RU2015119246A - METHOD FOR PRODUCING SYNTHETIC MICROFIBERAL NONWOVEN FABRIC UNDER SUEDE - Google Patents
METHOD FOR PRODUCING SYNTHETIC MICROFIBERAL NONWOVEN FABRIC UNDER SUEDE Download PDFInfo
- Publication number
- RU2015119246A RU2015119246A RU2015119246A RU2015119246A RU2015119246A RU 2015119246 A RU2015119246 A RU 2015119246A RU 2015119246 A RU2015119246 A RU 2015119246A RU 2015119246 A RU2015119246 A RU 2015119246A RU 2015119246 A RU2015119246 A RU 2015119246A
- Authority
- RU
- Russia
- Prior art keywords
- carried out
- stage
- pva
- coagulation
- impregnation
- Prior art date
Links
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract 4
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract 26
- 239000004814 polyurethane Substances 0.000 claims abstract 18
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract 16
- 229920002635 polyurethane Polymers 0.000 claims abstract 16
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract 16
- 230000015271 coagulation Effects 0.000 claims abstract 14
- 238000005345 coagulation Methods 0.000 claims abstract 14
- 238000005470 impregnation Methods 0.000 claims abstract 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 11
- 239000012736 aqueous medium Substances 0.000 claims abstract 9
- 229920001410 Microfiber Polymers 0.000 claims abstract 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract 6
- 239000007864 aqueous solution Substances 0.000 claims abstract 6
- 239000003658 microfiber Substances 0.000 claims abstract 6
- 239000000835 fiber Substances 0.000 claims abstract 4
- 238000007127 saponification reaction Methods 0.000 claims abstract 4
- 239000002253 acid Substances 0.000 claims abstract 3
- 150000007513 acids Chemical class 0.000 claims abstract 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract 3
- 239000003792 electrolyte Substances 0.000 claims abstract 3
- 239000013067 intermediate product Substances 0.000 claims abstract 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims abstract 2
- 239000012670 alkaline solution Substances 0.000 claims abstract 2
- 239000000463 material Substances 0.000 claims abstract 2
- 238000010186 staining Methods 0.000 claims abstract 2
- -1 polyethylene Polymers 0.000 claims 5
- 229920000139 polyethylene terephthalate Polymers 0.000 claims 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims 4
- 229920001634 Copolyester Polymers 0.000 claims 2
- 239000004793 Polystyrene Substances 0.000 claims 2
- 229920001707 polybutylene terephthalate Polymers 0.000 claims 2
- 229920000728 polyester Polymers 0.000 claims 2
- 239000000243 solution Substances 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- CARJPEPCULYFFP-UHFFFAOYSA-N 5-Sulfo-1,3-benzenedicarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(S(O)(=O)=O)=C1 CARJPEPCULYFFP-UHFFFAOYSA-N 0.000 claims 1
- 239000004677 Nylon Substances 0.000 claims 1
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 claims 1
- 230000001687 destabilization Effects 0.000 claims 1
- 239000003995 emulsifying agent Substances 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229920001778 nylon Polymers 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 159000000000 sodium salts Chemical class 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 claims 1
- 238000003776 cleavage reaction Methods 0.000 abstract 1
- 230000007017 scission Effects 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using ultra-fine two-component fibres, e.g. island/sea, or ultra-fine one component fibres (< 1 denier)
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using flocked webs or pile fabrics upon which a resin is applied; Teasing, raising web before resin application
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/02—Dispersion
- D06N2205/023—Emulsion, aqueous dispersion, latex
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/24—Coagulated materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23907—Pile or nap type surface or component
- Y10T428/2395—Nap type surface
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
1. Способ получения микроволокнистой нетканой ткани, который содержит следующие стадии:a) получение войлока иглопробиванием бикомпонентного волокна типа "остров-в-море",b) горячая пропитка указанного войлока водным раствором поливинилового спирта (ПВС), имеющего степень омыления, по меньшей мере, 94%, или горячая пропитка указанного войлока водой и затем холодная пропитка полиуретаном (ПУ),с) удаление компонента "моря" из промежуточного продукта стадии b),d) пропитка микроволокнистого промежуточного продукта ПУ,е) фиксирование ПУ с микроволокнистым промежуточным продуктом с помощью коагуляции и удаление ПВС, возможно введенного на стадии b),f) зашкуривание таким образом полученного материала на одной или обеих сторонах, окрашивание и расщепление, предпочтительно, выполняемые в определенном порядке.2. Способ по п. 1, в котором стадия b) осуществляется пропиткой водным раствором ПВС при температуре, по меньшей мере, 50˚С.3. Способ по п. 1, в котором стадия b) осуществляется пропиткой ПУ в водной среде при температуре не выше 50˚С.4. Способ по п. 1, в котором ПВС на стадии b) имеет степень омыления, по меньшей мере, 94%, даже более предпочтительно, свыше 97%.5. Способ по п. 1, в котором на стадии b) ПУ присутствует в водной среде, и коагуляция ПУ имеет место в воде, содержащей электролиты или кислоты, в горячей воде или посредством радиочастотной или паровой коагуляции.6. Способ по п. 1, в котором стадия с) удаления компонента "моря" имеет место при взаимодействии промежуточного продукта, как получено на стадии b), с водным щелочным раствором гидроксида щелочного металла или щелочно-земельного металла,предпочтительно, NaOH.7. Способ по п. 1, в котором стадия с) удаления компонента "моря" имеет место при1. A method of producing a microfiber nonwoven fabric, which comprises the following steps: a) obtaining felt by needle-piercing an island-in-sea-type bicomponent fiber, b) hot impregnating said felt with an aqueous solution of polyvinyl alcohol (PVA) having a degree of saponification of at least , 94%, or hot impregnation of the specified felt with water and then cold impregnation with polyurethane (PU), c) removal of the sea component from the intermediate product of step b), d) impregnation of the microfibrous intermediate PU, e) fixing PU from microfibers by coagulation and removal of PVA, possibly introduced in step b), f) sanding of the material thus obtained on one or both sides, staining and cleavage, preferably carried out in a specific order. 2. The method according to claim 1, wherein stage b) is carried out by impregnation with an aqueous solution of PVA at a temperature of at least 50 ° C. 3. The method according to claim 1, in which stage b) is carried out by impregnating the PU in an aqueous medium at a temperature not exceeding 50 ° C. A method according to claim 1, wherein the PVA in step b) has a saponification degree of at least 94%, even more preferably over 97%. The method according to claim 1, wherein in step b), the PU is present in the aqueous medium, and the coagulation of the PU occurs in water containing electrolytes or acids, in hot water, or by radio-frequency or steam coagulation. The method of claim 1, wherein step c) removing the “sea” component occurs by reacting the intermediate product as obtained in step b) with an aqueous alkaline solution of an alkali metal hydroxide or alkaline earth metal, preferably NaOH. The method of claim 1, wherein step c) removing the “sea” component occurs when
Claims (19)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT001780A ITMI20121780A1 (en) | 2012-10-22 | 2012-10-22 | NEW PROCESS FOR THE PREPARATION OF A NON-WOVEN FABRIC SYNTHETIC MICRO-FIBROUS SUEDE |
| ITMI2012A001780 | 2012-10-22 | ||
| PCT/IB2013/059498 WO2014087271A1 (en) | 2012-10-22 | 2013-10-21 | Process for the preparation of a non-woven microfibrous suede-like synthetic fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015119246A true RU2015119246A (en) | 2016-12-10 |
| RU2635607C2 RU2635607C2 (en) | 2017-11-14 |
Family
ID=47388545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015119246A RU2635607C2 (en) | 2012-10-22 | 2013-10-21 | Production method of synthetic microfibre nonwoven fabric in imitation of chamois-leather |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10400391B2 (en) |
| EP (1) | EP2780501B1 (en) |
| JP (1) | JP6371772B2 (en) |
| KR (1) | KR102076256B1 (en) |
| CN (1) | CN104854273B (en) |
| ES (1) | ES2543827T3 (en) |
| HU (1) | HUE025682T2 (en) |
| IT (1) | ITMI20121780A1 (en) |
| PL (1) | PL2780501T3 (en) |
| RU (1) | RU2635607C2 (en) |
| WO (1) | WO2014087271A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2774688C2 (en) * | 2017-08-02 | 2022-06-21 | Алькантара С.П.А. | Method for production of micro-fibrous non-woven synthetic suede-like material |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104838063B (en) * | 2012-11-30 | 2016-09-28 | 东丽株式会社 | Tablet and the manufacture method of this tablet |
| TWI629298B (en) * | 2014-09-30 | 2018-07-11 | 東麗股份有限公司 | Sheet material manufacturing method |
| TR201517806A2 (en) | 2015-12-31 | 2016-09-21 | Kipas Mensucat Isletmeleri Anonim Sirketi | OBJECTIVE OF SANDED FABRIC PROPERTIES WITHOUT COTTON YARN TOUCHED FABRIC SANDING PROCESS |
| US11266344B2 (en) | 2016-09-21 | 2022-03-08 | Samsung Electronics Co., Ltd. | Method for measuring skin condition and electronic device therefor |
| IT201700089038A1 (en) * | 2017-08-02 | 2019-02-02 | Alcantara Spa | NEW PROCESS FOR THE PREPARATION OF A NON-FABRIC SYNTHETIC MICRO-FIBROUS SUEDE FABRIC |
| US11834780B2 (en) | 2018-08-21 | 2023-12-05 | Dow Global Technologies Llc | Process for forming synthetic leather |
| BR112021002983A2 (en) | 2018-08-21 | 2021-05-11 | Dow Global Technologies Llc | process, and, synthetic leather. |
| WO2025233898A1 (en) | 2024-05-09 | 2025-11-13 | Alcantara S.P.A. | Use of vanillin for dyeing a microfibrous substrate |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3531368A (en) | 1966-01-07 | 1970-09-29 | Toray Industries | Synthetic filaments and the like |
| GB1195369A (en) | 1966-12-08 | 1970-06-17 | Engineering Developments Birmi | Improvements in, or relating to, Couplings for Tubes, Bars and the like |
| US3731352A (en) * | 1970-06-15 | 1973-05-08 | Toray Industries | Method of manufacturing a fibrous sheet |
| US3889292A (en) | 1970-09-21 | 1975-06-10 | Xerox Corp | Apparatus for making multiple alphanumeric copies of a binary coded message |
| JPS61215782A (en) * | 1985-03-15 | 1986-09-25 | Toray Ind Inc | Production of artificial leather sheet |
| JP2002249988A (en) * | 2001-02-20 | 2002-09-06 | Toray Ind Inc | Method for producing leather-like sheetlike material |
| ITMI20010516A1 (en) * | 2001-03-12 | 2002-09-12 | Alcantara Spa | PROCESS FOR THE PRODUCTION OF A MICROFIBROUS SUEDE NONWOVEN FABRIC WITHOUT THE USE OF ORGANIC SOLVENTS |
| JP4221956B2 (en) * | 2001-07-13 | 2009-02-12 | 東レ株式会社 | Napped leather-like sheet-like material and method for producing the same |
| CN1316119C (en) * | 2002-04-10 | 2007-05-16 | 阿尔坎塔拉股份有限公司 | Producing process and correlative method for microfiber chamois non-woven cloth |
| EP1353006B1 (en) * | 2002-04-10 | 2009-07-22 | ALCANTARA S.p.A. | Process for the production of micro-fibrous suede non-woven fabric |
| JP4419549B2 (en) * | 2003-07-18 | 2010-02-24 | 東レ株式会社 | Ultra-fine short fiber nonwoven fabric and leather-like sheet and production method thereof |
| CN1308539C (en) * | 2005-01-18 | 2007-04-04 | 山东同大纺织机械有限公司 | High strength ultrafine fiber simulation composite lether and its manufacturing method |
| JP5280303B2 (en) * | 2008-06-30 | 2013-09-04 | セーレン株式会社 | Nubuck-like sheet and method for producing the same |
| KR101056502B1 (en) * | 2009-09-21 | 2011-08-12 | (주)한올글로텍 | Manufacturing method of split microfiber nonwoven |
| CN101798763B (en) * | 2009-12-21 | 2014-01-22 | 厦门泓信超细纤维材料有限公司 | Superfine fiber polyurethane synthesis leather and preparation method thereof |
| CN102619095B (en) | 2011-01-27 | 2013-01-30 | 吉林润泽超细纤维科技有限公司 | Manufacturing method of environmentally-friendly flame-retardant bunched sea-island chamois leather |
-
2012
- 2012-10-22 IT IT001780A patent/ITMI20121780A1/en unknown
-
2013
- 2013-10-21 RU RU2015119246A patent/RU2635607C2/en active
- 2013-10-21 KR KR1020157013176A patent/KR102076256B1/en active Active
- 2013-10-21 EP EP13821945.6A patent/EP2780501B1/en active Active
- 2013-10-21 WO PCT/IB2013/059498 patent/WO2014087271A1/en not_active Ceased
- 2013-10-21 JP JP2015537409A patent/JP6371772B2/en active Active
- 2013-10-21 PL PL13821945T patent/PL2780501T3/en unknown
- 2013-10-21 HU HUE13821945A patent/HUE025682T2/en unknown
- 2013-10-21 ES ES13821945.6T patent/ES2543827T3/en active Active
- 2013-10-21 US US14/437,313 patent/US10400391B2/en active Active
- 2013-10-21 CN CN201380054812.8A patent/CN104854273B/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2774688C2 (en) * | 2017-08-02 | 2022-06-21 | Алькантара С.П.А. | Method for production of micro-fibrous non-woven synthetic suede-like material |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2780501B1 (en) | 2015-06-03 |
| ES2543827T3 (en) | 2015-08-24 |
| HK1208508A1 (en) | 2016-03-04 |
| KR102076256B1 (en) | 2020-03-02 |
| ITMI20121780A1 (en) | 2014-04-23 |
| JP2015536388A (en) | 2015-12-21 |
| US10400391B2 (en) | 2019-09-03 |
| EP2780501A1 (en) | 2014-09-24 |
| PL2780501T3 (en) | 2015-10-30 |
| CN104854273B (en) | 2017-10-27 |
| JP6371772B2 (en) | 2018-08-08 |
| WO2014087271A1 (en) | 2014-06-12 |
| HUE025682T2 (en) | 2016-04-28 |
| US20150275421A1 (en) | 2015-10-01 |
| RU2635607C2 (en) | 2017-11-14 |
| CN104854273A (en) | 2015-08-19 |
| KR20150084866A (en) | 2015-07-22 |
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