PL430174A1 - Inicjator polimeryzacji rodnikowej ATRP, sposób jego syntezy oraz sposób syntezy niskodyspersyjnych polimerów i kopolimerów z wykorzystaniem tego inicjatora - Google Patents
Inicjator polimeryzacji rodnikowej ATRP, sposób jego syntezy oraz sposób syntezy niskodyspersyjnych polimerów i kopolimerów z wykorzystaniem tego inicjatoraInfo
- Publication number
- PL430174A1 PL430174A1 PL430174A PL43017419A PL430174A1 PL 430174 A1 PL430174 A1 PL 430174A1 PL 430174 A PL430174 A PL 430174A PL 43017419 A PL43017419 A PL 43017419A PL 430174 A1 PL430174 A1 PL 430174A1
- Authority
- PL
- Poland
- Prior art keywords
- initiator
- synthesis
- functional group
- substituent
- radical polymerization
- Prior art date
Links
- 239000003999 initiator Substances 0.000 title abstract 3
- 101710141544 Allatotropin-related peptide Proteins 0.000 title abstract 2
- 238000010560 atom transfer radical polymerization reaction Methods 0.000 title abstract 2
- 239000007870 radical polymerization initiator Substances 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title 2
- 238000000034 method Methods 0.000 title 2
- 238000003786 synthesis reaction Methods 0.000 title 2
- 229920001577 copolymer Polymers 0.000 title 1
- 239000006185 dispersion Substances 0.000 title 1
- 229920000642 polymer Polymers 0.000 title 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract 6
- 125000000524 functional group Chemical group 0.000 abstract 5
- 125000001424 substituent group Chemical group 0.000 abstract 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 2
- JEQDSBVHLKBEIZ-REOHCLBHSA-N (2s)-2-chloropropanoyl chloride Chemical compound C[C@H](Cl)C(Cl)=O JEQDSBVHLKBEIZ-REOHCLBHSA-N 0.000 abstract 1
- SQZKNEFDRPEFEW-UHFFFAOYSA-N 2-chloro-n-(2-hydroxyethyl)propanamide Chemical compound CC(Cl)C(=O)NCCO SQZKNEFDRPEFEW-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 125000006239 protecting group Chemical group 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
- C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
- C07C233/18—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/55—Design of synthesis routes, e.g. reducing the use of auxiliary or protecting groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Graft Or Block Polymers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Przedmiotem zgłoszenia jest inicjator polimeryzacji rodnikowej ATRP posiadający grupę funkcyjną z podstawnikiem aktywnym w procesie polimeryzacji, charakteryzujący się tym, że jest to inicjator dwufunkcyjny o wzorze, który zawiera co najmniej dwie grupy funkcyjne przedzielone ugrupowaniem węglowodorowym Y, gdzie pierwsza grupa funkcyjna posiada podstawnik aktywny X, a druga grupa funkcyjna posiada grupę zabezpieczającą Z, którą można chemicznie modyfikować, takim samym lub innym podstawnikiem niż podstawnik aktywny X występujący w pierwszej grupie funkcyjnej. Zgłoszenie obejmuje też sposób otrzymywania inicjatora 2-chloro-N-(2-hydroksyetylo)propionamidu, NCPAE, znamienny tym, że etanoloaminę poddaje się reakcji acylowania za pomocą chlorku 2-chloropropionylu w obecności trietyloaminy (TEA), przy czym reakcję prowadzi się w atmosferze obojętnej, w temperaturze pokojowej, a pożądany związek otrzymuje się z wydajnością około 90%.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL430174A PL243003B1 (pl) | 2019-06-07 | 2019-06-07 | Inicjator polimeryzacji rodnikowej ATRP, sposób jego syntezy oraz sposób syntezy niskodyspersyjnych homopolimerów i kopolimerów blokowych z wykorzystaniem tego inicjatora |
| PCT/PL2020/000052 WO2020246902A1 (en) | 2019-06-07 | 2020-06-08 | An initiator of atrp radical polymerisation, a method of its synthesis, and a method of synthesis of low-dispersion polymer and copolymer using this initiator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL430174A PL243003B1 (pl) | 2019-06-07 | 2019-06-07 | Inicjator polimeryzacji rodnikowej ATRP, sposób jego syntezy oraz sposób syntezy niskodyspersyjnych homopolimerów i kopolimerów blokowych z wykorzystaniem tego inicjatora |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL430174A1 true PL430174A1 (pl) | 2020-12-14 |
| PL243003B1 PL243003B1 (pl) | 2023-06-05 |
Family
ID=71899805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL430174A PL243003B1 (pl) | 2019-06-07 | 2019-06-07 | Inicjator polimeryzacji rodnikowej ATRP, sposób jego syntezy oraz sposób syntezy niskodyspersyjnych homopolimerów i kopolimerów blokowych z wykorzystaniem tego inicjatora |
Country Status (2)
| Country | Link |
|---|---|
| PL (1) | PL243003B1 (pl) |
| WO (1) | WO2020246902A1 (pl) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115106025B (zh) * | 2022-05-30 | 2023-08-18 | 安阳九天精细化工有限责任公司 | 一种环保节能的二甲基甲酰胺的生产装置与生产方法 |
| CN115536883B (zh) * | 2022-10-19 | 2023-11-03 | 浙江理工大学 | 2d多层片状胶束及其制备方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0947527A1 (en) * | 1998-04-03 | 1999-10-06 | The B.F. Goodrich Company | Waterborne block copolymers and process for making the same |
| WO2007083097A1 (en) * | 2006-01-17 | 2007-07-26 | Warwick Effect Polymers Ltd. | Living radical polymerisation process |
-
2019
- 2019-06-07 PL PL430174A patent/PL243003B1/pl unknown
-
2020
- 2020-06-08 WO PCT/PL2020/000052 patent/WO2020246902A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2020246902A1 (en) | 2020-12-10 |
| PL243003B1 (pl) | 2023-06-05 |
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