PL8216B1 - A method of producing organic compounds or solutions that can be emulsified in water. - Google Patents
A method of producing organic compounds or solutions that can be emulsified in water. Download PDFInfo
- Publication number
- PL8216B1 PL8216B1 PL8216A PL821627A PL8216B1 PL 8216 B1 PL8216 B1 PL 8216B1 PL 8216 A PL8216 A PL 8216A PL 821627 A PL821627 A PL 821627A PL 8216 B1 PL8216 B1 PL 8216B1
- Authority
- PL
- Poland
- Prior art keywords
- water
- organic compounds
- solutions
- emulsified
- producing organic
- Prior art date
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- 150000002894 organic compounds Chemical class 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 5
- 239000002480 mineral oil Substances 0.000 claims description 3
- 150000003460 sulfonic acids Chemical class 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 4
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000011347 resin Chemical class 0.000 description 2
- 229920005989 resin Chemical class 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OJGMBLNIHDZDGS-UHFFFAOYSA-N N-ethyl-N-phenylamine Natural products CCNC1=CC=CC=C1 OJGMBLNIHDZDGS-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- -1 sulfonic acid salt Chemical class 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Description
Wytwarzanie emulsji odbywa sie na- ogól w ten sposób, ze emulgowany mate- rjal miesza sie z woda w obecnosci jakie¬ gos ochronnego koloidu, W praktyce wy¬ twarza sie najczesciej zgeszczony roztwór wodny, który w celu uzycia rozciencza sie jeszcze woda.Próby wykazaly, ze stale i plynne zwiazki organiczne, nierozpuszczalne w wodzie, jak np, weglowodory i ich po¬ chodne, dalej alkohole, ketony, kwasy zy¬ wicowe, smoly i t, d, mozna przeprowa¬ dzic w postac dajaca sie emulgowac, je¬ zeli sie je zmiesza z jakims zwiazkiem organicznym rozpuszczalnym w wodzie, jak np, alkohol, aceton i i d,, a potem rozpusci w tej mieszaninie kwasy sulfo¬ nowe olejów mineralnych. Okazalo sie, ze te sole kwasów sulfonowych oleju mine¬ ralnego nie sa jako takie rozpuszczalne ani w weglowodorach, wzglednie ich po¬ chodnych, ani w rozpuszczalnikach roz¬ puszczalnych w wodzie, lecz w mieszani¬ nie obu wymienionych skladników rozpu¬ szczaja sie bez trudnosci, W ten sposób otrzymuje sie silnie stezone, bezwodne roztwory podstawowe, które rozcienczone woda tworza emulsje nadajace sie dla wie¬ lu celów technicznych, np, w przemysle wlókienniczym, skórniczym, lakierniczym, oraz do zwalczania szkodników.Tak np, sól sodowa kwasu sulfonowe-go z oleju solarowego mozna rozpuscic w jednej czesci alkoholu etylowego i 4 cze¬ sciach aniliny, albo w jednej czesci alko¬ holu metylowego i 7 czesciach chloroben- zolu, podczas gdy w poszczególnych skladnikach wymieniona sól nie jest roz¬ puszczalna. Z takim samym wynikiem mozna tez rozpuszczac ciala stale; np. w mieszaninie alkoholu etylowego i aniliny lub alkoholu metylowego i chlorobenzolu mozna rozpuscic (przed lub po rozpuszcze¬ niu soli kwasu sulfonowego) okreslona ilosc kalafonji, albo innej zywicy, lub smoly. PL PLGenerally, the emulsion is produced by mixing the emulsified material with water in the presence of some protective colloid. In practice, a generally thickened aqueous solution is produced, which is still diluted with water for use. that solid and liquid organic compounds, insoluble in water, such as, for example, hydrocarbons and their derivatives, further alcohols, ketones, resin acids, tars, etc., can be converted into emulsifiable form, if they are mixed with some water-soluble organic compound, such as alcohol, acetone, and the like, and then the sulfonic acids of the mineral oils are dissolved in this mixture. It turned out that these mineral oil sulfonic acid salts are not as such soluble in hydrocarbons or their derivatives, or in water-soluble solvents, but dissolve without difficulty in a mixture of the two components mentioned. In this way, highly concentrated, anhydrous stock solutions are obtained, which, in dilution with water, form emulsions suitable for many technical purposes, e.g. in the textile, leather, paint, and pest control industries. Such as, for example, sodium sulfonic acid the solar oil can be dissolved in one part of ethyl alcohol and 4 parts of aniline, or in one part of methyl alcohol and 7 parts of chlorobenzol, while in the individual components the salt mentioned is not soluble. With the same result one can also dissolve the body constantly; for example, in a mixture of ethyl alcohol and aniline or methyl alcohol and chlorobenzol, a certain amount of rosin or other resin or tar may be dissolved (either before or after dissolving the sulfonic acid salt). PL PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL8216B1 true PL8216B1 (en) | 1928-01-31 |
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