PL430867A1 - Iminowe pochodne aldehydów salicylowych i hydrazydów kwasowych, sposób ich wytwarzania oraz ich zastosowanie - Google Patents

Iminowe pochodne aldehydów salicylowych i hydrazydów kwasowych, sposób ich wytwarzania oraz ich zastosowanie

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Publication number
PL430867A1
PL430867A1 PL430867A PL43086719A PL430867A1 PL 430867 A1 PL430867 A1 PL 430867A1 PL 430867 A PL430867 A PL 430867A PL 43086719 A PL43086719 A PL 43086719A PL 430867 A1 PL430867 A1 PL 430867A1
Authority
PL
Poland
Prior art keywords
hoc6h4
ch3oc6h4
formula
salicylaldehydes
acid hydrazides
Prior art date
Application number
PL430867A
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English (en)
Other versions
PL241843B1 (pl
Inventor
Mirosław Giurg
Halina Maniak
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Politechnika Wrocławska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Politechnika Wrocławska filed Critical Politechnika Wrocławska
Priority to PL430867A priority Critical patent/PL241843B1/pl
Publication of PL430867A1 publication Critical patent/PL430867A1/pl
Publication of PL241843B1 publication Critical patent/PL241843B1/pl

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
    • C07C243/24—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids
    • C07C243/38—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids with acylating carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P3/00—Fungicides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
    • C07C243/24—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids
    • C07C243/26—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids with acylating carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C249/16—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of hydrazones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72—Hydrazones
    • C07C251/86—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to carbon atoms of six-membered aromatic rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)

Abstract

Przedmiotem wynalazku są iminowe pochodne aldehydów salicylowych i hydrazydów kwasowych o wzorze 6 lub o wzorze ogólnym 1, w którym R1 oznacza H, t-Bu, Ph, R2 oznacza H, CH3, t-Bu, R3 oznacza H, OCH3, R4 oznacza Ph, 2-HOC6H4, 3-HOC6H4, 4-HOC6H4, 3-CH3OC6H4, 4-CH3OC6H4, 3,5-(HO)2C6H3, 3-pirydyl, 2-(1-HO-naftyl) a n stanowi liczbę 0 lub 1. Wynalazek dotyczy również sposobu wytwarzania iminowych pochodnych aldehydów salicylowych i hydrazydów kwasowych przedstawionych wzorem 6 lub wzorem ogólnym 1, w którym R1 oznacza H, t-Bu, Ph, R2 oznacza H, CH3, t-Bu, R3 oznacza H, OCH3, R4 oznacza Ph, 2-HOC6H4, 3-HOC6H4, 4-HOC6H4, 3-CH3OC6H4, 4-CH3OC6H4, 3,5-(HO)2C6H3, 3-pirydyl, 2-(1-HO-nafty1) a n stanowi liczbę 0 lub 1, polegający na tym, że równomolową mieszaninę aldehydu salicylowego o wzorze 4 lub aldehydów salicylowych o wzorze ogólnym 2, w którym R1 oznacza H, t-Bu, Ph, R2 oznacza H, CH3, t-Bu, R3 oznacza H, OCH3, oraz hydrazydu kwasu octowego 5 lub hydrazydów kwasowych o wzorze ogólnym 3, w których R4 oznacza Ph, 2-HOC6H4, 3-HOC6H4, 4-HOC6H4, 3-CH3OC6H4, 4-CH3OC6H4, 3,5-(HO)2C6H3, 3-pirydyl, 2-(1-HO-naftyl) a n stanowi liczbę 0 lub 1 w rozpuszczalniku traktuje się kwasem octowym i reakcję prowadzi się we wrzącym rozpuszczalniku w temperaturze 338 K do praktycznego przereagowania substratów a następnie z mieszaniny poreakcyjnej wydziela się produkty. Przedmiot wynalazku ujawnia zastosowanie hydrazydo-hydrazonów pochodnych hydrazydów kwasowych i aldehydów salicylowych jako środków ochrony roślin, zwłaszcza środków przeciwgrzybicznych.
PL430867A 2019-08-13 2019-08-13 Iminowe pochodne aldehydów salicylowych i hydrazydów kwasowych, sposób ich wytwarzania oraz ich zastosowanie PL241843B1 (pl)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL430867A PL241843B1 (pl) 2019-08-13 2019-08-13 Iminowe pochodne aldehydów salicylowych i hydrazydów kwasowych, sposób ich wytwarzania oraz ich zastosowanie

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL430867A PL241843B1 (pl) 2019-08-13 2019-08-13 Iminowe pochodne aldehydów salicylowych i hydrazydów kwasowych, sposób ich wytwarzania oraz ich zastosowanie

Publications (2)

Publication Number Publication Date
PL430867A1 true PL430867A1 (pl) 2021-02-22
PL241843B1 PL241843B1 (pl) 2022-12-12

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PL430867A PL241843B1 (pl) 2019-08-13 2019-08-13 Iminowe pochodne aldehydów salicylowych i hydrazydów kwasowych, sposób ich wytwarzania oraz ich zastosowanie

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118164872A (zh) * 2024-03-12 2024-06-11 贵州大学 一类含席夫碱核心骨架的丁香酚类化合物及其制备方法和应用

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN118164872A (zh) * 2024-03-12 2024-06-11 贵州大学 一类含席夫碱核心骨架的丁香酚类化合物及其制备方法和应用

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PL241843B1 (pl) 2022-12-12

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