SK2199A3 - Process for the recovery of sulfur from so2 containing gases - Google Patents

Process for the recovery of sulfur from so2 containing gases Download PDF

Info

Publication number: SK2199A3
Authority: SK; Slovakia
Prior art keywords: sulfur; claus; liquid sulfur; gas; catalyst
Prior art date: 1996-07-08

Application number

SK21-99A

Other languages

English (en)

Slovak (sk)

Inventor

Jan A Lagas

Johannes Borsboom

Peter D Clark

Original Assignee

Stork Eng & Contractors Bv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-07-08

Filing date

1997-07-07

Publication date

2000-03-13

1997-07-07 Application filed by Stork Eng & Contractors Bv filed Critical Stork Eng & Contractors Bv

2000-03-13 Publication of SK2199A3 publication Critical patent/SK2199A3/sk

Links

NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 103
229910052717 sulfur Inorganic materials 0.000 title claims abstract description 92
239000011593 sulfur Substances 0.000 title claims abstract description 92
239000007789 gas Substances 0.000 title claims abstract description 80
238000000034 method Methods 0.000 title claims abstract description 70
238000011084 recovery Methods 0.000 title description 7
238000006243 chemical reaction Methods 0.000 claims abstract description 56
239000003054 catalyst Substances 0.000 claims abstract description 46
239000007788 liquid Substances 0.000 claims abstract description 45
230000003197 catalytic effect Effects 0.000 claims abstract description 16
239000002638 heterogeneous catalyst Substances 0.000 claims abstract description 8
229910017464 nitrogen compound Inorganic materials 0.000 claims abstract description 6
150000002830 nitrogen compounds Chemical class 0.000 claims abstract description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
-1 aromatic nitrogen compounds Chemical class 0.000 claims description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
230000003647 oxidation Effects 0.000 claims description 4
238000007254 oxidation reaction Methods 0.000 claims description 4
239000011148 porous material Substances 0.000 claims description 4
229910044991 metal oxide Inorganic materials 0.000 claims description 3
150000004706 metal oxides Chemical class 0.000 claims description 3
PVXVWWANJIWJOO-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-N-ethylpropan-2-amine Chemical compound CCNC(C)CC1=CC=C2OCOC2=C1 PVXVWWANJIWJOO-UHFFFAOYSA-N 0.000 claims description 2
102100032373 Coiled-coil domain-containing protein 85B Human genes 0.000 claims description 2
101000868814 Homo sapiens Coiled-coil domain-containing protein 85B Proteins 0.000 claims description 2
QMMZSJPSPRTHGB-UHFFFAOYSA-N MDEA Natural products CC(C)CCCCC=CCC=CC(O)=O QMMZSJPSPRTHGB-UHFFFAOYSA-N 0.000 claims description 2
150000001412 amines Chemical group 0.000 claims description 2
229910021529 ammonia Inorganic materials 0.000 claims description 2
150000003863 ammonium salts Chemical class 0.000 claims description 2
LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
239000002245 particle Substances 0.000 claims 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 1
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims 1
239000000203 mixture Substances 0.000 claims 1
229910052757 nitrogen Inorganic materials 0.000 claims 1
238000000926 separation method Methods 0.000 claims 1
239000007787 solid Substances 0.000 claims 1
150000003512 tertiary amines Chemical class 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
GVGLGOZIDCSQPN-PVHGPHFFSA-N Heroin Chemical compound O([C@H]1[C@H](C=C[C@H]23)OC(C)=O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4OC(C)=O GVGLGOZIDCSQPN-PVHGPHFFSA-N 0.000 description 3
238000006477 desulfuration reaction Methods 0.000 description 3
230000023556 desulfurization Effects 0.000 description 3
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
238000005265 energy consumption Methods 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 1
239000011149 active material Substances 0.000 description 1
150000003973 alkyl amines Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000004982 aromatic amines Chemical class 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000003245 coal Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
150000002926 oxygen Chemical class 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
229920001021 polysulfide Polymers 0.000 description 1
239000005077 polysulfide Substances 0.000 description 1
150000008117 polysulfides Polymers 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
238000007670 refining Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
239000002341 toxic gas Substances 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
231100000925 very toxic Toxicity 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
- B01D53/8615—Mixtures of hydrogen sulfide and sulfur oxides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0426—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion
- C01B17/0439—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion at least one catalyst bed operating below the dew-point of sulfur
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0456—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Inorganic Chemistry (AREA)
Environmental & Geological Engineering (AREA)
Health & Medical Sciences (AREA)
Biomedical Technology (AREA)
Analytical Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Materials Engineering (AREA)
Catalysts (AREA)
Exhaust Gas Treatment By Means Of Catalyst (AREA)
Treating Waste Gases (AREA)

SK21-99A 1996-07-08 1997-07-07 Process for the recovery of sulfur from so2 containing gases SK2199A3 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP96201891		1996-07-08
PCT/NL1997/000392 WO1998001387A1 (en)	1996-07-08	1997-07-07	Process for the recovery of sulfur from so2 containing gases

Publications (1)

Publication Number	Publication Date
SK2199A3 true SK2199A3 (en)	2000-03-13

Family

ID=8224151

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK21-99A SK2199A3 (en)	1996-07-08	1997-07-07	Process for the recovery of sulfur from so2 containing gases

Country Status (16)

Country	Link
EP (1)	EP0910545A1 (cs)
JP (1)	JP2000514389A (cs)
CN (1)	CN1230158A (cs)
AR (1)	AR007727A1 (cs)
AU (1)	AU3361297A (cs)
BR (1)	BR9710240A (cs)
CA (1)	CA2259946A1 (cs)
CZ (1)	CZ4899A3 (cs)
EA (1)	EA199900090A1 (cs)
HU (1)	HUP9904020A3 (cs)
ID (1)	ID18897A (cs)
PL (1)	PL331044A1 (cs)
SK (1)	SK2199A3 (cs)
TW (1)	TW382617B (cs)
WO (1)	WO1998001387A1 (cs)
ZA (1)	ZA975859B (cs)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN104627966B (zh) *	2015-02-12	2016-09-07	中南大学	一种以二氧化硫烟气为原料制备纳米硫的方法
CN109534297B (zh) *	2017-09-21	2021-07-09	中国石油化工股份有限公司	一种硫化氢和二氧化硫反应脱硫的方法
CN109529580B (zh) *	2017-09-21	2021-07-09	中国石油化工股份有限公司	二氧化硫和硫化氢液相反应脱硫的工艺装置和工艺方法
CN109529578B (zh) *	2017-09-21	2021-07-09	中国石油化工股份有限公司	硫化氢和二氧化硫液相反应脱硫的工艺装置及工艺方法
CN109529579B (zh) *	2017-09-21	2021-07-09	中国石油化工股份有限公司	一种硫化氢和二氧化硫反应脱硫的工艺装置和工艺方法
CN109529573B (zh) *	2017-09-21	2021-07-09	中国石油化工股份有限公司	硫化氢和二氧化硫液相脱硫的工艺装置和工艺方法
CN109529567B (zh) *	2017-09-21	2021-07-09	中国石油化工股份有限公司	一种硫化氢和二氧化硫反应脱硫的工艺
CN109772134B (zh) *	2019-01-10	2021-12-28	昆明理工大学	一种循环脱除h2s和so2并回收硫的方法
CN118083918B (zh) *	2024-01-24	2026-02-03	江西理工大学	一种利用磷钼杂多酸盐改性离子液体制备硫磺的方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3447903A (en) *	1966-10-27	1969-06-03	Freeport Sulphur Co	Sulphur production
CA1142326A (en) *	1979-12-11	1983-03-08	Hudson's Bay Oil And Gas Company Limited	High pressure process for recovery of sulphur from gases

1997
- 1997-07-01 ZA ZA9705859A patent/ZA975859B/xx unknown
- 1997-07-04 AR ARP970103010A patent/AR007727A1/es unknown
- 1997-07-07 BR BR9710240-7A patent/BR9710240A/pt not_active Application Discontinuation
- 1997-07-07 CA CA002259946A patent/CA2259946A1/en not_active Abandoned
- 1997-07-07 HU HU9904020A patent/HUP9904020A3/hu unknown
- 1997-07-07 CZ CZ9948A patent/CZ4899A3/cs unknown
- 1997-07-07 SK SK21-99A patent/SK2199A3/sk unknown
- 1997-07-07 CN CN97197730A patent/CN1230158A/zh active Pending
- 1997-07-07 EA EA199900090A patent/EA199900090A1/ru unknown
- 1997-07-07 JP JP10505090A patent/JP2000514389A/ja active Pending
- 1997-07-07 PL PL97331044A patent/PL331044A1/xx unknown
- 1997-07-07 WO PCT/NL1997/000392 patent/WO1998001387A1/en not_active Ceased
- 1997-07-07 EP EP97929589A patent/EP0910545A1/en not_active Withdrawn
- 1997-07-07 AU AU33612/97A patent/AU3361297A/en not_active Abandoned
- 1997-07-08 ID IDP972355A patent/ID18897A/id unknown
- 1997-08-27 TW TW086109609A patent/TW382617B/zh active

Also Published As

Publication number	Publication date
CN1230158A (zh)	1999-09-29
EA199900090A1 (ru)	1999-08-26
EP0910545A1 (en)	1999-04-28
AR007727A1 (es)	1999-11-10
BR9710240A (pt)	2000-01-11
CA2259946A1 (en)	1998-01-15
PL331044A1 (en)	1999-06-21
TW382617B (en)	2000-02-21
JP2000514389A (ja)	2000-10-31
CZ4899A3 (cs)	1999-07-14
WO1998001387A1 (en)	1998-01-15
ZA975859B (en)	1998-02-03
HUP9904020A2 (hu)	2000-03-28
ID18897A (id)	1998-05-20
AU3361297A (en)	1998-02-02
HUP9904020A3 (en)	2000-06-28

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