SE429200B - Forfarande for atervinning av natriumcitrat fran vattenlosningar som anvents i ett absorptions/avdrivningsforfarande for so?712-atervinning - Google Patents

Forfarande for atervinning av natriumcitrat fran vattenlosningar som anvents i ett absorptions/avdrivningsforfarande for so?712-atervinning

Info

Publication number: SE429200B
Authority: SE; Sweden
Prior art keywords: sodium citrate; recovery; evaporation; absorption; mother liquor
Prior art date: 1978-10-31

Application number

SE7811278A

Other languages

English (en)

Swedish (sv)

Other versions

SE7811278L (sv

Inventor

S Bengtsson

T Lillestolen

Original Assignee

Flaekt Ab

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-10-31

Filing date

1978-10-31

Publication date

1983-08-22

1978-10-31 Application filed by Flaekt Ab filed Critical Flaekt Ab

1978-10-31 Priority to SE7811278A priority Critical patent/SE429200B/sv

1979-10-16 Priority to DE19792941882 priority patent/DE2941882A1/de

1979-10-24 Priority to CA338,313A priority patent/CA1127184A/fr

1979-10-31 Priority to US06/090,003 priority patent/US4310691A/en

1980-05-01 Publication of SE7811278L publication Critical patent/SE7811278L/xx

1983-08-22 Publication of SE429200B publication Critical patent/SE429200B/sv

Links

239000001509 sodium citrate Substances 0.000 title claims description 25
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 title claims description 25
238000000034 method Methods 0.000 title claims description 23
238000010521 absorption reaction Methods 0.000 title claims description 18
238000011084 recovery Methods 0.000 title claims description 8
229910001868 water Inorganic materials 0.000 title description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 5
239000012452 mother liquor Substances 0.000 claims description 19
239000002250 absorbent Substances 0.000 claims description 18
230000002745 absorbent Effects 0.000 claims description 18
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 15
238000001704 evaporation Methods 0.000 claims description 11
230000008020 evaporation Effects 0.000 claims description 11
238000001816 cooling Methods 0.000 claims description 9
229910052938 sodium sulfate Inorganic materials 0.000 claims description 9
235000011152 sodium sulphate Nutrition 0.000 claims description 9
239000000243 solution Substances 0.000 claims description 9
238000002425 crystallisation Methods 0.000 claims description 6
230000008025 crystallization Effects 0.000 claims description 6
238000001556 precipitation Methods 0.000 claims description 5
239000010865 sewage Substances 0.000 claims description 4
239000007864 aqueous solution Substances 0.000 claims description 3
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 20
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 13
239000007789 gas Substances 0.000 description 10
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical class [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 8
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000013078 crystal Substances 0.000 description 6
239000011734 sodium Substances 0.000 description 6
229910021653 sulphate ion Inorganic materials 0.000 description 6
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
239000012535 impurity Substances 0.000 description 4
239000007788 liquid Substances 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical class [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
229910000041 hydrogen chloride Inorganic materials 0.000 description 3
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
238000009825 accumulation Methods 0.000 description 2
229910052788 barium Inorganic materials 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
239000003344 environmental pollutant Substances 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
231100000719 pollutant Toxicity 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
229910052712 strontium Inorganic materials 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical class [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
159000000009 barium salts Chemical class 0.000 description 1
FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
239000001354 calcium citrate Substances 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
230000009918 complex formation Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000000428 dust Substances 0.000 description 1
229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
238000011081 inoculation Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000004064 recycling Methods 0.000 description 1
239000003507 refrigerant Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000004289 sodium hydrogen sulphite Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
238000010591 solubility diagram Methods 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
159000000008 strontium salts Chemical class 0.000 description 1
VTBSJEPGLHXIIS-UHFFFAOYSA-L strontium;sulfite Chemical compound [Sr+2].[O-]S([O-])=O VTBSJEPGLHXIIS-UHFFFAOYSA-L 0.000 description 1
DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
235000013337 tricalcium citrate Nutrition 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/048—Purification of waste water by evaporation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Environmental & Geological Engineering (AREA)
Water Supply & Treatment (AREA)
Life Sciences & Earth Sciences (AREA)
Crystallography & Structural Chemistry (AREA)
Hydrology & Water Resources (AREA)
Health & Medical Sciences (AREA)
Biomedical Technology (AREA)
Analytical Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Treating Waste Gases (AREA)
Gas Separation By Absorption (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

SE7811278A 1978-10-31 1978-10-31 Forfarande for atervinning av natriumcitrat fran vattenlosningar som anvents i ett absorptions/avdrivningsforfarande for so?712-atervinning SE429200B (sv)

Priority Applications (4)

Application Number	Priority Date	Filing Date	Title
SE7811278A SE429200B (sv)	1978-10-31	1978-10-31	Forfarande for atervinning av natriumcitrat fran vattenlosningar som anvents i ett absorptions/avdrivningsforfarande for so?712-atervinning
DE19792941882 DE2941882A1 (de)	1978-10-31	1979-10-16	Verfahren zum selektiven abtrennen von natriumzitrat aus einer waessrigen loesung
CA338,313A CA1127184A (fr)	1978-10-31	1979-10-24	Procede permettant de recuperer selectivement le citrate de sodium en solution aqueuse
US06/090,003 US4310691A (en)	1978-10-31	1979-10-31	Method for selectively recovering sodium citrate from an aqueous solution

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
SE7811278A SE429200B (sv)	1978-10-31	1978-10-31	Forfarande for atervinning av natriumcitrat fran vattenlosningar som anvents i ett absorptions/avdrivningsforfarande for so?712-atervinning

Publications (2)

Publication Number	Publication Date
SE7811278L SE7811278L (sv)	1980-05-01
SE429200B true SE429200B (sv)	1983-08-22

Family

ID=20336226

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE7811278A SE429200B (sv)	1978-10-31	1978-10-31	Forfarande for atervinning av natriumcitrat fran vattenlosningar som anvents i ett absorptions/avdrivningsforfarande for so?712-atervinning

Country Status (4)

Country	Link
US (1)	US4310691A (fr)
CA (1)	CA1127184A (fr)
DE (1)	DE2941882A1 (fr)
SE (1)	SE429200B (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO1989007973A1 (fr) *	1988-02-24	1989-09-08	Sintef	Procede de purification de solutions tampon aqueuses
WO1996016721A1 (fr) *	1994-11-28	1996-06-06	ABB Fläkt AB	Procede et appareillage de regulation de liquide pour l'epuration d'un gaz par voie humide

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4994609A (en) *	1990-06-06	1991-02-19	Innova S.A.	Production of citric acid
MX2013004816A (es)	2010-10-29	2013-07-02	Mecs Inc	Recuperacion regenerativa de dioxido de azufre de gases efluentes.
EP2844369B1 (fr)	2012-05-02	2020-09-02	MECS, Inc.	Récupération régénérative de contaminants à partir de gaz d'effluent
BR112015022004B8 (pt)	2013-03-15	2022-07-12	Mecs Inc	Processos para remoção de gás contaminante da fonte de gás e recuperação do referido gás e para a remoção de dióxido de enxofre de fonte de gás contendo dióxido de enxofre e recuperação do dióxido de enxofre
CN104557517B (zh) *	2014-12-19	2016-12-07	日照金禾博源生化有限公司	一种废柠檬酸钠母液综合处理工艺
CN117550762B (zh) *	2024-01-11	2024-03-12	上海第二工业大学	一种钠离子电池正极材料生产废水零排放处理方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2142987A (en) *	1935-12-24	1939-01-10	Bacon	Recovery of sulphur dioxide from gases
US2134482A (en) *	1935-12-28	1938-10-25	Commw Edison Co	Process of recovering so from waste gases
GB489745A (en)	1937-05-20	1938-08-03	Cons Mining & Smelting Company	Process for the absorption and subsequent recovery of sulphur dioxide from gases containing the same
NO133546C (fr) *	1972-11-24	1976-05-19	Sintef

1978
- 1978-10-31 SE SE7811278A patent/SE429200B/sv not_active IP Right Cessation
1979
- 1979-10-16 DE DE19792941882 patent/DE2941882A1/de not_active Withdrawn
- 1979-10-24 CA CA338,313A patent/CA1127184A/fr not_active Expired
- 1979-10-31 US US06/090,003 patent/US4310691A/en not_active Expired - Lifetime

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO1989007973A1 (fr) *	1988-02-24	1989-09-08	Sintef	Procede de purification de solutions tampon aqueuses
US5108625A (en) *	1988-02-24	1992-04-28	Sintef	Process for removing sodium sulfate from aqueous buffer solutions
WO1996016721A1 (fr) *	1994-11-28	1996-06-06	ABB Fläkt AB	Procede et appareillage de regulation de liquide pour l'epuration d'un gaz par voie humide

Also Published As

Publication number	Publication date
DE2941882A1 (de)	1980-05-14
CA1127184A (fr)	1982-07-06
SE7811278L (sv)	1980-05-01
US4310691A (en)	1982-01-12

Legal Events

Date

Code

Title

Description

1995-01-31

NUG

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Effective date: 19880322

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