SE524126C2 - Förfarande för framställning av dietylentriamin och högre polyetylenpolyaminer genom transaminering av etylendiamin - Google Patents

Förfarande för framställning av dietylentriamin och högre polyetylenpolyaminer genom transaminering av etylendiamin

Info

Publication number: SE524126C2
Authority: SE; Sweden
Prior art keywords: weight; catalyst; process according; alumina; ethylenediamine
Prior art date: 2001-07-24

Application number

SE0102590A

Other languages

English (en)

Swedish (sv)

Other versions

SE0102590D0 (sv

SE0102590L (sv

Inventor

Johan Lif

Kristina Ekenberg

Original Assignee

Akzo Nobel Nv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-07-24

Filing date

2001-07-24

Publication date

2004-06-29

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=20284920&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=SE524126(C2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2001-07-24 Application filed by Akzo Nobel Nv filed Critical Akzo Nobel Nv

2001-07-24 Priority to SE0102590A priority Critical patent/SE524126C2/sv

2001-07-24 Publication of SE0102590D0 publication Critical patent/SE0102590D0/xx

2002-07-05 Priority to KR1020047000634A priority patent/KR100847283B1/ko

2002-07-05 Priority to MXPA04000399A priority patent/MXPA04000399A/es

2002-07-05 Priority to CA2446989A priority patent/CA2446989C/en

2002-07-05 Priority to DE60237610T priority patent/DE60237610D1/de

2002-07-05 Priority to RU2004105150/04A priority patent/RU2281936C2/ru

2002-07-05 Priority to PCT/SE2002/001351 priority patent/WO2003010125A1/en

2002-07-05 Priority to CNB028130855A priority patent/CN1243718C/zh

2002-07-05 Priority to AT02749479T priority patent/ATE480514T1/de

2002-07-05 Priority to EP02749479A priority patent/EP1409447B1/de

2002-07-05 Priority to JP2003515486A priority patent/JP4979877B2/ja

2002-07-05 Priority to US10/484,323 priority patent/US7053247B2/en

2002-07-05 Priority to BR0211260-4A priority patent/BR0211260A/pt

2002-07-09 Priority to TW091115200A priority patent/TWI284121B/zh

2002-07-22 Priority to ARP020102742A priority patent/AR034834A1/es

2003-01-25 Publication of SE0102590L publication Critical patent/SE0102590L/xx

2004-06-29 Publication of SE524126C2 publication Critical patent/SE524126C2/sv

Links

238000000034 method Methods 0.000 title claims abstract description 24
-1 polyethylene Polymers 0.000 title claims abstract description 21
230000008569 process Effects 0.000 title claims abstract description 20
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 title claims abstract description 19
238000005891 transamination reaction Methods 0.000 title claims abstract description 18
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 title claims abstract description 12
239000004698 Polyethylene Substances 0.000 title claims description 13
229920000573 polyethylene Polymers 0.000 title claims description 13
229920000768 polyamine Polymers 0.000 title claims description 12
238000002360 preparation method Methods 0.000 title claims description 3
239000003054 catalyst Substances 0.000 claims abstract description 34
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 22
238000006243 chemical reaction Methods 0.000 claims abstract description 20
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 16
239000001257 hydrogen Substances 0.000 claims abstract description 16
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 16
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 34
239000000377 silicon dioxide Substances 0.000 claims description 17
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
229910052751 metal Inorganic materials 0.000 claims description 10
239000002184 metal Substances 0.000 claims description 10
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
239000000203 mixture Substances 0.000 claims description 8
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 8
229910052702 rhenium Inorganic materials 0.000 claims description 8
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 8
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 6
229910052763 palladium Inorganic materials 0.000 claims description 6
229910052707 ruthenium Inorganic materials 0.000 claims description 6
239000002245 particle Substances 0.000 claims description 5
229910052742 iron Inorganic materials 0.000 claims description 4
229910052697 platinum Inorganic materials 0.000 claims description 4
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
229910052796 boron Inorganic materials 0.000 claims description 3
229910017052 cobalt Inorganic materials 0.000 claims description 3
239000010941 cobalt Substances 0.000 claims description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
229910052770 Uranium Inorganic materials 0.000 claims description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
238000005576 amination reaction Methods 0.000 claims description 2
229910052788 barium Inorganic materials 0.000 claims description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
229910052793 cadmium Inorganic materials 0.000 claims description 2
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
229910052792 caesium Inorganic materials 0.000 claims description 2
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 2
229910052791 calcium Inorganic materials 0.000 claims description 2
239000011575 calcium Substances 0.000 claims description 2
238000010924 continuous production Methods 0.000 claims description 2
229910052802 copper Inorganic materials 0.000 claims description 2
239000010949 copper Substances 0.000 claims description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
229910052737 gold Inorganic materials 0.000 claims description 2
239000010931 gold Substances 0.000 claims description 2
229910052741 iridium Inorganic materials 0.000 claims description 2
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
229910052744 lithium Inorganic materials 0.000 claims description 2
229910052749 magnesium Inorganic materials 0.000 claims description 2
239000011777 magnesium Substances 0.000 claims description 2
229910052748 manganese Inorganic materials 0.000 claims description 2
239000011572 manganese Substances 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
239000011733 molybdenum Substances 0.000 claims description 2
229910052762 osmium Inorganic materials 0.000 claims description 2
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
239000011591 potassium Substances 0.000 claims description 2
229910052703 rhodium Inorganic materials 0.000 claims description 2
239000010948 rhodium Substances 0.000 claims description 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
229910052701 rubidium Inorganic materials 0.000 claims description 2
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 2
229910052709 silver Inorganic materials 0.000 claims description 2
239000004332 silver Substances 0.000 claims description 2
229910052708 sodium Inorganic materials 0.000 claims description 2
239000011734 sodium Substances 0.000 claims description 2
229910052712 strontium Inorganic materials 0.000 claims description 2
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
229910052719 titanium Inorganic materials 0.000 claims description 2
239000010936 titanium Substances 0.000 claims description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
229910052721 tungsten Inorganic materials 0.000 claims description 2
239000010937 tungsten Substances 0.000 claims description 2
229910052725 zinc Inorganic materials 0.000 claims description 2
239000011701 zinc Substances 0.000 claims description 2
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims 1
GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 abstract description 12
125000002015 acyclic group Chemical group 0.000 abstract description 7
229910052759 nickel Inorganic materials 0.000 abstract description 6
230000015572 biosynthetic process Effects 0.000 abstract description 4
238000004519 manufacturing process Methods 0.000 abstract 1
150000002739 metals Chemical class 0.000 description 6
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 6
150000003839 salts Chemical class 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
239000000047 product Substances 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
230000007306 turnover Effects 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 3
230000000295 complement effect Effects 0.000 description 3
239000007788 liquid Substances 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
230000000694 effects Effects 0.000 description 2
UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 2
238000005984 hydrogenation reaction Methods 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 description 1
239000004157 Nitrosyl chloride Substances 0.000 description 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
229920002873 Polyethylenimine Polymers 0.000 description 1
239000007868 Raney catalyst Substances 0.000 description 1
229910000564 Raney nickel Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
150000001260 acyclic compounds Chemical class 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
239000000969 carrier Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000004508 fractional distillation Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
NBTOZLQBSIZIKS-UHFFFAOYSA-N methoxide Chemical compound [O-]C NBTOZLQBSIZIKS-UHFFFAOYSA-N 0.000 description 1
150000002815 nickel Chemical class 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
PNPIRSNMYIHTPS-UHFFFAOYSA-N nitroso nitrate Chemical compound [O-][N+](=O)ON=O PNPIRSNMYIHTPS-UHFFFAOYSA-N 0.000 description 1
YLPJWCDYYXQCIP-UHFFFAOYSA-N nitroso nitrate;ruthenium Chemical compound [Ru].[O-][N+](=O)ON=O YLPJWCDYYXQCIP-UHFFFAOYSA-N 0.000 description 1
VPCDQGACGWYTMC-UHFFFAOYSA-N nitrosyl chloride Chemical compound ClN=O VPCDQGACGWYTMC-UHFFFAOYSA-N 0.000 description 1
235000019392 nitrosyl chloride Nutrition 0.000 description 1
WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 1
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
150000004885 piperazines Chemical class 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
230000008092 positive effect Effects 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
150000003384 small molecules Chemical class 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical group 0.000 description 1
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

SE0102590A 2001-07-24 2001-07-24 Förfarande för framställning av dietylentriamin och högre polyetylenpolyaminer genom transaminering av etylendiamin SE524126C2 (sv)

Priority Applications (15)

Application Number	Priority Date	Filing Date	Title
SE0102590A SE524126C2 (sv)	2001-07-24	2001-07-24	Förfarande för framställning av dietylentriamin och högre polyetylenpolyaminer genom transaminering av etylendiamin
US10/484,323 US7053247B2 (en)	2001-07-24	2002-07-05	Process for the manufacture of diethylenetriamine and higher polyethylenepolyamines
BR0211260-4A BR0211260A (pt)	2001-07-24	2002-07-05	Processo de preparação de dietilenotriamina e polietilenopoliaminas superiores
CNB028130855A CN1243718C (zh)	2001-07-24	2002-07-05	生产二亚乙基三胺和更高级的聚亚乙基多胺的方法
AT02749479T ATE480514T1 (de)	2001-07-24	2002-07-05	Verfahren zur herstellung von diethylentriamin und höheren polyethylenpolyaminen
CA2446989A CA2446989C (en)	2001-07-24	2002-07-05	A process for the manufacture of diethylenetriamine and higher polyethylenepolyamines
DE60237610T DE60237610D1 (de)	2001-07-24	2002-07-05	Verfahren zur herstellung von diethylentriamin und höheren polyethylenpolyaminen
RU2004105150/04A RU2281936C2 (ru)	2001-07-24	2002-07-05	Способ получения диэтилентриамина и других линейных полиэтиленполиаминов
PCT/SE2002/001351 WO2003010125A1 (en)	2001-07-24	2002-07-05	A process for the manufacture of diethylenetriamine and higher polyethylenepolyamines
KR1020047000634A KR100847283B1 (ko)	2001-07-24	2002-07-05	디에틸렌트리아민 및 고급 폴리에틸렌폴리아민의 제조 방법
MXPA04000399A MXPA04000399A (es)	2001-07-24	2002-07-05	Un proceso para la elaboracion de dietilentriamina y polietilenpoliaminas superiores.
EP02749479A EP1409447B1 (de)	2001-07-24	2002-07-05	Verfahren zur herstellung von diethylentriamin und höheren polyethylenpolyaminen
JP2003515486A JP4979877B2 (ja)	2001-07-24	2002-07-05	ジエチレントリアミンおよび高級ポリエチレンポリアミンの製造のための方法
TW091115200A TWI284121B (en)	2001-07-24	2002-07-09	A process for the manufacture of diethylenetriamine and higher polyethylenepolyamines
ARP020102742A AR034834A1 (es)	2001-07-24	2002-07-22	Un proceso para la manufactura de dietilentriamina y polietilenpoliaminas superiores.

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SE0102590A SE524126C2 (sv)	2001-07-24	2001-07-24	Förfarande för framställning av dietylentriamin och högre polyetylenpolyaminer genom transaminering av etylendiamin

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SE0102590D0 SE0102590D0 (sv)	2001-07-24
SE0102590L SE0102590L (sv)	2003-01-25
SE524126C2 true SE524126C2 (sv)	2004-06-29

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US (1)	US7053247B2 (de)
EP (1)	EP1409447B1 (de)
JP (1)	JP4979877B2 (de)
KR (1)	KR100847283B1 (de)
CN (1)	CN1243718C (de)
AR (1)	AR034834A1 (de)
AT (1)	ATE480514T1 (de)
BR (1)	BR0211260A (de)
CA (1)	CA2446989C (de)
DE (1)	DE60237610D1 (de)
MX (1)	MXPA04000399A (de)
RU (1)	RU2281936C2 (de)
SE (1)	SE524126C2 (de)
TW (1)	TWI284121B (de)
WO (1)	WO2003010125A1 (de)

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JP5469173B2 (ja) *	2008-10-06	2014-04-09	ユニオンカーバイドケミカルズアンドプラスティックステクノロジーエルエルシー	金属低配合、アルミナ担持触媒組成物及びアミノ化方法
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2001
- 2001-07-24 SE SE0102590A patent/SE524126C2/sv not_active IP Right Cessation
2002
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- 2002-07-05 CA CA2446989A patent/CA2446989C/en not_active Expired - Fee Related
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- 2002-07-05 MX MXPA04000399A patent/MXPA04000399A/es active IP Right Grant
- 2002-07-05 US US10/484,323 patent/US7053247B2/en not_active Expired - Fee Related
- 2002-07-05 CN CNB028130855A patent/CN1243718C/zh not_active Expired - Fee Related
- 2002-07-05 RU RU2004105150/04A patent/RU2281936C2/ru not_active IP Right Cessation
- 2002-07-05 KR KR1020047000634A patent/KR100847283B1/ko not_active Expired - Fee Related
- 2002-07-05 WO PCT/SE2002/001351 patent/WO2003010125A1/en not_active Ceased
- 2002-07-05 BR BR0211260-4A patent/BR0211260A/pt active Search and Examination
- 2002-07-05 DE DE60237610T patent/DE60237610D1/de not_active Expired - Lifetime
- 2002-07-05 EP EP02749479A patent/EP1409447B1/de not_active Expired - Lifetime
- 2002-07-09 TW TW091115200A patent/TWI284121B/zh not_active IP Right Cessation
- 2002-07-22 AR ARP020102742A patent/AR034834A1/es not_active Application Discontinuation

Also Published As

Publication number	Publication date
MXPA04000399A (es)	2004-03-18
CA2446989A1 (en)	2003-02-06
DE60237610D1 (de)	2010-10-21
EP1409447B1 (de)	2010-09-08
WO2003010125A1 (en)	2003-02-06
KR100847283B1 (ko)	2008-07-21
CN1522240A (zh)	2004-08-18
JP2004536866A (ja)	2004-12-09
BR0211260A (pt)	2004-07-27
CN1243718C (zh)	2006-03-01
ATE480514T1 (de)	2010-09-15
JP4979877B2 (ja)	2012-07-18
CA2446989C (en)	2010-09-14
RU2004105150A (ru)	2005-08-10
RU2281936C2 (ru)	2006-08-20
US20040171884A1 (en)	2004-09-02
KR20040029367A (ko)	2004-04-06
AR034834A1 (es)	2004-03-17
US7053247B2 (en)	2006-05-30
SE0102590D0 (sv)	2001-07-24
SE0102590L (sv)	2003-01-25
TWI284121B (en)	2007-07-21
EP1409447A1 (de)	2004-04-21

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2014-03-04	NUG	Patent has lapsed

Publication	Publication Date	Title
SE524126C2 (sv)	2004-06-29	Förfarande för framställning av dietylentriamin och högre polyetylenpolyaminer genom transaminering av etylendiamin
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RU2573637C2 (ru)	2016-01-27	Способ синтеза высших этаноламинов
EP2352585B1 (de)	2020-06-17	Aluminiumoxidgeträgerte katalysatorzusammensetzungen mit niedriger metallbeladung und aminierungsverfahren
EP2340113B1 (de)	2020-06-03	Einen niedrigen gehalt an metallen (nickel und rhenium) aufweisende katalysatorzusammensetzungen mit saurem gemischtem metalloxid als träger
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EP1385625A2 (de)	2004-02-04	Ein nickel-rheniumkatalysator verwendbar für reduktiven aminierungsverfahren
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JPS6165852A (ja)	1986-04-04	アクリルアミドの合成法
JPS6256787B2 (de)	1987-11-27
MX2008008490A (es)	2008-09-26	Proceso para producir compuestos que contienen nitrogeno.
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