SE444185B - Forfarande for utvinning av zirkonium ur en betningslosning - Google Patents

Forfarande for utvinning av zirkonium ur en betningslosning

Info

Publication number: SE444185B
Authority: SE; Sweden
Prior art keywords: solution; zirconium; column; resin; pickling
Prior art date: 1977-11-29

Application number

SE7812086A

Other languages

English (en)

Swedish (sv)

Other versions

SE7812086L (sv

Inventor

A P Lamaze

Original Assignee

Ugine Aciers

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-11-29

Filing date

1978-11-23

Publication date

1986-03-24

1978-11-23 Application filed by Ugine Aciers filed Critical Ugine Aciers

1979-05-30 Publication of SE7812086L publication Critical patent/SE7812086L/xx

1986-03-24 Publication of SE444185B publication Critical patent/SE444185B/sv

Links

229910052726 zirconium Inorganic materials 0.000 title claims description 36
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 title claims description 34
238000000034 method Methods 0.000 title claims description 20
238000011084 recovery Methods 0.000 title description 3
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 34
238000005554 pickling Methods 0.000 claims description 33
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 22
-1 nitrate ions Chemical class 0.000 claims description 17
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 16
239000011347 resin Substances 0.000 claims description 12
229920005989 resin Polymers 0.000 claims description 12
238000011282 treatment Methods 0.000 claims description 12
239000002253 acid Substances 0.000 claims description 9
229910021653 sulphate ion Inorganic materials 0.000 claims description 9
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 8
229910002651 NO3 Inorganic materials 0.000 claims description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
239000012153 distilled water Substances 0.000 claims description 4
239000003957 anion exchange resin Substances 0.000 claims description 2
150000003754 zirconium Chemical class 0.000 claims description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 3
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
239000012141 concentrate Substances 0.000 claims 1
239000000243 solution Substances 0.000 description 57
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical class O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 7
239000011737 fluorine Substances 0.000 description 7
229910052731 fluorine Inorganic materials 0.000 description 7
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
150000002739 metals Chemical class 0.000 description 6
229910017604 nitric acid Inorganic materials 0.000 description 6
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
229910045601 alloy Inorganic materials 0.000 description 3
239000000956 alloy Substances 0.000 description 3
150000001450 anions Chemical class 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
239000000203 mixture Substances 0.000 description 3
230000007704 transition Effects 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000000654 additive Substances 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
230000007423 decrease Effects 0.000 description 2
239000002245 particle Substances 0.000 description 2
229920001467 poly(styrenesulfonates) Polymers 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000000725 suspension Substances 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
229910001093 Zr alloy Inorganic materials 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
230000007547 defect Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
JVJQPDTXIALXOG-UHFFFAOYSA-N nitryl fluoride Chemical compound [O-][N+](F)=O JVJQPDTXIALXOG-UHFFFAOYSA-N 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000008237 rinsing water Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000011135 tin Substances 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
230000004580 weight loss Effects 0.000 description 1
150000003755 zirconium compounds Chemical class 0.000 description 1
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/36—Regeneration of waste pickling liquors
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
- B01J49/07—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing anionic exchangers
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/06—Sulfates
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/46—Regeneration of etching compositions
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Inorganic Chemistry (AREA)
Metallurgy (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
General Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Environmental & Geological Engineering (AREA)
General Life Sciences & Earth Sciences (AREA)
Geochemistry & Mineralogy (AREA)
Geology (AREA)
Manufacturing & Machinery (AREA)
Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Inorganic Compounds Of Heavy Metals (AREA)
Manufacture And Refinement Of Metals (AREA)

SE7812086A 1977-11-29 1978-11-23 Forfarande for utvinning av zirkonium ur en betningslosning SE444185B (sv)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR7736627A FR2421952A1 (fr)	1977-11-29	1977-11-29	Procede de recuperation des acides et du zirconium contenus dans les solutions de decapage

Publications (2)

Publication Number	Publication Date
SE7812086L SE7812086L (sv)	1979-05-30
SE444185B true SE444185B (sv)	1986-03-24

Family

ID=9198474

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE7812086A SE444185B (sv)	1977-11-29	1978-11-23	Forfarande for utvinning av zirkonium ur en betningslosning

Country Status (13)

Country	Link
US (1)	US4200612A (it)
JP (1)	JPS5485114A (it)
BE (1)	BE872325A (it)
BR (1)	BR7807687A (it)
CA (1)	CA1107480A (it)
CH (1)	CH634600A5 (it)
DE (1)	DE2850784C2 (it)
ES (1)	ES475436A1 (it)
FR (1)	FR2421952A1 (it)
GB (1)	GB2009125B (it)
IT (1)	IT1101432B (it)
SE (1)	SE444185B (it)
ZA (1)	ZA786685B (it)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4572824A (en) *	1984-11-01	1986-02-25	General Electric Company	Process for recovery of zirconium and acid from spent etching solutions
US4894170A (en) *	1989-02-27	1990-01-16	Billmyre Richard D	Liquid recovery system and method
US5037545A (en) *	1989-02-27	1991-08-06	Billmyre Richard D	Liquid recovery system and method
US4960515A (en) *	1989-02-27	1990-10-02	Billmyre Richard D	Liquid recovery system
US5377234A (en) *	1992-10-23	1994-12-27	General Electric Company	Colloidal resin slurry recycle concentrating system of nuclear reactor coolant water
JP3053651B2 (ja) *	1996-04-29	2000-06-19	ウオンリー、キ	金属表面の酸洗浄法、その酸洗浄液、および洗浄廃液の再生方法
RU2124589C1 (ru) *	1996-12-03	1999-01-10	Открытое акционерное общество "Чепецкий механический завод"	Способ переработки отработанных кислых электролитов, содержащих цирконий и медь
RU2120497C1 (ru) *	1997-03-20	1998-10-20	Открытое акционерное общество "Чепецкий механический завод"	Способ регенерации нитрато-фторидных травильных растворов, содержащих цирконий

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2567661A (en) *	1948-08-31	1951-09-11	John A Ayres	Zirconium and hafnium recovery and purification process
US2738322A (en) *	1953-05-12	1956-03-13	Dow Chemical Co	Process for removing sulfuric acid from aqueous solutions of inorganic sulfates
FR1425429A (fr) *	1964-12-07	1966-01-24	Commissariat Energie Atomique	Procédé de purification de solutions industrielles d'un sel de hafnium et de zirconium

1977
- 1977-11-29 FR FR7736627A patent/FR2421952A1/fr active Granted
1978
- 1978-10-31 CA CA315,441A patent/CA1107480A/fr not_active Expired
- 1978-11-07 US US05/958,491 patent/US4200612A/en not_active Expired - Lifetime
- 1978-11-22 IT IT30025/78A patent/IT1101432B/it active
- 1978-11-23 SE SE7812086A patent/SE444185B/sv not_active IP Right Cessation
- 1978-11-23 BR BR7807687A patent/BR7807687A/pt unknown
- 1978-11-23 DE DE2850784A patent/DE2850784C2/de not_active Expired
- 1978-11-23 CH CH1201078A patent/CH634600A5/fr not_active IP Right Cessation
- 1978-11-27 ES ES475436A patent/ES475436A1/es not_active Expired
- 1978-11-28 JP JP14706078A patent/JPS5485114A/ja active Granted
- 1978-11-28 ZA ZA786685A patent/ZA786685B/xx unknown
- 1978-11-28 BE BE191973A patent/BE872325A/xx not_active IP Right Cessation
- 1978-11-28 GB GB7846387A patent/GB2009125B/en not_active Expired

Also Published As

Publication number	Publication date
FR2421952A1 (fr)	1979-11-02
FR2421952B1 (it)	1980-08-29
ES475436A1 (es)	1979-04-01
US4200612A (en)	1980-04-29
SE7812086L (sv)	1979-05-30
DE2850784A1 (de)	1979-05-31
BE872325A (fr)	1979-05-28
JPS5485114A (en)	1979-07-06
IT7830025A0 (it)	1978-11-22
ZA786685B (en)	1980-01-30
BR7807687A (pt)	1979-07-31
IT1101432B (it)	1985-09-28
DE2850784C2 (de)	1982-09-30
CH634600A5 (fr)	1983-02-15
GB2009125A (en)	1979-06-13
JPS5647938B2 (it)	1981-11-12
GB2009125B (en)	1982-05-12
CA1107480A (fr)	1981-08-25

Legal Events

Date

Code

Title

Description

1995-01-31

NUG

Patent has lapsed

Ref document number: 7812086-2

Effective date: 19940610

Format of ref document f/p: F

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