PL444520A1 - Sposób otrzymywania reaktywnych surowców poliolowych na bazie odpadowej biomasy z produkcji rolnej i ich zastosowanie do otrzymywania spienionych, ogniobezpiecznych materiałów termoizolacyjnych - Google Patents

Sposób otrzymywania reaktywnych surowców poliolowych na bazie odpadowej biomasy z produkcji rolnej i ich zastosowanie do otrzymywania spienionych, ogniobezpiecznych materiałów termoizolacyjnych

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Publication number
PL444520A1
PL444520A1 PL444520A PL44452023A PL444520A1 PL 444520 A1 PL444520 A1 PL 444520A1 PL 444520 A PL444520 A PL 444520A PL 44452023 A PL44452023 A PL 44452023A PL 444520 A1 PL444520 A1 PL 444520A1
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Poland
Prior art keywords
production
fire
raw materials
application
foamed
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PL444520A
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English (en)
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PL248940B1 (pl
Inventor
Joanna Paciorek-Sadowska
Marek Isbrandt
Marcin Borowicz
Paweł Sander
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Uniwersytet Kazimierza Wielkiego
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Priority to PL444520A priority Critical patent/PL248940B1/pl
Priority to EP23169304.5A priority patent/EP4450531A1/en
Publication of PL444520A1 publication Critical patent/PL444520A1/pl
Publication of PL248940B1 publication Critical patent/PL248940B1/pl

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6886—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2045—Heterocyclic amines; Salts thereof containing condensed heterocyclic rings
    • C08G18/2063—Heterocyclic amines; Salts thereof containing condensed heterocyclic rings having two nitrogen atoms in the condensed ring system
    • C—CHEMISTRY; METALLURGY
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
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    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/36—Hydroxylated esters of higher fatty acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
    • C08G18/4676—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
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    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/6696—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/36 or hydroxylated esters of higher fatty acids of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
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    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
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    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/14—Macromolecular materials
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
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    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
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    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
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    • C08G2230/00—Compositions for preparing biodegradable polymers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób otrzymywania surowców poliolowych w procesie upłynniania produktów ubocznych pochodzących z produkcji rolnej, w postaci makuchów roślinnych, zwłaszcza przydatnych do wytwarzania ogniobezpiecznych, termoizolacyjnych pianek poliuretanowych, o zwiększonej podatności na biodegradację. Istotą zgłoszenia jest opracowanie sposobu otrzymywania uniepalniającego poliolu w procesie upłynniania produktów ubocznych pochodzących z produkcji rolnej w postaci zmielonych makuchów roślinnych rzepakowego, sojowego, palmowego, słonecznikowego, lnianego, ryżowego, kokosowego, krokoszowego, konopnego, dyniowego, rzepakowego, z wiesiołka dwuletniego, z ostropestu plamistego, z czarnuszki siewnej, a zwłaszcza z gorczycy białej (Sinapis alba) oraz zastosowanie go do syntezy ogniobezpiecznych, sztywnych pianek poliuretanowych, o zwiększonej podatności na biodegradację. Przedmiot zgłoszenia może znaleźć szerokie zastosowanie w przemyśle jako izolacja np. zbiorników, rurociągów itd., w chłodnictwie oraz w budownictwie jako materiał termo- i dźwiękoizolacyjny lub konstrukcyjny.
PL444520A 2023-04-20 2023-04-20 Sposób otrzymywania uniepalniającego poliolu oraz sposób otrzymywania pianek poliuretanowych z użyciem tego poliolu PL248940B1 (pl)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL444520A PL248940B1 (pl) 2023-04-20 2023-04-20 Sposób otrzymywania uniepalniającego poliolu oraz sposób otrzymywania pianek poliuretanowych z użyciem tego poliolu
EP23169304.5A EP4450531A1 (en) 2023-04-20 2023-04-21 A method for obtaining reactive polyol materials from waste agricultural biomass and their use in manufacturing flame-retardant foam thermal insulation materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL444520A PL248940B1 (pl) 2023-04-20 2023-04-20 Sposób otrzymywania uniepalniającego poliolu oraz sposób otrzymywania pianek poliuretanowych z użyciem tego poliolu

Publications (2)

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PL444520A1 true PL444520A1 (pl) 2023-11-13
PL248940B1 PL248940B1 (pl) 2026-02-16

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PL444520A PL248940B1 (pl) 2023-04-20 2023-04-20 Sposób otrzymywania uniepalniającego poliolu oraz sposób otrzymywania pianek poliuretanowych z użyciem tego poliolu

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL233221B1 (pl) * 2017-09-18 2019-09-30 Univ Kazimierza Wielkiego W Bydgoszczy Sposób otrzymywania surowca poliolowego do syntezy sztywnych pianek poliuretanowo-poliizocyjanurowych oraz sposób syntezy sztywnych pianek poliuretanowo-poliizocyjanurowych
PL439000A1 (pl) * 2021-09-21 2023-03-27 Uniwersytet Kazimierza Wielkiego Sposób otrzymywania surowca biopoliolowego zawierającego heteroatomy siarki i boru

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007149418A2 (en) 2006-06-22 2007-12-27 Meadwestvaco Corporation Nucleating agents for plastic foams
WO2020072725A1 (en) 2018-10-05 2020-04-09 The Chemours Company Fc, Llc Compositions comprising 1,2-dichloro-1,2-difluoroethylene for use in foam blowing applications

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL233221B1 (pl) * 2017-09-18 2019-09-30 Univ Kazimierza Wielkiego W Bydgoszczy Sposób otrzymywania surowca poliolowego do syntezy sztywnych pianek poliuretanowo-poliizocyjanurowych oraz sposób syntezy sztywnych pianek poliuretanowo-poliizocyjanurowych
PL439000A1 (pl) * 2021-09-21 2023-03-27 Uniwersytet Kazimierza Wielkiego Sposób otrzymywania surowca biopoliolowego zawierającego heteroatomy siarki i boru

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
J. PACIOREK-SADOWSKA I INNI: "POLIMERY 2018, 63, nr 10, 694-699", "NOWY BIOPOLIOL NA BAZIE OLEJU Z GORCZYCY BIAŁEJ (SINAPIS ALBA) JAKO ALTERNATYWNY SUROWIEC DLA PRZEMYSŁU POLIURETANOWEGO" *
M. BOROWICZ I INNI: "Polymers 2019, 11, 1816; DOI:10.3390/polym11111816", „BIODEGRADABLE, FLAME-RETARDANT, AND BIO-BASED RIGID POLYURETHANE/POLYISOCYANURATE FOAMS FOR THERMAL INSULATION APPLICATION" *

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EP4450531A1 (en) 2024-10-23
PL248940B1 (pl) 2026-02-16

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