RS50043B - Proizvodi od aramidnih mikrovlakana otporni na prosecanje - Google Patents

Proizvodi od aramidnih mikrovlakana otporni na prosecanje

Info

Publication number
RS50043B
RS50043B YUP-144/01A YU14401A RS50043B RS 50043 B RS50043 B RS 50043B YU 14401 A YU14401 A YU 14401A RS 50043 B RS50043 B RS 50043B
Authority
RS
Serbia
Prior art keywords
cut
resistant
microfibers
resistant product
gloves
Prior art date
Application number
YUP-144/01A
Other languages
English (en)
Inventor
Johannes Manten
Original Assignee
Teijin Twaron Gmbh.,
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Twaron Gmbh., filed Critical Teijin Twaron Gmbh.,
Publication of YU14401A publication Critical patent/YU14401A/sh
Publication of RS50043B publication Critical patent/RS50043B/sr

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00—Armour; Armour plates
    • F41H5/02—Plate construction
    • F41H5/04—Plate construction composed of more than one layer
    • F41H5/0471—Layered armour containing fibre- or fabric-reinforced layers
    • F41H5/0478—Fibre- or fabric-reinforced layers in combination with plastics layers
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/442—Cut or abrasion resistant yarns or threads
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H1/00—Personal protection gear
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H1/00—Personal protection gear
    • F41H1/02—Armoured or projectile- or missile-resistant garments; Composite protection fabrics
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2904—Staple length fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2936—Wound or wrapped core or coating [i.e., spiral or helical]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer
    • Y10T428/2969—Polyamide, polyimide or polyester
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/298—Physical dimension

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Gloves (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Artificial Filaments (AREA)
  • Organic Insulating Materials (AREA)
  • Materials For Medical Uses (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Lubricants (AREA)
  • Wrappers (AREA)
  • Outer Garments And Coats (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Packages (AREA)
  • Knitting Of Fabric (AREA)
  • Woven Fabrics (AREA)

Abstract

Proizvod otporan na presecanje sastoji se od aromatskih poliamidnih mikrovlakana. Prijava sadrži još 6 zahteva.

Description

Pronalazak se odnosi na proizvode od aromatskih poliamidnih mikrovlakana otpornih na prosecanje.
Poznato je da se proizvodi otporni na prosecanje mogu izradjivati od aromatskih poliamidnih (poliaramidnih) vlakana. U DE 29713824 opisan je zaštitna rukavica obložena fleksibilnim aramidnim vlaknom. U WO 9721334 izloženi su sastavi materijala otpornih na probod u kojima su tkanja od aramidnih vlakana povezana sa polimernom celinom. Ovaj materijal je prvenstveno namenjen telesnim oklopima za zaštitu od balističkih projektila, ali je isto opisano da se materijali ovog sastava mogu koristiti protiv oštrih objekata, kao što su igle,noževi i slični, za rukavice, rukave, cipele i slično. Rukavice napravljene od poli(para-fenilen tereftalata) tkanja (p-aramidnog tkanja) su komercijalno raspoložive, naprimer, pod imenom Tv/aron® siguronosne rukavice.
I pored toga Sto su ovi proizvodi, posebno rukavice, korisne u mnogim slučajevima, i dalje postoji potreba za poboljšanjima. Ovakva poboljšanja podrazumevaju veću otpornost prema proboju i prosecanju od strane oštrih objekata, kao što su igle, noževi i slično, ali i poboljšanje komfora nošenja, slobode kretanja i povećanje elastičnosti, što su već dugo tražena poboljšanja.
Sada je pronadjeno da se predmeti otporni na prosecanje, sa poboljšanim osobinama u poredjenju sa poznatim proizvodima, mogu ostvariti koristeći mikrovlakna od aromatskog poliamida (poliaramida).
Mikrovlakna od aromatskih poliamida, kakva su poznata , naprimer iz EP 241681, gde su proizvodi napravljeni od poliaramidnih vlakana objavljeni za korišćenje u odeći koja se koriste za zaštitu od balističkih projektila. Ipak, za proizvode napravljene od poliaramidnih vlakana nije poznato da imaju poboljšane osobine u odnosu na otpornost protiv prosecanja i komfor nošenja.
Sadašnji pronalazak se zato odnosi na proizvode napravljene od poliaramidnih vlakana, a posebno na rukavice, rukave i zaštitnu odeću od prosecanja, u opštem slučaju. Mogu se koristiti tkanine, tkanja ili valjani materijali. Da bi se poboljšale performanse može se primeniti više slojeva, i, ako se zahteva, dodatni slojevi od različitog materijala, naprimer, metaliziranih materijala, zbog dodatne zaštite od toplote.
Aromatski poliamid (poliaramid) može biti bilo koji aromatski poliamid, kao što je dobijen polimerizacijom jednog aromatskog diamina i aromatskog di-acid hlorida. Više se preporučuju para-aromatski poliamidi, a najviše se preporučuje poli (para-fenilen tereftalat) (PPD-T), koji se može dobiti iz p-fenilendiamina i tereftalol hlorida.
Aromatski poliamid je upreden u mikrovlakna na način koji je poznat u struci i upredeno vlakno se može koristiti kao vlaknasto predivo, elastično predivo ili, što je još bolje, upredeno tkanje vlaknaste gradje. Upredeno tkanje, prema ovom pronalasku, može se napraviti bilo kojim odgovarajućim procesom predenja, izmedju kojih se mogu navesti oni procesi predenja, kao što su kružni sistemi za predenje i otvoreni procesi predenja za pamuk, češljanu vunu i vunu. Ako se koriste vlaknasta gradja za proizvodnju proizvoda otpornih na prosecanje, preporučuju se da se koriste vlakna dužine izmedju 38 i 100 mm.
Mikrovlakna imaju finoću od najmanje 1,3 dteksa (l^lO""<4>, g/m) ili još povoljnije manju od vrednosti jednake ili manje od 1,0 dteksa (10"<*>, g/m).
Proizvodi otporni na prosecanje, prema ovom pronalasku, kao što su rukavice, proizvedeni su, naprimer, iz prediva dobijenih upredanjem aromatskih poliamidnih mikro-vlakana.
Prediva, prema sadašnjem pronalasku, su otpornija na prosecanje u poredjenju sa standardnim predivom sa finoćom iznad 1,3 dteksa (1,3x10^, g/m). Ako su rukavice napravljene od ovih mikro-vlakana, rukavice imaju bolji konfor nošenja u poredjenju sa rukavicama sa standardnim vlaknima Rukavice napravljene od ovih mikro-vlakana su elastičnije i time omogućavaju korisniku dobar komfor nošenja. Zbog toga su ove rukavice takodje izvanredne za ispunjavanje postavljenih zahteva .
Pronalazak je nadalje ilustrovan sledećim eksperimentima.
Uporedjivani su upredeni uzorci od standardnog ispredenog prediva i od ispredenog prediva od mikro-vlakana. Otpornost na prosecanje je utvrdjivana na osnovu standarda DIN EN 388:
Zaključak : najmanji indeks je veći za predivo od mikrovlakana, nego za standradno predivo. Performanse su uvek bolje za predivo od mikrovlakana. Tamo gde su vrednosti performansi istog broja prema DIN EN 388, standardni uzorak je na donjoj granici, a uzorak mikro-vlakana na gornjoj granici nivoa performansi.
Štaviše, ispredena tkanina od mikro.vlakana je mnogo mekša i imaju finiju "ruku" u poredjenju sa tkaninom od standardnih vlakana sa 1,7 dteksa.
Dodatno su ispitivane mehaničke karakteristike prediva od mikro.vlakana i standardnih vlakana. Kao što se može uočiti iz donjih tablica otpornost je osetno poboljšana za predivo od mikro-elemenata Veruje se da je veća otpornost na istezanje prediva od mikro-elemenata odgovorna za poboljšanu otpornost na prosecanje tkanina napravljenih od mikro-elemenata. Elastičnost je odredjena prema DIN 53362. Elastičnost, označena savojnom krutošću, je mera za " zahvat" i elastičnost rukavica.
Zaključak : Otpornost je znatno poboljšana za vlaknastu gradju od mikrovlakana , pri čemu je u svim slučajevima utvrdjena poboljšana savojna krutost rukavica napravljene od mikro-vlakana.

Claims (7)

1. Proizvod otporan na prosecanje sastoji se od aromatskih poliamidnih mikrovlakana
2. Proizvod otporan na prosecanje, prema Zahtevu 1, sastoji se od para-aramidnih mikrovlakana.
3 Proizvod otporan na prosecanje, prema Zahtevu 2, sastoji še od poh(para-fenilen terftalata) mikrovlakana.
4. Proizvod otporan na prosecanje, prema bilo kom od Zahteva 1-3, naznačen je time, što je finoća mikro-vlakana jednaka ili manja od 1,3 dteksa (1,3 . IO"4, g/m).
5. Proizvod otporan na prosecanje, prema bilo kom od Zahteva 1-4, naznačen je time, što si mikro-vlakna u obliku vlaknaste gradje dužine izmedju 38 i 100 mm.
6. Proizvod otporan na prosecanje, prema bilo kom od Zahteva 1-4, naznačen je time, što su mikrovlakna u obliku elastičnog prediva ili prediva od veoma dugačkih vlakana.
7. Proizvod otporan na prosecanje, prema bilo kom od Zahteva 1-6, naznačen je time, što je proizvod ruklavica.
YUP-144/01A 1998-08-07 1999-07-06 Proizvodi od aramidnih mikrovlakana otporni na prosecanje RS50043B (sr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP98202659 1998-08-07

Publications (2)

Publication Number Publication Date
YU14401A YU14401A (sh) 2003-07-07
RS50043B true RS50043B (sr) 2008-11-28

Family

ID=8234015

Family Applications (1)

Application Number Title Priority Date Filing Date
YUP-144/01A RS50043B (sr) 1998-08-07 1999-07-06 Proizvodi od aramidnih mikrovlakana otporni na prosecanje

Country Status (20)

Country Link
US (1) US6829881B1 (sr)
EP (1) EP1099088B1 (sr)
JP (1) JP2002522658A (sr)
CN (1) CN1093252C (sr)
AT (1) ATE236383T1 (sr)
AU (1) AU760746B2 (sr)
BR (1) BR9912863B1 (sr)
CA (1) CA2345048C (sr)
CZ (1) CZ2001491A3 (sr)
DE (1) DE69906535T2 (sr)
DK (1) DK1099088T3 (sr)
ES (1) ES2192065T3 (sr)
HU (1) HU223636B1 (sr)
PL (1) PL190170B1 (sr)
RS (1) RS50043B (sr)
RU (1) RU2001106648A (sr)
SI (1) SI1099088T1 (sr)
SK (1) SK1982001A3 (sr)
TR (1) TR200100619T2 (sr)
WO (1) WO2000008410A1 (sr)

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US6694719B2 (en) * 2001-08-21 2004-02-24 E. I. Du Pont De Nemours And Company Cut resistant yarns and process for making the same, fabric and glove
US8418262B2 (en) 2003-01-27 2013-04-16 Ross M. Angus Body armour protection system protective hockey undershirt
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FR2904009B1 (fr) * 2006-07-21 2008-09-12 Schappe Sa Sa Fil destine a la confection d'une surface textile resistant a la coupure et a l'abrasion
WO2008017400A1 (de) * 2006-08-11 2008-02-14 Teijin Aramid Gmbh Stapelfasergarn, textiles flächengebilde umfassend das stapelfasergarn und artikel umfassend das textile flächengebilde
US7638193B1 (en) 2006-10-10 2009-12-29 E. I. Du Pont De Nemours And Company Cut-resistant yarns and method of manufacture
US7767599B2 (en) * 2006-10-10 2010-08-03 E.I. Du Pont De Nemours And Company Multidenier fiber cut resistant fabrics and articles
EP2235244B1 (de) 2008-01-10 2012-09-26 Teijin Aramid GmbH Verfahren zur Herstellung eines textilen Artikels unter Verwendung eines Stapelfasergarns und textiler Artikel
US8640263B2 (en) * 2010-11-30 2014-02-04 Adidas Ag Glove having enhanced thumb crotch padding
US9409078B2 (en) * 2010-11-30 2016-08-09 adidas, AG Sports glove with 3-dimensional finger portion
EP4541588A3 (en) 2016-09-09 2025-07-09 Kevin M. Sorrels Protective gloves and method of making protective gloves

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Also Published As

Publication number Publication date
CN1093252C (zh) 2002-10-23
HU223636B1 (hu) 2004-10-28
SI1099088T1 (en) 2003-08-31
DE69906535T2 (de) 2003-11-20
AU760746B2 (en) 2003-05-22
US6829881B1 (en) 2004-12-14
SK1982001A3 (en) 2001-11-06
JP2002522658A (ja) 2002-07-23
EP1099088A1 (en) 2001-05-16
CZ2001491A3 (cs) 2002-05-15
EP1099088B1 (en) 2003-04-02
CA2345048C (en) 2006-11-14
DE69906535D1 (de) 2003-05-08
PL345892A1 (en) 2002-01-14
BR9912863B1 (pt) 2008-11-18
WO2000008410A1 (en) 2000-02-17
TR200100619T2 (tr) 2001-06-21
ES2192065T3 (es) 2003-09-16
CN1319175A (zh) 2001-10-24
ATE236383T1 (de) 2003-04-15
AU5158999A (en) 2000-02-28
HUP0103018A2 (hu) 2001-12-28
HUP0103018A3 (en) 2002-11-28
RU2001106648A (ru) 2003-05-20
CA2345048A1 (en) 2000-02-17
BR9912863A (pt) 2001-05-02
DK1099088T3 (da) 2003-07-21
YU14401A (sh) 2003-07-07
PL190170B1 (pl) 2005-11-30

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