RS62045B1 - Device for cooling products - Google Patents

Device for cooling products

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Publication number
RS62045B1
RS62045B1 RS20210820A RSP20210820A RS62045B1 RS 62045 B1 RS62045 B1 RS 62045B1 RS 20210820 A RS20210820 A RS 20210820A RS P20210820 A RSP20210820 A RS P20210820A RS 62045 B1 RS62045 B1 RS 62045B1
Authority
RS
Serbia
Prior art keywords
product
cyclone
pressure
coolant
rear part
Prior art date
Application number
RS20210820A
Other languages
Serbian (sr)
Inventor
Jean Michel Castel
Florian Follut
Emir Tebib
Original Assignee
Messer France Sas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Messer France Sas filed Critical Messer France Sas
Publication of RS62045B1 publication Critical patent/RS62045B1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D3/00Devices using other cold materials; Devices using cold-storage bodies
    • F25D3/10Devices using other cold materials; Devices using cold-storage bodies using liquefied gases, e.g. liquid air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2400/00Component parts or details not otherwise provided for in this subclass
    • F25B2400/02Centrifugal separation of gas, liquid or oil

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)

Description

Opis Description

[0001] Pronalazak se odnosi na uređaj za hlađenje proizvoda, sa ciklonom koji ima kućište sa kružnim cilindričnim zadnjim delom i susednim prednjim delom konusnog oblika, pri čemu je na gornjoj čeonoj strani zadnjeg dela koja se nalazi nasuprot prednjeg dela postavljen poklopac sa odvodom za izlaz gasova koji je koncentrično izveden kroz njega, i pruža se u unutrašnjosti ciklona odvojeno od poklopca sa kružnim otvorom za odvod gasova, sa dovodnom mlaznicom povezanom sa napojnim vodom kriogenog sredstva za hlađenje, koja se tangencijalno uliva u zadnji deo u području gornje čeone strane, i najmanje jednim napojnim vodom za proizvod koji treba hladiti koji se uliva u zadnji deo. [0001] The invention relates to a device for cooling products, with a cyclone that has a housing with a circular cylindrical rear part and an adjacent front part of a conical shape, wherein on the upper front side of the rear part, which is opposite the front part, a cover is placed with a drain for the exit of gases that is concentrically carried out through it, and is provided in the interior of the cyclone separately from the cover with a circular opening for the discharge of gases, with an inlet nozzle connected to the supply water of the cryogenic agent for cooling, which flows tangentially into the rear part in the area of the upper face, and at least one feed water for the product to be cooled, which flows into the rear part.

[0002] Tečni, kremasti ili praškasti proizvodi, posebno životne namirnice, kao filovi za kolače, sosovi i marinade, koji se proizvode na visokoj temperaturi, često moraju nakon proizvodnje brzo da se ohlade, na primer, da bi se sačuvala unutrašnja struktura proizvoda ili da bi se suzbio rast bakterija. Hlađenje, na primer, može da se izvede pomoću električnih klasičnih uređaja za hlađenje, ali je to povezano sa velikom potrošnjom energije. Alternativa je direktan kontakt proizvoda koji se hladi sa kriogenim rashladnim sredstvom. Rashladno sredstvo preuzima deo toplote proizvoda i zatim isparava ili sublimira bez ostatka. [0002] Liquid, creamy or powdered products, especially foodstuffs, such as fillings for cakes, sauces and marinades, which are produced at high temperature, often have to be cooled quickly after production, for example, to preserve the internal structure of the product or to suppress the growth of bacteria. Cooling, for example, can be done using electric conventional cooling devices, but this is associated with high energy consumption. An alternative is direct contact of the product being cooled with a cryogenic refrigerant. The refrigerant absorbs part of the heat of the product and then evaporates or sublimates without the rest.

[0003] Pod „kriogenim rashladnim sredstvom“ u nastavku se podrazumevaju takvi tečni, čvrsti ili gasoviti medijumi koji prilikom kontakta sa proizvodom koji se hladi imaju temperaturu -20°C i nižu. Posebno, kriogeno rashladno sredstvo je utečnjeni gas, kao, na primer, tečni azot, ili ugljen dioksid u čvrstom ili tečnom obliku. [0003] By "cryogenic refrigerant" in the following, we mean such liquid, solid or gaseous media which, when in contact with the product being cooled, have a temperature of -20°C and lower. In particular, the cryogenic refrigerant is a liquefied gas, such as, for example, liquid nitrogen, or carbon dioxide in solid or liquid form.

[0004] Prilikom primene ugljen dioksida kao kriogenog rashladnog sredstva, on se uobičajeno uvodi u tečnom obliku pod pritiskom većim od 5,18 bar, i na jednoj mlaznici, takozvanoj ekspanzionoj mlaznici, otpušta se na atmosferski pritisak (1 bar). Pri tome se ugljen dioksid hladi na temperaturu od minus 78,9°C (194 K), pri čemu nastaje smeša suvog leda i hladnog gasovitog ugljen dioksida. Zatim se barem čestice ugljen dioksida koriste za hlađenje proizvoda, i, na primer, nanose se na površinu proizvoda koji se hladi, ili se, u slučaju tečnog, kremastog ili praškastog proizvoda, pomešaju sa proizvodom. [0004] When using carbon dioxide as a cryogenic refrigerant, it is usually introduced in liquid form under a pressure greater than 5.18 bar, and on one nozzle, the so-called expansion nozzle, it is released to atmospheric pressure (1 bar). In doing so, carbon dioxide is cooled to a temperature of minus 78.9°C (194 K), whereby a mixture of dry ice and cold gaseous carbon dioxide is formed. Then at least the carbon dioxide particles are used to cool the product, and, for example, are applied to the surface of the product to be cooled, or, in the case of a liquid, cream or powder product, are mixed with the product.

[0005] Iz patenta EP 1734320 A2 poznat je uređaj, kod koga se proizvod koji se hladi, koji može da se pumpa, i kriogeno rashladno sredstvo, kao, na primer, tečni azot, tečni ugljen dioksid, tečni argon ili tečni vazduh, dovode u kontakt u vrtložnom pužnom hladnjaku i temeljno se mešaju. Smeša se zatim odvodi u separator, gde se izvlači ispareno kriogeno rashladno sredstvo. Ohlađeni proizvod je onda spreman za preradu u daljem postupku, ili za pakovanje. [0005] From the patent EP 1734320 A2 a device is known, in which the product to be cooled, which can be pumped, and a cryogenic refrigerant, such as, for example, liquid nitrogen, liquid carbon dioxide, liquid argon or liquid air, are brought into contact in a vortex screw cooler and thoroughly mixed. The mixture is then led to a separator, where the vaporized cryogenic refrigerant is extracted. The cooled product is then ready for further processing or packaging.

[0006] Iz WO 2005/053440 A1 poznat je uređaj za hlađenje tečnih proizvoda, pri čemu se u sud napunjen proizvodom koji se hladi dovodi kriogeno rashladno sredstvo, na primer, tečni azot ili tečni ugljen dioksid. Rashladno sredstvo isparava pri termičkom kontaktu sa proizvodom i izvlači se iz gornjeg dela posude. Nakon postupka hlađenja, rashlađeni proizvod se odvodi preko voda koji se priključuje na dnu posude. [0006] From WO 2005/053440 A1, a device for cooling liquid products is known, whereby a cryogenic refrigerant, for example, liquid nitrogen or liquid carbon dioxide, is introduced into the container filled with the product to be cooled. The coolant evaporates on thermal contact with the product and is extracted from the upper part of the container. After the cooling process, the cooled product is drained through the water that is connected at the bottom of the container.

[0007] Patent WO 2016/060869 A1 odnosi se na uređaj za hlađenje tečnih namirnica, na primer, sosova. Kod ovog predmeta, proizvod se sprovodi kroz cevovod na kome postoji jedno ili više mesta na kojima se uvodi kriogeno rashladno sredstvo, na primer, tečni azot. Međutim, konstrukcija opisanog uređaja je veoma složena, posebno zato što je za rashladno sredstvo, koje se brzo širi prilikom isparavanja, potrebna konstrukcija cevovoda stabilna pri pritisku. [0007] Patent WO 2016/060869 A1 relates to a device for cooling liquid foods, for example, sauces. In this subject matter, the product is carried through a pipeline in which there are one or more places where a cryogenic refrigerant, for example, liquid nitrogen, is introduced. However, the construction of the described device is very complex, especially because the refrigerant, which expands rapidly during evaporation, requires a pressure-stable pipeline construction.

[0008] U EP 3234 485 A1 opisan je postupak, u kome se proizvod koji se hladi, u ciklonu dovodi u kontakt sa ekspandovanim ugljen dioksidom. Dobija se smeša čvrstih čestica ugljen dioksida i proizvoda, koja se odvodi preko izlaznog otvora postavljenog na dnu ciklona. Samo kratak kontakt proizvoda i čestica ugljen dioksida dovodi samo do srazmerno slabog hlađenja proizvoda. [0008] EP 3234 485 A1 describes a process in which the cooled product is brought into contact with expanded carbon dioxide in a cyclone. A mixture of solid particles of carbon dioxide and products is obtained, which is discharged through the exit hole placed at the bottom of the cyclone. Only a short contact between the product and the carbon dioxide particles leads to only a relatively weak cooling of the product.

[0009] Patent DE 102014 018981 A1 takođe se odnosi na postupak za proizvodnju pothlađenog suvog leda, pri čemu se tečni ugljen dioksid preko ekspanzione mlaznice uvodi u ekspanzionu komoru, gde se širi uz nastajanje smeše gasovitog ugljen dioksida i suvog leda, i na kraju se smeša razdvaja na fazu koja pretežno sadrži suvi led, kao i na fazu koja pretežno sadrži gasoviti ugljen dioksid. [0009] Patent DE 102014 018981 A1 also refers to a process for the production of subcooled dry ice, whereby liquid carbon dioxide is introduced into the expansion chamber through an expansion nozzle, where it expands with the formation of a mixture of gaseous carbon dioxide and dry ice, and finally the mixture is separated into a phase that mainly contains dry ice, as well as a phase that mainly contains gaseous carbon dioxide.

[0010] Zato pronalazak ima za cilj da naznači efikasnu mogućnost, jednostavnu za rukovanje, za hlađenje tečljivih, posebno tečnih ili praškastih proizvoda. [0010] Therefore, the invention aims to indicate an efficient possibility, easy to handle, for cooling liquid, especially liquid or powder products.

[0011] Ovaj zadatak je rešen pomoću uređaja sa karakteristikama iz zahteva 1, i postupka uz primenu uređaja prema pronalasku sa karakteristikama iz zahteva 5. [0011] This task is solved by means of a device with the characteristics of claim 1, and a method with the application of the device according to the invention with the characteristics of claim 5.

[0012] Pogodna otelotvorenja su data u podzahtevima. [0012] Suitable embodiments are provided in the subclaims.

[0013] Prema pronalasku, uređaj pomenute vrste i svrhe takođe je naznačen time što je izlazni otvor prednjeg dela protočno povezan sa vodom za odvođenje proizvoda za rashlađeni proizvod, u kome se nalazi sredstvo za stvaranje kontrapritiska koji se suprotstavlja pritisku protoka proizvoda koji ističe iz voda za odvođenje proizvoda. [0013] According to the invention, the device of the mentioned type and purpose is also characterized by the fact that the outlet opening of the front part is fluidly connected to the product drain for the cooled product, in which there is a means for creating a counter-pressure that opposes the pressure of the product flow coming out of the product drain.

[0014] Uređaj prema pronalasku tako obuhvata ciklon, čije kućište na poznat način ima cilindrični zadnji deo i susedni prednji deo konusnog oblika, koji se uliva u izlazni otvor. Na gornjoj čeonoj strani zadnjeg dela koja se nalazi nasuprot prednjeg dela postavljen je poklopac sa odvodom za izlaz gasova koji je koncentrično izveden kroz njega i pruža se u unutrašnjosti ciklona odvojeno od poklopca sa kružnim otvorom za odvod gasova (naziva se i imerziona cev). Ciklon obično stoji uspravno, pri čemu je izlazni otvor prednjeg dela postavljen naniže a otvor za odvod gasova naviše. U zadnji deo ciklona tangencijalno se uliva napojni vod za rashladno sredstvo koji je sa čeone strane snabdeven otvorom mlaznice. [0014] The device according to the invention thus includes a cyclone, the housing of which, in a known manner, has a cylindrical rear part and an adjacent conical front part, which flows into the outlet opening. On the upper front side of the rear part, which is located opposite the front part, there is a cover with a drain for the exit of gases, which is concentrically made through it and extends inside the cyclone separately from the cover with a circular opening for the discharge of gases (also called an immersion tube). The cyclone usually stands upright, with the outlet of the front part placed downwards and the outlet of the gas discharge upwards. In the rear part of the cyclone, the supply line for the coolant is tangentially fed, which is provided with a nozzle opening on the front side.

Nadalje, u zadnji deo se uliva napojni vod za dovod proizvoda koji se hladi. Na primer, napojni vod za proizvod se uliva suštinski pod pravim uglom ili oštrim uglom u odnosu na smer strujanja rashladnog sredstva, u zadnjem delu, odvojeno od otvora mlaznice napojnog voda za rashladno sredstvo. Da bi se izbeglo smrzavanje proizvoda na zidovima ciklona, oni mogu biti snabdeveni grejačima, na primer, električnim. Furthermore, the supply line for the supply of the cooled product is poured into the rear part. For example, the product feed line is poured substantially at a right angle or sharp angle to the direction of the refrigerant flow, in the rear, separate from the nozzle opening of the refrigerant feed line. In order to avoid freezing of products on the cyclone walls, they can be supplied with heaters, for example, electric ones.

[0015] Prilikom upotrebe uređaja, u ciklonu se usled dovođenja rashladnog sredstva i njegove ekspanzije i/ili isparavanja vrši znatan pritisak protoka u smeru izlaznog otvora prednjeg dela. Iznenađujuće, pokazalo se da posebno efikasno hlađenje proizvoda može biti postignuto kada se nasuprot tom pritisku protoka stvara izvesni kontrapritisak. Uzrok za povećanu efikasnost hlađenja nije u potpunosti razjašnjen, možda kontrapritisak dovodi do dužeg boravka proizvoda u ciklonu, pa time i do dužeg vremena kontakta sa kriogenim rashladnim sredstvom. Pronalazak zato obezbeđuje da sredstva za stvaranje takvog kontrapritiska budu raspoređena na vodu za odvođenje proizvoda pored izlaznog otvora. [0015] During the use of the device, due to the introduction of the coolant and its expansion and/or evaporation, a significant flow pressure is exerted in the direction of the outlet opening of the front part. Surprisingly, it has been shown that particularly effective cooling of the product can be achieved when a certain back pressure is created against this flow pressure. The reason for the increased cooling efficiency is not fully clarified, perhaps the counter pressure leads to a longer stay of the product in the cyclone, and thus to a longer contact time with the cryogenic refrigerant. The invention therefore ensures that the means for creating such a back pressure are arranged on the water for the removal of the product next to the exit opening.

[0016] Sredstva za stvaranje kontrapritiska pri tome obuhvataju sredstva za stvaranje otpora protoku u vodu za odvođenje proizvoda, kao što je, na primer, dijafragma ili drugo smanjenje poprečnog preseka protoka. U jednom otelotvorenju, ona obuhvataju prigušni ventil, pomoću koga može da se podesi određeni ciljani kontrapritisak. To otelotvorenje je naročito preporučljivo kada u uređaju treba hladiti različite proizvode, i potreban je određeni efekat hlađenja, nezavisno od vrste i osobina proizvoda, kao što je, na primer, temperatura ili viskozitet i/ili temperatura koju treba podesiti. Prigušni ventil takođe može da bude izveden da bude podesiv, i da se tokom postupka hlađenja podešava kontrapritisak u zavisnosti od izmerenog parametra, kao što je, na primer, izlazna temperatura proizvoda. [0016] Means for creating counter pressure include means for creating resistance to the flow in the water for removing the product, such as, for example, a diaphragm or other reduction of the cross-section of the flow. In one embodiment, they include a throttle valve, by which a specific target back pressure can be set. This embodiment is particularly recommended when different products are to be cooled in the device, and a certain cooling effect is required, independent of the type and properties of the product, such as, for example, temperature or viscosity and/or the temperature to be adjusted. The throttle valve can also be made to be adjustable, and during the cooling process the back pressure is adjusted depending on the measured parameter, such as, for example, the outlet temperature of the product.

[0017] U drugom otelotvorenju, sredstva za stvaranje kontrapritiska obuhvataju odeljak voda za odvođenje proizvoda, koji je konstruisan kao sifon, i obuhvata najmanje jedan odeljak voda koji ide geodetski naviše. Kada uređaj radi, u odeljku voda koji ide vertikalno naviše formira se stub ohlađenog proizvoda, čija težina (kod tečnih proizvoda: hidrostatički pritisak) deluje kao kontrapritisak naspram pritiska protoka na izlaznom otvoru ciklona. Naravno, sredstva za stvaranje kontrapritiska takođe mogu da se kombinuju, na primer, dijafragma ili prigušni ventil u vodu za dovođenje proizvoda sa odeljkom voda koji ide vertikalno naviše. [0017] In another embodiment, the means for creating counter pressure comprise a section of water for draining the product, which is constructed as a siphon, and comprises at least one section of water that goes geodesically upwards. When the device is working, a column of cooled product is formed in the water section that goes vertically upwards, whose weight (for liquid products: hydrostatic pressure) acts as a counter pressure against the flow pressure at the outlet of the cyclone. Of course, the means for creating back pressure can also be combined, for example, a diaphragm or a throttle valve in the water supply line with a section of water that goes vertically upwards.

[0018] Posebno pogodno otelotvorenje pronalaska predviđa da se napojni vod proizvoda koji se hladi uliva u zadnji deo, tako da je struja proizvoda koja iz njega ističe usmerena na struju rashladnog sredstva dovedenu na napojnu mlaznicu. Usled toga, već nakon dovođenja proizvoda, postiže se temeljno mešanje proizvoda i rashladnog sredstva. [0018] A particularly suitable embodiment of the invention foresees that the supply line of the product being cooled flows into the rear part, so that the current of the product that flows out of it is directed to the current of the coolant supplied to the supply nozzle. As a result, already after introducing the product, a thorough mixing of the product and the coolant is achieved.

[0019] Proizvod se poželjno dovodi preko napojne linije koja se vertikalno uliva u tok rashladnog sredstva, koje se, na primer dovodi kroz poklopac zadnjeg dela, i najmanje svojim krajnjim delom ide paralelno sa uzdužnom osom ciklona. U ovom slučaju, proizvod se dovodi u ciklon suštinski upravno na smer toka rashladnog sredstva. Napojni vod za proizvod takođe može pod oštrim uglom da se uliva u zadnji deo, sa po jednom komponentom za usmeravanje paralelno i vertikalno na tok rashladnog sredstva. Pored toga, napojni vod za proizvod može biti opremljen mlaznicom za prskanje sa strane ulivanja. [0019] The product is preferably supplied via a supply line that is vertically poured into the flow of the coolant, which, for example, is supplied through the cover of the rear part, and at least its end part runs parallel to the longitudinal axis of the cyclone. In this case, the product is fed into the cyclone substantially perpendicular to the flow direction of the refrigerant. The product feed line can also be acutely angled into the rear, with one component each to direct parallel and vertical to the refrigerant flow. In addition, the product feed line can be equipped with a spray nozzle on the pour side.

[0020] U jednom posebno pogodnom otelotvorenju pronalaska, napojni vod za proizvod se ne uliva neposredno ispod napojne mlaznice za rashladno sredstvo u zadnji deo, nego je aksijalno odvojen od nje. Poželjno, napojni vod za proizvod se uliva u zadnji deo 1 cm do 10 cm ispred napojne mlaznice, posebno poželjno 2 cm do 5 cm. U ovom otelotvorenju, tok proizvoda nailazi na već prošireni tok rashladnog sredstva i biva njime nošen. [0020] In one particularly suitable embodiment of the invention, the supply line for the product does not flow directly under the supply nozzle for the coolant in the rear part, but is axially separated from it. Preferably, the product feed line is fed into the rear 1 cm to 10 cm in front of the feed nozzle, particularly preferably 2 cm to 5 cm. In this embodiment, the product stream encounters and is carried by the already expanded coolant stream.

[0021] Cilj ovog pronalaska je takođe postignut postupkom za hlađenje proizvoda, korišćenjem uređaja prema pronalasku, sa karakteristikama prema zahtevu 5. U tom slučaju, kriogeno rashladno sredstvo se tangencijalno uvodi u ciklon na ulazu napojne mlaznice u zadnjem delu ciklona. Istovremeno, proizvod koji treba hladiti uvodi se u tok proizvoda usmeren prema toku uvedenog rashladnog sredstva. Smeša rashladnog sredstva i proizvoda se u ciklonu razdvaja, pri čemu se proizvod odvodi preko voda za odvod proizvoda, koji izlazi iz konusno oblikovanog prednjeg dela u nastavku zadnjeg dela. Ispareno rashladno sredstvo se uklanja preko odvoda za izlaz gasova u zadnjem delu ciklona. [0021] The aim of the present invention is also achieved by a process for cooling the product, using a device according to the invention, with characteristics according to claim 5. In this case, the cryogenic coolant is introduced tangentially into the cyclone at the inlet of the feed nozzle in the rear part of the cyclone. At the same time, the product to be cooled is introduced into the product flow directed towards the flow of the introduced refrigerant. The mixture of coolant and product is separated in the cyclone, with the product being removed via the product drain line, which exits from the conically shaped front part in continuation of the rear part. The vaporized refrigerant is removed via the exhaust outlet in the rear part of the cyclone.

[0022] Prema pronalasku, kontrapritisak, koji deluje nasuprot pritisku protoka proizvoda koji ističe, nastaje u vodu za odvod proizvoda sa nizvodne strane. Kontrapritisak se pomoću pogodnog sredstva podešava na prethodno zadatu vrednost, ili se podešava u zavisnosti od neke izmerene vrednosti. Kao sredstvo može da se koristi, na primer, prigušni ventil ili suženje u vodu za odvod proizvoda, ili održavanje stuba tečnosti u odnosu na čiji hidrostatički pritisak treba da se izvrši isticanje proizvoda koji se hladi. Primenom kontrapritiska, uslovi strujanja u ciklonu se menjaju na takav način da postoji duže vreme kontakta proizvoda i rashladnog sredstva, pa tako dolazi do efikasnijeg hlađenja proizvoda. [0022] According to the invention, a counter pressure, which acts against the pressure of the product flow that is coming out, is created in the water for draining the product from the downstream side. The back pressure is adjusted to a predetermined value by means of a suitable means, or it is adjusted depending on some measured value. As a means can be used, for example, a throttle valve or a constriction in the water for draining the product, or maintaining a column of liquid in relation to which hydrostatic pressure is to be carried out to discharge the product being cooled. By applying counter pressure, the flow conditions in the cyclone are changed in such a way that there is a longer contact time between the product and the coolant, thus resulting in a more efficient cooling of the product.

[0023] Kontrapritisak je podešen na vrednost od 0,03 do 0,2 bar, naročito poželjno na vrednost od 0,05 do 0,1 bar. Kao kriogeno rashladno sredstvo, poželjno se koriste tečni azot ili tečni ugljen dioksid, koji se prilikom ulaska u ciklon širi, dajući smešu gasovitog i čvrstog ugljen dioksida. [0023] The counter pressure is set to a value of 0.03 to 0.2 bar, particularly preferably to a value of 0.05 to 0.1 bar. Liquid nitrogen or liquid carbon dioxide is preferably used as a cryogenic coolant, which expands upon entering the cyclone, giving a mixture of gaseous and solid carbon dioxide.

[0024] Postupak prema pronalasku i uređaj prema pronalasku pogodni su za hlađenje tečnog, fluidizovanog ili praškastog proizvoda. Uređaj prema pronalasku se posebno koristi za hlađenje životnih namirnica na bazi masnoće ili vode, posebno tečnih namirnica, kao što su, na primer, sosovi, supe ili sokovi, sa čvrstim sastojcima ili bez njih. Nakon hlađenja u uređaju prema pronalasku, proizvod može zatim da se podvrgne dodatnim postupcima prerade, ili da se odvede na pakovanje. Gasovito rashladno sredstvo koje nastaje pri postupku hlađenja, na primer gasoviti ugljen dioksid, uklanja se preko odvoda za izlaz gasova, i može, na primer, takođe da se koristi za prethodno hlađenje rashladnog sredstva dovedenog u ciklon. [0024] The method according to the invention and the device according to the invention are suitable for cooling a liquid, fluidized or powdered product. The device according to the invention is especially used for cooling fat- or water-based foodstuffs, especially liquid foodstuffs, such as, for example, sauces, soups or juices, with or without solid ingredients. After cooling in the device according to the invention, the product can then be subjected to additional processing procedures, or taken to packaging. Gaseous refrigerant produced during the cooling process, for example carbon dioxide gas, is removed via the gas outlet, and can, for example, also be used to pre-cool the refrigerant supplied to the cyclone.

Primer: Example:

[0025] [0025]

Zadnji deo ciklona uređaja prema pronalasku ima prečnik cevi, na primer, od 250 mm do 300 mm. U zadnji deo se dovodi vodeni proizvod sa masenim protokom od 2,5 m<3>/h. The rear part of the cyclone of the device according to the invention has a pipe diameter, for example, from 250 mm to 300 mm. A water product with a mass flow rate of 2.5 m<3>/h is fed into the rear part.

Istovremeno se dovodi tečni ugljen dioksid kao rashladno sredstvo, sa masenim protokom od 1,2 t/h. U vodu za odvod proizvoda stvara se kontrapritisak od 0,05 bar do 0,1 bar, na primer pomoću prigušnog ventila. Proizvod koji se odvodi na izlazu voda za odvod proizvoda ima temperaturu koja je do 40°C niža od temperature dovedenog proizvoda. At the same time, liquid carbon dioxide is supplied as a cooling agent, with a mass flow rate of 1.2 t/h. A back pressure of 0.05 bar to 0.1 bar is created in the product drain water, for example by means of a throttle valve. The product that is drained at the outlet of the product drain has a temperature that is up to 40°C lower than the temperature of the supplied product.

[0026] Jedan primer otelotvorenja će detaljnije biti opisan prema crtežu. Šematski prikaz predstavlja sledeće: [0026] One example of embodiment will be described in more detail according to the drawing. The schematic representation represents the following:

Sl. 1: Uređaj prema pronalasku na preseku duž linije I-I na Sl.2, Sl. 1: The device according to the invention in a section along the line I-I in Fig. 2,

Sl. 2: Uređaj sa Sl.1 na preseku duž linije II-II na Sl.1, Sl. 2: Device from Fig. 1 on the section along line II-II in Fig. 1,

[0027] Uređaj 1 za hlađenje proizvoda prikazan na crtežima obuhvata ciklon 2, čije kućište na poznat način ima zadnji deo 3 sa kružnim cilindričnim poprečnim presekom poluprečnika Rz, i susedni prednji deo konusnog oblika 4, koji se uliva u izlazni otvor 5 poluprečnika Rp. Ciklon 2 je izrađen od materijala koji slabo provodi toplotu, kao što je nerđajući čelik ili titan, i takođe može imati oblogu kao toplotnu izolaciju, što ovde nije prikazano. [0027] The device 1 for cooling the product shown in the drawings includes a cyclone 2, whose housing in a known manner has a rear part 3 with a circular cylindrical cross-section of radius Rz, and an adjacent front part of a conical shape 4, which flows into the outlet opening 5 of radius Rp. Cyclone 2 is made of a material that conducts heat poorly, such as stainless steel or titanium, and may also have a coating as thermal insulation, which is not shown here.

[0028] Na svojoj čeonoj strani koja se nalazi nasuprot prednjeg dela 4, zadnji deo 3 je zatvoren poklopcem 6. Cilindrična izduvna cev za gasove 7 unutrašnjeg poluprečnika RG, koja je na način koji ovde nije prikazan priključena na odvod za izlaz gasova, prolazi kroz sredinu poklopca 6, pri čemu između spoljnog zida izduvne cevi za gasove 7 i unutrašnjeg zida zadnjeg dela 3 postoji kružni prsten 8 širine BR. Izduvna cev za gasove 7 ulazi duboko u unutrašnjost ciklona 2 i završava se otvorom za izlaz gasova 11 otprilike u visini ravni 12 prelaza između zadnjeg dela 3 i prednjeg dela 4 ciklona 2. Zadnji deo 3, prednji deo 4 i izduvna cev za gasove 7 raspoređeni su duž zajedničke vertikalne ose 9, pri čemu se izlazni otvor 5 nalazi dole, a izduvna cev za gasove 7 gore u ciklonu 2. Na primer, poluprečnik Rz je od 10 cm do 15 cm, poluprečnik RGod 5 cm do 10 cm, i poluprečnik RPod 5 cm do 10 cm. [0028] On its front side, which is located opposite the front part 4, the rear part 3 is closed by a cover 6. The cylindrical exhaust pipe for gases 7 of the inner radius RG, which is connected to the gas outlet in a manner not shown here, passes through the middle of the cover 6, whereby between the outer wall of the exhaust pipe for gases 7 and the inner wall of the rear part 3 there is a circular ring 8 of width BR. The exhaust gas pipe 7 enters deep into the interior of the cyclone 2 and ends with the gas outlet opening 11 approximately at the height of the plane 12 of the transition between the rear part 3 and the front part 4 of the cyclone 2. The rear part 3, the front part 4 and the exhaust gas pipe 7 are arranged along a common vertical axis 9, with the outlet opening 5 located at the bottom and the exhaust gas pipe 7 at the top in the cyclone 2. For example, the radius Rz is from 10 cm to 15 cm, the radius RGod 5 cm to 10 cm, and the radius RPod 5 cm to 10 cm.

[0029] U zadnji deo 3 ciklona 2 uliva se napojna mlaznica 14 za kriogeno rashladno sredstvo, koja je preko napojnog voda 15 protočno povezana sa izvorom kriogenog rashladnog sredstva koji ovde nije prikazan. Izvor, na primer, može biti rezervoar za tečni kriogeni azot ili za ugljen dioksid utečnjen pod pritiskom. Krajnji deo napojnog voda 15, na čijoj čeonoj strani se nalazi napojna mlaznica 14, postavljen je u tangencijalnom dovodnom delu 16 ciklona 2, i aksijalno u odnosu na njega. Prirubnička veza 17 obezbeđuje gasno nepropusnu vezu između napojnog voda 15 i dovodnog dela 16. [0029] Into the rear part 3 of the cyclone 2, the feed nozzle 14 for the cryogenic coolant is poured, which is flow-connected via the feed line 15 to the source of the cryogenic coolant, which is not shown here. The source, for example, can be a reservoir for liquid cryogenic nitrogen or for pressurized liquefied carbon dioxide. The end part of the feed line 15, on the front side of which there is a feed nozzle 14, is placed in the tangential supply part 16 of the cyclone 2, and axially in relation to it. The flange connection 17 provides a gas-tight connection between the supply line 15 and the supply part 16.

[0030] Nadalje, predviđen je vod za dovođenje proizvoda 18, koji se na zadnjem delu 3 uliva u izlazni otvor 19 na poklopcu 6, vertikalno ili pod uglom, sa dodatnim tangencijalnim delom za usmeravanje. Izlazni otvor 19 je postavljen tako da je poravnat sa krajnjim delom napojnog voda 15, i uliva se na aksijalnom rastojanju D od napojne mlaznice 14 koje, na primer, iznosi od 2 cm do 5 cm. [0030] Furthermore, a line for supplying the product 18 is provided, which on the rear part 3 flows into the outlet opening 19 on the cover 6, vertically or at an angle, with an additional tangential part for direction. The outlet opening 19 is positioned so that it is aligned with the end part of the feed line 15, and is poured at an axial distance D from the feed nozzle 14 which is, for example, from 2 cm to 5 cm.

[0031] Na izlazni otvor 5 prednjeg dela 4 nastavlja se vod za odvod proizvoda 20, za odvođenje rashlađenog proizvoda, koji u ovde prikazanom otelotvorenju kontinuirano ima poluprečnik poprečnog preseka RP, koji odgovara poluprečniku izlaznog otvora 5 ciklona. Vod za odvod proizvoda 20 ima odeljak voda u obliku slova U, koji je prilikom upotrebe uređaja 1 usmeren geodetski naniže krivinom 21, a kracima 22, 23 naviše, pri čemu se krak 22 nastavlja neposredno na izlazni otvor 5. Krivina 21 i kraci 22, 23 odeljka voda u obliku slova U su tako dimenzionirani, da u njemu može da se održava stub tečnosti visine H, na primer, od 500 mm do 800 mm. [0031] The outlet opening 5 of the front part 4 continues with the product drain line 20, for draining the cooled product, which in the embodiment shown here continuously has a cross-sectional radius RP, which corresponds to the radius of the outlet opening 5 of the cyclone. The product drainage line 20 has a U-shaped water section, which, when using the device 1, is directed geodesically downwards by the bend 21, and by the arms 22, 23 upwards, whereby the arm 22 continues directly to the outlet opening 5. The bend 21 and the arms 22, 23 of the U-shaped water section are so dimensioned that it can maintain a liquid column of height H, for example, from 500 mm to 800 mm.

[0032] Prilikom rada uređaja 1, kriogeno rashladno sredstvo, na primer ugljen dioksid utečnjen pod pritiskom, koji se preko napojnog voda 15 dovodi pod pritiskom većim od 5,18 bar (aps.), na primer pritiskom od 18 do 20 bar (aps.), dovodi se u napojnu mlaznicu 14, i teče u ciklon 2. Na napojnoj mlaznici 14 ugljen dioksid se širi uz stvaranje struje gasovitog ugljen dioksida i suvog leda, koja teče tangencijalno u kružni prsten 8 između unutrašnjeg zida zadnjeg dela 3 i spoljnog zida izduvne cevi za gasove 7, i tu biva usmerena na spiralnu putanju 25 koja se spušta u smeru prednjeg dela, kao što je naznačeno na Sl.2. Umesto ugljen dioksida može da se koristi neko drugo kriogeno rashladno sredstvo, na primer tečni azot. [0032] During the operation of the device 1, a cryogenic refrigerant, for example carbon dioxide liquefied under pressure, which is supplied via the supply line 15 under a pressure greater than 5.18 bar (abs.), for example a pressure of 18 to 20 bar (abs.), is supplied to the feed nozzle 14, and flows into the cyclone 2. On the feed nozzle 14, carbon dioxide expands with the creation of a stream of gaseous carbon dioxide and of dry ice, which flows tangentially into the circular ring 8 between the inner wall of the rear part 3 and the outer wall of the exhaust pipe for gases 7, and is directed there to the spiral path 25 which descends in the direction of the front part, as indicated in Fig.2. Instead of carbon dioxide, another cryogenic refrigerant can be used, for example liquid nitrogen.

[0033] Istovremeno sa rashladnim sredstvom, preko voda za dovođenje proizvoda 18 dovodi se tečni proizvod koji treba ohladiti. Proizvod se ispred otvora 19 temeljno meša sa rashladnim sredstvom dovedenim preko napojne mlaznice 14, i biva nošen njegovim tokom. Pri tome, rashladno sredstvo uzima toplotu od proizvoda i pri tome isparava, odnosno sublimira, najmanje delimično, pri čemu se proizvod hladi. [0033] At the same time as the cooling agent, the liquid product to be cooled is supplied through the product supply line 18. The product is thoroughly mixed in front of the opening 19 with the coolant supplied via the feed nozzle 14, and is carried along by it. At the same time, the coolant takes heat from the product and evaporates, that is, sublimes, at least partially, whereby the product cools.

[0034] Na način poznat sam po sebi, spiralna putanja 25 isparenog rashladnog sredstva transformiše se na visini otvora za izlaz gasova 11 u spiralnu putanju koja se spušta unutar izduvne cevi za gasove 7. Gasovito rashladno sredstvo koje izlazi iz izduvne cevi za gasove 7 zatim se poželjno prikuplja i, na primer, koristi za prethodno hlađenje dovedenog rashladnog sredstva u napojnom vodu 15. Putem kružnog strujanja u ciklonu 2, kapljice tečnosti, odnosno čestice proizvoda, najkasnije nakon nekoliko obrtaja bivaju ubrzane usled centrifugalne sile na unutrašnjem zidu konusnog prednjeg dela 4, i bivaju tako prikočene, da se odvajaju od toka i idu naniže u smeru izlaznog otvora 5. Tečni proizvod se na kraju odvodi preko odeljka voda u obliku slova U voda za odvođenje proizvoda 20. [0034] In a manner known per se, the spiral path 25 of the vaporized refrigerant is transformed at the height of the gas outlet opening 11 into a spiral path that descends inside the gas exhaust pipe 7. The gaseous refrigerant that exits the gas exhaust pipe 7 is then preferably collected and, for example, used for pre-cooling the supplied refrigerant in the feed line 15. Through the circular flow in the cyclone 2, Liquid droplets, i.e. product particles, after a few revolutions at the latest, are accelerated due to the centrifugal force on the inner wall of the conical front part 4, and are attached in such a way that they separate from the flow and go downwards in the direction of the exit opening 5. The liquid product is finally drained through the U-shaped water section, the product drainage water 20.

[0035] Dovođenje i ekspanzija rashladnog sredstva u ciklonu 2 dovodi do jakog pritiska protoka proizvoda u smeru voda za odvođenje proizvoda 20. Prilikom strujanja preko voda za odvođenje proizvoda 20, proizvod mora da savlada krak 23 odeljka voda u obliku slova U, pa tako i hidrostatički pritisak koji odgovara hidrostatičkom pritisku visine H, koji deluje kao kontrapritisak pritisku protoka proizvoda. Na primer, kontrapritisak, od 0,05 bar do 0,08 bar dovodi do dužeg prosečnog vremena kontakta kapljica tečnosti proizvoda i rashladnog sredstva, pa tako dolazi do znatno boljeg hlađenja proizvoda u poređenju sa direktnim odvođenjem nadole. Pored toga, uređaj prema pronalasku 1 na isti način može da se koristi i za hlađenje praškastih proizvoda. [0035] The introduction and expansion of the cooling agent in the cyclone 2 leads to a strong pressure of the product flow in the direction of the product discharge lines 20. When flowing over the product discharge lines 20, the product must overcome the leg 23 of the U-shaped water section, and thus the hydrostatic pressure corresponding to the hydrostatic pressure of the height H, which acts as a counter-pressure to the pressure of the product flow. For example, a back pressure of 0.05 bar to 0.08 bar leads to a longer average contact time between the liquid droplets of the product and the coolant, thus resulting in significantly better cooling of the product compared to direct downward discharge. In addition, the device according to invention 1 can be used for cooling powder products in the same way.

Spisak referentnih oznaka List of reference marks

[0036] [0036]

1. Uređaj 1. Device

2. Ciklon 2. Cyclone

3. Zadnji deo 3. The back part

4. Prednji deo 4. Front part

5. Izlazni otvor 5. Outlet

6. Poklopac 6. Lid

7. Izduvna cev za gasove 7. Exhaust pipe

8. Kružni prsten 8. Circular ring

9. Osa 9. Wasp

10. -11. Otvor za izlaz gasova 10. -11. Gas outlet

12. Ravan 12. Flat

13. -14. Napojna mlaznica 13. -14. Feed nozzle

15. Napojni vod 15. Supply line

16. Dovodni deo 16. Inlet section

17. Prirubnička veza 17. Flange connection

18. Vod za dovođenje proizvoda 18. Product supply line

19. Izlazni otvor 19. Outlet

20. Vod za odvođenje proizvoda 20. Line for draining the product

21. Krivina 21. Curve

22. Krak 22. Arm

23. Krak 23. Arm

24. -25. Putanja 24th -25th Path

Bz Širina prstenastog zazora Bz Annular gap width

RGUnutrašnji poluprečnik odvoda gasova RGInner radius of gas outlet

Rp Unutrašnji poluprečnik voda za odvođenje proizvoda Rp Inner radius of the product drain line

Rz Unutrašnji poluprečnik zadnjeg dela ciklona Rz Internal radius of the rear part of the cyclone

H Visina stuba tečnosti u vodu za odvođenje proizvoda H The height of the liquid column in the water for removing the product

D Rastojanje između napojne mlaznice i voda za dovođenje proizvoda D The distance between the feed nozzle and the product supply line

1 1

Claims (7)

Patentni zahteviPatent claims 1. Uređaj za hlađenje proizvoda, sa ciklonom (2), koji ima kućište sa kružnim cilindričnim zadnjim delom (3) i susednim prednjim delom konusnog oblika (4) sa izlaznim otvorom (5), pri čemu je na gornjoj čeonoj strani zadnjeg dela (3) koja se nalazi nasuprot prednjeg dela (4) postavljen poklopac (6) sa odvodom za izlaz gasova (7) koji je koncentrično izveden kroz njega, i pruža se u unutrašnjosti ciklona (2) odvojeno od poklopca (6) sa kružnim otvorom za odvod gasova (11), sa dovodnom mlaznicom (14) povezanom sa napojnim vodom (15) kriogenog rashladnog sredstva, koja se tangencijalno uliva u zadnji deo (3) u području gornje čeone strane, i najmanje jednim napojnim vodom (18) za proizvod koji treba hladiti koji se uliva u zadnji deo (3),1. A product cooling device, with a cyclone (2), which has a housing with a circular cylindrical rear part (3) and an adjacent conical front part (4) with an outlet opening (5), whereby a cover (6) is placed on the upper front side of the rear part (3) opposite the front part (4) with a gas outlet (7) concentrically through it, and extends inside the cyclone (2) separately from the cover (6) with a circular a gas outlet (11), with a supply nozzle (14) connected to a feed water (15) of cryogenic coolant, which flows tangentially into the rear part (3) in the area of the upper face, and at least one feed water (18) for the product to be cooled that flows into the rear part (3), naznačen time,indicated by, što je izlazni otvor (5) prednjeg dela (4) protočno povezan sa vodom za odvođenje proizvoda (20) za rashlađeni proizvod, u kome se nalazi sredstvo (21, 22, 23) za stvaranje kontrapritiska koji se suprotstavlja pritisku protoka proizvoda koji ističe iz voda za odvođenje proizvoda (20), pri čemuwhich is the outlet opening (5) of the front part (4) fluidly connected to the product outlet (20) for the cooled product, in which there is a means (21, 22, 23) for creating a counter pressure that opposes the pressure of the product flow coming out of the product outlet (20), wherein sredstvo (21, 22, 23) za stvaranje kontrapritiska obuhvata prigušni ventil ili suženje i/ili odeljak voda koji ide geodetski naviše (23) voda za odvođenje proizvoda (20), u kome tokom rada uređaja može da nastane stub tečnosti čiji hidrostatički pritisak deluje kao kontrapritisak.means (21, 22, 23) for creating counter pressure includes a throttle valve or a constriction and/or a section of water that goes geodesically upwards (23) of water for removing the product (20), in which a column of liquid whose hydrostatic pressure acts as a counter pressure can form during the operation of the device. 2. Uređaj prema zahtevu 1, naznačen time, što se vod (18) za dovođenje proizvoda uliva u zadnji deo (3), tako da je tok proizvoda koji iz njega ističe usmeren na tok rashladnog sredstva doveden na napojnu mlaznicu (14).2. The device according to claim 1, characterized by the fact that the line (18) for supplying the product flows into the rear part (3), so that the flow of the product coming out of it is directed to the flow of the coolant supplied to the feed nozzle (14). 3. Uređaj prema jednom od prethodnih zahteva, naznačen time, što se vod (18) za dovođenje proizvoda, aksijalno udaljen od napojne mlaznice (14) za rashladno sredstvo, uliva u zadnji deo (3) ciklona (2).3. Device according to one of the previous claims, characterized in that the line (18) for supplying the product, axially distant from the feed nozzle (14) for the coolant, flows into the rear part (3) of the cyclone (2). 4. Uređaj prema jednom od prethodnih zahteva, naznačen time, što je vod (18) za dovođenje proizvoda barem svojim krajnjim delom koji se uliva u ciklon (2) suštinski paralelan sa uzdužnom osom (9) ciklona (2).4. Device according to one of the previous claims, characterized in that the line (18) for supplying the product is essentially parallel to the longitudinal axis (9) of the cyclone (2) at least with its end part that flows into the cyclone (2). 5. Postupak za hlađenje proizvoda uz korišćenje uređaja prema jednom od prethodnih zahteva, u kome se kriogeno rashladno sredstvo na dovodnoj mlaznici (14) tangencijalno dovodi u zadnji deo (3) kućišta ciklona (2), preko napojnog voda (18) koji se uliva u ciklon (2) dovodi se proizvod koji treba hladiti u tok dovedenog rashladnog sredstva i sa njime se meša, na kraju se smeša rashladnog sredstva i proizvoda razdvaja u ciklonu (2), pri čemu se proizvod odvodi preko voda za odvođenje proizvoda (20) koji izlazi iz prednjeg dela konusnog oblika (4) u produžetku zadnjeg dela (3), a ispareno rashladno sredstvo preko odvoda za izlaz gasova (7) koji se uliva u zadnji deo (3), naznačen time,5. A method for cooling the product using a device according to one of the previous requirements, in which the cryogenic coolant is fed tangentially to the rear part (3) of the cyclone housing (2) on the supply nozzle (14), through the feed line (18) which flows into the cyclone (2), the product to be cooled is fed into the flow of the supplied coolant and mixed with it, at the end the mixture of the coolant and the product is separated in the cyclone (2), while the product is drained through the water for removing the product (20) that comes out of the front part of the conical shape (4) in the extension of the back part (3), and the vaporized coolant through the outlet for the exit of gases (7) that flows into the back part (3), indicated by što u vodu za odvođenje proizvoda (20) na nizvodnoj strani toka nastaje kontrapritisak koji deluje naspram pritiska protoka izlazećeg proizvoda, pri čemu je kontrapritisak podešen na vrednost od 0,03 do 0,2 bar, poželjno od 0,05 do 0,1 bar.that in the water for removing the product (20) on the downstream side of the flow, a counter-pressure is created that acts against the flow pressure of the outgoing product, whereby the counter-pressure is set to a value of 0.03 to 0.2 bar, preferably from 0.05 to 0.1 bar. 6. Postupak prema zahtevu 5, naznačen time, što se kao kriogeno rashladno sredstvo koristi tečni ugljen dioksid ili tečni azot.6. The method according to claim 5, characterized in that liquid carbon dioxide or liquid nitrogen is used as a cryogenic refrigerant. 7. Postupak prema jednom od zahteva 5 ili 6, naznačen time, što je proizvod tečni ili praškasti proizvod.7. The method according to one of claims 5 or 6, characterized in that the product is a liquid or powder product.
RS20210820A 2018-04-06 2019-02-19 Device for cooling products RS62045B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102018002750.4A DE102018002750B8 (en) 2018-04-06 2018-04-06 Device for cooling products
EP19157971.3A EP3550225B1 (en) 2018-04-06 2019-02-19 Device for cooling products

Publications (1)

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DE2659546A1 (en) * 1976-12-30 1978-07-13 Boehringer Mannheim Gmbh METHOD FOR PRODUCING FROZEN GRANULES
FR2496851A1 (en) * 1980-12-23 1982-06-25 Anhydride Carbonique Ind Freezing prods. by contact with refrigerant fluid esp. carbon di:oxide - injected tangentially into vortex tube and released coaxially via Venturi tube
JPH089582Y2 (en) * 1990-08-31 1996-03-21 大陽酸素株式会社 Frozen grain production equipment
DE4113512C2 (en) * 1991-04-25 1995-04-20 Grolitsch Lisbeth Method and device for freeze drying and pulverizing food
ITMI20032367A1 (en) * 2003-12-03 2005-06-04 Air Liquide Italia S P A METHOD AND PLANT FOR FLUID COOLING
US20060283195A1 (en) * 2005-06-16 2006-12-21 Uwe Rosenbaum Process and apparatus for continuous cooling of pumpable material with a liquid cryogen
EP3009006B1 (en) * 2014-10-17 2018-10-03 Linde Aktiengesellschaft Apparatus, system and method for treating a flowable product
DE102014018981A1 (en) * 2014-12-18 2016-06-23 Messer France S.A.S Method and apparatus for producing supercooled carbon dioxide snow

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EP3550225B1 (en) 2021-05-26
EP3550225A1 (en) 2019-10-09
DE102018002750B8 (en) 2020-09-24
HUE054971T2 (en) 2021-10-28
DE102018002750A1 (en) 2019-10-10
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ES2882072T3 (en) 2021-12-01
PL3550225T3 (en) 2021-11-02

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