PL437781A1 - Katalizator do katalitycznej konwersji dwutlenku węgla do metanu oraz sposób katalitycznej konwersji dwutlenku węgla do metanu - Google Patents

Katalizator do katalitycznej konwersji dwutlenku węgla do metanu oraz sposób katalitycznej konwersji dwutlenku węgla do metanu

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Publication number
PL437781A1
PL437781A1 PL437781A PL43778121A PL437781A1 PL 437781 A1 PL437781 A1 PL 437781A1 PL 437781 A PL437781 A PL 437781A PL 43778121 A PL43778121 A PL 43778121A PL 437781 A1 PL437781 A1 PL 437781A1
Authority
PL
Poland
Prior art keywords
carbon dioxide
methane
catalytic conversion
nanoparticles
catalytic
Prior art date
Application number
PL437781A
Other languages
English (en)
Other versions
PL243334B1 (pl
Inventor
Maciej Kapkowski
Jarosław Polański
Tomasz Siudyga
Grzegorz Dercz
Daniel Lach
Izabela Matuła
Adrianna Chojnowska
Original Assignee
Uniwersytet Śląski W Katowicach
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uniwersytet Śląski W Katowicach filed Critical Uniwersytet Śląski W Katowicach
Priority to PL437781A priority Critical patent/PL243334B1/pl
Publication of PL437781A1 publication Critical patent/PL437781A1/pl
Publication of PL243334B1 publication Critical patent/PL243334B1/pl

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32Manganese, technetium or rhenium
    • B01J23/36Rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/755Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Przedmiotem wynalazku jest katalizator do katalitycznej konwersji dwutlenku węgla do metanu, charakteryzujący się tym, że stanowi niklowy nośnik katalityczny z naniesioną na nim fazą aktywną w postaci nanocząstek metali przejściowych Pd oraz Re, o rozmiarach nanocząstek od 1 do 100 nm, przy czym zawartość nanocząstek fazy aktywnej na powierzchni nośnika katalitycznego wynosi od 0,01% wag. do 6% wag., a stosunek molowy nanocząstek Pd do Re wynosi od 20:1 do 1:20. Przedmiotem wynalazku jest również sposób katalitycznej konwersji dwutlenku węgla do metanu polegający na tym, że strumień gazu w postaci dwutlenku węgla wraz z wodorem, przepuszcza się z natężeniem przepływu w zakresie od 0,5 do 12 dm<sup>3</sup>/h, przez umieszczone w reaktorze złoże katalizatora stanowiącego niklowy nośnik katalityczny z naniesioną na nim fazą aktywną w postaci nanocząstek metali przejściowych Pd oraz Re, o rozmiarach nanocząstek od 1 do 100 nm, przy czym zawartość nanocząstek fazy aktywnej na powierzchni nośnika katalitycznego wynosi od 0,0l% wag. do 6% wag., a stosunek molowy nanocząstek Pd do Re wynosi od 20:1 do 1:20, a proces prowadzi się w temperaturze od 195°C do 550°C.
PL437781A 2021-05-06 2021-05-06 Katalizator do katalitycznej konwersji dwutlenku węgla do metanu oraz sposób katalitycznej konwersji dwutlenku węgla do metanu PL243334B1 (pl)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL437781A PL243334B1 (pl) 2021-05-06 2021-05-06 Katalizator do katalitycznej konwersji dwutlenku węgla do metanu oraz sposób katalitycznej konwersji dwutlenku węgla do metanu

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL437781A PL243334B1 (pl) 2021-05-06 2021-05-06 Katalizator do katalitycznej konwersji dwutlenku węgla do metanu oraz sposób katalitycznej konwersji dwutlenku węgla do metanu

Publications (2)

Publication Number Publication Date
PL437781A1 true PL437781A1 (pl) 2022-11-07
PL243334B1 PL243334B1 (pl) 2023-08-07

Family

ID=83944931

Family Applications (1)

Application Number Title Priority Date Filing Date
PL437781A PL243334B1 (pl) 2021-05-06 2021-05-06 Katalizator do katalitycznej konwersji dwutlenku węgla do metanu oraz sposób katalitycznej konwersji dwutlenku węgla do metanu

Country Status (1)

Country Link
PL (1) PL243334B1 (pl)

Also Published As

Publication number Publication date
PL243334B1 (pl) 2023-08-07

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