafał Gawin
Original Assignee
Apeiron Synthesis Spółka Akcyjna
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=57045229&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=PL414234(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Apeiron Synthesis Spółka Akcyjna filed Critical Apeiron Synthesis Spółka Akcyjna
Priority to PL414234A priority Critical patent/PL238806B1/pl
Priority to RU2018113805A priority patent/RU2735724C1/ru
Priority to US15/764,123 priority patent/US11192911B2/en
Priority to EP16774982.9A priority patent/EP3356379B2/en
Priority to AU2016330158A priority patent/AU2016330158B2/en
Priority to PCT/IB2016/054486 priority patent/WO2017055945A1/en
Priority to CN201680056336.7A priority patent/CN108137631B/zh
Priority to KR1020187010104A priority patent/KR102637889B1/ko
Priority to JP2018516190A priority patent/JP6905978B2/ja
Priority to EP21161627.1A priority patent/EP3868769A1/en
Priority to CA2999412A priority patent/CA2999412C/en
Publication of PL414234A1 publication Critical patent/PL414234A1/pl
Priority to IL258354A priority patent/IL258354B/en
Publication of PL238806B1 publication Critical patent/PL238806B1/pl
Priority to US17/513,752 priority patent/US11976085B2/en
Priority to US18/234,753 priority patent/US12173015B2/en
Priority to US18/943,268 priority patent/US12448404B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/40—Non-coordinating groups comprising nitrogen
    • B01J2540/44—Non-coordinating groups comprising nitrogen being derivatives of carboxylic or carbonic acids, e.g. amide (RC(=O)-NR2, RC(=O)-NR-C(=O)R), nitrile, urea (R2N-C(=O)-NR2), guanidino (R2N-C(=NR)-NR2) groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Przedmiotem zgłoszenia jest nowy sposób wytwarzania kompleksów rutenu o wzorze (1) i związków pośrednich. Zgłoszenie dotyczy także zastosowania kompleksów rutenu o wzorze 1, jako prekatalizatorów i/lub katalizatorów w reakcjach metatezy olefin.
PL414234A 2015-09-30 2015-09-30 Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin PL238806B1 (pl)

Priority Applications (15)

Application Number Priority Date Filing Date Title
PL414234A PL238806B1 (pl) 2015-09-30 2015-09-30 Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
CA2999412A CA2999412C (en) 2015-09-30 2016-07-27 PROCESS FOR THE PRODUCTION OF RUTHENIUM COMPLEXES AND ASSOCIATED INTERMEDIARIES AND THEIR USE IN OLEFIN METATHESIS
CN201680056336.7A CN108137631B (zh) 2015-09-30 2016-07-27 制备钌配位化合物及其中间体的方法和它们在烯烃复分解中的用途
JP2018516190A JP6905978B2 (ja) 2015-09-30 2016-07-27 ルテニウム錯体およびその中間体の製造方法並びにオレフィンメタセシスにおけるその使用方法
EP16774982.9A EP3356379B2 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
AU2016330158A AU2016330158B2 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
PCT/IB2016/054486 WO2017055945A1 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
RU2018113805A RU2735724C1 (ru) 2015-09-30 2016-07-27 Способ получения комплексов рутения и их промежуточных соединений и их применение в метатезисе олефинов
KR1020187010104A KR102637889B1 (ko) 2015-09-30 2016-07-27 루테늄 복합체 및 그의 중간체를 제조하는 방법 및 올레핀 복분해에서 그의 사용방법
US15/764,123 US11192911B2 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
EP21161627.1A EP3868769A1 (en) 2015-09-30 2016-07-27 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
IL258354A IL258354B (en) 2015-09-30 2018-03-26 A process for creating complexes of ruthenium and their intermediates and their use in the metathesis of olefins
US17/513,752 US11976085B2 (en) 2015-09-30 2021-10-28 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
US18/234,753 US12173015B2 (en) 2015-09-30 2023-08-16 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis
US18/943,268 US12448404B2 (en) 2015-09-30 2024-11-11 Process for producing ruthenium complexes and intermediates thereof and their use in olefin metathesis

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL414234A PL238806B1 (pl) 2015-09-30 2015-09-30 Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin

Publications (2)

Publication Number Publication Date
PL414234A1 true PL414234A1 (pl) 2017-04-10
PL238806B1 PL238806B1 (pl) 2021-10-04

Family

ID=57045229

Family Applications (1)

Application Number Title Priority Date Filing Date
PL414234A PL238806B1 (pl) 2015-09-30 2015-09-30 Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin

Country Status (11)

Country Link
US (4) US11192911B2 (pl)
EP (2) EP3868769A1 (pl)
JP (1) JP6905978B2 (pl)
KR (1) KR102637889B1 (pl)
CN (1) CN108137631B (pl)
AU (1) AU2016330158B2 (pl)
CA (1) CA2999412C (pl)
IL (1) IL258354B (pl)
PL (1) PL238806B1 (pl)
RU (1) RU2735724C1 (pl)
WO (1) WO2017055945A1 (pl)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL441535A1 (pl) * 2022-06-23 2023-12-27 Uniwersytet Warszawski Nowe kompleksy rutenu, sposób ich otrzymywania, związki pośrednie stosowane w tym sposobie, sposób ich wytwarzania oraz zastosowanie nowych kompleksów rutenu w reakcjach metatezy olefin

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL3129347T3 (pl) 2014-04-10 2022-02-07 California Institute Of Technology Reakcje w obecności kompleksów rutenu
PL238806B1 (pl) 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
HUE069420T2 (hu) 2016-11-09 2025-03-28 Verbio Ver Bioenergie Ag Metatézisreakciók katalizálására hasznosító ruténiumkomplexek
PL241085B1 (pl) * 2016-11-10 2022-08-01 Apeiron Synthesis Spolka Akcyjna Zastosowanie kompleksów rutenu w reakcji metatezy olefin
PL243369B1 (pl) * 2018-04-16 2023-08-14 Apeiron Synthesis Spolka Akcyjna Nowe kompleksy rutenu oraz ich zastosowanie w reakcjach metatezy olefin
CN112088044B (zh) 2018-04-27 2023-10-24 阿朗新科德国有限责任公司 钌和锇催化剂用于丁腈橡胶复分解的用途
PL426318A1 (pl) * 2018-07-12 2020-01-13 Apeiron Synthesis Spółka Akcyjna Zastosowanie N-chelatujących kompleksów rutenu w reakcji metatezy
EP3650436A1 (en) * 2018-11-06 2020-05-13 Skotan S.A. Method of preparing a mixture of 9-decenoic acid ethyl and 1-decene in an ethenolysis reaction from a raw material of technical purity
WO2020109217A2 (en) * 2018-11-29 2020-06-04 Umicore Ag & Co. Kg Metal organic compounds
PL242934B1 (pl) * 2019-12-23 2023-05-22 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i zastosowanie kompleksu rutenu jako katalizatora
US20230095887A1 (en) * 2020-03-05 2023-03-30 Firmenich Sa Process for preparing perfuming intermediate
PL246181B1 (pl) 2020-08-17 2024-12-16 Apeiron Synthesis Spolka Akcyjna Nowe kompleksy rutenu i ich zastosowanie w reakcji krzyżowej metatezy olefin
PL439977A1 (pl) * 2021-12-23 2023-06-26 Apeiron Synthesis Spółka Akcyjna Nowe sterycznie aktywowane chelatujące kompleksy rutenu, sposób ich otrzymywania oraz ich zastosowanie w reakcjach metatezy olefin
CN114634436B (zh) * 2022-04-08 2022-12-02 安徽泽升科技有限公司 一种含钌催化剂及其制备方法与用途
PL442226A1 (pl) * 2022-09-08 2024-03-11 Uniwersytet Warszawski Nowe kompleksy rutenu, sposób ich otrzymywania, związki pośrednie stosowane w tym sposobie, sposób ich wytwarzania oraz zastosowanie nowych kompleksów rutenu w reakcjach metatezy olefin
WO2024262906A1 (ko) * 2023-06-20 2024-12-26 포항공과대학교 산학협력단 루테늄 착화합물, 이를 포함하는 촉매, 및 상기 루테늄 착화합물의 합성방법

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6613910B2 (en) 2001-04-02 2003-09-02 California Institute Of Technology One-pot synthesis of group 8 transition metal carbene complexes useful as olefin metathesis catalysts
US6818586B2 (en) 2001-08-01 2004-11-16 Cymetech, Llp Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
PL199412B1 (pl) 2002-10-15 2008-09-30 Boehringer Ingelheim Int Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania
EP1905777B2 (en) 2005-07-04 2018-06-27 Zannan Scitech Co., Ltd. Ruthenium complex ligand, ruthenium complex, carried ruthenium complex catalyst and the preparing methods and the use thereof
US8067610B2 (en) 2006-07-13 2011-11-29 Yann Schrodi Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
WO2008046106A2 (en) * 2006-10-13 2008-04-17 Elevance Renewable Sciences, Inc. Synthesis of terminal alkenes from internal alkenes via olefin metathesis
FR2934178B1 (fr) * 2008-07-25 2010-09-10 Rhodia Operations Compositions catalytiques pour la metathese de corps gras insatures avec des olefines et procedes de metathese les mettant en oeuvre
FR2947189B1 (fr) 2009-06-29 2011-07-29 Rhodia Operations Procede de peparation d'une composition catalytique pour la metathese de corps gras insatures
EP2498909B1 (en) * 2009-11-09 2014-08-27 ExxonMobil Chemical Patents Inc. Metathesis catalyst and process for use thereof
CN102985409A (zh) 2010-01-08 2013-03-20 蓝星有机硅法国两合公司 在溶液中制备卡宾的方法、尤其通过该方法获得的卡宾的新的稳定形式及其在催化中的应用
PL400162A1 (pl) * 2012-07-27 2014-02-03 Apeiron Synthesis Spólka Z Ograniczona Odpowiedzialnoscia Nowe kompleksy rutenu, ich zastosowanie w reakcjach metatezy oraz sposób prowadzenia reakcji metatezy
FR2999184B1 (fr) 2012-12-12 2015-01-09 Ecole Nationale Superieure De Chimie De Rennes Complexes de ruthenium comprenant un diaminocarbene n-heterocyclique insature dissymetrique
US9249170B2 (en) 2013-04-11 2016-02-02 California Institute Of Technology Cyclic alkyl amino carbene (CAAC) ruthenium complexes as improved catalysts for ethenolysis reactions
PL3129347T3 (pl) 2014-04-10 2022-02-07 California Institute Of Technology Reakcje w obecności kompleksów rutenu
PL238806B1 (pl) 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL441535A1 (pl) * 2022-06-23 2023-12-27 Uniwersytet Warszawski Nowe kompleksy rutenu, sposób ich otrzymywania, związki pośrednie stosowane w tym sposobie, sposób ich wytwarzania oraz zastosowanie nowych kompleksów rutenu w reakcjach metatezy olefin

Also Published As

Publication number Publication date
EP3356379B2 (en) 2025-09-03
KR102637889B1 (ko) 2024-02-19
EP3868769A1 (en) 2021-08-25
PL238806B1 (pl) 2021-10-04
US12448404B2 (en) 2025-10-21
RU2735724C1 (ru) 2020-11-06
AU2016330158B2 (en) 2021-05-13
IL258354A (en) 2018-05-31
IL258354B (en) 2022-03-01
US20240076308A1 (en) 2024-03-07
US20250066402A1 (en) 2025-02-27
US11192911B2 (en) 2021-12-07
KR20180059822A (ko) 2018-06-05
JP2018535194A (ja) 2018-11-29
US11976085B2 (en) 2024-05-07
CA2999412C (en) 2024-09-10
JP6905978B2 (ja) 2021-07-21
US12173015B2 (en) 2024-12-24
CA2999412A1 (en) 2017-04-06
US20180298046A1 (en) 2018-10-18
CN108137631B (zh) 2021-04-16
AU2016330158A1 (en) 2018-04-12
EP3356379B1 (en) 2021-03-10
WO2017055945A1 (en) 2017-04-06
EP3356379A1 (en) 2018-08-08
US20220073549A1 (en) 2022-03-10
CN108137631A (zh) 2018-06-08

Similar Documents

Publication Publication Date Title
PL414234A1 (pl) Sposób wytwarzania kompleksów rutenu i związków pośrednich oraz ich zastosowanie w metatezie olefin
PL400162A1 (pl) Nowe kompleksy rutenu, ich zastosowanie w reakcjach metatezy oraz sposób prowadzenia reakcji metatezy
EP4431180A3 (en) Olefin metathesis catalysts
BR112015023269A2 (pt) método de formação de olefinas a partir de uma primeira olefina e uma segunda olefina em uma reação de metátese, composto, uso de composto, composição e método para aumentar a reatividade de um composto.
JOP20170100B1 (ar) توليف مركبات إندازول
PL398247A1 (pl) Katalizatory metatezy zawierajace grupy oniowe
PH12017500833A1 (en) Synthesis of copanlisib and its dihydrochloride salt
AU2014324499A8 (en) Novel synthesis routes for prostaglandins and prostaglandin intermediates using metathesis
EA201890632A1 (ru) Хиральные фосфорамидимидаты и их производные
MX380550B (es) Sintesis de indazoles.
PL410329A1 (pl) Kompleksy rutenu, sposób ich wytwarzania oraz ich zastosowanie
PL419421A1 (pl) Zastosowanie kompleksów rutenu w reakcji metatezy olefin
MY176465A (en) Synthetic route to 2?-deoxy-2?,2?-difluorotetrahydrouridines
JO3487B1 (ar) تخليق كوبانليسيب وملح الدايهيدروكلوريد الخاص به
UY36746A (es) Método para la síntesis de derivados de rapamicina
MX2020006436A (es) Compuestos inhibidores del blanco mecanistico de rapamicina (mtor).
MX2020006434A (es) Nuevos compuestos inhibidores del blanco mecanistico de rapamicina (mtor).
PL401631A1 (pl) Nowe kompleksy rutenu, sposób ich wytwarzania oraz ich zastosowanie
NZ720106A (en) A process for the preparation of regadenoson
PL421462A1 (pl) Sposób wytwarzania cyklicznych związków w reakcji metatezy olefin oraz zastosowanie katalizatorów rutenowych do wytwarzania cyklicznych olefin w reakcjach metatezy olefin
EA201390368A1 (ru) Биарильные дифосфиновые лиганды, их промежуточные соединения и их применение в асимметричном катализе
FR3005049B1 (fr) Procede de metathese d'olefines issues de coupes fischer-tropsch utilisant un complexe du ruthenium comportant un diaminocarbene n-heterocyclique dissymetrique
WO2016014864A8 (en) Hydroxy-(r),(r)-2,2'-bismethylnaltrexones and uses thereof
PL400397A1 (pl) Nowe kompleksy metali, zwlaszcza rutenu oraz ich zastosowanie
PL419637A1 (pl) Nowy kompleks rutenu, sposób jego otrzymywania oraz zastosowanie w reakcji metatezy olefin