SE432604B - Forfarande for reformering av nafta med platina-rhenium-katalysator, samt katalytiskt kompositmaterial for anvendning dervid - Google Patents

Forfarande for reformering av nafta med platina-rhenium-katalysator, samt katalytiskt kompositmaterial for anvendning dervid

Info

Publication number: SE432604B
Authority: SE; Sweden
Prior art keywords: rhenium; platinum; catalyst; reforming; composite material
Prior art date: 1978-04-10

Application number

SE7903154A

Other languages

English (en)

Swedish (sv)

Other versions

SE7903154L (sv

Inventor

J P Gallagher

R M Yarrington

Original Assignee

Engelhard Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-04-10

Filing date

1979-04-09

Publication date

1984-04-09

1979-04-09 Application filed by Engelhard Corp filed Critical Engelhard Corp

1979-10-11 Publication of SE7903154L publication Critical patent/SE7903154L/

1984-04-09 Publication of SE432604B publication Critical patent/SE432604B/sv

Links

239000003054 catalyst Substances 0.000 title claims description 80
229910052702 rhenium Inorganic materials 0.000 title claims description 64
238000002407 reforming Methods 0.000 title claims description 20
239000002131 composite material Substances 0.000 title claims description 17
230000003197 catalytic effect Effects 0.000 title claims description 15
238000000034 method Methods 0.000 title claims description 15
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 135
229910052697 platinum Inorganic materials 0.000 claims description 64
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 63
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 33
229910052717 sulfur Inorganic materials 0.000 claims description 33
239000011593 sulfur Substances 0.000 claims description 33
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 14
239000000463 material Substances 0.000 claims description 10
229910052739 hydrogen Inorganic materials 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 8
239000000203 mixture Substances 0.000 claims description 8
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
150000004820 halides Chemical class 0.000 claims description 3
230000006866 deterioration Effects 0.000 claims 1
125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
DBJYYRBULROVQT-UHFFFAOYSA-N platinum rhenium Chemical compound [Re].[Pt] DBJYYRBULROVQT-UHFFFAOYSA-N 0.000 claims 1
239000007858 starting material Substances 0.000 claims 1
239000002994 raw material Substances 0.000 description 10
230000032683 aging Effects 0.000 description 7
238000002474 experimental method Methods 0.000 description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
230000000694 effects Effects 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
238000011160 research Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
241001026509 Kata Species 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000000571 coke Substances 0.000 description 3
238000011069 regeneration method Methods 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
-1 alkyl mercaptan Chemical compound 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000013058 crude material Substances 0.000 description 2
239000010779 crude oil Substances 0.000 description 2
230000007423 decrease Effects 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
238000004821 distillation Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
229910000041 hydrogen chloride Inorganic materials 0.000 description 2
229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000012263 liquid product Substances 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
230000008929 regeneration Effects 0.000 description 2
239000000243 solution Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
150000001348 alkyl chlorides Chemical class 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
VDTNNGKXZGSZIP-UHFFFAOYSA-N carbutamide Chemical compound CCCCNC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 VDTNNGKXZGSZIP-UHFFFAOYSA-N 0.000 description 1
238000001833 catalytic reforming Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
230000009089 cytolysis Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
230000002101 lytic effect Effects 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
230000000051 modifying effect Effects 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
239000003921 oil Substances 0.000 description 1
238000013021 overheating Methods 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
HRLYFPKUYKFYJE-UHFFFAOYSA-N tetraoxorhenate(2-) Chemical compound [O-][Re]([O-])(=O)=O HRLYFPKUYKFYJE-UHFFFAOYSA-N 0.000 description 1
229930192474 thiophene Natural products 0.000 description 1
230000004580 weight loss Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6567—Rhenium

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

SE7903154A 1978-04-10 1979-04-09 Forfarande for reformering av nafta med platina-rhenium-katalysator, samt katalytiskt kompositmaterial for anvendning dervid SE432604B (sv)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US89489078A	1978-04-10	1978-04-10

Publications (2)

Publication Number	Publication Date
SE7903154L SE7903154L (sv)	1979-10-11
SE432604B true SE432604B (sv)	1984-04-09

Family

ID=25403638

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE7903154A SE432604B (sv)	1978-04-10	1979-04-09	Forfarande for reformering av nafta med platina-rhenium-katalysator, samt katalytiskt kompositmaterial for anvendning dervid

Country Status (16)

Country	Link
JP (1)	JPS54145707A (da)
AU (2)	AU537495B2 (da)
BE (1)	BE875386A (da)
BR (1)	BR7902106A (da)
CA (1)	CA1127583A (da)
DE (1)	DE2913183A1 (da)
DK (1)	DK149692C (da)
EG (1)	EG13933A (da)
FI (1)	FI65798C (da)
FR (1)	FR2422711B1 (da)
GB (1)	GB2018278B (da)
IT (1)	IT1116165B (da)
MX (1)	MX151766A (da)
NL (1)	NL7902617A (da)
NO (1)	NO791160L (da)
SE (1)	SE432604B (da)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1223836A (en) *	1981-12-31	1987-07-07	William E. Winter	Catalytic reforming process
RU2206599C1 (ru) *	2002-04-25	2003-06-20	Макаров Павел Алексеевич	Способ получения ароматических углеводородов
FR2840548B1 (fr) *	2002-06-07	2005-03-18	Inst Francais Du Petrole	Lit homogene de catalyseur et procede de transformation d'hydrocarbures en composes aromatiques avec ledit lit

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3415737A (en) *	1966-06-24	1968-12-10	Chevron Res	Reforming a sulfur-free naphtha with a platinum-rhenium catalyst
CA1015298A (en) *	1968-04-24	1977-08-09	Ernest L. Pollitzer	Hydrocarbon conversion catalyst and processes for the manufacture and use thereof
CA949544A (en) *	1970-02-13	1974-06-18	Henry Erickson	Rhenium and platinum series metal-containing catalysts
FR2125126A1 (en) *	1971-02-12	1972-09-29	Universal Oil Prod Co	Hydrocarbon conversion - with a catalyst contg a platinum group metal,rhenium,tin and halogen
GB1374863A (en) *	1972-03-13	1974-11-20	Universal Oil Prod Co	Catalyst and process for the isomerization of hydrocarbons
CA1050917A (en) *	1973-05-07	1979-03-20	Atlantic Richfield Company	Hydrocarbon reforming process
FR2286187A1 (fr) *	1974-09-25	1976-04-23	Catalyse Soc Prod Francais	Catalyseurs d'hydroconversion des hydrocarbures

1979
- 1979-03-26 AU AU45470/79A patent/AU537495B2/en not_active Ceased
- 1979-04-02 DE DE19792913183 patent/DE2913183A1/de not_active Ceased
- 1979-04-03 NL NL7902617A patent/NL7902617A/xx not_active Application Discontinuation
- 1979-04-03 GB GB7911596A patent/GB2018278B/en not_active Expired
- 1979-04-04 FR FR7908480A patent/FR2422711B1/fr not_active Expired
- 1979-04-05 FI FI791128A patent/FI65798C/fi not_active IP Right Cessation
- 1979-04-05 DK DK140379A patent/DK149692C/da not_active IP Right Cessation
- 1979-04-05 BR BR7902106A patent/BR7902106A/pt unknown
- 1979-04-06 NO NO791160A patent/NO791160L/no unknown
- 1979-04-06 IT IT48661/79A patent/IT1116165B/it active
- 1979-04-06 BE BE0/194457A patent/BE875386A/xx not_active IP Right Cessation
- 1979-04-06 JP JP4118079A patent/JPS54145707A/ja active Granted
- 1979-04-09 EG EG212/79A patent/EG13933A/xx active
- 1979-04-09 CA CA325,146A patent/CA1127583A/en not_active Expired
- 1979-04-09 SE SE7903154A patent/SE432604B/sv not_active IP Right Cessation
- 1979-04-10 MX MX177265A patent/MX151766A/es unknown
1984
- 1984-04-18 AU AU27076/84A patent/AU2707684A/en not_active Abandoned

Also Published As

Publication number	Publication date
NO791160L (no)	1979-10-11
FI791128A7 (fi)	1979-10-11
FI65798B (fi)	1984-03-30
JPS6353239B2 (da)	1988-10-21
AU537495B2 (en)	1984-06-28
IT7948661A0 (it)	1979-04-06
SE7903154L (sv)	1979-10-11
DK149692C (da)	1987-03-30
BR7902106A (pt)	1979-11-27
FR2422711A1 (fr)	1979-11-09
AU4547079A (en)	1979-10-18
BE875386A (fr)	1979-10-08
CA1127583A (en)	1982-07-13
FR2422711B1 (fr)	1985-11-29
DE2913183A1 (de)	1979-10-18
AU2707684A (en)	1984-08-02
MX151766A (es)	1985-03-07
GB2018278B (en)	1982-08-11
IT1116165B (it)	1986-02-10
FI65798C (fi)	1984-07-10
NL7902617A (nl)	1979-10-12
JPS54145707A (en)	1979-11-14
GB2018278A (en)	1979-10-17
DK140379A (da)	1979-10-11
DK149692B (da)	1986-09-08
EG13933A (en)	1983-03-31

Legal Events

Date

Code

Title

Description

1995-01-31

NUG

Patent has lapsed

Ref document number: 7903154-8

Effective date: 19931110

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US4134823A (en)	1979-01-16	Catalyst and hydrocarbon conversion process
JPS62192488A (ja)	1987-08-24	少なくとも２つの触媒床を通る接触リホ−ミング方法
US3006841A (en)	1961-10-31	Hydrocarbon conversion process
US4018711A (en)	1977-04-19	Catalytic composition
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US3424669A (en)	1969-01-28	Reforming-aromatization process with sulfided catalyst
US4613424A (en)	1986-09-23	Catalytic reforming process
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US4440667A (en)	1984-04-03	Catalyst regeneration in a catalytic reforming process
US2906699A (en)	1959-09-29	Adding a nitrogen compound to suppress hydrocracking in the reforming of a sulfur-containing naphtha