SE465879B - Foerfarande foer framstaellning av gummimodifierade styrenpolymerer - Google Patents

Foerfarande foer framstaellning av gummimodifierade styrenpolymerer

Info

Publication number: SE465879B
Authority: SE; Sweden
Prior art keywords: parts; weight; solution; rubber; styrene
Prior art date: 1983-12-30

Application number

SE8406665A

Other languages

English (en)

Swedish (sv)

Other versions

SE8406665L (sv

SE8406665D0 (sv

Inventor

R Wirth

M Lemattre

Original Assignee

Charbonnages Ste Chimique

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-12-30

Filing date

1984-12-28

Publication date

1991-11-11

1984-12-28 Application filed by Charbonnages Ste Chimique filed Critical Charbonnages Ste Chimique

1984-12-28 Publication of SE8406665D0 publication Critical patent/SE8406665D0/xx

1985-07-01 Publication of SE8406665L publication Critical patent/SE8406665L/xx

1991-11-11 Publication of SE465879B publication Critical patent/SE465879B/sv

Links

229920000642 polymer Polymers 0.000 title claims description 30
238000000034 method Methods 0.000 title description 22
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 48
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 30
229920001971 elastomer Polymers 0.000 claims description 24
239000005060 rubber Substances 0.000 claims description 22
229920002857 polybutadiene Polymers 0.000 claims description 18
239000000203 mixture Substances 0.000 claims description 17
239000000654 additive Substances 0.000 claims description 16
239000005062 Polybutadiene Substances 0.000 claims description 13
125000000129 anionic group Chemical group 0.000 claims description 12
238000006116 polymerization reaction Methods 0.000 claims description 9
-1 polyethylene Polymers 0.000 claims description 8
239000004698 Polyethylene Substances 0.000 claims description 7
150000001875 compounds Chemical class 0.000 claims description 7
229920000573 polyethylene Polymers 0.000 claims description 7
238000005336 cracking Methods 0.000 claims description 6
229920002545 silicone oil Polymers 0.000 claims description 6
YASDJUXENMYIBH-UHFFFAOYSA-N 3-methyl-3-phenyl-1,2-dihydroindene Chemical compound C1CC2=CC=CC=C2C1(C)C1=CC=CC=C1 YASDJUXENMYIBH-UHFFFAOYSA-N 0.000 claims description 4
LGLDSEPDYUTBNZ-UHFFFAOYSA-N 3-phenylbuta-1,3-dien-2-ylbenzene Chemical compound C=1C=CC=CC=1C(=C)C(=C)C1=CC=CC=C1 LGLDSEPDYUTBNZ-UHFFFAOYSA-N 0.000 claims description 4
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 4
239000000539 dimer Substances 0.000 claims description 4
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 claims description 3
239000002202 Polyethylene glycol Substances 0.000 claims description 3
230000000996 additive effect Effects 0.000 claims description 3
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 3
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 3
125000003827 glycol group Chemical group 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
150000002430 hydrocarbons Chemical class 0.000 claims description 3
229920001223 polyethylene glycol Polymers 0.000 claims description 3
150000003440 styrenes Chemical class 0.000 claims description 3
UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims description 3
RMPAXPOFLJVREM-UHFFFAOYSA-N (1-phenylcyclobutyl)benzene Chemical compound C1CCC1(C=1C=CC=CC=1)C1=CC=CC=C1 RMPAXPOFLJVREM-UHFFFAOYSA-N 0.000 claims description 2
239000000470 constituent Substances 0.000 claims description 2
239000013256 coordination polymer Substances 0.000 claims 1
239000000243 solution Substances 0.000 description 15
239000001993 wax Substances 0.000 description 14
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
239000005662 Paraffin oil Substances 0.000 description 9
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
239000000047 product Substances 0.000 description 7
FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 description 7
239000003963 antioxidant agent Substances 0.000 description 5
230000008961 swelling Effects 0.000 description 5
238000010438 heat treatment Methods 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000003921 oil Substances 0.000 description 4
235000019198 oils Nutrition 0.000 description 4
239000002245 particle Substances 0.000 description 4
230000003078 antioxidant effect Effects 0.000 description 3
239000003518 caustics Substances 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
238000005259 measurement Methods 0.000 description 3
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 3
239000000376 reactant Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
241000251468 Actinopterygii Species 0.000 description 2
229920004511 Dow Corning® 200 Fluid Polymers 0.000 description 2
239000008186 active pharmaceutical agent Substances 0.000 description 2
238000012662 bulk polymerization Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000001816 cooling Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
238000007872 degassing Methods 0.000 description 2
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
238000009826 distribution Methods 0.000 description 2
239000000806 elastomer Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
230000009477 glass transition Effects 0.000 description 2
239000000463 material Substances 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000007669 thermal treatment Methods 0.000 description 2
YGVYHUGLHHFGNN-UHFFFAOYSA-N (2-phenylcyclobuten-1-yl)benzene Chemical compound C1CC(C=2C=CC=CC=2)=C1C1=CC=CC=C1 YGVYHUGLHHFGNN-UHFFFAOYSA-N 0.000 description 1
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
BKZXZGWHTRCFPX-UHFFFAOYSA-N 2-tert-butyl-6-methylphenol Chemical compound CC1=CC=CC(C(C)(C)C)=C1O BKZXZGWHTRCFPX-UHFFFAOYSA-N 0.000 description 1
WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical class C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
101100298295 Drosophila melanogaster flfl gene Proteins 0.000 description 1
240000001812 Hyssopus officinalis Species 0.000 description 1
235000010650 Hyssopus officinalis Nutrition 0.000 description 1
240000007930 Oxalis acetosella Species 0.000 description 1
235000008098 Oxalis acetosella Nutrition 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
241001494479 Pecora Species 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
241000220317 Rosa Species 0.000 description 1
239000011324 bead Substances 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
239000001273 butane Substances 0.000 description 1
VNWKTOKETHGBQD-YPZZEJLDSA-N carbane Chemical class [10CH4] VNWKTOKETHGBQD-YPZZEJLDSA-N 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000001831 conversion spectrum Methods 0.000 description 1
231100001010 corrosive Toxicity 0.000 description 1
239000003599 detergent Substances 0.000 description 1
229910003460 diamond Inorganic materials 0.000 description 1
239000010432 diamond Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000008187 granular material Substances 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
230000002045 lasting effect Effects 0.000 description 1
229940057995 liquid paraffin Drugs 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
239000004006 olive oil Substances 0.000 description 1
235000008390 olive oil Nutrition 0.000 description 1
IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
239000010690 paraffinic oil Substances 0.000 description 1
239000002530 phenolic antioxidant Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000005057 refrigeration Methods 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
230000035939 shock Effects 0.000 description 1
239000011343 solid material Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

SE8406665A 1983-12-30 1984-12-28 Foerfarande foer framstaellning av gummimodifierade styrenpolymerer SE465879B (sv)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR8321059A FR2557575B1 (fr)	1983-12-30	1983-12-30	Procede de preparation de polystyrene-choc presentant un bon comportement aux agents corrosifs

Publications (3)

Publication Number	Publication Date
SE8406665D0 SE8406665D0 (sv)	1984-12-28
SE8406665L SE8406665L (sv)	1985-07-01
SE465879B true SE465879B (sv)	1991-11-11

Family

ID=9295733

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE8406665A SE465879B (sv)	1983-12-30	1984-12-28	Foerfarande foer framstaellning av gummimodifierade styrenpolymerer

Country Status (15)

Country	Link
JP (1)	JPS60158212A (fr)
KR (1)	KR920006762B1 (fr)
AT (1)	AT394369B (fr)
BE (1)	BE901418A (fr)
CA (1)	CA1241484A (fr)
CH (1)	CH662815A5 (fr)
DE (1)	DE3446592A1 (fr)
DK (1)	DK626184A (fr)
FR (1)	FR2557575B1 (fr)
GB (1)	GB2153370B (fr)
IT (1)	IT1177474B (fr)
LU (1)	LU85713A1 (fr)
NL (1)	NL191336C (fr)
NO (1)	NO845237L (fr)
SE (1)	SE465879B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP3686681B2 (ja) *	1992-03-10	2005-08-24	住友化学株式会社	ゴム変性スチレン系樹脂組成物
EP0770632B2 (fr)	1995-10-25	2006-02-01	Fina Technology, Inc.	Polymère monovinylaromatique à la fissuration sous contrainte améliorée
RU2294941C2 (ru) *	2005-04-06	2007-03-10	Открытое акционерное общество "Пластполимер"	Способ получения стойкого к растрескиванию ударопрочного полистирола
US7638559B2 (en)	2005-05-10	2009-12-29	Nova Chemicals Inc.	Expandable resins

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2646418A (en) *	1951-05-25	1953-07-21	Dow Chemical Co	Process for polymerizing monovinyl aromatic compounds with rubber
BE599395A (fr) *	1960-01-25	1900-01-01
DE1495638B2 (de) *	1960-09-07	1973-03-22	Farbwerke Hoechst AG, vormals Meister Lucius & Brüning, 6000 Frankfurt	Verfahren zur herstellung von schlagfestem polystyrol
NL279121A (fr) *	1961-06-01
GB1025573A (en) *	1962-12-24	1966-04-14	Foster Grant Co Inc	Improvements in or relating to polymer processes and compositions
FR1351613A (fr) *	1963-01-07	1964-02-07	Dow Chemical Co	Compositions polymérisées oléfiniques à base de résines et d'élastomères et leur procédé d'obtention
CA936297A (en) *	1963-08-15	1973-10-30	Dart Industries Inc.	Impact resistant graft copolymers
DE1495837C3 (de) *	1964-09-30	1974-02-14	Bayer Ag, 5090 Leverkusen	Verfahren zur Herstellung thermoplastisch-elastischer Formmassen
GB1229409A (fr) *	1967-05-11	1971-04-21
WO1980002144A1 (fr) *	1979-03-29	1980-10-16	Dow Chemical Co	Polystyrenes presentant une resistance a l'impact amelioree
JPS5919577B2 (ja) *	1980-08-25	1984-05-07	日本エラストマ−株式会社	耐衝撃性ポリスチレンの製造方法
DE3047303A1 (de) *	1980-12-16	1982-07-29	Basf Ag, 6700 Ludwigshafen	Verfahren zur kontinuierlichen herstellung von mit kautschuk modifizierten polymerisaten von vinylaromaten, verwendung derselben zum spritzgiessen, sowie formteile aus diesen
FR2505342A1 (fr) *	1981-05-07	1982-11-12	Bp Chemical Ltd	Procede de fabrication d'un polymere vinyl-aromatique tres tenace

1983
- 1983-12-30 FR FR8321059A patent/FR2557575B1/fr not_active Expired
1984
- 1984-12-13 GB GB08431498A patent/GB2153370B/en not_active Expired
- 1984-12-20 IT IT24147/84A patent/IT1177474B/it active
- 1984-12-20 DE DE3446592A patent/DE3446592A1/de not_active Ceased
- 1984-12-21 CA CA000470934A patent/CA1241484A/fr not_active Expired
- 1984-12-21 DK DK626184A patent/DK626184A/da not_active Application Discontinuation
- 1984-12-24 NL NL8403940A patent/NL191336C/xx not_active IP Right Cessation
- 1984-12-27 CH CH6193/84A patent/CH662815A5/fr not_active IP Right Cessation
- 1984-12-27 LU LU85713A patent/LU85713A1/fr unknown
- 1984-12-27 NO NO845237A patent/NO845237L/no unknown
- 1984-12-28 SE SE8406665A patent/SE465879B/sv unknown
- 1984-12-28 AT AT0412184A patent/AT394369B/de not_active IP Right Cessation
- 1984-12-28 BE BE0/214272A patent/BE901418A/fr not_active IP Right Cessation
- 1984-12-29 KR KR1019840008533A patent/KR920006762B1/ko not_active Expired
- 1984-12-29 JP JP59282028A patent/JPS60158212A/ja active Granted

Also Published As

Publication number	Publication date
ATA412184A (de)	1991-09-15
BE901418A (fr)	1985-06-28
AT394369B (de)	1992-03-25
CA1241484A (fr)	1988-08-30
SE8406665L (sv)	1985-07-01
IT1177474B (it)	1987-08-26
NL8403940A (nl)	1985-07-16
SE8406665D0 (sv)	1984-12-28
KR920006762B1 (ko)	1992-08-17
DE3446592A1 (de)	1985-07-11
GB8431498D0 (en)	1985-01-23
IT8424147A0 (it)	1984-12-20
KR850004786A (ko)	1985-07-27
JPS6343413B2 (fr)	1988-08-30
CH662815A5 (fr)	1987-10-30
GB2153370A (en)	1985-08-21
JPS60158212A (ja)	1985-08-19
GB2153370B (en)	1987-12-23
DK626184D0 (da)	1984-12-21
DK626184A (da)	1985-07-01
LU85713A1 (fr)	1985-07-24
FR2557575A1 (fr)	1985-07-05
NL191336B (nl)	1995-01-02
NL191336C (nl)	1995-06-01
NO845237L (no)	1985-07-01
FR2557575B1 (fr)	1987-02-06

Legal Events

Date

Code

Title

Description

1995-01-31

NAL

Patent in force

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