PT101011A - Shampoo compositions containing silicone, cationic polymer and liquid and oily conditioning agents - Google Patents

Abstract

Hair conditioning shampoo compositions are described comprising: (a) from approximately 5% to approximately 50% by mass of an anionic surfactant component, (b) from approximately 0.05% to approximately 10% by mass of a silicone hair conditioning agent, which is dispersed or insoluble, non-volatile and non-ionic, (c) from approximately 0.05% to approximately 10% by mass of an organic and cationic polymer agent which acts as a hair conditioner and is soluble in water, (d) from approximately 0.05% to approximately 5% by mass of a liquid and oily conditioner agent which is organic, non-volatile and insoluble in water and selected from the group comprising hydrocarbon oils and fatty esters and their mixtures, and (e) an aqueous carrier agent. The shampoo compositions presented here provide excellent general hair conditioning benefits together with excellent cleaning performance.

Description

OvJODO

1 CHEMICAL COMPOSITION CONTAINING SILICONE, CATIONIC POLYMER AND LIQUID AND OIL CONDITIONING ABENTS. 5 10 15

Mod. 7! - 20,000 ex. - 70J08 20 25 30 35

Field of the Invention This invention relates to shampoo compositions containing ingredients which act as hair conditioners. The present invention relates to shampoo compositions containing ingredients which act as hair conditioners. , most often due to the sebum secreted by the head. The effect of. sebum makes the head look dirty and unattractive. Dirt on the hair causes it to be washed with shampoo regularly. Washing the hair with shampoo cleans it as it removes excess dirt and sebum. However, the shampooing process has drawbacks as the hair becomes wet, embarrassed and generally a less than amenable condition. Shampooing may also result in dry or "frizzy" hair, and lack luster, due to the removal of natural oils or other hydrant substances. After shampooing, the hair may also suffer a loss of " softness " which is perceptible to the user after drying. Hair can also suffer increased static electricity due to drying after shampooing. This can interfere with hair brushing and styling, which can result in hair that is difficult to comb and " in the air ". A number of methodologies have been developed to alleviate the problems that arise after shampooing. These vary from the inclusion of adjuvants, hair conditioners into shampoos to the application, after shampooing, of conditioners It is possible to use 9 solutions to be used after 3 ≤ 5386

1 5 10 15

Mod. 71-20,000 ex. - 70/08 20 25 30 «<V hair washing. These latter compositions are generally liquid and have to be applied in a separate step, following the shampoo, also having to be left in the hair for some cover, being posterior- &quot; This process is time-consuming and is less convenient than shampoos: of course, the cleansing ingredients and the hair conditioning agents are well known. containing adjuvants have not been fully satisfactory for a number of reasons. The cationic conditioning agents are well suited for use in hair conditioning compositions, because of their ability to control static stability, improve the release of the hair while wet, and provide the wearer with urna.v Sensation of silky hair while wet. A problem encountered in shampoos relates to problems of compatibility between good anionic cleansing agents and the many conventional cationic agents which have historically been used as conditioning agents. Efforts have been made to minimize the adverse interaction through the use of alternative therapeutics and cationic conditioning agents. Cationic surfactants which have good properties as generic conditioners in products for use after hair washing. usually has a tendency to complex with anionic cleansing active agents, performing poor performance as conditioning agents when in a shampoo context. In particular, the use of ten-io-ac soluble cationic compounds which form soluble, ionic complexes are not soluble,

1 5 10 15

Mod. 71 -20,000 ex. - 90J08 20 25 30 deposit well over σ hair. Soluble cationic surfactants which form insoluble N-functional complexes are deposited on the hair, but do not have great benefits as conditioning agents, and tend to cause a sensation of hair dirt. The use of insoluble cationic surfactants , for example? tridecyl methyl ammonium chloride may provide excellent anti-static benefits but will not act as good general conditioning agents. Cationic polymers tend to settle on the hair giving rise to an undesirable feeling of dirt. Thus, the polymers conventional cationic compounds are preferably used at limited levels to minimize this problem. however, it may limit the overall conditioning benefits that are obtained. cationic conditions commonly do not provide optimum overall conditioning, particularly in the area of &quot; softness &quot;, and specific gravity when used as ingredients in a champagne composition. The nonionic icons may provide greater smoothness. The use of silicones in fields of shampoos have been reported in a number of different publications. These publications include U.S. Patent No. 6,551, Geer, dated March 11, 19585 U.S. Patent 3, 964,500, from Drakoff, issued June 4, 1961 to U.S. Patent 4,364,837 to Pader, issued December 4, 1982, and U.S. Patent No. 849,433, Woolston, dated September 8, 1960. Although these patents have compositions containing an icon, they also do not provide a totally satisfactory product, since it is difficult to maintain 5 35 10 15

Mod. 71-20,000 ex. - 90/08 20 25 30 35 65386 the well-dispersed silicone

and suspended in the product, compositions of stable conditioner shampoos containing insoluble silicone have been described in U.S. Patent No. 4,741,8559 to Grete and Russe 1, dated May 3, 1988; U.S. Patent Nos. 4,788,066, Boiich and Williams 3, issued November 89, 1988. These shampoo compositions can provide excellent hair conditioning overall benefits while maintaining excellent cleaning performance even with use of anionic detersive surfactants for a wide variety of hair types. More recently, improved shampoo compositions have been presented on Serial No. 07 / 688,699 of the United States of America, by Robert L. Wells, filed December 5, 1990, now abandoned, and in his Serial No. 027 / 778,765, filed October 81, 1991, featuring shampoos containing anionic surfactants, insoluble silicone dispersed in certain cationic polymers with relatively weak ionic strength. These compositions have excellent washing and conditioning properties for a wide variety of head types, including a better conditioning action on hair that is damaged by permanent discoloration, discoloration, etc. The Japanese Patent Application No. 5678095, of June 16, 1996, from I-etho et al., CKao Soap Corp.) also discloses shampoos containing cationic polymers and silicone as agents. Other patent publications which refer to. shampoos. with cationic and iV silicone agents include Application Publication EP0 0413,, 417, 6-7 65336

1 10 15 published February 20, 1291, by Hartnett et al. At "

Mod. 71-20,000 e *. - 90/08 20 25

Another method of providing hair conditioning benefits in shampoo compositions has been the use of substances which are oily to the touch. These substances provide a greater gloss and gloss to the hair. The oily substances have also been combined with cationic substances in shampoo formulations. Japanese Patent Application Showa 53/35902, opened October 6, 1979 (Showa 54 / 189,135), by M. Uchino 'V (Lion Yushi Co.) has compositions for the treatment of hair containing fatty acid salt, and at least 10% of an oily component, for use before or after washing with shampoo. The oily components are hydrocarbons, high molecular weight alcohols, fatty acid esters, glycerides, ε fatty acids. Japanese Patent Application 621119371 - 327-266, filed December 25, 1987, issued July 4, 1987, opened with HEI No. 987 3-168 "612, from H orie et al. discloses detergent compositions containing cationic cationic surfactants or cationic polymer, anionic surfactant, and specific esters of the formula RC00R 'wherein R and R' represent straight or branched alkyl chains. obtain optimal combinations of cleansing and hair conditioning ability 'it remains desirable to obtain shampoo compositions with improved properties as conditioners. For example, it remains desirable to improve overall conditioning, and in particular gloss and gloss, hair styling. hair while wet and dry, hair sensing after drying for hair treated with shampoos containing an icon and cationic substances.

5 10 15 shampoos containing oily substances in combination with cationic substances, it is still desirable to improve general conditioning, especially the brushing and disentangling of wet hair, the brushing of dry hair, and the treatment of hair However, simple increase in the content of one or both of the conditioning ingredients may result in adverse effects, such as a greasy hair sensation and loss of velums, it is desirable to improve the conditioning without suffering

Mod. 71-20,000 ex. An attempt to achieve this is disclosed in EPO Patent Publication No. 0,413,416, issued February 6, 1991, by Robbins et al., Which discloses polymers containing amino acid, anionic surfactant, cationic active agent, and a hydrocarbon component. In relation to such formulations, it would normally be expected to result in an excess deposition of amino silicon on hair, and consequently on a greasy appearance and loss of hair velums, or in a reliably limited improvement due to the intensive use of very low levels of aminosilicone, to avoid these adverse effects. The cationic surfactants would have a limited ability to condition hair due to interaction with the anionic surfactant. EPO Patent Publication No. 413,417, published February 1, 1991 discloses shampoos containing anionic surfactants and conditioning agents such as insoluble silicone (preferably aminosilicone), cationic surfactant, polyethylenes, paraffins, microcrystalline waxes, Ct-CaI fatty acids or trig lyphorides, esters of high molecular weight fatty alcohols or

65380

1 5 10 15

Mod. 71-20,000 ex. High molecular weight fatty acids'. and beeswax. Another patent document which discloses shampoo compositions and a variety of conditioning agents is U.S. Patent 3,964,500 to Drakoff, issued June 2, 1976. This patent relates to shampoos containing An icon which acts as a conditioner and a hair bulking agent selected from resins of certain woods, gums, sucrose acetate isobutyrate, and cationic amino cellulose. Despite all these approaches and attempts to obtain combinations it remains to be desired to provide improved conditioner shampoos. It has now been discovered that improved overall conditioning can be achieved by combining anionic surfactant in a shampoo with nonionic silicone, , dispersed and insoluble with soluble cationic organic polymer acting as a conditioning agent, and with specific oily organic liquids These compositions may provide improved conditioning properties, while reducing undesirable side effects which may result from the increase in the conditioning agent content in the prior art conditioning systems. As previously discussed, a conditioner system containing too much silicone N may result in deposition of the silicone on the hair after repeated use, leading to a loss of hair volume. Too much oil results in an oily sensation and a loss of hair volume. Too much cationic conditioning agent results in smooth, oily-looking hair. It has now been found that by combining these specific types of non-ionic lenses, insoluble ionic acids. liquids 9 t

1 5 10 15

Mod. 71-20,000 ex. And cationic polymers can provide better overall conditioning of the head, while minimizing the adverse effects of deposition of the conditioning agent which could occur when levels of individual components in the conditioning systems previously known. Furthermore, the use of the aionic polymer in the compositions disclosed herein can improve the performance over similar systems with the nonionic surfactant in combination with. silicone conditioning agents and oily liquids. It is an object of this invention to provide shampoo compositions which can provide excellent washing performance and improved conditioning levels while minimizing any adverse side effects associated with deposition due to it is also an object of this invention to provide a method for washing and conditioning JV hair which can provide excellent cleaning in combination with improved conditioning while minimizing adverse side effects' associated with excessive deposition of the agent? hair conditioner. These objects will become apparent from the following description, as well as other objects, which also become apparent upon reading said description.

This invention provides liquid shampoo compositions containing detersive anionic fentanyl agents and which can provide both excellent performance and / or ease of use.

5 10 15

Mod. 71-20,000 ex. - 90/08 20 25 30 '. Cleaning as benefits associated with the conditioning of a wide variety of hair types. This can be achieved by incorporating into the composition of the shampoo of a system, conditioner with components. , including a non-volatile, non-ionic and nonionic silicone hair conditioning agent specifically varying the cationic charge density, a conditioner consisting of a water soluble cationic polymer and an organic, insoluble, liquid oily liquid in water and non-volatile. The shampoo compositions presented herein also include an aqueous carrier. The conditioning agents comprised of cationic polymers which are presented in this invention are organic polymers containing amino or ammonium groups. amino groups are cationic or pH of the shampoo composition, which is preferably between about 1% H 3 and about pH 9, and still preferably between about pH 4 and about pH 5. The insoluble silicone which acts as a conditioning agent is dispersed in the composition in the form of drops or particles. an appropriate suspension agent sV is used to facilitate the stability of the s. The oily liquid acting as a conditioning agent is mixed and distributed throughout the composition. The oily liquid is generally selected from the group consisting of hydrocarbon oils and fatty esters. As used herein, the term &quot; fatty ester &quot; means esters containing 10 or more carbon atoms. More particularly, the present invention provides hair conditioning shampoo compositions comprising (a) from about 5% to about 50% by weight of a 35 1 ώ'- 386

5 10 15

Mod. 71-20,000 ex. (B) from about 0.05% to about 10% by weight of a non-volatile, non-volatile, insoluble dispersible silicone conditioning agent. c) from about 0.05% to about 5% by weight of a hair conditioning agent comprised of a water-soluble organic cationic polymer having a cationic charge denaturation of from about 0.9 to about 4 meq / grams d) from about 0.05% to about 5% by weight of an organic, non-volatile, water-insoluble liquid selected from the group consisting of hydrocarbon oils, fatty esters containing carbon atoms, or mixtures thereof; and c) an aqueous carrier agent, As used herein, the terms &quot; soluble &quot; and &quot; insoluble &quot; referring to particular ingredients of the shampoo compositions, refer to the solubility or insolubility, respectively, of that ingredient in the shampoo composition, unless specifically indicated otherwise. For example, the terms &quot; water &quot; and &quot; water-insoluble &quot;, as used herein, refer to the solubility of the specific ingredient in water, M as opposed to solubility in the shampoo composition. The invention, including its preferred applications, The compositions of the present invention may contain, consist essentially of, or consist of, a number of essential and / or optional ingredients described herein. Λ * All the percentages are calculated in terms of the total N composition, except in the specific cases 12 1 10 15

Mod. 71-20,000 ex. · 90/08 20 25

All the ratios are by weight, except for the rivers specifically indicated. '

The essential ingredients as well as a variety of preferred and optional ingredients of the compositions of the present invention are described hereinbelow. The hair shampoo and conditioner compositions of the present invention contain a surfactant component anionic surfactant, which may comprise one or more anionic detersive surfactants or amphoteric detersive surfactants which are anionic at the pH of the shampoo, the ability to clean the composition. The anionic surfactant component will generally be present at a level ranging from about 5% to about 50%, preferably from about 8% to about 30%, and most preferably from about 10% to about The present invention relates to anionic detersive detergents useful in this invention including alkyl sulfates and alkyl ether sulfates. These substances have the formulas RDSOgM and R0 (CeH * Q) x80si in wherein R represents an alkyl or alkenyl group of from &quot; about B to about 24 ° to the? carbon, X is between? 1 and 10 and M represents a water-soluble catalyst such as ammonium, sodium, potassium, and triethanolamine. The alkyl sulfates are typically obtained as condensation products of ethyl ether and mannitol alcohols containing from about 8 ' to about 4-carbon atoms. From 13 35 1 65386 5

Preferably, R has from about 1 to about 18 carbon atoms in both the alkyl and alkyl ether sulfates. These alcohols may be derived from fats, for example cesium or tallow oil, or may be synthetic. The preferred alcohol is alcohol. These alcohols are reacted with from about 1 to about 10%, and especially from 1 to about 10%

&lt; V &lt; / RTI &gt; about 3% molar portions of ethylene oxide, and 10-15 mol / mol of molecular weight and which

Mod. 71-20,000 ex. For example, for example, an average of 3 moles of ethylene oxide per mole of alcohol is then sulfated and neutralized. Specific examples of alkyl ether sulfates which may be present are sodium and ammonium salts of alkyl triethylene glycol ether sulphate, tallow alkyl triethylene glycol ether sulphate, and tallow alkyl hexylene oxyphosphate. The alkyl ether sulphates which are particularly preferred are which are a mixture of individual compounds, said mixture having an average alkyl chain length of from about 12 to about 16 carbon atoms and a mean degree of ethoxylation of from about 1 to about 4 moles of ethylene oxide. This mixture is also comprised of from about 0 to about 0.5% by weight Cielapen Compounds from about 60 to about 100% by weight of Compounds 18-16 from about 0 to about £ 0 in mass of compounds of Cl 7 18-17 of from about 3 to about 30% by weight of compounds having a degree of ethoxylation of 0; from about 45 to about 90% by weight of compounds having a degree of ethoxylation of from about 1 to about 4% from about 10 to about 5% by weight of compounds having a degree. of ethoxylation of from about 4 to 14 ϊ ΐ

1 to about 8% and from about 0.1 to about 5% by weight of composites having a degree of ethoxylation of greater than about 8.5

Another class of suitable anionic surfactants are suitable for. this invention is the salts

The water-soluble organic solvents of the organic reaction products with sulfuric acid with the general formula wherein R 1 is selected from the group consisting of aliphatic and saturated hydrocarbon radicals , straight chain or. branched, and containing from about 8 to about 24, preferably from about 12 to about 10, carbon atoms; and M represents a cation "

As important examples are the salts of an organic sulfuric acid reaction product of a hydrocarbon,

Mod. 71-20,000. - 90/08 20 methane series, including iscr, neo &quot;. ineso &quot; to paraffins, containing from about 8 to about 24 carbon atoms, and preferably from about 12 to about 13 carbon atoms, and an? for example, sulphonation, for example, sulfur dioxide, sulphonated sulphonation, sulphonated sulphonate, sulfonated sulphonate, sulphonated, sulphonated, sulphonated, sulphonated, e.g. sulfonated C1E_1B paraffins * 25

Further examples of synthetic ammonium detersive surfactants which are within the

In accordance with the present invention are the reaction products of fatty acids esterified with isethionic acid and neutralized with sodium hydroxide in which, for example, the fatty acids are derived from coconut oil; sodium or potassium salts of methyl tauride fatty acid amides in which the fatty acids, for example, are derived from coconut oil. Other detersive surfactants

&quot; J anionic compounds of this variety are presented in the following table.

Mod. 71-20,000 eu. -90/08 20 25 30 35

U.S. Patents Nos. 2, 4S, 6, 9, 15, 2 = 486, = 922 and 2 = 396 = 278. Still other synthetic ammonium detersive tensides are in the class designated as succinamates. This class includes tetra-N-di-carboxyethyl-N-octadecylsulphosuccinamate, and the sodium salt of sulfosuccinic acid, dihydrochloride. 1 sodium salt of sulfosuccinic acid, salt dioctyl esters. sodium sulphosuccinic acid. Other anionic detersive detergents, including those containing from about 12 to about 24 carbon atoms. carbon, the term &quot; sulfonates of &quot; is used herein to mean compounds which may be produced by the sulphonation of X-olefins by the use of uncomplexed sulfur trioxide followed by neutralization of the acid reaction mixture under conditions such that any sulfones which are formed in the reaction are hydrolyzed to give the corresponding hydroxyalkanesulfonates. The sulfur trioxide may be liquid or gas, and usually not, but not necessarily diluted by inert diluents, for example, liquid, chlorinated hydrocarbons, etc. when used in gaseous form. The olefins, of which the sulfonates of the formula are derivatives, are monoolethers containing from about of 12 to about 24 carbon atoms, preferably about 14 to about 16 carbon atoms. Preferably, they are straight chain oxyines. In addition to the actual alkene sulfonates, and a proportion of hi hydroxy-alkane sulfonates: Glyphine sulphonates may contain minor amounts of other substances 3 such as alkene disulfonates, depending on the reaction conditions, proportion of the reactants, nature of the starting olefins and impurities in the olefin, and secondary reactions during the process of south africa, 10

A specific blend of the type of α-olefin sulphonate of the type shown above is described in more detail in U.S. Patent No. 3,332,880 to Pflaumer and Kessler, dated July 5, 1967; incorporated herein by reference "15

Another class of anionic detersive surfactants are the Î ± -alkyloxy alkane sulfonates. These compounds have the following formula:

H

I 20

W

C-SOAM

R 25 is a straight chain alkyl group containing from about 6 to about 10 carbon atoms, R a is a lower alkyl group containing from 1 to 10 carbon atoms. (preferably 5 to about 3 carbon atoms), and ΙΊ is a water soluble catalyst as described above.

H

Many other synthetic anionic surfactants are described in McCutcheon's Emulsifiers and Detergents, 1989, published by M, C, Publishing Go, which is hereby incorporated by reference. Also, U.S. Patent No. 3,989,667, Laughlin et al., Issued December 30, 1975, discloses many other 17 351 65386

5 10 15

Mod. 71-20,000 ex. Anionic surfactants, as well as other types of surfactants, are incorporated herein by reference. Preferred anionic detersive surfactants for use in such shampoo compositions include ammonium xauril sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate, monosodium lauryl sulfate, lauryl sulfate of distal lamina, diethanolamine laureth sulfate, lauryl monoglyceride sodium sulfate sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate, potassium laureth sulfate? sodium lauryl sarcosinate, sodium lauroyl sarcosinate, sodium lauryl sarcosinate, lauryl sarcosine, COCO1 sarcosine, ammonium cocoyl sulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate, potassium cocoyl sulfate, lauryl sulphate, potassium lauryl sulphate, trisulphuryl lauryl sulphate, ammonium cocoyl sulphate, 1-amine, 1-monodanolamine, sodium tridecyl benzene sulphonate, and dodecyl Sodium benzylation of sodium, iv 25

Examples of amphoteric detersive surfactants which may be used in the compositions of the present invention are those which are generically described as derivatives of amines secondary to Xylol and secondary amines in which the aliphatic radical may be a linear or branched and wherein one of the 1-alpha-substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group promoting water solubility, for example, a carboxy sulfonate, sulfate, phosphate, or phosphonate. Examples of compounds falling within this definition 18 35 Τ AECO-86

are sodium dodecylaminopropionate, sodium 3-dodecylaminopropane sulfonate, sodium lauryl sarcosinate, N-alkyltaurines such as those prepared by the reaction. of dodecylamine with sodium isethionate according to what is disclosed in U.S. Patent No. 5,658,072, aspartic acids having high molecular weight N-alkyl groups such as oroducides according to the US Pat. U.S.A. No. 2 = 438, 091, and the products sold under the tradename &quot; MIRAN0L &quot; described in U.S. Patent No. 9,2,5b28 =

Agents, surfactants Optional Detersives In addition to the anionic active component

The composition of the present invention may optionally contain other detersive surfactants.

V

These include the nonionic surfactants, the amphoteric surfactants which are not anionic for the pH of the shampoo, and the zwitterionic active agents. The optional detersive active agents, when used, are typically present at levels of from about 0.13% to about 20%, and are typically from about 1% to about 10%, although they may be used higher levels or lower levels. The total amount of the active agent

In the compositions containing optional detersive active agents in addition to the anionic active agent, between about 5.13% and about 50%, preferably between about 8% and about. 30%, and most preferably between about 10% and about 25%. The etheric detersive active agents may also be used, but are generally, less suitable since they may interact adversely with the active agent.

Mod. 71-20,000. The cationic detersive detersive agents, if used, are preferably present at levels not higher than about 5 ° C. The tensioactive agents, acyclic and v. if used, are typically conditioning agents which may optionally be included in the compositions disclosed herein. Nonionic detersive tensioactive agents which may be used include those generically defined as compounds produced by the condenser (hydrophilic in nature) with an organic hydrophobic compound, which may be aliphatic or aromatic alkyl groups. Examples of preferred classes of non-detersive active agents are The condensation products of alkyl phenols containing an alkyl group having from about 6 to about 10 carbon atoms in either a chain with The linear configuration is either in a branched chain with ethylene oxide, said ethylene oxide being present in amounts equal to from about 10 to about 60 m The condensation products of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene diamine products. The product of the condensation of aliphatic alcohols containing from about 8 to about 18 atoms. carbon, either in a straight chain or in a branched configuration? with ethylene oxide; for example a condensation of coconut alcohol such as ethylene oxide containing from about 10 to about 30 DEG C.

1 mole of the ethylene oxide per mole of coconut alcohol having the coconut alcohol moiety of from about 10 to about 14 carbon atoms. Long chain ternary ammonium oxides 5 corresponding to the following generic formula 10 15

Mod. 71-20,000 ex. - 70/08 20 25 30 * WaN ........-..... &gt; Wherein Rt contains an alkyl, alkenyl or mono-hydroxyalkyl radical having from about 3 to about 13 carbon atoms, from 0 to about 10 ethylene oxide groups, and from 0 to about 1 glyceryl group " and R 3 and R 3 contain from about 1 to about 3 carbon atoms and from 0 to about 1 hydroxy group, for example methyl, ethyl, propyl, hydroxyethyl or hydroxypropyl radicals. The seven in the formula is a conventional of a semipolar bond. 5 - Long-chain third-party phosphine oxides, corresponding to the following generic formula RR'R''P -... & In which R contains an alkyl, alkenyl or monohydroxyalkyl radical ranging from about 8 to about 18 carbon chain length carbon atoms, from 0 to about 10 ethylene oxide groups and from about 1 to about 0 carbon atoms, to about one glyceryl group and R 'and R "are each alkyl or monohydroxyalkyl groups containing from 1 to about 3 carbon atoms. Long chain dialkyl sulfoxides containing a radical of alkyl or hydroxy-lower alkyl, from about 1 to about 3 carbon atoms (usually methyl), and a long chain radical

5 10 15

Mod. 71-20,000 ex. - 90/08 20 25 30 hydrophobic? which includes alkyl, alkenyl, hydroxy alkyl, or. alkyl having from about S up to about 20 carbon atoms, from 0 to about. 10 ethylene oxide groups and from about 0 to about 1 glyceryl group, 7 '' Alkyl polyisocyanates (APS 3 which act as surfactants, such as 1% i.p. The present inventories are described in U.S. Patent 4,450,546, filed January 1, 1786, incorporated herein by reference, which is incorporated herein by reference, which has APS-active agents containing a hydrophobic group having from about 6 to about 30 carbon atoms and a polysaccharide (for example, polypeptide 3 as a hydrophilic group). Optionally, there may be a group (i.e., the hydrophobic group) may be saturated or unsaturated, branched or unbranched, and unsubstituted or substituted (for example with hydroxy or cyclic rings) B polyethylene glycol (PEG) glyceryl fatty esters, such as those of formula R (Q) OCH Wherein n is from about 5 to about 200, preferably from about 20 to about 100, and R is a hydrocarbyl aliphatic having from about 8 to about E0 carbon atoms,

Zwitterionic detersive deoxygenating agents are exemplified by those generally described as being derived from aliphatic, phosphoric, sulfonium, quaternary ammonium compounds, in which the aliphatic radicals may be straight or branched chain, and in which one of the substitutes

The aliphatic groups contain from about 8 to about 18 carbon atoms and a substituent contains an anionic group? for example carboxy, sulfonate, sulfate, phosphate or phosphonate. A generic formula for these compounds is &lt; R3) x ps CHe - R * - ··· Z (-)

Mod. 71-20,000 ex. In which Re contains an alkyl, alkenyl or hydroxy alkyl radical having from about 8 to about 18 carbon atoms from 0 to about 10 ethylene oxide groups from 0 to about 1 glyceryl group Y is selected from the group consisting of nitrogen, phosphorus and sulfur. Ra is an alkyl or monohydroxy alkyl group containing from about 1 to about 3 carbon atoms and X is 1 when Y is a sulfur atom, and when Y is a nitrogen or phosphorus atom R4 is an alkylene or hydroxyalkylene of from about 1 to about 4 carbon atoms and 2 is a radical selected from the group consisting of carboxylate groups sulfonate, sulfate, phosphonate and phosphate. Other Zwitterionics such as betaines may also be used in the present invention. Examples of betaines useful in this invention include the high molecular weight alkyl betaines, such as coconut dimethyl carboxymethyl betaine, cocoamidopropyl betaine, cocobetaine, lauryl. amidopropyl betaine, olsyl betaine,! lauryl dimethyl carboxymethyl betaine, lauryl dimethyl alfacarboxyethyl betaine, cetyl dimethyl carboxy. methyl betaine and lauryl bis (S-hydroxyethyl) carboxymethyl betaine-3-stearyl bis-2-hydroxypropyl) carboxymethyl 23

) GÒ

1 5 10 15

Mod. 71-20,000 ex. - 908 20 25 30 35 betaine, oleyl dimethyl. carboxymethyl betaine, and lauryl bis-β-hydroxy-β- The sulfobutants can be represented by coconut dimethyl sulfopropyl betaine, stearyl dimethyl sulfopropyl betaine, lauryl dimethyl sulfoctyl betaine, lauryl bis- (2-hydroxyethyl) sulfopropyl betaine, and the like amidobetaines and amidosuIbeobetaines, wherein the radical RCONH <CH 2> 3 is attached to the nitrogen atom of the betaine are also useful in this invention. Preferred shampoos of this invention contain Pi combinations of anionic active agents with Zwitterionic surfactants and / or agents amphoteric surfactants. Especially preferred are champols which contain from about 0% to about 16% of alkyl sulfates, from 0% to about 10% of ethoxylated alkyl sulfates, and from about 0% to about 10% of optional detersive surfactants selected from nonionic, amphoteric and amphoteric detersive surfactants, with at least 5% alkyl sulfate, or ethoxylated alkyl sulfate or a mixture thereof, and a total level of the tenacious agent. from about 10% to about 5%.

An essential component of the present invention is a silicone hair conditioning agent which is nonionic, non-volatile and insoluble in the shampoo compositions. of the invention, the silicone hair conditioner is mixed in the shampoo composition in the form of dispersed insoluble particles, or in the form of droplets. The silicone agent which is used as the hair conditioner is 10 15

Mod. 71-20,000 ex. · 90/08 20 25 30 35

A silicone gum which is insoluble in the composition of the shampoo as a whole but which is soluble in the s i-1 icone fluid. The agent which acts as a hair conditioner may also contain other ingredients, such as a resin for improving the deposition efficiency, the ionic conditioning agent may contain reduced levels of components of the composition. volatile silicone however. volatile silicones preferably not more than about 0.5% by weight of the shampoo composition. Typically, if volatile silicones are present, this will be due to their use as a solvent or carrier in commercially available forms there is provided levels of other ingredients of the composition, such as gums and silicone resins. The silicone conditioning agent for use in this invention will preferably have a viscosity of from about 1,000 to about 2000,000 centistokes 25 DEG C., and preferably from about 10,000 to about 1,800, 000, more preferably from about 100,000 to about 500,000. The viscosity can be measured through a capillary glass viscosity as set forth in Dow Corning Corporate Test Method CTM0004, dated July 30, 1970. The silicone hair conditioning agent will be used in the shampoo compositions shown herein at levels from about 0.05% to about 10% by weight of the composition, preferably from about 0.1% to about 10%, preferably from about 0.5 to about 8%, and more preferably from about 0% , 5% to about 5 μl. Non-volatile and insoluble silicone oxides 25

1 5 10 15

Mod. 71-20,000 ex. Suitable polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers, and mixtures thereof are also suitable. Other non-volatile and insoluble silicone fluids with properties as hair conditioners N may also be used The term &quot; non-volatile &quot; as used herein means that the silicone exhibits a very low or non-significant vapor pressure under ambient conditions as is understood by those of ordinary skill in the art. of silicone &quot; should mean silicone substances which may have a certain flow and have a viscosity of less than 1,000,000 centistokes, the viscosity of the fluid will be between about 5 and 1, , 000 "000 centistokes at 25 ° C? preferably from about 10 to about 100,000. The silicone fluids of this invention also include polyalkyl or polyaryl siloxanes having the following structure:

Si - 0

Si - in which R is alkyl or aryl, and X is an integer from about 7 to about 8, 000, "A" represents groups which block the ends of the silicone chains. aryl groups substituted on the siloxane (R) chain or at the ends of the (A) chain may have any structure so long as the resulting silicas remain fluid at ambient temperature, are hydrophobic, are neither irritant nor 26 15 10 15

Mod. 71 -20,000. -90/08 20 25 30

toxic or otherwise detrimental when applied to hair, are compatible with the other components of the composition, are chemically stable under conditions. which may be deposited on the hair and act as conditioners. Suitable A groups include methyl, methoxy, ethoxy, propyl, and aryloxy. The two R groups on the silicone atom may represent the same The preferred R groups include methyl, ethyl, propyl, phenyl, phenyl, methylphenyl and phenylmethyl. Preferred silicones are 1-methoxyethyl, 1-oxoethyl , po 1. i. polysiloxane and polymethylenylsiloxane, polydimethylsiloxane is especially preferred. Non-volatile polyalkyl siloxane fluids which may be used include, for example, polydimethylsiloxanes. These siloxanes are available, for example, from General Electric: Company in its series of Viscasiit® and SF96, in Dow Corning in its series Dow Corning SOO. The polyalkylaryl siloxane fluids which may be used , also include, for example, polymethylphenol. loxanes. These siloxanes are available, for example, from the General Electric Company as methylsilane. 1F 875 fluid or from Dow Corning as cosmetic grade fluid 556 of the polyether siloxane leros which may be used include, for example, a polypropylene oxide modified polydimethylsiloxane (e.g., Dow Corning DC-1S4S) although it may ethylene oxide and mixtures of ethylene oxide and propylene oxide may also be used. The level of ethylene oxide and

Mod. 71-20,000 e *. - 90/08 20 25 30

Polypropylene has to be sufficiently reduced to avoid solubility in water and in the composition. References having suitable silicone fluids include U.S. Patent No. 8,862,561, United States Patent No. 3,900,500 to Drakoff, issued June 88, 1976, U.S. Patent Nos. 4,364, 837, Paders, and British Patent No. 849,433 to Woolston, All of these patents are incorporated herein by reference. Also incorporated by reference is &quot; Silicon Compounds &quot; distributed by Petrarch System's. Inc., 1984. This reference provides an extensive (though not exclusive) listing of suitable silicone fluids. Another silicone substance which may be especially useful in the silicone conditioning agents is the insoluble silicone gum. The term &quot; silicone gum &quot; as used herein means polyorganosiloxane substances having a viscosity at 850 ° C greater than or equal to 1,, 000 = 000 centistokes. Silicone gums are described by Petrarch et al., Including U.S. Patent No. 4, 158, 416, Spiter et al., 5, dated 1 Halo, 1979 and No. 11, Walter et al. &quot; Chemistry and Technology of Silicones &quot; s New York Academic Press 1968. Also describing silicone gums are General Silicone Rubber Product Data Shots (SE) data failures SE 30, SE 33 , SE 54, SE 76, and all references herein are incorporated by reference herein. &Quot; Gums, silicone &quot; will typically have a molecular mass greater than about 800,000; generally from about 800,000 to about 1,000,000. Specific examples include polydimethylsiloxane, copolymers of isoxazole / methyl-in-iesiloxane, and copolymers of 28-35 * 15 10 15

Mod. 71 -20,000 ex. - 90/08 20 25 30 o53Qá

polydimethylsiloxane / diphenylsiloxane / methylisiloxane. Preferably, the hair conditioning agent comprises a blend of a polydimethylsiloxane gum having a viscosity greater than about 1,000,000 centistokes and polydimethylsiloxane fluid having a viscosity of from about 100 centistokes to about 100,000 centistokes. as a ratio of gum to fluid of from about 30:70 to about 70:30, preferably from about 70 to about 60. Other optional ingredients which may be included in the silicone agent which acts as a conditioner is the silicone resin. Silicone resins are palladium siloxane systems with many crosslinks. Cross-linking is achieved by the incorporation of tri-functional and tetrafunctional silanes with monofunctional or double bond silanes or both during the preparation of the silicone resin. As is well known in the middle ? the degree of crosslinking that is required to result in a silicone resin will vary in accordance with the specific silicone units incorporated in the silicone resin. In general, the silicone substances which contain a sufficient level of the trifunctional siloxane monomer units are tetrafunctional and consequently a level N of sufficiently crosslinked bonds so that after drying they are present as a rigid or hard film are considered to be silicone resins. The ratio of oxygen atoms to silicon atoms is indicative of the level of crosslinking in a specific silicone substance. Silicone substances having at least about 1: 1 oxygen atoms per silicon atom will be Here generally referred to as silicone resins. Preferably, the ratio of oxygen to silicon atoms is 29

1 5 10 15

Mod. 71-20,000 βκ. The materials used in the production of silicone resins include monomethyl-, dimethyl-, trimethyl-, monophosphene-1-carboxylic acid, Monovinyl and methylvinyl chlorosilanes, and tetrachlorosilanes, the substituents being substituted with the methyl groups most commonly used. Preferred resins are offered by General Electric as BE SS4E30 and SS4E67. Commercially available silicone resins are usually supplied in a form dissolved in a volatile or non-volatile silicone fluid of low viscosity. The silicone resins for use herein. invention should be provided and incorporated into the present compositions in this dissolved form, as will be apparent to those skilled in the art, Base material on materials, including sections discussing silicone fluids, gums and resins as well as the preparation of such icons can be found in the Encyclopedia of Polymorph Science and Engineering, Volume 15, Issue 4, pages 04-308, from John Miley & Sons, Inc., 1989 incorporated herein by reference. Silicone substances, and silicone resins in particular, can be identified in a convincing manner according to an abbreviated nomenclature system well known to those skilled in the art such as the nomenclature &quot; MDTQ &quot; According to this system, the silicone is described according to the presence of the various siloxane monomeric units constituting the silicone. Briefly, M represents the monofunctional unit (CHa) Si00> ss. D represents the difunctional moiety (CH 2) a SiO 2 represents the Trifunctional moiety &lt; CH 3) S, R 1 and R 5 is Q or a functional unit of the symbol units of the units with an apostrophe, , D ', T' and 0 '30 35 1 5 10 15

Mod. 71-20,000 ex. - 90 ^ 08 20 25 30

are other substituents which are non-methyl and need to be defined speci fi cally for each occurrence. Typical substituents include groups such as vinyl, phenols, hydroxyls, and the like. The molar ratio of the various units, either in terms of the indicia to the symbols indicating the total number of. each unit type in the silicon was one of its mean) or. in. For the purpose of the present invention, the present invention relates to a process for the preparation of a compound of the general formula (III): ## STR1 ## in which R 1, R 2 and R 3 are as defined above, , M and / or M 'on a silicone resin indicate higher crosslinking levels. As previously discussed, however, the overall level of crosslinked V bonds may also be indicated by the ratio of oxygen to silicon The silicone resins for use in this invention which are preferred are resins MG, MT, MTQ, MQ, and MDTQ. Thus, the preferred substituent is especially preferred are those resins in which the ratio MH is between about 0.5, 1.0 and about 1.5, 1.0, and wherein the weight The average molecular weight of the resin is between about 1000 and about 10,000. The weight ratio of the component consisting of non-volatile silicone fluid and the silicone resin component when used is between about 4: 1 and about 400: 1, this ratio being preferably between about 9: 1 to about And more preferably between about 19: 1 and about 100: 1, particularly when the silicone fluid component is to a fluid of the polydimethylsiloxane or a mixture of polydimethylsiloxane fluid to the polydimethylsiloxane gum as described above. 5 10 16 65386

Mod. 71 -20,000 e *. - 90/08 20 25 30

_____ Cajy ^ jog ____ a.ue "______ Ac tu como. The present invention relates to a shampoo composition of the present invention which contains as essential element a water soluble cationic organic polymer which acts as a hair conditioning agent. This polymer and cationic agent which acts as a hair conditioner will generally be present in these compositions at levels of from about 0.05% to about 5%, preferably from about 0.1% to about 5%, and still more preferably from about 0.2% to about 3%. % by weight of the shampoo composition. By "water soluble cationic organic polymer", what is meant is that there is a polymer which is sufficiently soluble in water to form a substantially clear solution (to a concentration of 0.1% in water (distilled or equivalent) at 25 ° C. Preferably, the polymer will be sufficiently soluble to form. a substantially clear solution at a concentration of 0.5%, and most preferably at a concentration of 1%. The cationic organic polymers useful in the hair conditioning agent of this invention are organic polymers which may provide benefits as hair conditioners and which are soluble in the shampoo compositions. Any cationic polymers which can provide these benefits may be used. the term &quot; polymer &quot; should include substances which are produced by polymerization of either a single type of monomer or two or more types of monomers, ie, copolymers). The cationic polymers of this invention will generally have a mean molecular mass which will be at least about of 5,000, typically at least about 10,000, and which is less than about 10 million. Preferably, at 32 35 10 16

Mod. 71-20,000 ex. Molecular weight &gt; about S million, it is estimated that around 100,000

The cationic polymers will have cationic nitrogen containing groups such as cationic amino or quaternary ammonium groups, or mixtures thereof. The cationic ketone density is at least about 0.9 meq / gram, more preferably at least about 1, 0 meq / gram, even more preferably at least about 1.1 meq / gram, more preferably at least about 1.2 meq / gram. The cationic charge density should not generally be greater than about , more preferably not more than about 30 meq / gram, more preferably not greater than about 2.0 meq / gram. The cationic charge density of the cationic polymer may be determined in accordance with These techniques will recognize that the charge density of the amino-containing polymers can vary depending on the pH and the isoelectric point of the amino groups. The charge density should be within the above limits at a pH of the use which will generally be of a pH of about 3 &amp; about 9, more generally from about pH 4 to about pH 8. Suitable counter-ions include the halides (e.g. Cl, Br, I, or F, preferably Cl, Br or I), sulfate, and melysulfate. Others may also be used since this list is not exclusive. The cationic group containing nitrogen will generally be present as a substituent in a fraction of the total monomeric units of the cationic polymers which act as hair conditioners. cationic polymer may include copolymers, terpolymers etc., of quaternary ammonia or monomeric units substituted with ammonia and other

10 15

Mod.? 1 - 20,000 ex. These polymers are known in the art, and various can be found in the CTFA Cosmetic Ingredient iV Dictionanv &quot; The appropriate cationic polymers include, for example, mannomer copolymers of the compounds of the formula (I) and the like, and the like. vinyl containing functional groups of amine amine or quaternary ammonia with water soluble spacing monomers such as acrylamide, methacrylamide, alkyl and dialkyl acrylamides, alkyl and ethers, alkyl acrylate, alkyl methiacyi, vinyl capro Xacton ,. and vinyl pyrrolidone. Preferred alkyl and dialkyl monomers preferably have Câ, -Câ, "alkyl groups and more preferably â € ƒâ € ƒâ € ƒâ € ƒâ € ƒâ € ƒâ € ƒâ € ƒ Other suitable spacing monomers include vinyl esters, vinyl alcohol obtained by the hydrolysis of polyvinyl acetate), maleic anhydride, propylene glycol, and ethylene glycol. Cationic amines may be primary, secondary, or In particular, the secondary amines are preferred, and in particular the tertiary amines. The amine-substituted vinyl monomers can be polymerized in the amine form. may optionally be converted into ammonia through a quaternization reaction. The amines may also be quaternized after formation of the polymer. For example, the functional groups may be quaternized by reaction with a salt. of formula E 'X in which E' is a lower alkyl group, preferably a C 1 -C 4 alkyl. and more preferably a Cy-Gg alkyl,

and X is an anion which forms a water-soluble salt with the quaternized ammonia. Suitable cationic ammonium and quaternary ammonium monomers include, for example, dialkylaminoalkyl acrylate-substituted vinyl compounds. . 1-methoxyethanol. trialkyl methacryloxyalkyl ammonium salt, trialkyl acryloxyalkyl ammonium salt, diallyl quaternary ammonium salts, and quaternary vinyl ammonium monomers ring-containing cationic nitrogen cyclic groups such as pyridinium, imidazolium and quaternized pyrrolidone, for example alkyl vinyl imidazolium, alkyl vinyl pyridinium, alkyl vinyl pyrrolidone salts. The alkyl portions of these monomers are preferably low molecular weight alkyl such as C1-6 alkyl Preferred vinylic monomers which are suitable for use in this invention include dienylaminoalkyl acrylate, dienylaminoalkyl acrylamide, dialkylaminoalkyl methacrylamide, dialkylaminoalkyl acrylamide, dialkylaminoalkyl acrylamide, dialkylaminoalkyl acrylamide, dialkylaminoalkyl methacrylamide, which ones alkyl groups are preferably C 1 -C 7 hydrocarbons, and most preferably C 1 -C 3 alkyls. The cationic polymers of this invention may be composed of mixtures of monomeric units derived from amine-substituted monomers. and / or quaternary ammonia and / or compatible spacer monomers. Suitable hair conditioning cationic polymers which are suitable for this invention include, for example, copolymers of 1-vinyl-S-pyrrolidone and the 1-vinyl-3-methylimidazolium salt (e.g., chloride salt) (referred to in the industry as Polyquaternium-16, by the Association of Cosmetics, Toilste Articles and Fragrances 35 1 65386

5 10 15

Mod. 71 -20,000 ex. 90 08 20 25 30 &quot; CTFA11), such as those commercially available from BASF Wjandolte Corp. (Parsippany, NJ, USA) under the trademark LUVIQUAT (for example, LiJVIGUAT FC 370), copolymers of i-vinyl-2-pyrrolidone and dimethylaminoethyl methacrylate (referred to in the art by CTFA as polyquaternium- those commercially available from Safff Corporation (Wayne, MJ, USA) under the trade name GAFQUAT (for example, GAFQUAT 755N) 5 polymers containing diallyl cationic quaternary ammonium, including, for example, homopolymer of dimethyldiallylammonium chloride and copolymers acrylamide and dimethyldiallylammonium chloride (CTFA) as Polyquaternium 6, Polyquaternium 7, and salts of aminoalkyl esters of homopolymer esters of unsaturated carboxylic acids having from 3 to 5 5 carbon atoms, as described in U.S. Patent No. 5,009,556, incorporated herein by reference. Other cationic polymers which may be used include polysaccharide polymers such as poly cationic cellulose derivatives and cationic starch derivatives. Suitable cationic polysaccharide polymers for use in this invention include those of the formulas wherein A is an anhydroglucose residual group , such as an anhydroglucose or starch residue. cellulose. 35 36

1 5 10 15

Mod. 71 -20,000 e *. R 90 is an alkylene oxyalkylene, polyxyalkylene, or hydroxyalkylene group, or the combination thereof; R 15 and R 33 are independently alkyl, aryl, alkyl, arylalkyl, alkoxyalkyl, or alkoxy groups containing each group up to 1 carbon atoms, a being the total number of carbon atoms. for each cationic group (i.e., the sum of carbon atoms in R1, RB and Ra), preferably about 10 or less, and: is anionic, as previously described. Cationic cellulose is commercially available from Americoi Corp. (Edison, NJ, USA) in its Polymer JR'R> s in the polymer chains LRtRI, as salts of hydroxyethylcellulose reacted with trimethyl ammonium substituted epoxide, referred to in the industry as Polyquaternium 10. Another type of cationic cellulose includes the polymeric quaternary ammonium salts of hydroxyethyl cellulose reacted with lauryl dimethyl ammonium substituted opioid, Polyamide) as Polyquaternium These substances are marketed by Amerchoi Corp. (Edison, NJ, USA) under the trademark Polymer Lil-EOO. Other cationic polymers which may be used include cationic guar gum derivatives such as chloride of guar hydroxypropyltrienium (commercially available from Celanese Corp. in its Jaguar &lt; RI series). Other substances include quaternary nitrogen-containing cellulose ethers (for example, as described in U.S. Patent 3,911,188 , incorporated herein by reference), and copolymers of etherified cellulose and starch (for example, as described in U.S. Patent 3,958,585 here. incorporated 37 30 10 15

Mod. 71-20,000 ex. - 90/08 20 25 30 35 65386

by reference). As discussed above, the cationic polymer. of this invention is water soluble. This does not mean, however, that it has to be soluble in the shampoo composition, however, preferably the cationic polymer is soluble in the shampoo composition or in a complex coacervata phase in the shampoo composition formed by the cationic polymer and the anionic substance. The complex coacervates of the cationic polymer may be formed with anionic surfactants or anionic polymers which may optionally be added to the compositions of this invention (for example, sodium polystyrene sulfate). The formation of coacervates is dependent upon various " N criteria such as molecular mass, concentration, and scission between the ionic substances that react with each other, ionic strength (including ionic strength changes, for example, by the addition of salts), charge density of cationic and anionic species , pH, and temperature. The coacervate systems and the effect of these parameters were previously studied. See, for example, J.Caelles et al., Anionic and Cationic Compounds in Mixed Systems, April 1991,

Cosmetics &amp; Tailetries, Volume 106, pages 49-543 of C, J, Van Oss &quot; coacervation, Complex Coacervation and Flocarlation &quot;, J. Dispersion Science and Technology, Volume 9 (5,6), 1988-89, pages 561-573, and DJ Burgess, "Practical Analysis of Complex Coacervate Systems &quot;, J. of Colloid and It is believed that it is particularly advantageous for the cationic polymer to be present in the shampoo in a coacerate phase, or to form a coacerate phase when &quot; ap ap- or when hair is removed by rinsing. The complex coacervates are believed to settle more rapidly on the hair. Thus, it is believed that the complex coacervates are more rapidly deposited on the hair. in general, it is preferred that the cationic polymer exists in the shampoo as a coacerate phase or that forms a coacerate phase when diluted. If a coacervata does not form in the shampoo, the cationic polymer will preferably exist in a complex form after dilution with water in a water-based shampoo shampoo composition of about 80 to 13 preferably 1 to about 10, and most preferably about 1! For example, microscopic analyzes of the shampoo compositions may be used in any dilution state to identify whether a coacerate phase has formed. This coacerate phase will be identifiable as an additional emulsifying phase in the composition. The use of pigments may assist in distinguishing between the coacervata phase and other dispersed insoluble phases in the composition. Examples of complex coacervate shampoo compositions are set forth in the Examples. Many other cationic polymers, depending on the other parameters of the &quot; shampoo composition &quot; can also form coacervates &quot; as will be understood by those skilled in the art. It will be appreciated that for compositions containing both an icon and an oily conditioner liquid (as described below), cationic polymer conditioning agents having a sufficiently high density cationic charge within the above range may provide cofactor formation and increased conditional capacity. "35 39 1 ób3Sé &gt;

5 10 15

Mod. 71-20,000 ex. - 90 (08 20 25 30 35

Oily Liquid Hair Conditioner Á? The shampoo compositions of the present invention include an oily, nonvolatile, and water-insoluble organic liquid as a third essential type of hair conditioning agent. The oily liquid which acts as a conditioner can provide shine and luster to the hair. In addition to this fact, it may also improve the hair styling when dry, and the sensation caused by dry hair. The liquid oily conditioner is typically present in the compositions at a level of from about 0.5% to about 5% by weight of the composition, preferably from about 0.1% to about 8%, and most preferably from about 0.5% to about 100%. By the term &quot; non-volatile &quot; it is meant that the oily substance exhibits a very low or no significant vapor pressure under ambient conditions (eg 1 atmosphere, 250C), as understood by those in the medium. Non-volatile oily compounds are preferably ft The term &quot; water insoluble &quot; is intended to mean that the oily liquid is not soluble in water (distilled or equivalent) at a temperature in the range of from about 0.degree. concentration of 0.1% and 25 The oily liquids which act as hair conditioners in this invention will generally have a viscosity of about 3 million centistokes or less, preferably about 2 million centistokes or less, and most preferably about 1, 5 million centistokes or less. The oily substances which act as hair conditioners in this invention are liquids.

selected from the group consisting of hydrocarbon oils and fatty esters. The fatty esters of this invention are characterized by having at least 10 carbon atoms and include esters with hydrocarbyl chains derived from alcohols or fatty acids, for example, mono esters, polyhydric alcohol esters. and esters of di- and tri-carboxylic acids. The radicals

The hydrocarbyl ester of the fatty esters of this invention may also include, or have them covalently bonded, other functional functional groups such as amide and alkoxy groups (e.g., ether or ethoxy bonds, and tc)

The hydrocarbon oils include cyclic hydrocarbons, straight chain (saturated or unsaturated) aliphatic hydrocarbons, and branched chain (saturated or unsaturated) aliphatic hydrocarbons. fsi

The straight chain hydrocarbon oils will preferably contain from about 1% to about 19 carbon atoms, although not necessarily the limit of the hydrocarbons in this range. The branched chain hydrocarbon oils typically may contain a greater number of ftf carbon atoms. Also included herein are polymeric hydrocarbons of alkenyl monomers, such as C6 -C6 alkenyl monomers. Such polymers may be straight or branched chain. Such linear chain polymers will typically be relatively small in length, has a total number of carbon atoms as described above for straight chain hydrocarbons in general. The branched chain polymers may have a substantially higher chain length. The number average molecular weight of such materials may vary widely but will be typically up to about 500, preferably from about 100 to 411 65386

5 10 15

Mod. 71-20,000 ex. - Examples of suitable substances include paraffin oil-mineral oil, saturated and unsaturated dodecane, saturated tridecane, and saturated unsaturated tridecane and unsaturated, saturated and unsaturated pentadecane, saturated and unsaturated hexadecane, and mixtures thereof. The branched chain isomers of these compounds, as well as those of hydrocarbons having a longer chain length, may also be used. Examples of such branched chain isomers the branched saturated or unsaturated alkanes such as the perimethyl-substituted isomers, for example, the pre-methyl substituted isomers of hexadecane and spixane, such as 2,2,4,4,6,6,8,8- diene-10-methylundecane. and 2,2,4,4,6,6, &quot; dimethyl-8-methylnonane, sold by Permethye Corporation. Polybutene is a preferred hydrocarbon polymer, such as the copolymer of isobutylene and butene. A commercially available material The esters of the monocarboxylic acids used in this invention include esters of alcohols and / or acids of the formula R'C00R in which the alkyl or alkenyl radicals and the alkoxy radicals of the present invention are polybutene 1-14 of Amoco Chemical Co. (Chicago, Illinois, USA) the sum of the carbon atoms in the R 'and R' is at least 10, preferably at least 20. Fatty esters include, for example, alkyl s alkenyl esters of fatty acids containing aliphatic chains with from about 10 to about 22 atoms and esters of alkyl to alkenyl fatty alcohols carboxylic acids having an alkyl and / or alkenyl chain derived from alcohol which is aliphatic and contains from about 10 to about 22 carbon atoms,

combinations. Examples include isopropyl isostearate, hexyl laureate, isohexyl laureate, isohexyl paitimitate, ispropyl palmitate, decyl oleate, isodecyl oleate, α-tolyl stearate, decyl stearate, isopropyl isostearate, dihexyl decyl adipate, lauryl lactate.

C6-C6 alkyl, cetyl lactate, oleyl stearate, oleyl 10 15

Mod. 71-20,000 ex. - 90/08 20 25 30 oleate ,. oleyl myristate, lauryl acetate, cetyl propionate, and oleyl adipate. Monocarboxylic acid esters, however, do not necessarily contain at least one chain of at least 10 carbon atoms, provided that the total number of carbon atoms in chains diisopropyl adipate, diisohexyl adipate, propyl isobutyl, di- and tri-alkyl and alkenyl esters of carboxylic acids. These include, for example, esters of C6 -C6 carboxylic acids such as C1 -C6 esters (preferably C1 -C6) esters of succinic acid, glutaric acid, adipic acid, hexanoic acid, heptanoic acid, and octanoic acid. Specific examples include propyl stearate, diisopropyl adipate, and triethylamine. The polyhydric alcohol esters include fatty acid esters, esters of propylene glycol, polypropylene glycol, 1-mannylmethylcellulose, and 1-mono- And polypropylene, polypropylene, polypropylene, polypropylene, polypropylene, polypropylene, polypropylene and polypropylene. 1 fatty acids, polyglycerol esters of polyglycerol, glyceryl ethoxyacetamide, 1,3-butylene glycol monostearate, 1,3-butylene glycol. diaryl ester, polyoxyethylene ester 43 35 1 ΰ · -

5 10 15

Mod. 71-20,000 ex. Fatty acid polyol esters, fatty acid esters of polyoxyethylene sorbitan fatty acid esters and polyhydric esters which are satisfactory for use in this invention. Glycerides include mono- &quot; di- and tricarboxylic acids. More specifically, they include mono- and di-esters of glycerol and long chain carboxymic acids, such as C 10 -C 20 carboxylic acids, Various substances of this type may be obtained from vegetable and animal fats such as beaver oil, safflower oil, cottonseed oil, corn oil, aseite, cod liver oil, oil of almond oil, avocado oil, palm oil, sesame oil, lanolin and soybean oil. Synthetic oils include triolein and tetrazole glieeryl dilaureate. Preferred glycerides are di- and triglycerides. Particularly preferred are triglycerides "

The shampoo compositions of the present invention are typically liquids which may preferably be poured at ambient temperature. The compositions of this invention contain an aqueous carrier , i.e., mare, which will generally be present at a level of about 0.05% to about 95% by weight of the composition, preferably from about 0.0% to about 85% for liquid N, V formulations. The compositions of the present invention may also have other forms, such as glycosides, etc. In these cases, suitable suitable components such as gelling agents (for example hydroxyethyl cellulose), etc., may be included in the compositions. The geysers typically contain from about 50% to about 90% water. The compositions are viscosity compositions.

Mod. 71-20,000 ex. - 70/08 20

65386 and reduced therein as a sprayable liquid, typically in a serous container 1 including a propellant or a means of producing a serous spray,

Since the conditioning agent constituted

As the icon used in the present compositions is composed of an insoluble silicone dispersed in the compositions, it is preferred to use an agent to facilitate the suspension of the silicone. Suitable suspending agents

N are long chain acyl derivatives, long chain amine oxides, and mixtures thereof, the suspending agents being present in the shampoo compositions in crystalline form. Several of these

ft The suspension is described in U.S. Patent 4,441,785, issued October 3, 1938, the ethylene glycol distearate is especially preferred.

Also included among the long chain acyl derivatives useful as suspending agents are N, N-di- b idr ogenado &gt; (Preferably C 18 -C 18 preferably C 14 -C 18) amido benzoic acid, or its soluble salt (for example, K, Na salts), particularly N, N-dihydrogenated tallow) amido acid benzoic acid which is marketed by Stepan Company CNorth, Illinois, USA) x

Other suspending agents useful for the

The silicone conditioner of the present invention is xanthan gum as described in U.S. Patent No. 4,878,006 to Bolich et al., issued June 5, 1984. The combination of bird derivatives with long chain and xenical rubber as a system for suspending the silicone is described in U.S. Patent No. 4,704,194 to Dh et al., issued November 3, 1987, 45

10 16

Mod. 71-20,000 ex. 90/08 20 25 30 may also be used in the compositions of this invention.

The invention-

Generally the shampoo compositions will contain from about 0.1% to about 5.0%, preferably from about 0.5% to about 3.0% of the suspending agent to suspend the conditioning agent constituted by si1icone.

Compositions The compositions of the present invention may also include various optional and non-essential shampoo components suitable to provide these compositions with cosmetic or cosmetic aspects which are acceptable or to provide additional benefits during use. Various ingredients are well known to those skilled in the art, and include, without limiting characterizing adjuvants to provide a pearl appearance, such as coated mica, and titanium dioxide diesterates, such as TiO-5 preservatives, such as benzyl alcohol, 1,3-bis (hydroxymethyl) -5,5-dimethyl-2,3-imidazo1,5-dodecanoic acid (for example, dimethyl sulfoxide), Slyco, Inc., Greenwich (E.g., Kathon (R), Rohm & Haas Co., Philadelphia, PA, USA), methyl paraben, propyl paraben and imidazoxythi urea, fatty alcohols such as cetearyl alcohol, and sodium stearyl alcohol, sodium chloride, ammonium chloride, sodium sulphate, ethyl alcohol, pH adjusting adjuvants, such as citric acid, sodium citrate, succinic acid, phosphonic acid,

Monosodium phosphate, sodium phosphate, sodium hydroxide, and sodium carbonate; coloring agents or pigments; perfumes; sequestering agents, such as tetra-ethyl acetate;

Another optional ingredient which can be obtained is

65386

Mod. 71-20,000 oc. The anti-static agent should not interfere in an unjustified way with the performance of the shampoo when in use, and with the anti-static agent. the final benefits of shampoo 5 in particular, the antistatic agent should not interfere with the detersive anionic surfactant. Suitable antistatic agents include, for example, tricetil methyl ammonium chloride. Typically, it is incorporated from about 0.5% to about 5% of this anti-static agent in the shampoos. Although the silicone suspending component may act to some extent as a thickener of the present invention, may also optionally contain other dispersants and viscosity modifiers such as ethanol amide and long chain fatty acid (for example, polyethylene (3) glycol lauramide and coconut monoethanolamide) and ammonium xylene sulfonate . These optional components are generally used individually in the compositions of the present invention at a level of from about 0.01% to about 10%, preferably from about 0.05% to about 5.0% of The composition of the shampoo is as follows: The compositions of the present invention, in general, may be prepared by mixing the various substances together at an elevated temperature, for example about 70 ° C, the silicone resin, if present, and the fluid component of silicone oils are mixed first before being mixed with the other ingredients. The other ingredients are added and the following ingredients are added: 47 1 5 10 15

Mod. 71-20,000 ex. - 90/08 20 25 ésb33é

The whole mixture is then carefully mixed at the elevated temperature and then pumped through a high shear mill and through a heat exchanger to cool it to room temperature. The average particle size of silicone is preferably in the range of about 0.3 microns to about 80 microns. Alternatively, the silicone-containing conditioning agent may be mixed with the anionic surfactant and as the fatty alcohol such as the cstyl and stearyl alcohols at elevated temperature to form a premix containing dispersed silicone. The premix may then be added and mixed with the remaining shampoo ingredients, V being pumped through a high shear mill, and cooled. Also alternatively, a portion of the liquid components or soluble components (including, for example, the conditioning agent comprised of the cationic polymer) may be added to the compositions upon cooling of the surfactant and solids mixture. The shampoo compositions of the present invention are used in a conventional manner, i.e. the hair is washed through the application of an effective amount of the shampoo composition over the head, and is then withdrawn with water. The application of the shampoo. to the head generally encompasses the massage or shampoo work on the hair so that all or most of the hair on the head is contacted. The term &quot; effective amount &quot; as used herein, is an amount that is effective in washing and conditioning the hair. Generally, from about 1 g to about 50 g of the lavage and conditioning composition is applied.

Mod. 71 · 20,000 ex. - 90/08 20 25 30 65386

Preferably, the shampoo is applied to the hair in a wet-wet state. The compositions of this invention may also be useful for washing and conditioning the skin. For such applications, the composition will be applied to the skin in a conventional manner, such as by wiping or massaging the skin with the composition, optionally in the presence of water, is then removed (rinsing) with water. EXAMPLES The following examples illustrate the present invention. It will be appreciated that further modifications of the present invention, within the knowledge of those involved in the art of formulation of hair treatments may be carried out without departing from the spirit and scope of the invention. All parts, percentages, and the reasons given herein are physical except where otherwise indicated. Some of the components may come from the suppliers as dilute solutions. The contents given reflect a mass percentage of the active substance, unless otherwise specified. The river .. ff excluded diluents and other substances are included in &quot; components Minaritários &quot;. Examples I j and ΛΓ A. The following composition is a shampoo composition ft. of the present invention.

Copanente s. Aur .1 1 Su fact of ammonia% Masica 8.5 35

Laureie131 Ammonium sulphate 49

CK 386

0.3 1, 0 S, 0 i? 0 0.5 2.0 0.2 1.0 0.6 0.4 to 100? - JAGUAR C-17 &quot;

Caco Honostanol amide Ethylene Glycol Diesterate Isocetii Stearoyl Stearate Triceyl Methyl Ammonium Chloride Purification Ammonium Chloride A ceo 1 ce tic Aromatic alcohol Perfume

Solution stained

Preservative?

Water and Minority Components (Trade Mark Name for hydroxypropylmethyl chloride an anionic polymer marketed by Rhone-Poulene (Branbury, NJ, USA) (A mixture having a mass ratio of 40/60 poly (SE SE 76, available from General Electric Co., Division of Silicone Products, Waterford, NY, USA) and polydimethylsiloxane fluid (about 350 centistokes). The composition may provide an excellent washing and conditioning of the hair, when used. As an alternative, JAGUAR C17 may be replaced by SUVIQUAT FC 370 (see Example III, note .1. &gt;

The following composition is a f-i shampoo composition of the present invention.

(S) Ammonium sulfate 13.2 P0LYMER LR 400 â † 'gt; 1.0 Coco Monoethanol amide 1.0 Ethylene Glycol Distearate-. 2 5 0 Light Mineral Oil 1.0 Clartrate of Trichloride Methion Ammonia 0 5 5 Powdered Isisoxane &lt; s &gt; 1.5 Ethyl Alcohol 0.4 Alkaline Sodium 0.2 Perfume 1.2 Colored Solution 0.6 Preservative 0.4 Water and Minority Components - up to 100%

Mod. 71-20,000 ex. - 90/08 α &gt; - Cellulose, S-E2 "hydraxy" 3- (triethyl ammonia) propa; 13 ethyl ether, chloride, a cationic polymer available from Amerchol Corp. (Edison, NJ USA), 25 (a) A mixture in the 40/60 mass ratio of polydimethylsilaxane gum (SE SE 76, available from the General Electric Co., Division of Silicon Products, Waterford NY, USA) and polyimethylsiloxane (about 350 centimeters). The composition when used may provide excellent hair washing and conditioning. example of a shampoo composition of the present invention in which the cationic polymer and the tannin-active-anionic component form a phase

5386 complex coscervata ,.

Please. % Hsical

LauriX Sulfate of Ammonia - 13.5

Laureth &lt; 3) Ammonium Sulphate 4.0 LUVIQUAT FC 37041 * 0.5

Coco Monoethanol Am.

Ethylene Glycol Distearate 8.0}

Oieo Light Mineral 0.5 Cl o to T e r. c s t i .1 M e t i 1 Ammonia 0.5

Po i id ime t i 1 s i o xan o &lt; s &gt; 3.0 cetyl alcohol 0.4 Stearyl Alcohol 0.2

Perfume 'i, 0

iV

Reduced Solution 0.6

Preservative 0.4 /

Water and Minority Components 73.8 u &gt; (Registered trademark of BASF Wyandotte Corporation, Paris, NJ, USA) for the copolymer of vinyl pyrrolidone and methyl vinyl chloride imidazolium,

tV &lt; s &gt; A blend in the 40/60 ratio of polydimethylsiloxane gum (GE SE 76, available from General Electric Co., Division of Water Products, Waterford, NY, USA) and polydimethylsiloxane fluid (about 350 centistokes)

When used, the composition can provide excellent washing of hair conditioning. As an aquiline triva, LUVXQUAT FC 370 may be replaced by JAGUAR C-17 (see example I, note I)., M: 52

10 15

Mod. 71 -20,000 = χ. - 90/08 20 05386

EXAMPLE IV

The segment is an example of a composition of

This call was given in advance "

Component Cocoamidopropyl betaine Laurete &lt; 3 &gt; Ammonium sulfate Coco Monoltanol Triamide Amide. Polymer JR-iS5m 1apos; -propionylpropionate 1methanol to trichloride chloride Methyl ammonium chloride 1id imethyl isohexane. 1 ic o Acoo 1 Estearí 1 ico Perfume Colourized solution Preservative Water and minor components% Cosmic 4oO 12 yOS, 0 Ξ yO 1, 0: i. , 0 and 5: t. , 50.4, s5. , 0 and y) 0 and 4 IUUa art 25 a> - Cellulose., E-EE-hydroxy-S-trimethyl ammonia, propoxyethyl ether chloride, available from Amerchol Corp. (Edison, MJ 5 USA) &lt; e) "VISCAS1L Silicone Fluid with Viscosity 1E.500 CS" available from General Electric (Waterford NJ, USA)

Example V 30

The following is an example of a composition of the present invention.

Compose

Laur 11 sul farto oe Amonxa 53 35 1

Laureteta &gt; 4 · Ammonia Sulphate, Polymer LM-SOO111 1.0! Oleo Light Mineral 1.0 Coca Manoetanol Amide Ml Ethylene Glycol Distearate 2.0 Tricetil Methyl Ammonium Chloride 0.5 P o l i d i m e t i s i. 1 oxa η o121 3.0 Cetyl alcohol 0.4 f Acoo1 Stearic acid ο, ε Perfume 1.0 IY Solution stained 0.6 Preservative 0.4 Water and minor components - up to 100% 15 (η ... po I a quaternary ammonium salt of hydroxyethyl cellulose reacted with euryxide substituted with lauryl dimethyl ammonia available from Amerchol Corp. (Edison, MJ, USA,

»V tS! A mixture in the 40/60 mass ratio of polydimethylsiloxane gum (SE SE, available from the Beeral

25

Electric Co., Division of Products of Sxlicone, Waterford, NY, USA) and polydimethylsiloxane fluid (about 350 c in t is to kes) *

The following composition is a shampoo composition of the present invention in which the cationic polymer and the active anionic surfactant form a complex cofactor phase. OxySymic

Ammonium Lauryl Sulfate 8.5 54 *

Laurete &lt; 3 &gt; Ammonia Sulphate 8.5 BAFGUAT 755N (1) 1 0.5 FLE X AN 130ta &gt; 0.5 Coco Honoethane1. Amide K1 Ethylene Glycol Distearate 2.0 1 Sodium Chloride 0.1 Trisilic Acid Chloride Ammonia 0.5% Polyoxyalkylene (ε), Cetyl Alcohol 0.4% Stearyl Alcohol 0 Perfume 1.0 Solution Reduced 0.6 Preserve 0.4 Water Minor components - up to 100 ° (1) 1-β-1-nitrobenzene-2-pyrrolidone and dimethylamino ethylmethacrylate copolymer, available from BAF Coro, Wargne, NJ, USA (a &gt; VISCASIL 60000 CS from General Electric, , Wa ter for d, NJ, USA "131 Sodium polystyrene sulfonate, an anionic polymer available from National Starch and Chemical Corp., Bridgenwater, NJ, USA.

N

When used, the composition can provide excellent hair washing and conditioning.

The compositions exemplified herein may be prepared by a pre-mixing of the total amount of silicon-containing conditioning agent to be incorporated into the shampoo together with ammonium sulfate and cetyl alcohol and ethanol sufficient. in such a way that the premix contains about 30% of the active agent having a carboxylic acid content of from 8% to 7% by weight of the active substance, % of the alcohols. The amounts of the pre- The mixture is stirred at 80 DEG C. for about 10 minutes, and the premix is conventionally mixed with the remaining hot ingredients (70 DEG C.). The cooled catalyst composition is then pumped through a ΛΓ Q e eieV8Clê3. 'ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ ύ

By THE PROCTER &amp; GAMBLE COMPANY

? A5 € 0 MARQUES UflC Official Affiliate «ie Industry Propnsds! Osrlóri © - Are® da Concelçè ·, 3, 1Λ-11ΘΦ iTjffH 56

Claims (1)

Ί- 6-5386 10 Mod. 71-20,000 ex. - 70/08 20 25 30 = R E I V I N D I C F E C E S = Λ · 1§ »· &quot; Composition of conditioning shampoo of the head characterized in that it contains from (a) from about 5% to 50% by weight of an anionic surfactant component selected from the group consisting of anionic surfactants and surfactant are anionic at the pH of the composition 5 (b) from about 0.05% to 10% by weight of a hair conditioning silicone agent, which is N dispersible and is insoluble, non-volatile and nonionic | (c) from 0.05% to 5% by weight of an organic and cationic polymeric agent, which as the hair conditioner is soluble in water having a cationic charge density of from about 0.9% grams at about 4 meq / gram (d) from about 0.05% to about 5% by weight of a nonvolatile organic liquid, is insoluble in water, selected from the group consisting of hydrocarbon oils and fatty esters with at least 10 carbon atoms, and mixtures thereof, and an aqueous carrier agent according to claim 1, characterized in that it additionally contains a suspending agent for said hair conditioning agent as a hair conditioner. The composition of hair conditioning shampoo according to claim 1 or 2, wherein said cationic polymer is M in one phase complex coacervata in said composition or form a coacervate complex after dilution of said Shampoo composition according to Claim 3, characterized in that said cationic polymer exists in a complex form after drying the shampoo with water at a water rate: V Shampoo composition according to Claim 1, characterized in that the component &lt; d) is selected from the group consisting of linear or branched chain hydrocarbon oils and fatty esters having at least about 10 carbon atoms, and mixtures thereof. The shampoo composition according to claim 5, wherein said component (d) has a viscosity of about (2 million cS) or less at about 50 ° C. - Shampoo composition according to claim 5, wherein said fatty esters are selected from the group consisting of fatty alkyl esters, alkyl esters and alkenyl esters of fatty alcohols, esters of polyhydric alcohols, esters of dicarboxylic acids, esters of A composition according to any one of the preceding claims, characterized in that said hair conditioning agent comprises a compound of the formula: ## STR1 ## wherein R 1 and R 2 are as defined above. po i id ime 1 s i. Shampoo composition according to claim 5, characterized in that said conditioning agent for the hair comprises a rubber blend of the formula (I). loxane and polydimethylsiloxane fluid. 1 * 5 10 15 Mod. 71-20,000 ex. - 90/08 20 25 30 35 Shampoo composition according to claim 1, characterized in that said cationic hair conditioning agent has a cationic density of from about 1.0 meq / grams to about of 3, 0 meq / grams and is selected from the group consisting of substituted ammonium and aminocarboxylic polymers and their amides. The shampoo composition according to claim 10, , characterized in that said hair conditioning cationic polymer is selected from the group consisting of cationic polysaccharides and polymers comprising vinyl ketone monomers. The composition of claim 1, , characterized in that said cationic polymeric hair conditioning agent is selected from the group consisting of cellulose and cationic, cationic amide, cationic guar, dialkylaminoalkyl acrylate, dialkyl chiral amine u i 1 ms ac r t 1 a t io n 1 1 u u 1 1 in u 1 1 u u 1 acrylatc? to 1 to 1 kiloalkylalkyl methacrylate trialkylmethacryloylkyalkyl ammonium salt, trialkyl acryloxyalkyl ammonium salt, diallyl quaternary ammonium salt, pyridinium, imidazole pyrrolidone quaternized, etc. The composition according to claim 1, Characterized in that said cationic polymeric hair conditioning agent is selected from the group consisting of cationic cellulose, cationic starch, cationic guar, copolymers of 1-vinylpyrrolidone and salts dimethyl diallyl ammonium salt, copolymers of 1-vinyl-3-methyl imidazolium, copolymers of acrylamide and dimethyl diallylammonium salts and copolymers of 1-vinyl-E-.beta.-p-rolidone and dimethylaminoethyl methacrylate Shampoo composition according to claim 7, characterized in that said hair conditioner cationic polymeric agent comprises polyvinylpyrrolidone and polyvinylpyrrolidone. Shampoo composition according to claim 14, characterized in that said cationic hair conditioning agent is selected from the group consisting of cationic polysaccharides and polymers comprising vinyl cationic monomers. Shampoo composition according to claim 15, characterized in that said cationic hair conditioning agent is selected from the group consisting of cationic cellulose, cationic starch, cationic guanine dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, monocarboxylic acid amine acrylate ammonium salt trialkyl acrylaminoalkyl, dialkyl quaternary ammonium salts, pyridinium, imidazolium, quaternized pyrrolidone, trialkyl methacryloxyalkyl ammonium salt, trialkyl acryloylmyalkyl ammonium salt. Shampoo composition according to claim 16, characterized in that it comprises from about 0.0% to about 25% anionic surfactants, from about 0.5% to about 5% of the silicone agent hair conditioner, from about 0.1% to about 4% of the cationic hair conditioning agent, from about 0.2% to about 3% of component (d). The hair conditioner W according to claim 1, wherein said cationic charge density is from about 1.0 meq / grams to about 3.0 meq / grams. Hair conditioning shampoo composition according to claim 18, characterized in that the composition of the hair conditioning shampoo according to any one of the preceding claims, wherein: - 20 * 08 20 25 30 The said cationic charge density is from about 1.1 ml / gram to about 1.0 mg / gram. The hair washing method, characterized in that the hair is applied in an amount The composition according to claim 1, for washing and conditioning the hair, followed by a hair dressing, for withdrawing said composition. applying to the hair an effective amount NN of the composition obtained according to claim 15, for washing and conditioning the hair, followed by rinsing, to remove therefrom said composition. an effective amount of the composition obtained according to claim 17 is applied to the hair to wash and condition the hair, followed by rinsing the hair, to remove therefrom said composition, By THE PROCT ER &amp; GAMBLE CQHPANY FASCO MARQUES 1HW * 9 '' '' '' - - - - - - - - - - - - - - - - - -