PT90771B - Processo para a preparacao de composicoes detergentes liquidas de elevada alcalinidade, para maquina automatica de lavar louca, contendo um agente tixotropico a base de argila - Google Patents

Processo para a preparacao de composicoes detergentes liquidas de elevada alcalinidade, para maquina automatica de lavar louca, contendo um agente tixotropico a base de argila Download PDF

Info

Publication number: PT90771B
Authority: PT; Portugal
Prior art keywords: composition; process according; weight; chlorine; clay
Prior art date: 1988-06-09

Application number

PT90771A

Other languages

English (en)

Portuguese (pt)

Other versions

PT90771A (pt

Inventor

Myriam Delvaux

Franco Angeli

Julien Drapier

Daniel Van De Gaer

Original Assignee

Colgate Palmolive Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-06-09

Filing date

1989-06-07

Publication date

1995-03-31

1989-06-07 Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co

1989-12-29 Publication of PT90771A publication Critical patent/PT90771A/pt

1995-03-31 Publication of PT90771B publication Critical patent/PT90771B/pt

Links

239000000203 mixture Substances 0.000 title claims abstract description 146
239000007788 liquid Substances 0.000 title claims abstract description 26
239000003599 detergent Substances 0.000 title claims description 39
238000000034 method Methods 0.000 title claims description 32
230000008569 process Effects 0.000 title claims description 22
239000003795 chemical substances by application Substances 0.000 title claims description 8
238000002360 preparation method Methods 0.000 title claims description 8
229910052751 metal Inorganic materials 0.000 claims abstract description 45
239000002184 metal Substances 0.000 claims abstract description 45
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 44
239000000460 chlorine Substances 0.000 claims abstract description 44
229910052801 chlorine Inorganic materials 0.000 claims abstract description 44
150000003839 salts Chemical class 0.000 claims abstract description 39
239000007844 bleaching agent Substances 0.000 claims abstract description 26
239000004927 clay Substances 0.000 claims abstract description 23
230000009974 thixotropic effect Effects 0.000 claims abstract description 21
150000004668 long chain fatty acids Chemical class 0.000 claims abstract description 14
239000002562 thickening agent Substances 0.000 claims abstract description 13
229910052782 aluminium Inorganic materials 0.000 claims abstract description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
239000011575 calcium Substances 0.000 claims abstract description 6
239000011777 magnesium Substances 0.000 claims abstract description 6
229910052791 calcium Inorganic materials 0.000 claims abstract description 5
229910052749 magnesium Inorganic materials 0.000 claims abstract description 5
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 4
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 45
-1 alkali metal tripolyphosphate Chemical class 0.000 claims description 32
239000000194 fatty acid Substances 0.000 claims description 32
235000014113 dietary fatty acids Nutrition 0.000 claims description 31
229930195729 fatty acid Natural products 0.000 claims description 31
239000006260 foam Substances 0.000 claims description 28
238000004140 cleaning Methods 0.000 claims description 24
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
150000001875 compounds Chemical class 0.000 claims description 19
150000004665 fatty acids Chemical class 0.000 claims description 19
239000002253 acid Substances 0.000 claims description 16
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 16
239000003381 stabilizer Substances 0.000 claims description 15
238000004061 bleaching Methods 0.000 claims description 12
238000005406 washing Methods 0.000 claims description 11
229910052783 alkali metal Inorganic materials 0.000 claims description 10
239000004115 Sodium Silicate Substances 0.000 claims description 9
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 9
150000008041 alkali metal carbonates Chemical class 0.000 claims description 9
239000006185 dispersion Substances 0.000 claims description 9
229910021647 smectite Inorganic materials 0.000 claims description 9
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 9
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 9
229910052911 sodium silicate Inorganic materials 0.000 claims description 9
235000019832 sodium triphosphate Nutrition 0.000 claims description 9
239000005708 Sodium hypochlorite Substances 0.000 claims description 8
125000004432 carbon atom Chemical group C* 0.000 claims description 8
239000000463 material Substances 0.000 claims description 8
239000013008 thixotropic agent Substances 0.000 claims description 8
125000000217 alkyl group Chemical group 0.000 claims description 7
229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
229910019142 PO4 Inorganic materials 0.000 claims description 6
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 5
229910052910 alkali metal silicate Inorganic materials 0.000 claims description 5
HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 5
238000005191 phase separation Methods 0.000 claims description 5
239000011701 zinc Substances 0.000 claims description 5
230000015572 biosynthetic process Effects 0.000 claims description 4
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 4
239000000084 colloidal system Substances 0.000 claims description 4
230000000737 periodic effect Effects 0.000 claims description 4
239000010452 phosphate Substances 0.000 claims description 4
229910052725 zinc Inorganic materials 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
150000001340 alkali metals Chemical class 0.000 claims description 3
229910052787 antimony Inorganic materials 0.000 claims description 3
229910052793 cadmium Inorganic materials 0.000 claims description 2
235000013539 calcium stearate Nutrition 0.000 claims description 2
239000008116 calcium stearate Substances 0.000 claims description 2
235000019359 magnesium stearate Nutrition 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
229910052718 tin Inorganic materials 0.000 claims description 2
229910052720 vanadium Inorganic materials 0.000 claims description 2
229910052726 zirconium Inorganic materials 0.000 claims description 2
125000005907 alkyl ester group Chemical group 0.000 claims 3
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 1
125000001931 aliphatic group Chemical group 0.000 claims 1
239000012141 concentrate Substances 0.000 claims 1
229910052742 iron Inorganic materials 0.000 claims 1
229910052748 manganese Inorganic materials 0.000 claims 1
229910052759 nickel Inorganic materials 0.000 claims 1
125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims 1
229910052719 titanium Inorganic materials 0.000 claims 1
239000010936 titanium Substances 0.000 claims 1
238000010936 aqueous wash Methods 0.000 abstract description 8
238000009472 formulation Methods 0.000 abstract description 8
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 abstract description 3
229910000271 hectorite Inorganic materials 0.000 abstract description 3
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract description 3
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 abstract description 2
229910052901 montmorillonite Inorganic materials 0.000 abstract description 2
239000004411 aluminium Substances 0.000 abstract 1
229960000892 attapulgite Drugs 0.000 abstract 1
229910052625 palygorskite Inorganic materials 0.000 abstract 1
239000004615 ingredient Substances 0.000 description 21
239000004094 surface-active agent Substances 0.000 description 18
238000004851 dishwashing Methods 0.000 description 13
235000011121 sodium hydroxide Nutrition 0.000 description 13
150000002739 metals Chemical class 0.000 description 11
239000000047 product Substances 0.000 description 10
239000011734 sodium Substances 0.000 description 9
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 8
239000004033 plastic Substances 0.000 description 8
229910052708 sodium Inorganic materials 0.000 description 8
239000000243 solution Substances 0.000 description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
239000000499 gel Substances 0.000 description 6
CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 5
238000003860 storage Methods 0.000 description 5
239000000126 substance Substances 0.000 description 5
229940063655 aluminum stearate Drugs 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
239000013256 coordination polymer Substances 0.000 description 4
238000005520 cutting process Methods 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
230000006872 improvement Effects 0.000 description 4
239000002609 medium Substances 0.000 description 4
238000002156 mixing Methods 0.000 description 4
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
229910052573 porcelain Inorganic materials 0.000 description 4
239000000843 powder Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
230000008901 benefit Effects 0.000 description 3
239000007853 buffer solution Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
230000005764 inhibitory process Effects 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 3
235000021317 phosphate Nutrition 0.000 description 3
239000000375 suspending agent Substances 0.000 description 3
239000003760 tallow Substances 0.000 description 3
235000013162 Cocos nucifera Nutrition 0.000 description 2
244000060011 Cocos nucifera Species 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
235000010469 Glycine max Nutrition 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
235000021355 Stearic acid Nutrition 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
150000008051 alkyl sulfates Chemical class 0.000 description 2
229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 2
150000008052 alkyl sulfonates Chemical class 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
229960003237 betaine Drugs 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
238000005238 degreasing Methods 0.000 description 2
210000003298 dental enamel Anatomy 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
239000000975 dye Substances 0.000 description 2
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
150000004687 hexahydrates Chemical class 0.000 description 2
VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
239000010451 perlite Substances 0.000 description 2
235000019362 perlite Nutrition 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
159000000001 potassium salts Chemical class 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
230000000087 stabilizing effect Effects 0.000 description 2
239000008117 stearic acid Substances 0.000 description 2
150000003462 sulfoxides Chemical class 0.000 description 2
235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
230000002087 whitening effect Effects 0.000 description 2
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
235000019737 Animal fat Nutrition 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
229910020630 Co Ni Inorganic materials 0.000 description 1
GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
244000068988 Glycine max Species 0.000 description 1
206010020751 Hypersensitivity Diseases 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
241001465754 Metazoa Species 0.000 description 1
229910019093 NaOCl Inorganic materials 0.000 description 1
239000005642 Oleic acid Substances 0.000 description 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
240000007594 Oryza sativa Species 0.000 description 1
235000007164 Oryza sativa Nutrition 0.000 description 1
235000021314 Palmitic acid Nutrition 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
229910010413 TiO 2 Inorganic materials 0.000 description 1
239000003082 abrasive agent Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
239000011149 active material Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000004520 agglutination Effects 0.000 description 1
229910001854 alkali hydroxide Inorganic materials 0.000 description 1
229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
230000007815 allergy Effects 0.000 description 1
229940037003 alum Drugs 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
229940083916 aluminum distearate Drugs 0.000 description 1
RDIVANOKKPKCTO-UHFFFAOYSA-K aluminum;octadecanoate;hydroxide Chemical compound [OH-].[Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O RDIVANOKKPKCTO-UHFFFAOYSA-K 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000002585 base Substances 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
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SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
229940077388 benzenesulfonate Drugs 0.000 description 1
229910052790 beryllium Inorganic materials 0.000 description 1
238000006065 biodegradation reaction Methods 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000003518 caustics Substances 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
239000012459 cleaning agent Substances 0.000 description 1
238000010954 commercial manufacturing process Methods 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
238000010411 cooking Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000001687 destabilization Effects 0.000 description 1
230000000368 destabilizing effect Effects 0.000 description 1
CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
UGMCXQCYOVCMTB-UHFFFAOYSA-K dihydroxy(stearato)aluminium Chemical compound CCCCCCCCCCCCCCCCCC(=O)O[Al](O)O UGMCXQCYOVCMTB-UHFFFAOYSA-K 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
235000021186 dishes Nutrition 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000428 dust Substances 0.000 description 1
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238000003379 elimination reaction Methods 0.000 description 1
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239000008233 hard water Substances 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
230000003165 hydrotropic effect Effects 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
230000007794 irritation Effects 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
230000007774 longterm Effects 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000011707 mineral Substances 0.000 description 1
150000004712 monophosphates Chemical class 0.000 description 1
ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 1
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
235000021313 oleic acid Nutrition 0.000 description 1
239000011368 organic material Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000002304 perfume Substances 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
239000000049 pigment Substances 0.000 description 1
238000005498 polishing Methods 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
235000021395 porridge Nutrition 0.000 description 1
150000003112 potassium compounds Chemical class 0.000 description 1
SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000012827 research and development Methods 0.000 description 1
230000000284 resting effect Effects 0.000 description 1
235000009566 rice Nutrition 0.000 description 1
235000021462 rice dishes Nutrition 0.000 description 1
239000004576 sand Substances 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
229910000275 saponite Inorganic materials 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
XFMZNMJZQJDSHM-UHFFFAOYSA-M sodium 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-phenylphenyl)phenyl]phenyl]phenyl]phenyl]phenyl]phenyl]phenyl]phenyl]phenyl]benzenesulfonate Chemical class [Na+].[O-]S(=O)(=O)c1ccccc1-c1ccccc1-c1ccccc1-c1ccccc1-c1ccccc1-c1ccccc1-c1ccccc1-c1ccccc1-c1ccccc1-c1ccccc1-c1ccccc1-c1ccccc1 XFMZNMJZQJDSHM-UHFFFAOYSA-M 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
235000019795 sodium metasilicate Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
GIPRGFRQMWSHAK-UHFFFAOYSA-M sodium;2-propan-2-ylbenzenesulfonate Chemical class [Na+].CC(C)C1=CC=CC=C1S([O-])(=O)=O GIPRGFRQMWSHAK-UHFFFAOYSA-M 0.000 description 1
238000010186 staining Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
230000008961 swelling Effects 0.000 description 1
TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
PBYVKELNSIHHMK-UHFFFAOYSA-K tetrasodium;2-[bis(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O PBYVKELNSIHHMK-UHFFFAOYSA-K 0.000 description 1
FEJQDYXPAQVBCA-UHFFFAOYSA-J tetrasodium;ethane-1,2-diamine;tetraacetate Chemical compound [Na+].[Na+].[Na+].[Na+].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.NCCN FEJQDYXPAQVBCA-UHFFFAOYSA-J 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Dispersion Chemistry (AREA)
Health & Medical Sciences (AREA)
Emergency Medicine (AREA)
Detergent Compositions (AREA)

PT90771A 1988-06-09 1989-06-07 Processo para a preparacao de composicoes detergentes liquidas de elevada alcalinidade, para maquina automatica de lavar louca, contendo um agente tixotropico a base de argila PT90771B (pt)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US20447688A	1988-06-09	1988-06-09

Publications (2)

Publication Number	Publication Date
PT90771A PT90771A (pt)	1989-12-29
PT90771B true PT90771B (pt)	1995-03-31

Family

ID=22758050

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PT90771A PT90771B (pt)	1988-06-09	1989-06-07	Processo para a preparacao de composicoes detergentes liquidas de elevada alcalinidade, para maquina automatica de lavar louca, contendo um agente tixotropico a base de argila

Country Status (14)

Country	Link
EP (1)	EP0345611B1 (da)
JP (1)	JPH0243300A (da)
AT (1)	ATE130028T1 (da)
AU (1)	AU3598789A (da)
BR (1)	BR8902755A (da)
CA (1)	CA1319308C (da)
DE (1)	DE68924727D1 (da)
DK (1)	DK284689A (da)
IL (1)	IL90481A0 (da)
MX (1)	MX169914B (da)
NO (1)	NO892361L (da)
NZ (1)	NZ229351A (da)
PT (1)	PT90771B (da)
ZA (1)	ZA894153B (da)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5279755A (en) *	1991-09-16	1994-01-18	The Clorox Company	Thickening aqueous abrasive cleaner with improved colloidal stability
US5346641A (en) *	1992-01-17	1994-09-13	The Clorox Company	Thickened aqueous abrasive cleanser with improved colloidal stability
JP2871941B2 (ja) *	1992-02-19	1999-03-17	ザ、プロクター、エンド、ギャンブル、カンパニー	カルシウムイオンを含有する硬質表面用水性洗剤組成物
CA2107938C (en) *	1993-01-11	2005-01-11	Clement K. Choy	Thickened hypochlorite solutions with reduced bleach odor and methods of manufacture and use
US5529711A (en) *	1993-09-23	1996-06-25	The Clorox Company	Phase stable, thickened aqueous abrasive bleaching cleanser
US5470499A (en) *	1993-09-23	1995-11-28	The Clorox Company	Thickened aqueous abrasive cleanser with improved rinsability
US5929008A (en) *	1997-09-29	1999-07-27	The Procter & Gamble Company	Liquid automatic dishwashing compositions providing high pH wash solutions
US20080108537A1 (en) *	2006-11-03	2008-05-08	Rees Wayne M	Corrosion inhibitor system for mildly acidic to ph neutral halogen bleach-containing cleaning compositions

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4752409A (en) *	1985-06-14	1988-06-21	Colgate-Palmolive Company	Thixotropic clay aqueous suspensions
US4801395A (en) *	1986-08-07	1989-01-31	Colgate-Palmolive Company	Thixotropic clay aqueous suspensions containing long chain saturated fatty acid stabilizers
NZ226289A (en) *	1987-09-29	1990-09-26	Colgate Palmolive Co	Gel-like aqueous dishwashing composition with sodium silicate and silica anti-filming agent

1989
- 1989-05-30 NZ NZ229351A patent/NZ229351A/en unknown
- 1989-05-30 DE DE68924727T patent/DE68924727D1/de not_active Expired - Lifetime
- 1989-05-30 AT AT89109765T patent/ATE130028T1/de not_active IP Right Cessation
- 1989-05-30 MX MX016249A patent/MX169914B/es unknown
- 1989-05-30 EP EP89109765A patent/EP0345611B1/en not_active Expired - Lifetime
- 1989-06-01 IL IL90481A patent/IL90481A0/xx unknown
- 1989-06-01 ZA ZA894153A patent/ZA894153B/xx unknown
- 1989-06-02 AU AU35987/89A patent/AU3598789A/en not_active Abandoned
- 1989-06-07 CA CA000602003A patent/CA1319308C/en not_active Expired - Fee Related
- 1989-06-07 PT PT90771A patent/PT90771B/pt not_active IP Right Cessation
- 1989-06-08 NO NO89892361A patent/NO892361L/no unknown
- 1989-06-09 DK DK284689A patent/DK284689A/da unknown
- 1989-06-09 BR BR898902755A patent/BR8902755A/pt not_active Application Discontinuation
- 1989-06-09 JP JP1148184A patent/JPH0243300A/ja active Pending

Also Published As

Publication number	Publication date
NZ229351A (en)	1992-07-28
ATE130028T1 (de)	1995-11-15
MX169914B (es)	1993-07-30
EP0345611A3 (en)	1990-12-12
JPH0243300A (ja)	1990-02-13
DE68924727D1 (de)	1995-12-14
EP0345611B1 (en)	1995-11-08
EP0345611A2 (en)	1989-12-13
IL90481A0 (en)	1990-01-18
DK284689D0 (da)	1989-06-09
AU3598789A (en)	1989-12-14
DK284689A (da)	1989-12-10
BR8902755A (pt)	1990-02-01
CA1319308C (en)	1993-06-22
ZA894153B (en)	1991-02-27
NO892361D0 (no)	1989-06-08
NO892361L (no)	1989-12-11
PT90771A (pt)	1989-12-29

Legal Events

Date

Code

Title

Description

1995-03-31

FG3A

Patent granted, date of granting

Effective date: 19940916

1996-07-31

MM3A

Annulment or lapse

Free format text: LAPSE DUE TO NON-PAYMENT OF FEES

Effective date: 19960331

Publication	Publication Date	Title
US4752409A (en)	1988-06-21	Thixotropic clay aqueous suspensions
US4857226A (en)	1989-08-15	Thixotropic clay aqueous suspensions containing polyacrylic acid polymer or copolymer stabilizers
PT85508B (pt)	1990-06-29	Processo para a preparacao de suspensoes aquosas fixotropicas a base de argilas contendo estabilizadores de acidos gordos saturados de cadeia longa
US4836946A (en)	1989-06-06	Thixotropic clay aqueous suspensions containing alkali metal fatty acid salt stabilizers
GB2176495A (en)	1986-12-31	Dishwasher detergent compositions
NZ204916A (en)	1985-11-08	Thixotropic,automatic dishwasher composition
PT88598B (pt)	1992-11-30	Processo para a preparacao de uma composicao detergente aquosa liquida tixotropica para lavagem automatica de louca contendo um agente anti-formacao de pelicula a base de silica
US4968445A (en)	1990-11-06	Thixotropic aqueous liquid automatic dishwashing detergent composition
US5089161A (en)	1992-02-18	Thixotropic aqueous liquid automatic dishwashing detergent composition
PT88563B (pt)	1992-11-30	Processo para a preparacao de um composicao de limpeza estruturada aquosa espessada, com nenhum ou pouco conteudo em fosfato contendo um zeolito de aluminossilicato
PT88871B (pt)	1993-01-29	Processo para a preparacao de uma composicao detergente liquida aquosa tixotropica para lavagem automatica de louca, contendo um agente anti-formacao de pelicula a base de silica
PT88929B (pt)	1993-01-29	Processo para a preparacao de uma composicao detergente, liquida aquosa tixotropica para lavagem automatica de louca, contendo um agente anti-formacao de pelicula a base de alumina ou de dioxido de titanio
PT90771B (pt)	1995-03-31	Processo para a preparacao de composicoes detergentes liquidas de elevada alcalinidade, para maquina automatica de lavar louca, contendo um agente tixotropico a base de argila
US5057237A (en)	1991-10-15	Thixotropic liquid automatic dishwasher detergent composition with improved physical stability
PT86717B (pt)	1992-04-30	Processo para a preparacao de suspensoes aquosas tixotropicas a base de argila contendo estabilizadores de sais de metal de acidos gordos e de polifostos de potassio
US4971717A (en)	1990-11-20	Aqueous liquid automatic dishwashing detergent composition with improved anti-filming and anti-spotting properties
AU616206B2 (en)	1991-10-24	Thixotropic aqueous liquid automatic dishwashing detergent composition