PL439000A1 - Sposób otrzymywania surowca biopoliolowego zawierającego heteroatomy siarki i boru - Google Patents
Sposób otrzymywania surowca biopoliolowego zawierającego heteroatomy siarki i boruInfo
- Publication number
- PL439000A1 PL439000A1 PL439000A PL43900021A PL439000A1 PL 439000 A1 PL439000 A1 PL 439000A1 PL 439000 A PL439000 A PL 439000A PL 43900021 A PL43900021 A PL 43900021A PL 439000 A1 PL439000 A1 PL 439000A1
- Authority
- PL
- Poland
- Prior art keywords
- reaction
- boron
- obtaining
- sulfuric acid
- boric acid
- Prior art date
Links
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title abstract 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000002994 raw material Substances 0.000 title 1
- 229910052717 sulfur Inorganic materials 0.000 title 1
- 239000011593 sulfur Substances 0.000 title 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 6
- 238000006243 chemical reaction Methods 0.000 abstract 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 3
- 239000004327 boric acid Substances 0.000 abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 2
- 235000006463 Brassica alba Nutrition 0.000 abstract 2
- 244000140786 Brassica hirta Species 0.000 abstract 2
- 235000011371 Brassica hirta Nutrition 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 229910052796 boron Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000008164 mustard oil Substances 0.000 abstract 2
- 238000003786 synthesis reaction Methods 0.000 abstract 2
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 229960000583 acetic acid Drugs 0.000 abstract 1
- 238000006735 epoxidation reaction Methods 0.000 abstract 1
- 125000003700 epoxy group Chemical group 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 239000012362 glacial acetic acid Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 238000007142 ring opening reaction Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
- C08G18/4676—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5072—Polyethers having heteroatoms other than oxygen containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/698—Polyesters containing atoms other than carbon, hydrogen and oxygen containing boron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2636—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/334—Polymers modified by chemical after-treatment with organic compounds containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Przedmiotem zgłoszenia jest sposób otrzymywania biopolioli na bazie oleju z gorczycy białej, zawierających w swojej strukturze heteroatomy boru oraz siarki charakteryzujący się tym, że reakcję przeprowadza się w kilku etapach obejmujących epoksydację wiązań nienasyconych (w reakcji oleju surowego z gorczycy białej z lodowatym kwasem octowym i 30% nadtlenkiem wodoru oraz 96% kwasem siarkowym, jako katalizatorem) zawartych w oleju, syntezę czynników otwierających pierścienie zawierających heteroatomy boru i siarki (w reakcji kwasu borowego, 2,2-tiodietanolu i kwasu siarkowego, jako katalizatora), otwieranie pierścieni epoksydowych odpowiednimi czynnikami i/lub estryfikację grup hydroksylowych zawartych w półprodukcie (wprowadzenie atomów boru do poliolu zawierającego atomy siarki w reakcji z kwasem borowym; wprowadzenie atomów boru z półproduktem otrzymanym podczas syntezy kwasu borowego, 2,2'-tiodietanolu, kwasu siarkowego i ksylenu, jako rozpuszczalnika).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL439000A PL244304B1 (pl) | 2021-09-21 | 2021-09-21 | Sposób otrzymywania biopoliolu zawierającego heteroatomy siarki i boru |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL439000A PL244304B1 (pl) | 2021-09-21 | 2021-09-21 | Sposób otrzymywania biopoliolu zawierającego heteroatomy siarki i boru |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL439000A1 true PL439000A1 (pl) | 2023-03-27 |
| PL244304B1 PL244304B1 (pl) | 2024-01-08 |
Family
ID=85785120
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL439000A PL244304B1 (pl) | 2021-09-21 | 2021-09-21 | Sposób otrzymywania biopoliolu zawierającego heteroatomy siarki i boru |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL244304B1 (pl) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL444520A1 (pl) * | 2023-04-20 | 2023-11-13 | Uniwersytet Kazimierza Wielkiego | Sposób otrzymywania reaktywnych surowców poliolowych na bazie odpadowej biomasy z produkcji rolnej i ich zastosowanie do otrzymywania spienionych, ogniobezpiecznych materiałów termoizolacyjnych |
| PL444324A1 (pl) * | 2023-04-04 | 2024-10-07 | Uniwersytet Kazimierza Wielkiego | Sposób otrzymywania reaktywnych surowców poliolowych zawierającego heteroatomy siarki, boru i fosforu i ich zastosowanie do otrzymywania sztywnych pianek poliuretanowo/poliizocyjanurowych |
-
2021
- 2021-09-21 PL PL439000A patent/PL244304B1/pl unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL444324A1 (pl) * | 2023-04-04 | 2024-10-07 | Uniwersytet Kazimierza Wielkiego | Sposób otrzymywania reaktywnych surowców poliolowych zawierającego heteroatomy siarki, boru i fosforu i ich zastosowanie do otrzymywania sztywnych pianek poliuretanowo/poliizocyjanurowych |
| PL247291B1 (pl) * | 2023-04-04 | 2025-06-09 | Univ Kazimierza Wielkiego | Sposób otrzymywania reaktywnych surowców poliolowych zawierającego heteroatomy siarki, boru i fosforu i ich zastosowanie do otrzymywania sztywnych pianek poliuretanowo/poliizocyjanurowych |
| PL444520A1 (pl) * | 2023-04-20 | 2023-11-13 | Uniwersytet Kazimierza Wielkiego | Sposób otrzymywania reaktywnych surowców poliolowych na bazie odpadowej biomasy z produkcji rolnej i ich zastosowanie do otrzymywania spienionych, ogniobezpiecznych materiałów termoizolacyjnych |
| PL248940B1 (pl) * | 2023-04-20 | 2026-02-16 | Univ Kazimierza Wielkiego | Sposób otrzymywania uniepalniającego poliolu oraz sposób otrzymywania pianek poliuretanowych z użyciem tego poliolu |
Also Published As
| Publication number | Publication date |
|---|---|
| PL244304B1 (pl) | 2024-01-08 |
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