RU2012122590A - Фторуретаны в качестве добавки в фотополимерной композиции - Google Patents

Фторуретаны в качестве добавки в фотополимерной композиции Download PDF

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RU2012122590A
RU2012122590A RU2012122590/05A RU2012122590A RU2012122590A RU 2012122590 A RU2012122590 A RU 2012122590A RU 2012122590/05 A RU2012122590/05 A RU 2012122590/05A RU 2012122590 A RU2012122590 A RU 2012122590A RU 2012122590 A RU2012122590 A RU 2012122590A
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composition according
photopolymer composition
groups
carbon atoms
fluorourethanes
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Томас РЕЛЛЕ
Фридрих-Карл БРУДЕР
Томас ФЭККЕ
Марк-Штэфан ВАЙЗЕР
Деннис ХЕНЕЛЬ
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Байер Матириальсайенс Аг
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Abstract

1. Фотополимерная композиция, включающая в себя полимеры матрикса, пишущие мономеры и фотоинициаторы, отличающаяся тем, что в качестве пластификаторов она содержит фторуретаны.2. Фотополимерная композиция по п.1, отличающаяся тем, что фторуретаны включают в себя по меньшей мере один структурный элемент общей формулы (I)и замещены по меньшей мере одним атомом фтора.3. Фотополимерная композиция по п.1, отличающаяся тем, что фторуретаны имеют общую формулу (II),в которой n≥1 и n≤8 и R, R, Rпредставляют собой водород и/или независимо друг от друга линейные, разветвленные, циклические или гетероциклические, незамещенные или при необходимости замещенные гетероатомами органические остатки, причем по меньшей мере один из остатков R, R, Rзамещен по меньшей мере одним атомом фтора.4. Фотополимерная композиция по п.3, отличающаяся тем, что Rпредставляет собой органический остаток по меньшей мере с одним атомом фтора.5. Фотополимерная композиция по п.3, отличающаяся тем, что Rвключает в себя 1-20 групп CFи/или одну или несколько групп CF, особенно предпочтительно 1-15 групп CFи/или одну или несколько групп CF, особенно предпочтительно 1-10 групп CFи/или одну или несколько групп CF, наиболее предпочтительно 1-8 групп CFи/или одну или несколько групп CF, Rможет включать в себя алкильный остаток с 1-20 атомами углерода, предпочтительно алкильный остаток с 1-15 атомами углерода, особенно предпочтительно алкильный остаток с 1-10 атомами углерода или водород, и/или Rможет включать в себя алкильный остаток с 1-20 атомами углерода, предпочтительно алкильный остаток с 1-15 атомами углерода, особенно предпочтительно алкильный остаток с 1-10 атомами углерода или водород.6. Ф

Claims (15)

1. Фотополимерная композиция, включающая в себя полимеры матрикса, пишущие мономеры и фотоинициаторы, отличающаяся тем, что в качестве пластификаторов она содержит фторуретаны.
2. Фотополимерная композиция по п.1, отличающаяся тем, что фторуретаны включают в себя по меньшей мере один структурный элемент общей формулы (I)
Figure 00000001
и замещены по меньшей мере одним атомом фтора.
3. Фотополимерная композиция по п.1, отличающаяся тем, что фторуретаны имеют общую формулу (II)
Figure 00000002
,
в которой n≥1 и n≤8 и R1, R2, R3 представляют собой водород и/или независимо друг от друга линейные, разветвленные, циклические или гетероциклические, незамещенные или при необходимости замещенные гетероатомами органические остатки, причем по меньшей мере один из остатков R1, R2, R3 замещен по меньшей мере одним атомом фтора.
4. Фотополимерная композиция по п.3, отличающаяся тем, что R1 представляет собой органический остаток по меньшей мере с одним атомом фтора.
5. Фотополимерная композиция по п.3, отличающаяся тем, что R1 включает в себя 1-20 групп CF2 и/или одну или несколько групп CF3, особенно предпочтительно 1-15 групп CF2 и/или одну или несколько групп CF3, особенно предпочтительно 1-10 групп CF2 и/или одну или несколько групп CF3, наиболее предпочтительно 1-8 групп CF2 и/или одну или несколько групп CF3, R2 может включать в себя алкильный остаток с 1-20 атомами углерода, предпочтительно алкильный остаток с 1-15 атомами углерода, особенно предпочтительно алкильный остаток с 1-10 атомами углерода или водород, и/или R3 может включать в себя алкильный остаток с 1-20 атомами углерода, предпочтительно алкильный остаток с 1-15 атомами углерода, особенно предпочтительно алкильный остаток с 1-10 атомами углерода или водород.
6. Фотополимерная композиция по п.1, отличающаяся тем, что фторуретаны имеют уретдионовые, изоциануратные, биуретовые, аллофанатовые, полимочевинные, оксадиазадионовые и/или иминооксадиазиндионовые структурные элементы и/или смеси этих структурных элементов.
7. Фотополимерная композиция по п.1, отличающаяся тем, что коэффициент преломления фторуретанов n D 20 ≤ 1,4600
Figure 00000003
 , предпочтительно ≤1,4500, особенно предпочтительно ≤1,4400 и наиболее предпочтительно ≤1,4300.
8. Фотополимерная композиция по п.1, отличающаяся тем, что содержание фтора во фторуретанах составляет 10-80 масс.%, предпочтительно 12,5-75 масс.%, особенно предпочтительно 15-70 масс.% и наиболее предпочтительно - 17,5-65 масс.%.
9. Фотополимерная композиция по п.1, отличающаяся тем, что полимеры матрикса представляют собой фторуретаны.
10. Фотополимерная композиция по п.1, отличающаяся тем, что пишущие мономеры представляют собой акрилаты предпочтительно с коэффициентом преломления n D 20 > 1,50
Figure 00000004
 , более предпочтительно уретанакрилаты, особенно предпочтительно ароматические уретанакрилаты, предпочтительно с коэффициентом преломления n D 20 > 1,50
Figure 00000005
 .
11. Фотополимерная композиция по одному из пп.1-10, отличающаяся тем, что она содержит 15-79, предпочтительно 30-60 масс.%, полимеров матрикса, 5-50, предпочтительно 10-40 масс.% пишущих мономеров, 1-10, предпочтительно 1-3 масс.% фотоинициаторов и 5-50, предпочтительно 10-40 масс.% фторуретанов и 0-10 масс.% других добавок, причем сумма компонентов составляет 100 масс.%.
12. Применение фотополимерной композиции по одному из пп.1-11 для получения оптических элементов, особенно для получения топографических элементов и изображений.
13. Способ экспозиции топографических сред из фотополимерной композиции по одному из пп.1-11, при реализации которого посредством электромагнитного излучения вызывают избирательную полимеризацию пишущих мономеров с разрешением по месту.
14. Фторуретан, получаемый реакцией полиизоцианата, содержащего иминооксадиазиндион или оксадиазиндион, который имеет по меньшей мере одну свободную изоцианатную группу, со спиртом, причем полиизоцианат и/или спирт замещены по меньшей мере одним атомом фтора.
15. Фторуретаны, соответствующие общей формуле (III)
Figure 00000006
,
в которой m≥1 и m≤8 и R4, R5, R6 представляют собой водород и/или независимо друг от друга линейные, разветвленные, циклические или гетероциклические незамещенные или при необходимости замещенные гетероатомами органические остатки и иминооксадиазиндионовые и/или оксадиазиндионовые структурные элементы, причем одновременно по меньшей мере два из остатков R4, R5, R6 замещены по меньшей мере одним атомом фтора.
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EP2497082A1 (de) 2012-09-12
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WO2011054795A1 (de) 2011-05-12
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JP2017071790A (ja) 2017-04-13
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EP2497082B1 (de) 2013-09-04
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TWI506011B (zh) 2015-11-01
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