PL90874B1 - - Google Patents
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- PL90874B1 PL90874B1 PL16353173A PL16353173A PL90874B1 PL 90874 B1 PL90874 B1 PL 90874B1 PL 16353173 A PL16353173 A PL 16353173A PL 16353173 A PL16353173 A PL 16353173A PL 90874 B1 PL90874 B1 PL 90874B1
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- PL
- Poland
- Prior art keywords
- weight
- parts
- wood
- sodium
- acid
- Prior art date
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- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 239000002023 wood Substances 0.000 claims description 7
- 238000010276 construction Methods 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 229910021538 borax Inorganic materials 0.000 claims description 4
- 238000005470 impregnation Methods 0.000 claims description 4
- 239000004328 sodium tetraborate Substances 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 230000035515 penetration Effects 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 150000001639 boron compounds Chemical class 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- UZXLOVYBQPDQCA-UHFFFAOYSA-N 2-butylnaphthalene-1-sulfonic acid;sodium Chemical compound [Na].C1=CC=CC2=C(S(O)(=O)=O)C(CCCC)=CC=C21 UZXLOVYBQPDQCA-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001559 benzoic acids Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 229960004889 salicylic acid Drugs 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- QXQAPNSHUJORMC-UHFFFAOYSA-N 1-chloro-4-propylbenzene Chemical compound CCCC1=CC=C(Cl)C=C1 QXQAPNSHUJORMC-UHFFFAOYSA-N 0.000 description 1
- VGVRPFIJEJYOFN-UHFFFAOYSA-N 2,3,4,6-tetrachlorophenol Chemical class OC1=C(Cl)C=C(Cl)C(Cl)=C1Cl VGVRPFIJEJYOFN-UHFFFAOYSA-N 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- -1 alkali metal salts Chemical class 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical class [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003870 salicylic acids Chemical class 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Przedmiotem wynalazku jest srodek do impregnacji drewna stanowiacego elementy konetrufccyjn* we wszelkiego rodzaju obiektach zwiazanych z wytwarzaniem lub magazynowaniem artykulów iywnoffciowydl.Znane i powszechnie stosowane srodki impregnacyjne do drewnianych elementów bactowteflyeh wbudowanych wenatrz budynków sa na ogól preparatami typu solnego, stepowanymi de Impraflnaeii w poetad roztworów wodnych. Pod wzgledem chemicznym stanowia one mieszaniny fóll niwrgtnfóinyeh lub organiczno-nieorganicznych o wlasciwosciach grzybo lub owadobójczych. Sklad znanych JrWlIcdw i&wych impregnacyjnych oparty jest glównie na silnych fungicydach typu fluorków, fluorokrzemtonów wkwtibtaacfech recepturowych z solami typu dwuchromianów w celu uzyskania efektu nrewymywalnofcl »« zdrawna. Do znanych fungicydów naleza równiez sole metali alkalicznych fenoli lub chlorofenoli.Srodki tego typu bedac skutecznymi impregnatami w sensie ochrony przed korozja biologiczna., nie moga byc jednak stosowane do impregnacji elementów drewnianych przeznaczonych do budowy budynków majacych sluzyc jako magazyny lub hale produkcyjne dla srodkówzywnosciowych. _ Wymienione bowiem wyzej ich glówne skladniki toksyczne skuteczne wobec grzybów ntezcracycn drewno, sa zarazem substancjami szkodliwymi dla zdrowia ludzi, nierzadko zaliczanymi do klasy trucizn jak "P-^™ czy fluorokrzemiany. Stad tez dla celów impregnacyjnych w budownictwie obiektów P""™™** "" magazyny srodków spozywczych itp. stosuje sie specjalne preparaty impregnacyjne zawierajace glownie sole ^^^^ one nieskuteczne d,a .zybów typu workowców igrzybów tlskonalych powodujacych tzw. rozklad plesniowy drewna. *«£%££FSZ tym, preparatami w warunkach podwyzszonej wilgotnosci pokrywa s,e "J^^+T? P£^Sn? wystepowanie rozkladu plesniowego stwierdza sie np. na drewnianych konstrukcjach chlodn,, p.eczarkarn,. i plesniobójcze, nie bedac jednoczesnie szkodliwym dla zdrowia organizmów staloceplnych.2 90 874 Okazalo sie, ze cel ten spelnia srodek, którego sklad oparty jest na mieszaninie 40-80 czesci wagowych kwasu borowego lub jego soli korzystnie boraksu i 15-30 czesci wagowych kwasów organicznych: salicylowego i/lub benzoesowego lub ich soli.Stwierdzono, ze zastosowanie mieszaniny zwiazków borowych z kwasami organicznymi salicylowymi/lub benzoesowym wykazuje nieoczekiwanie wysoka sile grzybobójcza, oraz dodatkowo wlasnosci plesniobójcze zwlaszcza w stosunku do popularnego gatunku plesni Aspergillus Niger. Ponadto w sklad srodka wchodza wypelniacze typu weglanów lub siarczanów oraz zwiazki ulatwiajace wnikanie roztworu srodka w glab drewna np. sól sodowa kwasu butylonaftalenosulfonowego.Srodek stosowany jest w postaci 10-20% roztworów wodnych.Srodek wedlug wynalazku wykazuje wysoka skutecznosc dzialania impregnacyjnego bedac przy tym nieszkodliwym toksycznie dla otoczenia zarówno w trakcie wykonywania zabiegów impregnacyjnych, jak i w czasie eksploatacji zaimpregnowanego nim drewna.Przykladowy zestaw skladników srodka.Przyklad L Kwas benzoesowy 10 czesci wagowych, kwas salicylowy 15 czesci wagowych, boraks 55 czesci wagowych, weglan sodowy 10 czesci wagowych, siarczan sodowy 9,5 czesci wagowych, sól sodowa kwasu butylonaftanenosulfonowego 0,5 czesci wagowych.Przyklad II. Kwas sylicylowy 15 czesci wagowych, boraks 70 czesci wagowych, siarczan sodowy t4yB czysci wagowych, sól sodowa kwasu butylonaftalenosulfonowego 0,3 czesci wagowych, barwnik 0,2 czesci wagowych. Otrzymanie srodka polega na dokladnym rozdrobnieniu skladników i ich wymieszaniu. Forme uzytkowa stanowia roztwory wodne, które moga byc uzywane do matowania, opryskiwania lub kapiel! drewna.Srodek moze byc równiez stosowany w postaci sypkiej do dezynfekcji podsypek budowlanych. -30 czesci wagowych, kwasów orgeHcznych salicylowego i/!ub benzoesowego tub Ich soli 3k^d~Prac. Poligraf. UP PRL Druk WOSJ „Wspólna Sprawa" Format A4.Nak ted 120 + 18. Cena 10 zl PLThe subject of the invention is an agent for impregnating wood, which is a confrontational element * in all kinds of facilities related to the production or storage of and resin products. Known and commonly used impregnating agents for wooden bactowtefly elements embedded in buildings are generally salt-type preparations, which are dehydrated in water steps. . In terms of chemical substances, they are mixtures of anti-inflammatory or organic-inorganic compounds with fungal or insecticidal properties. The composition of well-known impregnating agents is based mainly on strong fluoride fungicides, formulated fluorosilitones with dichromate salts in order to obtain a non-corrosive effect. The known fungicides also include the alkali metal salts of phenols or chlorophenols. Agents of this type are effective impregnants in terms of protection against biological corrosion, but cannot be used for the impregnation of wooden elements intended for the construction of buildings intended to serve as warehouses or production halls for foodstuffs. _ The above-mentioned main toxic ingredients are effective against fungi and are also harmful to human health, often included in the class of poisons such as "P- ^ ™ or fluorosilicates. Therefore, for impregnation purposes in the construction of buildings P" "™yszne * * "" foodstuff warehouses, etc., special impregnating preparations containing mainly salts ^^^^ are used, but they are ineffective, but they are ineffective, but they cause the so-called mold decay of wood. * «£% £ of high humidity is covered by s that "J ^^ + T? P £ ^ Sn? the occurrence of mildew decomposition is noted, for example, on wooden constructions of cold, potted trees. and mold-killers, while not being harmful to the health of solidocidal organisms. 2 90 874 It turned out that this goal is met by a measure whose composition is based on a mixture of 40-80 parts by weight of boric acid or its salts, preferably borax and 15-30 parts by weight of organic acids : salicylic and / or benzoic acid or their salts. It was found that the use of a mixture of boric compounds with organic salicylic / or benzoic acids shows unexpectedly high fungicidal power, and additionally mildew, especially in relation to the popular species of mildew, Aspergillus Niger. In addition, the composition of the agent includes fillers such as carbonates or sulfates and compounds facilitating the penetration of the agent solution into the depth of wood, e.g. sodium butylnaphthalene sulfonic acid. The agent is used in the form of 10-20% aqueous solutions. toxic to the environment, both during impregnation treatments and during the operation of impregnated wood. Example set of the ingredients of the agent. Example L Benzoic acid 10 parts by weight, salicylic acid 15 parts by weight, borax 55 parts by weight, sodium carbonate 10 parts by weight, sodium sulphate 9.5 parts by weight, sodium salt of butylnaphthanesulfonic acid 0.5 parts by weight. Example II. Silicylic acid 15 parts by weight, borax 70 parts by weight, sodium sulfate t4yB pure by weight, sodium butylnaphthalenesulfonic acid 0.3 parts by weight, colorant 0.2 parts by weight. The preparation is based on the precise grinding of the ingredients and their mixing. The application form consists of aqueous solutions that can be used for matting, spraying or bathing! The product can also be used in a loose form for disinfecting construction ballast. -30 parts by weight of organic salicylic acids and / or benzoic acids in their salts 3% work. Typographer. UP PRL Print WOSJ "Common Case" A4 format. On the way 120 + 18. Price PLN 10 PL
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL16353173A PL90874B1 (en) | 1973-06-22 | 1973-06-22 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL16353173A PL90874B1 (en) | 1973-06-22 | 1973-06-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL90874B1 true PL90874B1 (en) | 1977-02-28 |
Family
ID=19963150
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL16353173A PL90874B1 (en) | 1973-06-22 | 1973-06-22 |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL90874B1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001007217A1 (en) * | 1999-07-28 | 2001-02-01 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Wood preservative and method for protecting wood using said preservative |
| US7156906B2 (en) | 2001-02-13 | 2007-01-02 | Yara International Asa | Impregnating agent |
-
1973
- 1973-06-22 PL PL16353173A patent/PL90874B1/pl unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001007217A1 (en) * | 1999-07-28 | 2001-02-01 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Wood preservative and method for protecting wood using said preservative |
| US7156906B2 (en) | 2001-02-13 | 2007-01-02 | Yara International Asa | Impregnating agent |
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