SI9300526A - Use of polyoxyethylenic compounds as vulcanization co-adjuvant for chloroacrylic rubbers - Google Patents

Use of polyoxyethylenic compounds as vulcanization co-adjuvant for chloroacrylic rubbers Download PDF

Info

Publication number: SI9300526A
Authority: SI; Slovenia
Prior art keywords: polyethers; polyoxyethylene; vulcanization; general formula; chloroacrylic
Prior art date: 1992-10-05

Application number

SI9300526A

Other languages

English (en)

Slovenian (sl)

Inventor

Maurizio Penco

Laura Lanzavecchia

Angelo Lucio Spelta

Original Assignee

Enichem Elastomers

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-10-05

Filing date

1993-10-05

Publication date

1994-06-30

1993-10-05 Application filed by Enichem Elastomers filed Critical Enichem Elastomers

1994-06-30 Publication of SI9300526A publication Critical patent/SI9300526A/sl

Links

229920001971 elastomer Polymers 0.000 title claims abstract description 36
239000005060 rubber Substances 0.000 title claims abstract description 33
238000004073 vulcanization Methods 0.000 title claims abstract description 31
150000001875 compounds Chemical class 0.000 title abstract description 19
239000002671 adjuvant Substances 0.000 title abstract 2
229920000570 polyether Polymers 0.000 claims abstract description 26
238000006243 chemical reaction Methods 0.000 claims abstract description 10
-1 polyoxyethylene Polymers 0.000 claims description 37
229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 21
239000000203 mixture Substances 0.000 claims description 16
125000003118 aryl group Chemical group 0.000 claims description 12
125000004432 carbon atom Chemical group C* 0.000 claims description 9
125000002877 alkyl aryl group Chemical group 0.000 claims description 6
125000006353 oxyethylene group Chemical group 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
125000006177 alkyl benzyl group Chemical group 0.000 claims description 2
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims 1
150000001559 benzoic acids Chemical class 0.000 claims 1
150000002170 ethers Chemical class 0.000 claims 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 18
239000011593 sulfur Substances 0.000 abstract description 11
229910052717 sulfur Inorganic materials 0.000 abstract description 11
239000004721 Polyphenylene oxide Substances 0.000 abstract description 5
239000000344 soap Substances 0.000 abstract description 5
239000003795 chemical substances by application Substances 0.000 abstract description 3
239000000806 elastomer Substances 0.000 abstract description 3
241000894007 species Species 0.000 description 11
229920000800 acrylic rubber Polymers 0.000 description 7
229920000058 polyacrylate Polymers 0.000 description 7
235000014113 dietary fatty acids Nutrition 0.000 description 6
239000000194 fatty acid Substances 0.000 description 6
229930195729 fatty acid Natural products 0.000 description 6
238000000034 method Methods 0.000 description 6
235000021355 Stearic acid Nutrition 0.000 description 3
239000002253 acid Substances 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
239000006229 carbon black Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
238000003756 stirring Methods 0.000 description 3
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
241001441571 Hiodontidae Species 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
239000000470 constituent Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
239000000945 filler Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000000178 monomer Substances 0.000 description 2
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
239000004014 plasticizer Substances 0.000 description 2
239000008117 stearic acid Chemical class 0.000 description 2
OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical class CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Chemical class CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Chemical class CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Chemical class CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
239000004593 Epoxy Substances 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000005642 Oleic acid Chemical class 0.000 description 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Chemical class CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
239000012752 auxiliary agent Substances 0.000 description 1
150000001558 benzoic acid derivatives Chemical class 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
125000004965 chloroalkyl group Chemical group 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
230000007547 defect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000004519 grease Substances 0.000 description 1
159000000011 group IA salts Chemical class 0.000 description 1
239000010440 gypsum Substances 0.000 description 1
229910052602 gypsum Inorganic materials 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Chemical class CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical class CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical class CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Chemical class CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
229960003656 ricinoleic acid Drugs 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910000859 α-Fe Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

SI9300526A 1992-10-05 1993-10-05 Use of polyoxyethylenic compounds as vulcanization co-adjuvant for chloroacrylic rubbers SI9300526A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
ITMI922292A IT1255715B (it)	1992-10-05	1992-10-05	Uso di composti poliossietilenici come coadiuvanti di vulcanizzazione di gomme cloroacriliche

Publications (1)

Publication Number	Publication Date
SI9300526A true SI9300526A (en)	1994-06-30

Family

ID=11364056

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SI9300526A SI9300526A (en)	1992-10-05	1993-10-05	Use of polyoxyethylenic compounds as vulcanization co-adjuvant for chloroacrylic rubbers

Country Status (11)

Country	Link
EP (1)	EP0592036A1 (pt)
JP (1)	JPH06192530A (pt)
KR (1)	KR970005378B1 (pt)
CN (1)	CN1090858A (pt)
BR (1)	BR9304145A (pt)
CA (1)	CA2107618A1 (pt)
CZ (1)	CZ205693A3 (pt)
IT (1)	IT1255715B (pt)
MX (1)	MX9306201A (pt)
SI (1)	SI9300526A (pt)
ZA (1)	ZA937352B (pt)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR100819558B1 (ko)	2006-09-04	2008-04-07	삼성전자주식회사	반도체 저항소자들 및 그의 형성방법들

1992
- 1992-10-05 IT ITMI922292A patent/IT1255715B/it active IP Right Grant
1993
- 1993-10-01 CZ CZ932056A patent/CZ205693A3/cs unknown
- 1993-10-02 EP EP93202807A patent/EP0592036A1/en not_active Withdrawn
- 1993-10-04 CA CA002107618A patent/CA2107618A1/en not_active Abandoned
- 1993-10-04 ZA ZA937352A patent/ZA937352B/xx unknown
- 1993-10-05 BR BR9304145A patent/BR9304145A/pt not_active Application Discontinuation
- 1993-10-05 CN CN93114415A patent/CN1090858A/zh active Pending
- 1993-10-05 KR KR1019930020456A patent/KR970005378B1/ko not_active Expired - Lifetime
- 1993-10-05 MX MX9306201A patent/MX9306201A/es unknown
- 1993-10-05 JP JP5271164A patent/JPH06192530A/ja not_active Withdrawn
- 1993-10-05 SI SI9300526A patent/SI9300526A/sl unknown

Also Published As

Publication number	Publication date
CA2107618A1 (en)	1994-04-06
BR9304145A (pt)	1994-05-10
CN1090858A (zh)	1994-08-17
CZ205693A3 (en)	1994-04-13
ZA937352B (en)	1994-04-22
IT1255715B (it)	1995-11-10
JPH06192530A (ja)	1994-07-12
ITMI922292A0 (it)	1992-10-05
EP0592036A1 (en)	1994-04-13
MX9306201A (es)	1995-01-31
KR970005378B1 (ko)	1997-04-15
ITMI922292A1 (it)	1994-04-05
KR940009224A (ko)	1994-05-20

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