PL439977A1 - Nowe sterycznie aktywowane chelatujące kompleksy rutenu, sposób ich otrzymywania oraz ich zastosowanie w reakcjach metatezy olefin - Google Patents

Nowe sterycznie aktywowane chelatujące kompleksy rutenu, sposób ich otrzymywania oraz ich zastosowanie w reakcjach metatezy olefin

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Publication number
PL439977A1
PL439977A1 PL439977A PL43997721A PL439977A1 PL 439977 A1 PL439977 A1 PL 439977A1 PL 439977 A PL439977 A PL 439977A PL 43997721 A PL43997721 A PL 43997721A PL 439977 A1 PL439977 A1 PL 439977A1
Authority
PL
Poland
Prior art keywords
application
ruthenium complexes
olefin metathesis
preparation
metathesis reactions
Prior art date
Application number
PL439977A
Other languages
English (en)
Inventor
Krzysztof Skowerski
Konrad KURCBACH
Michał CHWALBA
Patryk KRAJCZY
Mateusz Krzysztof CYBULSKI
Original Assignee
Apeiron Synthesis Spółka Akcyjna
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Apeiron Synthesis Spółka Akcyjna filed Critical Apeiron Synthesis Spółka Akcyjna
Priority to PL439977A priority Critical patent/PL439977A1/pl
Priority to PCT/PL2022/050096 priority patent/WO2023121492A1/en
Priority to EP22862363.3A priority patent/EP4452490A1/en
Priority to US18/722,570 priority patent/US20250051380A1/en
Publication of PL439977A1 publication Critical patent/PL439977A1/pl

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/235—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring and to a carbon atom of a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Przedmiotem zgłoszenia są nowe sterycznie aktywowane chelatujące kompleksy rutenu o wzorze 1a, łatwe do otrzymywania na drodze wydajnych reakcji chemicznych. Zgłoszenia dotyczy także sposobu otrzymywania oraz zastosowania kompleksów rutenu o wzorze 1a, jako prekatalizatorów i/lub katalizatorów w szerokim spektrum znanych reakcji metatezy olefin.
PL439977A 2021-12-23 2021-12-23 Nowe sterycznie aktywowane chelatujące kompleksy rutenu, sposób ich otrzymywania oraz ich zastosowanie w reakcjach metatezy olefin PL439977A1 (pl)

Priority Applications (4)

Application Number Priority Date Filing Date Title
PL439977A PL439977A1 (pl) 2021-12-23 2021-12-23 Nowe sterycznie aktywowane chelatujące kompleksy rutenu, sposób ich otrzymywania oraz ich zastosowanie w reakcjach metatezy olefin
PCT/PL2022/050096 WO2023121492A1 (en) 2021-12-23 2022-12-22 New sterically activated chelating ruthenium complexes, method of their preparation and their use in olefin metathesis reactions
EP22862363.3A EP4452490A1 (en) 2021-12-23 2022-12-22 New sterically activated chelating ruthenium complexes, method of their preparation and their use in olefin metathesis reactions
US18/722,570 US20250051380A1 (en) 2021-12-23 2022-12-22 New sterically activated chelating ruthenium complexes, method of their preparation and their use in olefin metathesis reactions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL439977A PL439977A1 (pl) 2021-12-23 2021-12-23 Nowe sterycznie aktywowane chelatujące kompleksy rutenu, sposób ich otrzymywania oraz ich zastosowanie w reakcjach metatezy olefin

Publications (1)

Publication Number Publication Date
PL439977A1 true PL439977A1 (pl) 2023-06-26

Family

ID=85384491

Family Applications (1)

Application Number Title Priority Date Filing Date
PL439977A PL439977A1 (pl) 2021-12-23 2021-12-23 Nowe sterycznie aktywowane chelatujące kompleksy rutenu, sposób ich otrzymywania oraz ich zastosowanie w reakcjach metatezy olefin

Country Status (4)

Country Link
US (1) US20250051380A1 (pl)
EP (1) EP4452490A1 (pl)
PL (1) PL439977A1 (pl)
WO (1) WO2023121492A1 (pl)

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003044060A2 (en) * 2001-11-15 2003-05-30 Materia, Inc. Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts
EP2639219B1 (en) * 2012-03-14 2016-08-10 Umicore AG & Co. KG Ruthenium-based metathesis catalysts and precursors for their preparation
SG11201408648YA (en) * 2012-06-29 2015-01-29 Apeiron Synthesis Sa Metal complexes, their application and methods of carrying out of metathesis reaction
EP2725030A1 (en) * 2012-10-29 2014-04-30 Umicore AG & Co. KG Ruthenium-based metathesis catalysts, precursors for their preparation and their use
US9676676B2 (en) * 2014-07-02 2017-06-13 California Institute Of Technology Selective olefin metathesis with cyclometalated ruthenium complexes
EP3115368A1 (en) * 2015-07-10 2017-01-11 Bergen Teknologioverforing AS Improved olefin metathesis catalysts
PL238806B1 (pl) * 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
CN108368001B (zh) * 2015-12-10 2021-07-23 优美科股份公司及两合公司 烯烃复分解催化剂
WO2018236191A1 (ko) * 2017-06-23 2018-12-27 광주과학기술원 루테늄 착물 형성을 위한 리간드, 루테늄 착물 촉매 및 이의 제조방법과 용도
US20210380619A1 (en) * 2018-03-09 2021-12-09 Uniwersytet Warszawski Production method of cyclic compounds by olefin metathesis reaction and use of ruthenium catalysts in production of cyclic olefines by olefin metathesis reaction
AU2021283190A1 (en) 2020-06-01 2022-12-15 Provivi, Inc. Synthesis of pheromone derivatives via Z-selective olefin metathesis

Also Published As

Publication number Publication date
WO2023121492A1 (en) 2023-06-29
US20250051380A1 (en) 2025-02-13
EP4452490A1 (en) 2024-10-30

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