PL446666A1 - Ogniotrwałe bezchromowe tworzywo spinelowe na bazie układu Mg-Cu-Fe-Al-O i sposób wytwarzania ogniotrwałego bezchromowego tworzywa spinelowego - Google Patents

Ogniotrwałe bezchromowe tworzywo spinelowe na bazie układu Mg-Cu-Fe-Al-O i sposób wytwarzania ogniotrwałego bezchromowego tworzywa spinelowego

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PL446666A1
PL446666A1 PL446666A PL44666623A PL446666A1 PL 446666 A1 PL446666 A1 PL 446666A1 PL 446666 A PL446666 A PL 446666A PL 44666623 A PL44666623 A PL 44666623A PL 446666 A1 PL446666 A1 PL 446666A1
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chromium
spinel material
free refractory
free
molar parts
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PL446666A
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Ilona Jastrzębska
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Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie
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Priority to PL446666A priority Critical patent/PL446666A1/pl
Priority to EP24153417.1A priority patent/EP4553057A1/en
Publication of PL446666A1 publication Critical patent/PL446666A1/pl

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Abstract

Przedmiotem wynalazku jest wysokoogniotrwałe bezchromowe tworzywo spinelowe na bazie układu Mg-Cu-Fe-Al-O, charakteryzujące się tym, że posiada zwartą mikrostrukturę zawierającą w swoim składzie wieloskładnikową wysokoogniotrwałą fazę spinelową bezchromową, zsyntetyzowaną przez stopienie z użyciem plazmy łukowej, której to fazy spinelowej skład jest określony wzorem sumarycznym Mg0,5Fe0,25Cu0,25Al4,0O4, zawierającym 0,5 części molowych Mg, 0,25 części molowych Fe, 0,25 części molowych Cu i 4,0 części molowych Al, przy czym to monofazowe tworzywo zawierające złożoną wieloskładnikową fazę spinelową bezchromową (Mg,Cu)(Fe,Al)2O4 posiada gęstość piknometryczną w zakresie od 3,9643 do 4,0580 g/cm3 oraz sposób wytwarzania tego ogniotrwałego bezchromowego tworzywa spinelowego.
PL446666A 2023-11-07 2023-11-07 Ogniotrwałe bezchromowe tworzywo spinelowe na bazie układu Mg-Cu-Fe-Al-O i sposób wytwarzania ogniotrwałego bezchromowego tworzywa spinelowego PL446666A1 (pl)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL446666A PL446666A1 (pl) 2023-11-07 2023-11-07 Ogniotrwałe bezchromowe tworzywo spinelowe na bazie układu Mg-Cu-Fe-Al-O i sposób wytwarzania ogniotrwałego bezchromowego tworzywa spinelowego
EP24153417.1A EP4553057A1 (en) 2023-11-07 2024-01-23 Refractory chrome-free spinel material based on mg-cu-fe-al-o system and method of producing refractory chrome-free spinel material

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PL446666A PL446666A1 (pl) 2023-11-07 2023-11-07 Ogniotrwałe bezchromowe tworzywo spinelowe na bazie układu Mg-Cu-Fe-Al-O i sposób wytwarzania ogniotrwałego bezchromowego tworzywa spinelowego

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3458430A1 (de) * 2016-05-19 2019-03-27 Refratechnik Holding GmbH Zur elastifizierung von grobkeramischen feuerfesterzeugnissen geeignete feuerfeste spinellgranulate, verfahren zu ihrer herstellung und ihre verwendung

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5344802A (en) 1993-11-15 1994-09-06 Indresco Inc. MgO-spinel refractory mix and shapes made therefrom
JP5449924B2 (ja) * 2009-08-27 2014-03-19 ダイハツ工業株式会社 酸素吸蔵放出材
CN103896613B (zh) 2014-03-27 2015-04-22 北京科技大学 一种高铁镁砂烧结刚玉复合无铬高铁镁砖及制备方法
CN108129136B (zh) 2018-01-04 2020-10-30 武汉科技大学 炼铜转炉下部用氧化镁-镁橄榄石-碳复合材料及其制备方法
CN113061045B (zh) 2021-04-21 2022-10-04 营口丰华耐火材料有限公司 一种水泥窑烧成带用镁铁锌铝复合尖晶石耐火砖及其制备方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3458430A1 (de) * 2016-05-19 2019-03-27 Refratechnik Holding GmbH Zur elastifizierung von grobkeramischen feuerfesterzeugnissen geeignete feuerfeste spinellgranulate, verfahren zu ihrer herstellung und ihre verwendung

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
ILONA JASTRZĘBSKA ET AL.: "January 2017 High Temperature Materials and Processes 63(3):299-303 DOI:10.1515/htmp-2015-0252", „STRUCTURAL AND MICROSTRUCTURAL STUDY ON THE ARC-PLASMA SYNTHESIZED (APS) FEAL2O4–MGAL2O4 TRANSITIONAL REFRACTORY COMPOUND" *
ILONA JASTRZĘBSKA ET AL.: "Materials & Design Volume 235, November 2023, 112449 Available online 3 November 2023 https://doi.org/10.1016/j.matdes.2023.112449", „STABILIZATION OF HERCYNITE STRUCTURE AT ELEVATED TEMPERATURES BY MG SUBSTITUTION" *
ILONA JASTRZĘBSKA ET AL.: "UNITECR 2023 - 27TH - 29TH September 2023 - Frankfurt, Germany (pages 542-545)", „AL2O3-MGAL2O4 REFRACTORY MATERIAL AS A CR-FREE ALTERNATIVE DEDICATED TO THE COPPER INDUSTRY" *
L.N. PADHI ET AL.: "July 2017 Transactions of the Indian Ceramic Society 76(3):196-201 DOI:10.1080/0371750X.2017.1334597", „A NOVEL PROCESS FOR SYNTHESIS OF IRON-ALUMINA SPINEL AND ITS APPLICATION IN REFRACTORY FOR CEMENT ROTARY KILN" *

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