PL432924A1 - Kopolimer metakrylowy poli([2-metyloprop-2-enian 2-[{4-[(E)-(4-nitrofenylo)diazenylo]}etylo)amino]etylu]-co-[2-metyloprop-2-enian 2-[4-[(E)-(4-fluorofenylo)azo]-N-etylo-anilino]etylu)] i sposób jego wytwarzania - Google Patents
Kopolimer metakrylowy poli([2-metyloprop-2-enian 2-[{4-[(E)-(4-nitrofenylo)diazenylo]}etylo)amino]etylu]-co-[2-metyloprop-2-enian 2-[4-[(E)-(4-fluorofenylo)azo]-N-etylo-anilino]etylu)] i sposób jego wytwarzaniaInfo
- Publication number
- PL432924A1 PL432924A1 PL432924A PL43292420A PL432924A1 PL 432924 A1 PL432924 A1 PL 432924A1 PL 432924 A PL432924 A PL 432924A PL 43292420 A PL43292420 A PL 43292420A PL 432924 A1 PL432924 A1 PL 432924A1
- Authority
- PL
- Poland
- Prior art keywords
- ethyl
- methylprop
- enoate
- diazenyl
- nitrophenyl
- Prior art date
Links
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 title abstract 8
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 title abstract 5
- 229920001577 copolymer Polymers 0.000 title abstract 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- RUTHYURWHHEOPP-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound [CH2]COC(=O)C(C)=C RUTHYURWHHEOPP-UHFFFAOYSA-N 0.000 title 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 4
- 125000000636 p-nitrophenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)[N+]([O-])=O 0.000 abstract 4
- 125000001255 4-fluorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1F 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 abstract 2
- 239000011261 inert gas Substances 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
Landscapes
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Wynalazek ujawnia kopolimer metakrylowy poli([2-metyloprop-2-enian 2-[{4-[(E)–(4-nitrofenylo)diazenylo]}etylo)amino]etylu]-co-[2-metyloprop-2-enian 2-[4-[(E)-(4-fluorofenylo)azo]-N-etylo-anilino]etylu])o wzorze ogólnym 1, w którym n oznacza liczbę merów od 1 do 50 2-metyloprop-2-enianu 2-[{4-[(E)-(4-nitrofenylo)diazenylo]}etylo)amino]etylu, natomiast m oznacza liczbę merów od 1 do 50 2-metyloprop-2-enianu 2-[4-[(E)-(4-fluorofenylo)azo]-N-etylo-anilino]etylu. Wynalazek ujawnia również sposób wytwarzania kopolimeru metakrylowego poli([2-metyloprop-2-enianu 2-[{4-[(E)-(4-nitrofenylo)diazenylo]}etylo)amino]etylu]-co-[2-metyloprop-2-enianu 2-[4-[(E)- (4-fluorofenylo)azo]-N-etylo-anilino]etylu]) o wzorze 1 znamienny tym, że obydwa monomery rozpuszcza się w tetrahydrofuranie lub mieszaninie tetrahydrofuran/γ-butyrolakton 7/3 i poddaje kopolimeryzacji w obecności inicjatora rodnikowego w postaci nadtlenku benzoilu lub azobis(izobutyronitrylu), w atmosferze gazu inertnego, w temperaturze od 60 do 100°C, przy czym reakcję kopolimeryzacji prowadzi się przy stosunku molowym monomeru 2-metyloprop-2-enianu 2-2-[{4-[(E)-(4-nitrofenylo)diazenylo]}etylo)amino]etylu do 2 metyloprop-2-enianu 2-[4-[(E)- (4-fluorofentylo)azo]-N-etylo-anilino]etylu od 1:1 do 4:1 i stosuje się od 5 do 12 % wagowych inicjatora rodnikowego w stosunku do sumy mas monomerów oraz reakcje prowadzi się w obecności gazu inertnego przez czas od 48 do 72 godzin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL432924A PL244626B1 (pl) | 2020-02-17 | 2020-02-17 | Kopolimer metakrylowy poli([2-metyloprop-2-enian 2-[{4-[(E)-(4-nitrofenylo)diazenylo]}etylo)amino]etylu]-co-[2-metyloprop- 2-enian 2-[4-[(E)-(4-fluorofenylo)azo]-N-etylo-anilino]etylu)] i sposób jego wytwarzania |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL432924A PL244626B1 (pl) | 2020-02-17 | 2020-02-17 | Kopolimer metakrylowy poli([2-metyloprop-2-enian 2-[{4-[(E)-(4-nitrofenylo)diazenylo]}etylo)amino]etylu]-co-[2-metyloprop- 2-enian 2-[4-[(E)-(4-fluorofenylo)azo]-N-etylo-anilino]etylu)] i sposób jego wytwarzania |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL432924A1 true PL432924A1 (pl) | 2021-08-23 |
| PL244626B1 PL244626B1 (pl) | 2024-02-19 |
Family
ID=77561348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL432924A PL244626B1 (pl) | 2020-02-17 | 2020-02-17 | Kopolimer metakrylowy poli([2-metyloprop-2-enian 2-[{4-[(E)-(4-nitrofenylo)diazenylo]}etylo)amino]etylu]-co-[2-metyloprop- 2-enian 2-[4-[(E)-(4-fluorofenylo)azo]-N-etylo-anilino]etylu)] i sposób jego wytwarzania |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL244626B1 (pl) |
-
2020
- 2020-02-17 PL PL432924A patent/PL244626B1/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL244626B1 (pl) | 2024-02-19 |
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