PL442870A1 - Adhesive composition and method of its preparation - Google Patents

Adhesive composition and method of its preparation

Info

Publication number
PL442870A1
PL442870A1 PL442870A PL44287022A PL442870A1 PL 442870 A1 PL442870 A1 PL 442870A1 PL 442870 A PL442870 A PL 442870A PL 44287022 A PL44287022 A PL 44287022A PL 442870 A1 PL442870 A1 PL 442870A1
Authority
PL
Poland
Prior art keywords
composition
weight
amount
sup
filler
Prior art date
Application number
PL442870A
Other languages
Polish (pl)
Other versions
PL245699B1 (en
Inventor
Izabela Miturska-Barańska
Anna Rudawska
Elżbieta Doluk
Original Assignee
Politechnika Lubelska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Politechnika Lubelska filed Critical Politechnika Lubelska
Priority to PL442870A priority Critical patent/PL245699B1/en
Publication of PL442870A1 publication Critical patent/PL442870A1/en
Publication of PL245699B1 publication Critical patent/PL245699B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Przedmiotem zgłoszenia jest kompozycja klejowa, która charakteryzuje się tym, że składa się z żywicy epoksydowej, będącej produktem reakcji bisfenolu A, epichlorohydryny oraz rozcieńczalnika z nasyconej żywicy poliestrowej, o średniej masie cząsteczkowej ≤ 700 i liczbie epoksydowej ≥ 0,40 mol/100 g w ilości 80% wagowo składu kompozycji, utwardzacza aminowego aminy alifatycznej o liczbie aminowej co najmniej 1100 mg KOH/g w ilości 8% wagowo składu kompozycji oraz napełniacza w postaci węgla amorficznego o gęstości nasypowej 20 - 200 kg/m<sup>3</sup> w ilości 12% wagowo składu kompozycji. Zgłoszenie zawiera także sposób wytwarzania kompozycji klejowej, który polega na tym, że do pojemnika z podgrzaną do temperatury 50 C żywicą epoksydową, będącą produktem reakcji bisfenolu A, epichlorohydryny oraz rozcieńczalnika z nasyconej żywicy poliestrowej, o średniej masie cząsteczkowej ≤ 700 i liczbie epoksydowej ≥ 0,40 mol/100 g w ilości 80% wagowo składu kompozycji dodaje się napełniacz w postaci węgla amorficznego o gęstości nasypowej 20 - 200 kg/m<sup>3</sup> w ilości 12% wagowo składu kompozycji, po czym miesza się żywicę epoksydową z napełniaczem z prędkością obrotową 1170 obr./min przez 2 minuty mieszadłem turbinowym tarczowym z zębami trapezowymi z jednoczesnym odpowietrzaniem w temperaturze 23 C i przy wilgotności powietrza 26%. Następnie po wymieszaniu żywicy epoksydowej z napełniaczem dodaje się utwardzacz aminowy aminy alifatycznej o liczbie aminowej co najmniej 1100 mg KOH/g w ilości 8% wagowo składu kompozycji, po czym miesza się całość z prędkością obrotową 1170 obr./min przez 2 minuty mieszadłem turbinowym tarczowym z zębami trapezowymi z jednoczesnym odpowietrzaniem w temperaturze 23 C i przy wilgotności powietrza 26%. Następnie całość utwardza się przez 7 dni w temperaturze 23 C i przy wilgotności powietrza 26%.The subject of the application is an adhesive composition, which is characterized by the fact that it consists of an epoxy resin, which is a reaction product of bisphenol A, epichlorohydrin and a saturated polyester resin diluent, with an average molecular weight ≤ 700 and an epoxy number ≥ 0.40 mol/100 g in the amount 80% by weight of the composition, an aliphatic amine hardener with an amine number of at least 1100 mg KOH/g in an amount of 8% by weight of the composition and amorphous carbon filler with a bulk density of 20 - 200 kg/m<sup>3</sup> in an amount of 12% by weight of the composition. The application also includes a method of producing an adhesive composition, which consists in filling a container with an epoxy resin, heated to a temperature of 50°C, which is a reaction product of bisphenol A, epichlorohydrin and a saturated polyester resin diluent, with an average molecular weight ≤ 700 and an epoxy number ≥ 0 .40 mol/100 g in the amount of 80% by weight of the composition, a filler in the form of amorphous carbon with a bulk density of 20 - 200 kg/m<sup>3</sup> is added in the amount of 12% by weight of the composition, and then the epoxy resin is mixed with a filler at a rotational speed of 1170 rpm for 2 minutes with a disk turbine agitator with trapezoidal teeth with simultaneous de-aeration at a temperature of 23 C and air humidity of 26%. Then, after mixing the epoxy resin with the filler, an aliphatic amine amine hardener with an amine value of at least 1100 mg KOH/g is added in the amount of 8% by weight of the composition, and then the whole thing is mixed at a rotational speed of 1170 rpm for 2 minutes with a disk turbine mixer and trapezoidal teeth with simultaneous venting at 23°C and 26% air humidity. Then the whole is cured for 7 days at 23°C and 26% humidity.

PL442870A 2022-11-18 2022-11-18 Adhesive composition and method of producing it PL245699B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL442870A PL245699B1 (en) 2022-11-18 2022-11-18 Adhesive composition and method of producing it

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL442870A PL245699B1 (en) 2022-11-18 2022-11-18 Adhesive composition and method of producing it

Publications (2)

Publication Number Publication Date
PL442870A1 true PL442870A1 (en) 2023-03-13
PL245699B1 PL245699B1 (en) 2024-09-23

Family

ID=85480528

Family Applications (1)

Application Number Title Priority Date Filing Date
PL442870A PL245699B1 (en) 2022-11-18 2022-11-18 Adhesive composition and method of producing it

Country Status (1)

Country Link
PL (1) PL245699B1 (en)

Also Published As

Publication number Publication date
PL245699B1 (en) 2024-09-23

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