SE465569B - Foerfarande foer framstaellning av klordioxid - Google Patents
Foerfarande foer framstaellning av klordioxidInfo
- Publication number
- SE465569B SE465569B SE8901392A SE8901392A SE465569B SE 465569 B SE465569 B SE 465569B SE 8901392 A SE8901392 A SE 8901392A SE 8901392 A SE8901392 A SE 8901392A SE 465569 B SE465569 B SE 465569B
- Authority
- SE
- Sweden
- Prior art keywords
- methanol
- chlorine dioxide
- formaldehyde
- reducing agent
- weight
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 81
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 61
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 42
- 239000004155 Chlorine dioxide Substances 0.000 claims description 21
- 239000003638 chemical reducing agent Substances 0.000 claims description 21
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 10
- -1 alkali metal chlorate Chemical class 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000012429 reaction media Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052936 alkali metal sulfate Inorganic materials 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 238000002425 crystallisation Methods 0.000 claims 1
- 230000008025 crystallization Effects 0.000 claims 1
- 230000008020 evaporation Effects 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 description 17
- 238000002474 experimental method Methods 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE8901392A SE465569B (sv) | 1989-04-18 | 1989-04-18 | Foerfarande foer framstaellning av klordioxid |
| US07/426,714 US4986973A (en) | 1989-04-18 | 1989-10-26 | Process for the production of chlorine dioxide |
| NZ233318A NZ233318A (en) | 1989-04-18 | 1990-04-12 | Preparation of chlorine dioxide |
| JP2096604A JPH02293301A (ja) | 1989-04-18 | 1990-04-13 | 二酸化塩素の製造方法 |
| CA002014691A CA2014691C (fr) | 1989-04-18 | 1990-04-17 | Procede pour la production de dioxyde de chlore |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE8901392A SE465569B (sv) | 1989-04-18 | 1989-04-18 | Foerfarande foer framstaellning av klordioxid |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE8901392D0 SE8901392D0 (sv) | 1989-04-18 |
| SE8901392L SE8901392L (sv) | 1990-10-19 |
| SE465569B true SE465569B (sv) | 1991-09-30 |
Family
ID=20375706
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8901392A SE465569B (sv) | 1989-04-18 | 1989-04-18 | Foerfarande foer framstaellning av klordioxid |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4986973A (fr) |
| JP (1) | JPH02293301A (fr) |
| CA (1) | CA2014691C (fr) |
| NZ (1) | NZ233318A (fr) |
| SE (1) | SE465569B (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5348683A (en) * | 1990-02-06 | 1994-09-20 | Olin Corporation | Chloric acid - alkali metal chlorate mixtures and chlorine dioxide generation |
| US5322598A (en) * | 1990-02-06 | 1994-06-21 | Olin Corporation | Chlorine dioxide generation using inert load of sodium perchlorate |
| US5242554A (en) * | 1990-02-06 | 1993-09-07 | Olin Corporation | Electrolytic production of chloric acid and sodium chlorate mixtures for the generation of chlorine dioxide |
| US5435984A (en) * | 1992-04-28 | 1995-07-25 | Degussa Corporation | Catalyst for the synthesis of chlorine dioxide |
| US5599518A (en) * | 1994-12-01 | 1997-02-04 | Olin Corporation | Catalytic process for chlorine dioxide generation from chloric acid |
| US6322768B1 (en) | 1998-09-29 | 2001-11-27 | International Paper Company | Recovery of chlorine dioxide from gas streams |
| US6306281B1 (en) | 1999-11-30 | 2001-10-23 | Joseph Matthew Kelley | Electrolytic process for the generation of stable solutions of chlorine dioxide |
| CN110272023A (zh) * | 2019-07-24 | 2019-09-24 | 广州市佰分佰环境治理有限公司 | 一种全天候室内除醛装置及其使用方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE517755C (de) * | 1929-08-26 | 1931-02-11 | Willy Becher Dr | Herstellung von Chlordioxyd |
| US2936219A (en) * | 1957-02-18 | 1960-05-10 | Hooker Chemical Corp | Production of chlorine dioxide |
| US3864456A (en) * | 1964-08-13 | 1975-02-04 | Electric Reduction Co | Manufacture of chlorine dioxide, chlorine and anhydrous sodium sulphate |
| US3446584A (en) * | 1965-03-12 | 1969-05-27 | Hooker Chemical Corp | Method of production of chlorine dioxide and sodium sulfate |
| US3563702A (en) * | 1968-03-05 | 1971-02-16 | Hooker Chemical Corp | Production of chlorine dioxide |
| CA1080434A (fr) * | 1976-03-19 | 1980-07-01 | Erco Industries Limited | Production elevee de dioxyde de chlore avec l'hc1 comme acide |
| SE425322B (sv) * | 1976-05-11 | 1982-09-20 | Kemanobel Ab | Forfarande vid framstellning av alkalimetall- eller jordalkalimetallklorit |
| JPS5444278A (en) * | 1977-09-16 | 1979-04-07 | Tateishi Roka Kougiyou Kk | Method of producing filter cylinder for cartridge filter |
| JPS5545483A (en) * | 1978-09-29 | 1980-03-31 | Matsushita Electric Works Ltd | Outer edge device of reciprocating electric razor |
| DE3522934A1 (de) * | 1985-06-27 | 1987-01-08 | Thomson Brandt Gmbh | Videorecorder |
| SE460046B (sv) * | 1987-03-27 | 1989-09-04 | Eka Nobel Ab | Foerfarande foer framstaellning av klordioxid |
-
1989
- 1989-04-18 SE SE8901392A patent/SE465569B/sv not_active IP Right Cessation
- 1989-10-26 US US07/426,714 patent/US4986973A/en not_active Expired - Lifetime
-
1990
- 1990-04-12 NZ NZ233318A patent/NZ233318A/en unknown
- 1990-04-13 JP JP2096604A patent/JPH02293301A/ja active Pending
- 1990-04-17 CA CA002014691A patent/CA2014691C/fr not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2014691A1 (fr) | 1990-10-18 |
| SE8901392D0 (sv) | 1989-04-18 |
| US4986973A (en) | 1991-01-22 |
| SE8901392L (sv) | 1990-10-19 |
| CA2014691C (fr) | 1997-09-30 |
| JPH02293301A (ja) | 1990-12-04 |
| NZ233318A (en) | 1991-07-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
Ref document number: 8901392-4 Effective date: 19941110 Format of ref document f/p: F |