PL437782A1 - Sposób katalitycznej konwersji amoniaku do azotu i wodoru - Google Patents

Sposób katalitycznej konwersji amoniaku do azotu i wodoru

Info

Publication number
PL437782A1
PL437782A1 PL437782A PL43778221A PL437782A1 PL 437782 A1 PL437782 A1 PL 437782A1 PL 437782 A PL437782 A PL 437782A PL 43778221 A PL43778221 A PL 43778221A PL 437782 A1 PL437782 A1 PL 437782A1
Authority
PL
Poland
Prior art keywords
ammonia
nitrogen
hydrogen
catalytic conversion
nanoparticles
Prior art date
Application number
PL437782A
Other languages
English (en)
Other versions
PL243335B1 (pl
Inventor
Maciej Kapkowski
Jarosław Polański
Tomasz Siudyga
Grzegorz Dercz
Daniel Lach
Izabela Matuła
Karolina Wieczorek
Original Assignee
Uniwersytet Śląski W Katowicach
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uniwersytet Śląski W Katowicach filed Critical Uniwersytet Śląski W Katowicach
Priority to PL437782A priority Critical patent/PL243335B1/pl
Publication of PL437782A1 publication Critical patent/PL437782A1/pl
Publication of PL243335B1 publication Critical patent/PL243335B1/pl

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32Manganese, technetium or rhenium
    • B01J23/36Rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/755Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/04Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of inorganic compounds
    • C01B3/047Decomposition of ammonia

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)

Abstract

Przedmiotem wynalazku jest sposób katalitycznej konwersji amoniaku do wodoru i azotu polegający na tym, że strumień gazu w postaci amoniaku, przy obciążeniu 0,5 - 6,5 kg/h•kg<sub>kat</sub>, przepuszcza się przez umieszczony w reaktorze katalizator stanowiący niklowy nośnik katalityczny z naniesioną na nim fazą aktywną w postaci nanocząstek metali przejściowych Pd oraz Re, o rozmiarach nanocząstek od 1 do 100 nm, przy czym zawartość nanocząstek fazy aktywnej na powierzchni nośnika katalitycznego wynosi od 0,01% wag. do 6% wag., a stosunek molowy nanocząstek Pd do Re wynosi od 1:20 do 20:1, a proces prowadzi się w temperaturze od 340°C do 580°C.
PL437782A 2021-05-06 2021-05-06 Sposób katalitycznej konwersji amoniaku do azotu i wodoru PL243335B1 (pl)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL437782A PL243335B1 (pl) 2021-05-06 2021-05-06 Sposób katalitycznej konwersji amoniaku do azotu i wodoru

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL437782A PL243335B1 (pl) 2021-05-06 2021-05-06 Sposób katalitycznej konwersji amoniaku do azotu i wodoru

Publications (2)

Publication Number Publication Date
PL437782A1 true PL437782A1 (pl) 2022-11-07
PL243335B1 PL243335B1 (pl) 2023-08-07

Family

ID=83944934

Family Applications (1)

Application Number Title Priority Date Filing Date
PL437782A PL243335B1 (pl) 2021-05-06 2021-05-06 Sposób katalitycznej konwersji amoniaku do azotu i wodoru

Country Status (1)

Country Link
PL (1) PL243335B1 (pl)

Also Published As

Publication number Publication date
PL243335B1 (pl) 2023-08-07

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