PL7314B1 - Soap substitute, wetting and emulsifying agent. - Google Patents
Soap substitute, wetting and emulsifying agent. Download PDFInfo
- Publication number
- PL7314B1 PL7314B1 PL7314A PL731426A PL7314B1 PL 7314 B1 PL7314 B1 PL 7314B1 PL 7314 A PL7314 A PL 7314A PL 731426 A PL731426 A PL 731426A PL 7314 B1 PL7314 B1 PL 7314B1
- Authority
- PL
- Poland
- Prior art keywords
- wetting
- emulsifying agent
- soap substitute
- group
- soap
- Prior art date
Links
- 238000009736 wetting Methods 0.000 title claims description 4
- 239000000344 soap Substances 0.000 title claims description 3
- 239000000080 wetting agent Substances 0.000 title claims description 3
- 239000003995 emulsifying agent Substances 0.000 title claims 2
- -1 mitrow group Chemical group 0.000 claims description 7
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical class 0.000 claims description 2
- 150000003460 sulfonic acids Chemical class 0.000 claims description 2
- 150000001721 carbon Chemical class 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 235000019645 odor Nutrition 0.000 claims 1
- 239000002253 acid Substances 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BINNYHPVWXUIDU-UHFFFAOYSA-N CC(C)C(C(Cl)=CC1=CC=CC=C11)=C1S(O)(=O)=O Chemical compound CC(C)C(C(Cl)=CC1=CC=CC=C11)=C1S(O)(=O)=O BINNYHPVWXUIDU-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- AZBNIIQGHYYHQF-UHFFFAOYSA-M sodium;pentane-3-sulfonate Chemical compound [Na+].CCC(CC)S([O-])(=O)=O AZBNIIQGHYYHQF-UHFFFAOYSA-M 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Description
Pewne pochodne kwasów sulfonowych, weglowodorowych, a mianowicie o gru¬ pach propylowych posiadaja silnie wyra¬ zone wlasnosci (zwilzajace,. Obecnie zauwa¬ zono, ze wogóle kwasy sulfonowe aroma¬ tyczne lub ich sole, zawierajace w pierscie¬ niu grupe halogenowa, nitrowa, hydroksy¬ lowa lub aminowa lub kilka podstawników podobnych i to bez wzgledu na to, czy za¬ wieraja one jedna lub kilka grup alkylo- wych w pierscieniu, czy w podstawnikach, wykazuja silnie wyrazone wlasnosci zwil¬ zajace i moga byc stosowane jako srodki zwilzajace, jako namiastki mydla i t. d. jak równiez moga sluzyc do wytwarzania e- mulsji plynów organicznych, ido zarabiania barwników sproszkowanych lub jako srodek dyspersyjny do innych celów. Zwiajzki rze¬ czone posiadaja te wyzszosc, iz rozpu¬ szczaja sie równiez w roztworach kwa¬ snych i w obecnosci soli wapniowych lub magnez j owych.Jako zwiazki tego rodzaju mozna przy¬ toczyc np. kwasy dwuetylometanilinowy, dwubuty 1 oaminosul f onowy, ^dwuamy 1 o- a -naf tylaminosulfonowy, chloroizopropylo- naftalinosulfonowy, izopropylowany nafto- losulfonowy i i d. oraz ich sole. Stosowa¬ nia kwasu etylobenlzyloanilitnosulfonowe- go, jak równiez produktów, dzialajacych jako garbniki, które to produkty mozna o- trzymac zapomoca kondensacji kwasów sulfonowych oksyzwiazków aromatycznych z aldehydem mrówkowym, w danym wy¬ padku sie nie zastrzega.Przyklad L 10 cz. wag. soli sodowej o-trzymanego z a -chloronaftalinu zapomoca sulfonowania i kondensacji alkoholu izopro¬ pylowego kwasu izopiropylochloronaftalino- sulfooowego rozpuszcza sie w 1000 !ciz. wag, wody. Welna po zanurzeniu w roztworize po¬ dobnym zwilza sie natychmiast. Roztwór rzeczony pieni sie dobrze.Podobne wlasnosci wykazuja równiez i roztwory wodne produktów rzeczonych, o- trzymywanych zapomoca sulfonowania p-naftolu i nastepnie kondensacji z alko¬ holami alifatycznemi.Przyklad II. 100 cz, wag. wodnistej 10%-ej pasty blekitu indantreinowego RS, zarabia sie dokladnie roztwlotrem, zawieraja¬ cym 1 cz,. wag. dwuetylometanilosulfonianu sodowego, po wysuszeniu otrzymuje sie pro¬ szek, zwilzajacy sie iz latwoscia, który po za¬ robieniu woda rozdziela sie w niej równo¬ miernie. W isposób podobny mozna przera¬ biac na proszek i inne barwniki np. stosujac równiez dwuamylo- a-naftylaminosulfonian sodowy. PL PLCertain derivatives of sulfonic and hydrocarbon acids, namely those of propyl groups, have strongly expressed (wetting) properties. It has now been noticed that aromatic sulfonic acids or their salts in the ring contain halogen, nitro, hydroxyl or amine, or several similar substituents, and regardless of whether they contain one or more alkyl groups in the ring or in the substituents, they exhibit strong wetting properties and can be used as wetting agents, as soap substitutes and hence, they can also be used for the production of emulsions of organic liquids, and for the preparation of powdered dyes or as a dispersion medium for other purposes. The concoctions have the advantage that they dissolve also in acidic solutions and in the presence of calcium or magnesium salts. Compounds of this type include, for example, diethylmethanilic acid, dibutyl, amino-sulfonic acid, diamines and naphthyls. nasulfonic acid, chloroisopropyl naphthaline sulfonic acid, isopropylated naphthyl sulfonic acid and and d. and salts thereof. The use of ethylbenlzyl anilitnesulfonic acid, as well as products which act as tannins, which products can be obtained by condensation of sulfonic acids of aromatic oxides with formaldehyde, is not reserved in this case. wt. The sodium salt obtained from the? -chloronaphthaline by sulfonation and condensation of isopropyl alcohol of isopyropylchloronaphthaline sulfoic acid is dissolved in 1000%. w, water. The wool is immersed in a similar solution and immediately wet. Said solution foams well. Similar properties are also shown by aqueous solutions of said products, obtained by sulfonating p-naphthol and subsequent condensation with aliphatic alcohols. Example II. 100 parts by weight 10% aqueous indanthreine blue paste RS, is prepared exactly with a solution of 1 part wt. After drying, the sodium diethylmethanyl sulfonate produces a wettable and easy-to-use powder, which, after mixing, distributes evenly in the water. In a similar manner, it is possible to convert into powder and other dyes, for example also by using sodium diamyl-α-naphthylaminosulfonate. PL PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL7314B1 true PL7314B1 (en) | 1927-05-31 |
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