RU2013123714A - Композиция для катализатора конверсии углеводородов - Google Patents

Композиция для катализатора конверсии углеводородов Download PDF

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RU2013123714A
RU2013123714A RU2013123714/04A RU2013123714A RU2013123714A RU 2013123714 A RU2013123714 A RU 2013123714A RU 2013123714/04 A RU2013123714/04 A RU 2013123714/04A RU 2013123714 A RU2013123714 A RU 2013123714A RU 2013123714 A RU2013123714 A RU 2013123714A
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composition
catalyst
particles
aluminum
zeolite
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RU2013123714/04A
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RU2581043C2 (ru
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Ласло ДОМОКОС
Лоран Жорж ЮВЕ
Херманус ЙОНГКИНД
Ан Хендрик КЛАЗИНГА
Марселло Стефано РЕГУТТО
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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Abstract

1. Композиция для катализатора конверсии углеводородов, которая содержит частицы цеолита ZSM-48 и/или EU-2 и жаропрочное оксидное связующее, по существу, не содержащее оксида алюминия, причем средняя концентрация алюминия в частицах цеолита ZSM-48 и/или EU-2 по меньшей мере в 1,1 раз больше концентрации алюминия на поверхности частиц.2. Композиция для катализатора конверсии углеводородов, в которой цеолит ZSM-48 и/или EU-2 имеют мольное отношение диоксида кремния к оксиду алюминия по меньшей мере 100 и до максимум 250.3. Композиция для катализатора конверсии углеводородов по любому из пп. 1-2, где содержание цеолита, в расчете на сухое вещество, составляет от 20 до 70 вес.% от всей готовой каталитической композиции.4. Композиция для катализатора конверсии углеводородов, где средняя концентрация алюминия в частицах цеолита ZSM-48 и/или EU-2 по меньшей мере в 2 раза выше концентрации алюминия на поверхности частиц.5. Способ получения композиции для катализатора конверсии углеводородов по любому из пп. 1-4, причем способ включает контакт цеолита ZSM-48 и/или EU-2 с раствором фторсодержащей соли.6. Способ получения катализатора конверсии углеводородов, содержащего каталитически активный металл, причем способ включает приготовление композиции для катализатора конверсии углеводородов способом по п. 5 и введение одного или болеекаталитически активных металлов в каталитическую композицию.7. Способ конверсии углеводородного сырья, причем способ включает контакт сырья с каталитической композицией по любому из пп. 1-4 при температуре от 100 до 600°C и абсолютном давлении от 1 до 100 бар.8. Способ по п. 7, где сырье имеет точку 10%-ной отгонки, измеренную согласно ASTM

Claims (8)

1. Композиция для катализатора конверсии углеводородов, которая содержит частицы цеолита ZSM-48 и/или EU-2 и жаропрочное оксидное связующее, по существу, не содержащее оксида алюминия, причем средняя концентрация алюминия в частицах цеолита ZSM-48 и/или EU-2 по меньшей мере в 1,1 раз больше концентрации алюминия на поверхности частиц.
2. Композиция для катализатора конверсии углеводородов, в которой цеолит ZSM-48 и/или EU-2 имеют мольное отношение диоксида кремния к оксиду алюминия по меньшей мере 100 и до максимум 250.
3. Композиция для катализатора конверсии углеводородов по любому из пп. 1-2, где содержание цеолита, в расчете на сухое вещество, составляет от 20 до 70 вес.% от всей готовой каталитической композиции.
4. Композиция для катализатора конверсии углеводородов, где средняя концентрация алюминия в частицах цеолита ZSM-48 и/или EU-2 по меньшей мере в 2 раза выше концентрации алюминия на поверхности частиц.
5. Способ получения композиции для катализатора конверсии углеводородов по любому из пп. 1-4, причем способ включает контакт цеолита ZSM-48 и/или EU-2 с раствором фторсодержащей соли.
6. Способ получения катализатора конверсии углеводородов, содержащего каталитически активный металл, причем способ включает приготовление композиции для катализатора конверсии углеводородов способом по п. 5 и введение одного или более
каталитически активных металлов в каталитическую композицию.
7. Способ конверсии углеводородного сырья, причем способ включает контакт сырья с каталитической композицией по любому из пп. 1-4 при температуре от 100 до 600°C и абсолютном давлении от 1 до 100 бар.
8. Способ по п. 7, где сырье имеет точку 10%-ной отгонки, измеренную согласно ASTM D 86, выше 343°C.
RU2013123714/04A 2010-10-25 2011-10-20 Композиция для катализатора конверсии углеводородов RU2581043C2 (ru)

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