SE432103B - Forfarande for framstellning av dispersioner av polymerer eller sampolymerer av vinylacetat - Google Patents

Forfarande for framstellning av dispersioner av polymerer eller sampolymerer av vinylacetat

Info

Publication number: SE432103B
Authority: SE; Sweden
Prior art keywords: parts; acetate; vinyl acetate; water; mixture
Prior art date: 1976-11-22

Application number

SE7713139A

Other languages

English (en)

Swedish (sv)

Other versions

SE7713139L (sv

Inventor

A Caporossi

C Foschi

Original Assignee

Anic Spa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-11-22

Filing date

1977-11-21

Publication date

1984-03-19

1977-11-21 Application filed by Anic Spa filed Critical Anic Spa

1978-05-23 Publication of SE7713139L publication Critical patent/SE7713139L/xx

1984-03-19 Publication of SE432103B publication Critical patent/SE432103B/sv

Links

238000000034 method Methods 0.000 title claims description 26
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title claims description 23
239000006185 dispersion Substances 0.000 title claims description 5
229920000642 polymer Polymers 0.000 title claims description 4
229920001577 copolymer Polymers 0.000 title claims 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 24
NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 claims description 20
239000000203 mixture Substances 0.000 claims description 19
239000000178 monomer Substances 0.000 claims description 15
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 14
238000006243 chemical reaction Methods 0.000 claims description 14
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims description 10
238000006116 polymerization reaction Methods 0.000 claims description 10
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 9
239000004372 Polyvinyl alcohol Substances 0.000 claims description 9
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 9
229920002451 polyvinyl alcohol Polymers 0.000 claims description 9
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 7
238000006136 alcoholysis reaction Methods 0.000 claims description 7
150000002148 esters Chemical class 0.000 claims description 7
230000001590 oxidative effect Effects 0.000 claims description 7
229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 7
235000017557 sodium bicarbonate Nutrition 0.000 claims description 7
239000000084 colloidal system Substances 0.000 claims description 6
GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical group [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 6
229920000151 polyglycol Polymers 0.000 claims description 6
239000010695 polyglycol Substances 0.000 claims description 6
230000001681 protective effect Effects 0.000 claims description 6
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 claims description 6
229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 6
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 5
239000012986 chain transfer agent Substances 0.000 claims description 5
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 5
230000000737 periodic effect Effects 0.000 claims description 5
239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 4
229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
150000001342 alkaline earth metals Chemical class 0.000 claims description 4
235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 4
229920000609 methyl cellulose Polymers 0.000 claims description 4
239000001923 methylcellulose Substances 0.000 claims description 4
235000010981 methylcellulose Nutrition 0.000 claims description 4
239000003513 alkali Substances 0.000 claims description 3
229910052783 alkali metal Inorganic materials 0.000 claims description 3
150000001340 alkali metals Chemical class 0.000 claims description 3
229910017052 cobalt Inorganic materials 0.000 claims description 3
239000010941 cobalt Substances 0.000 claims description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 claims description 3
MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 claims description 3
229920003063 hydroxymethyl cellulose Polymers 0.000 claims description 3
229940031574 hydroxymethyl cellulose Drugs 0.000 claims description 3
150000002978 peroxides Chemical class 0.000 claims description 3
229910021653 sulphate ion Inorganic materials 0.000 claims description 3
239000004094 surface-active agent Substances 0.000 claims description 3
230000002378 acidificating effect Effects 0.000 claims description 2
150000001299 aldehydes Chemical class 0.000 claims description 2
150000001735 carboxylic acids Chemical class 0.000 claims description 2
229910052742 iron Inorganic materials 0.000 claims description 2
229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
HSJXWMZKBLUOLQ-UHFFFAOYSA-M potassium;2-dodecylbenzenesulfonate Chemical compound [K+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HSJXWMZKBLUOLQ-UHFFFAOYSA-M 0.000 claims description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
150000002170 ethers Chemical class 0.000 claims 1
MGJURKDLIJVDEO-UHFFFAOYSA-N formaldehyde;hydrate Chemical compound O.O=C MGJURKDLIJVDEO-UHFFFAOYSA-N 0.000 claims 1
229910000028 potassium bicarbonate Inorganic materials 0.000 claims 1
235000015497 potassium bicarbonate Nutrition 0.000 claims 1
239000011736 potassium bicarbonate Substances 0.000 claims 1
239000002245 particle Substances 0.000 description 15
238000002474 experimental method Methods 0.000 description 11
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
239000007787 solid Substances 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
239000013049 sediment Substances 0.000 description 9
238000007710 freezing Methods 0.000 description 8
230000008014 freezing Effects 0.000 description 8
238000004458 analytical method Methods 0.000 description 7
238000010790 dilution Methods 0.000 description 7
239000012895 dilution Substances 0.000 description 7
230000035882 stress Effects 0.000 description 7
-1 Sodium dodecylbenzene sulfonate Sodium formaldehyde sulphoxylate Cobalt acetate Chemical compound 0.000 description 5
229940011182 cobalt acetate Drugs 0.000 description 4
QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
229920002554 vinyl polymer Polymers 0.000 description 4
238000005299 abrasion Methods 0.000 description 3
FJOPOOBDMDAVIW-UHFFFAOYSA-N ethenyl acetate;hydrate Chemical compound O.CC(=O)OC=C FJOPOOBDMDAVIW-UHFFFAOYSA-N 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
MGMBEMDBZKTGRG-UHFFFAOYSA-M sodium;hydrogen carbonate;hydrogen peroxide Chemical compound [Na+].OO.OC([O-])=O MGMBEMDBZKTGRG-UHFFFAOYSA-M 0.000 description 3
IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
239000000853 adhesive Substances 0.000 description 2
230000001070 adhesive effect Effects 0.000 description 2
238000003556 assay Methods 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
VYGBQXDNOUHIBZ-UHFFFAOYSA-L sodium formaldehyde sulphoxylate Chemical compound [Na+].[Na+].O=C.[O-]S[O-] VYGBQXDNOUHIBZ-UHFFFAOYSA-L 0.000 description 2
XXURNZLYJUXXCF-HJWRWDBZSA-N (z)-4-octan-3-yloxy-4-oxobut-2-enoic acid Chemical compound CCCCCC(CC)OC(=O)\C=C/C(O)=O XXURNZLYJUXXCF-HJWRWDBZSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
239000002253 acid Substances 0.000 description 1
238000004026 adhesive bonding Methods 0.000 description 1
230000032683 aging Effects 0.000 description 1
125000005250 alkyl acrylate group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000009089 cytolysis Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
NLVXSWCKKBEXTG-UHFFFAOYSA-M ethenesulfonate Chemical compound [O-]S(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-M 0.000 description 1
229940071826 hydroxyethyl cellulose Drugs 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000010309 melting process Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
229960002900 methylcellulose Drugs 0.000 description 1
239000003973 paint Substances 0.000 description 1
229920006316 polyvinylpyrrolidine Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
235000011056 potassium acetate Nutrition 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
LFYCPBYLRDFURN-UHFFFAOYSA-M sodium;acetic acid;hydrogen carbonate Chemical compound [Na+].CC(O)=O.OC([O-])=O LFYCPBYLRDFURN-UHFFFAOYSA-M 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/04—Vinyl esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Adhesives Or Adhesive Processes (AREA)
Polymerisation Methods In General (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polymerization Catalysts (AREA)
Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

SE7713139A 1976-11-22 1977-11-21 Forfarande for framstellning av dispersioner av polymerer eller sampolymerer av vinylacetat SE432103B (sv)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT29601/76A IT1064497B (it)	1976-11-22	1976-11-22	Procedimento per la produzione di dispersioni di polimeri o copolimeri da esteri vinilici e/o esteri di acidi carbossilici

Publications (2)

Publication Number	Publication Date
SE7713139L SE7713139L (sv)	1978-05-23
SE432103B true SE432103B (sv)	1984-03-19

Family

ID=11228080

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE7713139A SE432103B (sv)	1976-11-22	1977-11-21	Forfarande for framstellning av dispersioner av polymerer eller sampolymerer av vinylacetat

Country Status (19)

Country	Link
AT (1)	AT363683B (de)
BE (1)	BE861061A (de)
CH (1)	CH629227A5 (de)
DE (1)	DE2752102C2 (de)
DK (1)	DK516177A (de)
EG (1)	EG12967A (de)
ES (1)	ES464654A1 (de)
FI (1)	FI63247C (de)
FR (1)	FR2392042A1 (de)
GB (1)	GB1567704A (de)
GR (1)	GR64097B (de)
IE (1)	IE45992B1 (de)
IT (1)	IT1064497B (de)
LU (1)	LU78551A1 (de)
NL (1)	NL7712817A (de)
NO (1)	NO150318C (de)
PT (1)	PT67300B (de)
SE (1)	SE432103B (de)
TR (1)	TR19944A (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102007044788A1 (de) *	2007-09-19	2009-04-02	Wacker Chemie Ag	Herstellung von Vinylacetat-Vinylester-Mischpolymerisaten mit geringem Gehalt an hochsiedenden Vinylestern

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2998400A (en) *	1958-05-15	1961-08-29	Wyandotte Chemicals Corp	Floc-free polyvinyl acetate emulsions employing polyvinylmethyl ether copolymer as prtective colloid and process of preparation
FR1441940A (fr) *	1964-07-18	1966-06-10	Hoechst Ag	Procédé de préparation de dispersions aqueuses de polymères de composés oléfiniques

1976
- 1976-11-22 IT IT29601/76A patent/IT1064497B/it active
1977
- 1977-11-02 GR GR54696A patent/GR64097B/el unknown
- 1977-11-11 FI FI773416A patent/FI63247C/fi not_active IP Right Cessation
- 1977-11-16 EG EG647/77A patent/EG12967A/xx active
- 1977-11-17 TR TR19944A patent/TR19944A/xx unknown
- 1977-11-18 NO NO773948A patent/NO150318C/no unknown
- 1977-11-18 CH CH1415077A patent/CH629227A5/it not_active IP Right Cessation
- 1977-11-21 NL NL7712817A patent/NL7712817A/xx not_active Application Discontinuation
- 1977-11-21 FR FR7734945A patent/FR2392042A1/fr active Granted
- 1977-11-21 GB GB48444/77A patent/GB1567704A/en not_active Expired
- 1977-11-21 DK DK516177A patent/DK516177A/da not_active Application Discontinuation
- 1977-11-21 AT AT0832177A patent/AT363683B/de not_active IP Right Cessation
- 1977-11-21 LU LU78551A patent/LU78551A1/xx unknown
- 1977-11-21 PT PT67300A patent/PT67300B/pt unknown
- 1977-11-21 SE SE7713139A patent/SE432103B/sv unknown
- 1977-11-22 ES ES464654A patent/ES464654A1/es not_active Expired
- 1977-11-22 IE IE2367/77A patent/IE45992B1/en unknown
- 1977-11-22 DE DE2752102A patent/DE2752102C2/de not_active Expired
- 1977-11-22 BE BE182819A patent/BE861061A/xx not_active IP Right Cessation

Also Published As

Publication number	Publication date
NO773948L (no)	1978-05-23
GB1567704A (en)	1980-05-21
NO150318C (no)	1984-09-26
GR64097B (en)	1980-01-22
TR19944A (tr)	1980-05-08
PT67300B (en)	1979-04-20
PT67300A (en)	1977-12-01
LU78551A1 (de)	1978-04-13
DK516177A (da)	1978-05-23
FR2392042B1 (de)	1981-10-23
SE7713139L (sv)	1978-05-23
NL7712817A (nl)	1978-05-24
NO150318B (no)	1984-06-18
IE45992B1 (en)	1983-01-26
FI773416A7 (fi)	1978-05-23
AT363683B (de)	1981-08-25
BE861061A (fr)	1978-05-22
CH629227A5 (en)	1982-04-15
IE45992L (en)	1978-05-22
EG12967A (en)	1980-03-31
FR2392042A1 (fr)	1978-12-22
IT1064497B (it)	1985-02-18
FI63247C (fi)	1983-05-10
DE2752102C2 (de)	1982-11-04
ATA832177A (de)	1981-01-15
DE2752102A1 (de)	1978-05-24
ES464654A1 (es)	1978-09-01
FI63247B (fi)	1983-01-31

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