RU2346977C2 - Способ улучшения температуры потери подвижности углеводородного сырья, полученного в процессе фишера-тропша, использующий катализатор на основе смеси цеолитов - Google Patents

Способ улучшения температуры потери подвижности углеводородного сырья, полученного в процессе фишера-тропша, использующий катализатор на основе смеси цеолитов Download PDF

Info

Publication number: RU2346977C2
Authority: RU; Russia
Prior art keywords: catalyst; temperature; zeolite; fraction; loss
Prior art date: 2003-07-03

Application number

RU2006103076/04A

Other languages

English (en)

Russian (ru)

Other versions

RU2006103076A (ru

Inventor

Эрик БЕНАЗЗИ (FR)

Эрик БЕНАЗЗИ

Эмманюэль ГИЙОН (FR)

Эмманюэль ГИЙОН

Original Assignee

Энститю Франсэ Дю Петроль

Эни Спа

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2003-07-03

Filing date

2004-07-02

Publication date

2009-02-20

2004-07-02 Application filed by Энститю Франсэ Дю Петроль, Эни Спа filed Critical Энститю Франсэ Дю Петроль

2006-06-10 Publication of RU2006103076A publication Critical patent/RU2006103076A/ru

2009-02-20 Application granted granted Critical

2009-02-20 Publication of RU2346977C2 publication Critical patent/RU2346977C2/ru

Links

239000003054 catalyst Substances 0.000 title claims abstract description 121
239000010457 zeolite Substances 0.000 title claims abstract description 105
238000000034 method Methods 0.000 title claims abstract description 95
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 76
229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 61
239000000203 mixture Substances 0.000 title claims description 26
230000015572 biosynthetic process Effects 0.000 title abstract description 20
150000002430 hydrocarbons Chemical class 0.000 title abstract description 18
229930195733 hydrocarbon Natural products 0.000 title abstract description 16
238000003786 synthesis reaction Methods 0.000 title abstract description 16
239000004215 Carbon black (E152) Substances 0.000 title abstract description 10
239000000463 material Substances 0.000 title abstract description 6
238000006243 chemical reaction Methods 0.000 claims abstract description 24
239000011159 matrix material Substances 0.000 claims abstract description 14
230000000737 periodic effect Effects 0.000 claims abstract description 11
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 53
239000001257 hydrogen Substances 0.000 claims description 42
229910052739 hydrogen Inorganic materials 0.000 claims description 42
239000002994 raw material Substances 0.000 claims description 36
238000009835 boiling Methods 0.000 claims description 29
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 28
230000003197 catalytic effect Effects 0.000 claims description 27
238000004821 distillation Methods 0.000 claims description 24
229910052697 platinum Inorganic materials 0.000 claims description 24
230000008569 process Effects 0.000 claims description 22
229910000510 noble metal Inorganic materials 0.000 claims description 17
229910052763 palladium Inorganic materials 0.000 claims description 14
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 12
150000001875 compounds Chemical class 0.000 claims description 11
238000004517 catalytic hydrocracking Methods 0.000 claims description 7
238000000926 separation method Methods 0.000 claims description 7
238000006356 dehydrogenation reaction Methods 0.000 claims description 6
239000000314 lubricant Substances 0.000 claims description 6
238000012545 processing Methods 0.000 claims description 5
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
239000007788 liquid Substances 0.000 claims description 4
229910052750 molybdenum Inorganic materials 0.000 claims description 4
239000011733 molybdenum Substances 0.000 claims description 4
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 3
239000000356 contaminant Substances 0.000 claims description 3
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
229910052721 tungsten Inorganic materials 0.000 claims description 3
239000010937 tungsten Substances 0.000 claims description 3
229910052799 carbon Inorganic materials 0.000 claims description 2
239000002199 base oil Substances 0.000 abstract description 10
239000002808 molecular sieve Substances 0.000 abstract description 10
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract description 10
239000000126 substance Substances 0.000 abstract description 5
230000000694 effects Effects 0.000 abstract description 2
239000003921 oil Substances 0.000 description 48
239000000047 product Substances 0.000 description 41
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 39
229910052751 metal Inorganic materials 0.000 description 34
239000002184 metal Substances 0.000 description 34
239000000758 substrate Substances 0.000 description 20
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 14
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
239000002253 acid Substances 0.000 description 12
229910000323 aluminium silicate Inorganic materials 0.000 description 12
239000007789 gas Substances 0.000 description 12
JZRWCGZRTZMZEH-UHFFFAOYSA-N thiamine Chemical compound CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N JZRWCGZRTZMZEH-UHFFFAOYSA-N 0.000 description 11
239000003795 chemical substances by application Substances 0.000 description 10
238000005984 hydrogenation reaction Methods 0.000 description 10
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
238000002360 preparation method Methods 0.000 description 9
150000001491 aromatic compounds Chemical class 0.000 description 8
239000012298 atmosphere Substances 0.000 description 8
238000005470 impregnation Methods 0.000 description 8
239000003350 kerosene Substances 0.000 description 8
150000002739 metals Chemical class 0.000 description 8
239000012188 paraffin wax Substances 0.000 description 8
-1 for example Inorganic materials 0.000 description 7
238000005194 fractionation Methods 0.000 description 7
238000006317 isomerization reaction Methods 0.000 description 7
239000011148 porous material Substances 0.000 description 7
239000000843 powder Substances 0.000 description 7
230000009467 reduction Effects 0.000 description 7
238000011282 treatment Methods 0.000 description 7
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
238000005336 cracking Methods 0.000 description 6
238000000465 moulding Methods 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
239000000243 solution Substances 0.000 description 6
239000010953 base metal Substances 0.000 description 5
239000003502 gasoline Substances 0.000 description 5
150000002431 hydrogen Chemical class 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
150000003057 platinum Chemical class 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
239000007787 solid Substances 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
238000001354 calcination Methods 0.000 description 4
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
238000005342 ion exchange Methods 0.000 description 4
MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 description 4
229910003446 platinum oxide Inorganic materials 0.000 description 4
238000012360 testing method Methods 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
230000002349 favourable effect Effects 0.000 description 3
229910052731 fluorine Inorganic materials 0.000 description 3
239000011737 fluorine Substances 0.000 description 3
229910052736 halogen Inorganic materials 0.000 description 3
150000002367 halogens Chemical class 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
238000009434 installation Methods 0.000 description 3
DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 3
MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 3
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
238000002203 pretreatment Methods 0.000 description 3
239000001294 propane Substances 0.000 description 3
238000011084 recovery Methods 0.000 description 3
229910052814 silicon oxide Inorganic materials 0.000 description 3
238000001308 synthesis method Methods 0.000 description 3
238000005292 vacuum distillation Methods 0.000 description 3
229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
229910004298 SiO 2 Inorganic materials 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 2
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 2
239000011609 ammonium molybdate Substances 0.000 description 2
229940010552 ammonium molybdate Drugs 0.000 description 2
235000018660 ammonium molybdate Nutrition 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
230000008901 benefit Effects 0.000 description 2
230000001588 bifunctional effect Effects 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
238000005341 cation exchange Methods 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
238000009826 distribution Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000005530 etching Methods 0.000 description 2
238000000605 extraction Methods 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
239000000446 fuel Substances 0.000 description 2
125000005842 heteroatom Chemical group 0.000 description 2
229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
PQLXHQMOHUQAKB-UHFFFAOYSA-N miltefosine Chemical compound CCCCCCCCCCCCCCCCOP([O-])(=O)OCC[N+](C)(C)C PQLXHQMOHUQAKB-UHFFFAOYSA-N 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
150000002927 oxygen compounds Chemical class 0.000 description 2
230000036961 partial effect Effects 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
239000011343 solid material Substances 0.000 description 2
150000003464 sulfur compounds Chemical class 0.000 description 2
238000005987 sulfurization reaction Methods 0.000 description 2
AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical class CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
239000004113 Sepiolite Substances 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
QZYDAIMOJUSSFT-UHFFFAOYSA-N [Co].[Ni].[Mo] Chemical compound [Co].[Ni].[Mo] QZYDAIMOJUSSFT-UHFFFAOYSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
230000004913 activation Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
238000005349 anion exchange Methods 0.000 description 1
238000000137 annealing Methods 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
238000001479 atomic absorption spectroscopy Methods 0.000 description 1
229960000892 attapulgite Drugs 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
235000012216 bentonite Nutrition 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
229910052810 boron oxide Inorganic materials 0.000 description 1
150000001649 bromium compounds Chemical class 0.000 description 1
239000001273 butane Substances 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
230000008859 change Effects 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
239000003245 coal Substances 0.000 description 1
WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
JPNWDVUTVSTKMV-UHFFFAOYSA-N cobalt tungsten Chemical compound [Co].[W] JPNWDVUTVSTKMV-UHFFFAOYSA-N 0.000 description 1
230000002860 competitive effect Effects 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
239000012084 conversion product Substances 0.000 description 1
230000008021 deposition Effects 0.000 description 1
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
238000011066 ex-situ storage Methods 0.000 description 1
150000002222 fluorine compounds Chemical class 0.000 description 1
238000001879 gelation Methods 0.000 description 1
229910021472 group 8 element Inorganic materials 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
KWUUWVQMAVOYKS-UHFFFAOYSA-N iron molybdenum Chemical compound [Fe].[Fe][Mo][Mo] KWUUWVQMAVOYKS-UHFFFAOYSA-N 0.000 description 1
GXBKELQWVXYOPN-UHFFFAOYSA-N iron tungsten Chemical compound [W][Fe][W] GXBKELQWVXYOPN-UHFFFAOYSA-N 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
GSWAOPJLTADLTN-UHFFFAOYSA-N oxidanimine Chemical class [O-][NH3+] GSWAOPJLTADLTN-UHFFFAOYSA-N 0.000 description 1
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
229910052625 palygorskite Inorganic materials 0.000 description 1
239000012071 phase Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
229910052624 sepiolite Inorganic materials 0.000 description 1
235000019355 sepiolite Nutrition 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
230000008719 thickening Effects 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
238000004448 titration Methods 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
238000012546 transfer Methods 0.000 description 1
150000003657 tungsten Chemical class 0.000 description 1
239000001993 wax Substances 0.000 description 1
238000004846 x-ray emission Methods 0.000 description 1
238000004876 x-ray fluorescence Methods 0.000 description 1
LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical class [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/10—Lubricating oil

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

RU2006103076/04A 2003-07-03 2004-07-02 Способ улучшения температуры потери подвижности углеводородного сырья, полученного в процессе фишера-тропша, использующий катализатор на основе смеси цеолитов RU2346977C2 (ru)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR0308153A FR2857020B1 (fr)	2003-07-03	2003-07-03	Procede d'amelioration du point d'ecoulement de charges hydrocarbonees issues du procede fischer-tropsch, utilisant un catalyseur a base d'un melange de zeolithes
FR0308153		2003-07-03

Publications (2)

Publication Number	Publication Date
RU2006103076A RU2006103076A (ru)	2006-06-10
RU2346977C2 true RU2346977C2 (ru)	2009-02-20

Family

ID=33522750

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
RU2006103076/04A RU2346977C2 (ru)	2003-07-03	2004-07-02	Способ улучшения температуры потери подвижности углеводородного сырья, полученного в процессе фишера-тропша, использующий катализатор на основе смеси цеолитов

Country Status (6)

Country	Link
DE (1)	DE112004001058B4 (fr)
FR (1)	FR2857020B1 (fr)
IT (1)	ITMI20041313A1 (fr)
RU (1)	RU2346977C2 (fr)
WO (1)	WO2005012461A1 (fr)
ZA (1)	ZA200509837B (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2490307C1 (ru) *	2012-10-01	2013-08-20	Андрей Владиславович Курочкин	Способ переработки нефти
RU2515938C1 (ru) *	2013-04-24	2014-05-20	Андрей Владиславович Курочкин	Способ переработки нефти
WO2015080611A1 (fr)	2013-11-26	2015-06-04	Infra XTL Technology Limited	Catalyseur pour diriger la production d'huile synthétique riche en isoparaffines et procédé de préparation du catalyseur
RU2662825C2 (ru) *	2012-06-28	2018-07-31	Шелл Интернэшнл Рисерч Маатсхаппий Б.В.	Способ получения фракции газойля и остаточного базового масла

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8940253B2 (en)	2012-03-29	2015-01-27	Uop Llc	Process and apparatus for producing diesel from a hydrocarbon stream
US8871082B2 (en) *	2012-03-29	2014-10-28	Uop Llc	Process and apparatus for producing diesel from a hydrocarbon stream
CN108816279B (zh) *	2018-05-23	2021-03-16	中国中化股份有限公司	一种正构烷烃临氢异构化催化剂的制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0046504A1 (fr) *	1980-08-21	1982-03-03	BASF Aktiengesellschaft	Zéolite métalsilicate cristalline ZBM-30 et procédé pour sa préparation

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2805762B1 (fr) *	2000-03-02	2004-01-16	Inst Francais Du Petrole	Catalyseur a base de zeolithe zsm-48 et procede pour l'amelioration du point d'ecoulement de charges paraffiniques
FR2808028B1 (fr) *	2000-04-21	2003-09-05	Inst Francais Du Petrole	Procede flexible de production de bases huiles avec une zeolithe zsm-48
FR2818284B1 (fr) *	2000-12-15	2006-08-04	Inst Francais Du Petrole	Procede flexible ameliore de production de bases huiles et distillats moyens avec une conversion-hydroisomerisation suivie d'un deparaffinage catalytique
FR2818285B1 (fr) *	2000-12-15	2004-12-17	Inst Francais Du Petrole	Procede flexible ameliore de production de bases huiles et de distillats par une conversion-hydroisomerisation sur un catalyseur faiblement disperse suivie d'un deparaffinage catalytique

2003
- 2003-07-03 FR FR0308153A patent/FR2857020B1/fr not_active Expired - Lifetime
2004
- 2004-06-30 IT ITMI20041313 patent/ITMI20041313A1/it unknown
- 2004-07-02 RU RU2006103076/04A patent/RU2346977C2/ru not_active IP Right Cessation
- 2004-07-02 WO PCT/FR2004/001715 patent/WO2005012461A1/fr not_active Ceased
- 2004-07-02 DE DE112004001058T patent/DE112004001058B4/de not_active Expired - Fee Related
2005
- 2005-12-05 ZA ZA200509837A patent/ZA200509837B/en unknown

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0046504A1 (fr) *	1980-08-21	1982-03-03	BASF Aktiengesellschaft	Zéolite métalsilicate cristalline ZBM-30 et procédé pour sa préparation

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2662825C2 (ru) *	2012-06-28	2018-07-31	Шелл Интернэшнл Рисерч Маатсхаппий Б.В.	Способ получения фракции газойля и остаточного базового масла
RU2490307C1 (ru) *	2012-10-01	2013-08-20	Андрей Владиславович Курочкин	Способ переработки нефти
RU2515938C1 (ru) *	2013-04-24	2014-05-20	Андрей Владиславович Курочкин	Способ переработки нефти
WO2015080611A1 (fr)	2013-11-26	2015-06-04	Infra XTL Technology Limited	Catalyseur pour diriger la production d'huile synthétique riche en isoparaffines et procédé de préparation du catalyseur

Also Published As

Publication number	Publication date
FR2857020B1 (fr)	2007-08-17
ITMI20041313A1 (it)	2004-09-30
DE112004001058T5 (de)	2006-04-27
RU2006103076A (ru)	2006-06-10
FR2857020A1 (fr)	2005-01-07
DE112004001058B4 (de)	2009-04-23
WO2005012461A1 (fr)	2005-02-10
ZA200509837B (en)	2007-02-28

Legal Events

Date	Code	Title	Description
2020-05-27	MM4A	The patent is invalid due to non-payment of fees	Effective date: 20190703

Publication	Publication Date	Title
KR100695181B1 (ko)	2007-03-16	분산도가 낮은 촉매를 사용하는 전환-수소화 이성화 반응후 접촉 탈왁스화 처리에 의한 베이스 오일 및 증류물의 플렉시블 제조 방법
US7670983B2 (en)	2010-03-02	Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product
RU2458969C2 (ru)	2012-08-20	Комплексная гидропереработка с высокопроизводительными катализаторами
EP2384815A1 (fr)	2011-11-09	Catalyseur d'isomérisation par hydrogénation, procédé destiné à le produire, procédé destiné à déparaffiner une huile d'hydrocarbure et procédé destiné à produire une huile de base lubrifiante
JP5479610B2 (ja)	2014-04-23	軽質供給原料からの基油製造のための接触方法及びシステム
EP3050625B1 (fr)	2017-03-01	Procédé d'hydroconversion et catalyseur utilisé avec celui-ci
KR100695180B1 (ko)	2007-03-16	전환-수소화 이성화 반응후 접촉 탈왁스화 처리에 의한베이스 오일 및 중간 증류물의 융통적인 제조 방법
US7371315B2 (en)	2008-05-13	Flexible method for producing oil bases and distillates by hydroisomerization-conversion on a weakly dispersed catalyst followed by a catalyctic dewaxing
CN116685399A (zh)	2023-09-01	正链烷烃的选择性加氢裂化
US7449421B2 (en)	2008-11-11	Catalyst and its use for improving the pour point of hydrocarbon charges
US20150114882A1 (en)	2015-04-30	Method for dewaxing hydrocarbon oil and method for producing lubricating-oil base oil
US5273645A (en)	1993-12-28	Manufacture of lubricating oils
RU2346977C2 (ru)	2009-02-20	Способ улучшения температуры потери подвижности углеводородного сырья, полученного в процессе фишера-тропша, использующий катализатор на основе смеси цеолитов
RU2343184C2 (ru)	2009-01-10	Способ улучшения температуры потери подвижности углеводородного сырья, полученного в процессе фишера-тропша, использующий катализатор на основе цеолита zbm-30
US8845881B2 (en)	2014-09-30	Process for middle distillae production form fischer-tropsch waxes using a modified-zeolite-based catalyst
US7282465B2 (en)	2007-10-16	Catalyst and its use for improving the pour point of hydrocarbon charges
KR20230162011A (ko)	2023-11-28	분자체 ssz-92, 촉매, 및 이의 사용 방법
FR2950896A1 (fr)	2011-04-08	Procede de production de distillats moyens par hydroisomerisation et hydrocraquage de charges issues du procede fischer-tropsch mettant en oeuvre un catalyseur a base de carbure de silicium
CZ20001570A3 (cs)	2001-03-14	Způsob výroby výchozího materiálu a střední frakce destilace konverzí-hydrogenační isomeraci a následným katalytickým odparafínováním

Info

Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (2)

Family

ID=33522750

Family Applications (1)

Country Status (6)

Cited By (4)

Families Citing this family (3)

Citations (1)

Family Cites Families (4)

Patent Citations (1)

Cited By (4)

Also Published As

Similar Documents

Legal Events