SK282599B6 - Spôsob povrchovej úpravy vonkajšej plochy medeného alebo z medenej zliatiny vytvoreného prvku formy na plynulé odlievanie kovov pozostávajúci z pokovovania niklom a odstraňovania niklu - Google Patents

Spôsob povrchovej úpravy vonkajšej plochy medeného alebo z medenej zliatiny vytvoreného prvku formy na plynulé odlievanie kovov pozostávajúci z pokovovania niklom a odstraňovania niklu Download PDF

Info

Publication number: SK282599B6
Authority: SK; Slovakia
Prior art keywords: nickel; electrolyte; plating; carried out; copper
Prior art date: 1996-04-12

Application number

SK457-97A

Other languages

English (en)

Slovak (sk)

Other versions

SK45797A3 (en

Inventor

Jean-Claude Catonne

Christian Allely

R�My Nicolle

G�Rard Raisson

Original Assignee

Usinor

Thyssen Stahl Aktiengesellschaft

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-04-12

Filing date

1997-04-09

Publication date

2002-10-08

1997-04-09 Application filed by Usinor, Thyssen Stahl Aktiengesellschaft filed Critical Usinor

1998-04-08 Publication of SK45797A3 publication Critical patent/SK45797A3/sk

2002-10-08 Publication of SK282599B6 publication Critical patent/SK282599B6/sk

Links

PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 353
229910052759 nickel Inorganic materials 0.000 title claims abstract description 178
229910052802 copper Inorganic materials 0.000 title claims abstract description 41
239000010949 copper Substances 0.000 title claims abstract description 41
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 40
238000007747 plating Methods 0.000 title claims description 53
238000000034 method Methods 0.000 title claims description 46
238000004381 surface treatment Methods 0.000 title claims description 12
238000009749 continuous casting Methods 0.000 title description 6
229910001371 Er alloy Inorganic materials 0.000 title 1
239000003792 electrolyte Substances 0.000 claims abstract description 50
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims abstract description 12
239000002253 acid Substances 0.000 claims abstract description 9
238000005498 polishing Methods 0.000 claims abstract description 9
239000007864 aqueous solution Substances 0.000 claims abstract description 7
238000001465 metallisation Methods 0.000 claims abstract 4
239000000243 solution Substances 0.000 claims description 23
238000005266 casting Methods 0.000 claims description 15
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
238000000576 coating method Methods 0.000 claims description 9
229910000881 Cu alloy Inorganic materials 0.000 claims description 8
239000011248 coating agent Substances 0.000 claims description 8
238000004140 cleaning Methods 0.000 claims description 7
238000005868 electrolysis reaction Methods 0.000 claims description 7
238000005554 pickling Methods 0.000 claims description 6
230000008569 process Effects 0.000 claims description 6
229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 5
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 5
239000004327 boric acid Substances 0.000 claims description 5
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 5
239000000126 substance Substances 0.000 claims description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
239000012298 atmosphere Substances 0.000 claims description 4
230000015556 catabolic process Effects 0.000 claims description 4
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 3
230000002378 acidificating effect Effects 0.000 claims description 3
230000007797 corrosion Effects 0.000 claims description 3
238000005260 corrosion Methods 0.000 claims description 3
239000011261 inert gas Substances 0.000 claims description 3
150000008051 alkyl sulfates Chemical class 0.000 claims description 2
150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
239000003945 anionic surfactant Substances 0.000 claims description 2
238000009713 electroplating Methods 0.000 claims description 2
230000016507 interphase Effects 0.000 claims description 2
229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
235000019341 magnesium sulphate Nutrition 0.000 claims description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
239000002023 wood Substances 0.000 claims description 2
230000002045 lasting effect Effects 0.000 claims 2
239000003795 chemical substances by application Substances 0.000 claims 1
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims 1
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims 1
238000005058 metal casting Methods 0.000 claims 1
239000011814 protection agent Substances 0.000 claims 1
238000002360 preparation method Methods 0.000 abstract description 6
230000001590 oxidative effect Effects 0.000 abstract description 4
230000036961 partial effect Effects 0.000 abstract description 2
238000000746 purification Methods 0.000 abstract description 2
KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical compound [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 abstract 2
238000010186 staining Methods 0.000 abstract 1
239000010410 layer Substances 0.000 description 24
238000000354 decomposition reaction Methods 0.000 description 17
229910052751 metal Inorganic materials 0.000 description 11
239000002184 metal Substances 0.000 description 11
238000002161 passivation Methods 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
229910000831 Steel Inorganic materials 0.000 description 9
239000010959 steel Substances 0.000 description 9
239000000203 mixture Substances 0.000 description 8
230000008021 deposition Effects 0.000 description 6
238000011109 contamination Methods 0.000 description 5
239000000463 material Substances 0.000 description 5
-1 steel Chemical class 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
239000003153 chemical reaction reagent Substances 0.000 description 4
150000002815 nickel Chemical class 0.000 description 4
238000011084 recovery Methods 0.000 description 4
239000000758 substrate Substances 0.000 description 4
239000010936 titanium Substances 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
230000008901 benefit Effects 0.000 description 3
238000004210 cathodic protection Methods 0.000 description 3
230000007423 decrease Effects 0.000 description 3
230000007062 hydrolysis Effects 0.000 description 3
238000006460 hydrolysis reaction Methods 0.000 description 3
229910001338 liquidmetal Inorganic materials 0.000 description 3
239000004033 plastic Substances 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
230000009467 reduction Effects 0.000 description 3
230000008929 regeneration Effects 0.000 description 3
238000011069 regeneration method Methods 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
229910001093 Zr alloy Inorganic materials 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
229910052921 ammonium sulfate Inorganic materials 0.000 description 2
235000011130 ammonium sulphate Nutrition 0.000 description 2
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
230000007547 defect Effects 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
229940043264 dodecyl sulfate Drugs 0.000 description 2
238000005098 hot rolling Methods 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000003754 machining Methods 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
239000000047 product Substances 0.000 description 2
239000010802 sludge Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
239000002699 waste material Substances 0.000 description 2
229910052726 zirconium Inorganic materials 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
QZLJNVMRJXHARQ-UHFFFAOYSA-N [Zr].[Cr].[Cu] Chemical compound [Zr].[Cr].[Cu] QZLJNVMRJXHARQ-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
229910001422 barium ion Inorganic materials 0.000 description 1
238000005422 blasting Methods 0.000 description 1
239000002775 capsule Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000004020 conductor Substances 0.000 description 1
239000002826 coolant Substances 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000002950 deficient Effects 0.000 description 1
230000000593 degrading effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000005108 dry cleaning Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000003912 environmental pollution Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
238000000227 grinding Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
239000007769 metal material Substances 0.000 description 1
238000005457 optimization Methods 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
230000020477 pH reduction Effects 0.000 description 1
230000037361 pathway Effects 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000000750 progressive effect Effects 0.000 description 1
239000011241 protective layer Substances 0.000 description 1
230000002829 reductive effect Effects 0.000 description 1
239000003507 refrigerant Substances 0.000 description 1
238000009419 refurbishment Methods 0.000 description 1
230000001172 regenerating effect Effects 0.000 description 1
238000004904 shortening Methods 0.000 description 1
XMDUIJHKDOLYSR-UHFFFAOYSA-M sodium;2,3-dinitrobenzenesulfonate Chemical compound [Na+].[O-][N+](=O)C1=CC=CC(S([O-])(=O)=O)=C1[N+]([O-])=O XMDUIJHKDOLYSR-UHFFFAOYSA-M 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
238000005507 spraying Methods 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
230000000930 thermomechanical effect Effects 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F5/00—Electrolytic stripping of metallic layers or coatings
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0637—Accessories therefor
- B22D11/0648—Casting surfaces
- B22D11/0651—Casting wheels
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
- C23F1/32—Alkaline compositions
- C23F1/34—Alkaline compositions for etching copper or alloys thereof
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F1/00—Electrolytic cleaning, degreasing, pickling or descaling
- C25F1/02—Pickling; Descaling
- C25F1/04—Pickling; Descaling in solution

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Electrochemistry (AREA)
Mechanical Engineering (AREA)
General Chemical & Material Sciences (AREA)
Electroplating Methods And Accessories (AREA)
Continuous Casting (AREA)
Electroplating And Plating Baths Therefor (AREA)
Electrolytic Production Of Metals (AREA)
ing And Chemical Polishing (AREA)
Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Coating With Molten Metal (AREA)
Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
Non-Insulated Conductors (AREA)

SK457-97A 1996-04-12 1997-04-09 Spôsob povrchovej úpravy vonkajšej plochy medeného alebo z medenej zliatiny vytvoreného prvku formy na plynulé odlievanie kovov pozostávajúci z pokovovania niklom a odstraňovania niklu SK282599B6 (sk)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR9604562A FR2747400B1 (fr)	1996-04-12	1996-04-12	Procede de conditionnement de la surface externe en cuivre ou alliage de cuivre d'un element d'une lingotiere de coulee continue des metaux, du type comportant une etape de nickelage et une etape de denickelage

Publications (2)

Publication Number	Publication Date
SK45797A3 SK45797A3 (en)	1998-04-08
SK282599B6 true SK282599B6 (sk)	2002-10-08

Family

ID=9491130

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK457-97A SK282599B6 (sk)	1996-04-12	1997-04-09	Spôsob povrchovej úpravy vonkajšej plochy medeného alebo z medenej zliatiny vytvoreného prvku formy na plynulé odlievanie kovov pozostávajúci z pokovovania niklom a odstraňovania niklu

Country Status (23)

Country	Link
US (1)	US5788824A (fr)
EP (1)	EP0801154B1 (fr)
JP (1)	JP3955933B2 (fr)
KR (1)	KR100446036B1 (fr)
CN (1)	CN1117180C (fr)
AT (1)	ATE183559T1 (fr)
AU (1)	AU707062B2 (fr)
BR (1)	BR9701780A (fr)
CA (1)	CA2201448C (fr)
CZ (1)	CZ292537B6 (fr)
DE (1)	DE69700420T2 (fr)
DK (1)	DK0801154T3 (fr)
ES (1)	ES2137041T3 (fr)
FR (1)	FR2747400B1 (fr)
GR (1)	GR3031874T3 (fr)
PL (1)	PL185431B1 (fr)
RO (1)	RO119130B1 (fr)
RU (1)	RU2177857C2 (fr)
SK (1)	SK282599B6 (fr)
TR (1)	TR199700291A2 (fr)
TW (1)	TW367375B (fr)
UA (1)	UA54377C2 (fr)
ZA (1)	ZA973094B (fr)

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PT1212159E (pt) *	1999-08-26	2003-10-31	Concast Standard Ag	Molde de fundicao para o vazamento continuo de aco em barras brutas e formas de barras pre-laminadas.
DE19951324C2 (de) *	1999-10-20	2003-07-17	Atotech Deutschland Gmbh	Verfahren und Vorrichtung zum elektrolytischen Behandeln von elektrisch leitfähigen Oberflächen von gegeneinander vereinzelten Platten- und Folienmaterialstücken sowie Anwendung des Verfahrens
DE10134074C1 (de) *	2001-07-13	2003-01-23	Thyssenkrupp Nirosta Gmbh	Gießwalze für das Vergießen von Metallschmelze und Verfahren zur Herstellung einer solchen Gießwalze
DE102007003548B3 (de) *	2007-01-24	2008-09-04	Thyssenkrupp Nirosta Gmbh	Gießwalze für eine Zweiwalzengießvorrichtung und Zweiwalzengießvorrichtung
CN101319338A (zh) *	2007-06-04	2008-12-10	武济群	用金属镍电铸法制造压力容器的方法
ATE530680T1 (de) *	2009-03-20	2011-11-15	Universo Sa	Galvanisches beschichtungsverfahren zur aufbringung einer anthrazitfarbenen beschichtung und mit dieser beschichtung versehene metallteile
DE202009013126U1 (de) *	2009-09-29	2009-12-10	Egon Evertz Kg (Gmbh & Co.)	Kokille zum Stranggießen
CN104911684B (zh) *	2015-04-15	2017-09-26	京东方科技集团股份有限公司	阵列基板的制造方法和电解液
CN110565134A (zh) *	2019-10-09	2019-12-13	深圳华络电子有限公司	一种电感器件的电极制备方法
CN111334829A (zh) *	2020-04-09	2020-06-26	广汉龙润科贸有限责任公司	一种纯度高的铜盘镀镍方法
CN113005487A (zh) *	2021-02-20	2021-06-22	湖北海富镍网科技股份有限公司	一种超精细低应力电铸镍网及其制备方法
CN117053611B (zh) *	2023-10-12	2024-02-06	广州市迈源科技有限公司	一种板式换热器板片及其制备、清洗和应用方法
CN117817282A (zh) *	2024-01-12	2024-04-05	长沙升华微电子材料有限公司	一种热沉材料凸台侧面镍层的去除方法
DE102024115221B3 (de) *	2024-05-31	2025-05-15	Cunova Gmbh	Kokillenkörper und Verfahren zur Herstellung eines Kokillenkörpers

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Publication number	Priority date	Publication date	Assignee	Title
DE1250712B (de) *	1963-05-22	1967-09-21	International Nickel Limited, London	Galvanisches Nickelsulfamatbad und Verfahren zum Abscheiden von Nickeluberzugen
FR2025951A1 (en) *	1968-12-12	1970-09-11	Foseco Trading Ag	Protective casting mould coating
BE822181A (fr) *	1974-11-14	1975-05-14		Produit destine a etre utilise en vue de la formation de revetements de lingotieres.
US4264420A (en) *	1979-10-29	1981-04-28	Oxy Metal Industries Corporation	Electrolytic stripping bath and process
GB2100154B (en) *	1981-04-27	1985-11-06	Sumitomo Metal Ind	Molds for continuously casting steel
JPS5838637A (ja) *	1981-09-01	1983-03-07	Nippon Steel Corp	連続鋳造用鋳型の補修方法
US4554049A (en) *	1984-06-07	1985-11-19	Enthone, Incorporated	Selective nickel stripping compositions and method of stripping
GB2175922B (en) *	1985-07-03	1989-07-05	Inst Phisikochimia	Nickel sulphamate aqueous electrolyte composition
FR2646174B1 (fr) *	1989-04-25	1992-04-30	Pechiney Aluminium	Procede et dispositif de revetement en continu de substrats conducteurs de l'electricite par electrolyse a grande vitesse

1996
- 1996-04-12 FR FR9604562A patent/FR2747400B1/fr not_active Expired - Fee Related
1997
- 1997-03-27 AT AT97400692T patent/ATE183559T1/de active
- 1997-03-27 DE DE69700420T patent/DE69700420T2/de not_active Expired - Lifetime
- 1997-03-27 EP EP97400692A patent/EP0801154B1/fr not_active Expired - Lifetime
- 1997-03-27 DK DK97400692T patent/DK0801154T3/da active
- 1997-03-27 ES ES97400692T patent/ES2137041T3/es not_active Expired - Lifetime
- 1997-04-01 CA CA002201448A patent/CA2201448C/fr not_active Expired - Fee Related
- 1997-04-08 AU AU17760/97A patent/AU707062B2/en not_active Ceased
- 1997-04-09 UA UA97041696A patent/UA54377C2/uk unknown
- 1997-04-09 SK SK457-97A patent/SK282599B6/sk not_active IP Right Cessation
- 1997-04-10 TR TR97/00291A patent/TR199700291A2/xx unknown
- 1997-04-10 CZ CZ19971097A patent/CZ292537B6/cs not_active IP Right Cessation
- 1997-04-11 US US08/838,847 patent/US5788824A/en not_active Expired - Lifetime
- 1997-04-11 RO RO97-00703A patent/RO119130B1/ro unknown
- 1997-04-11 CN CN97111609A patent/CN1117180C/zh not_active Expired - Lifetime
- 1997-04-11 BR BR9701780A patent/BR9701780A/pt not_active IP Right Cessation
- 1997-04-11 RU RU97106251/02A patent/RU2177857C2/ru not_active IP Right Cessation
- 1997-04-11 ZA ZA9703094A patent/ZA973094B/xx unknown
- 1997-04-12 KR KR1019970013530A patent/KR100446036B1/ko not_active Expired - Lifetime
- 1997-04-12 PL PL97319470A patent/PL185431B1/pl not_active IP Right Cessation
- 1997-04-14 JP JP11194197A patent/JP3955933B2/ja not_active Expired - Fee Related
- 1997-04-15 TW TW086104825A patent/TW367375B/zh not_active IP Right Cessation
1999
- 1999-11-18 GR GR990402963T patent/GR3031874T3/el unknown

Also Published As

Publication number	Publication date
KR100446036B1 (ko)	2005-05-24
RO119130B1 (ro)	2004-04-30
KR970070248A (ko)	1997-11-07
UA54377C2 (uk)	2003-03-17
GR3031874T3 (en)	2000-02-29
EP0801154B1 (fr)	1999-08-18
FR2747400B1 (fr)	1998-05-22
TW367375B (en)	1999-08-21
JPH1034285A (ja)	1998-02-10
MX9702662A (es)	1998-06-30
CN1117180C (zh)	2003-08-06
PL185431B1 (pl)	2003-05-30
CZ109797A3 (cs)	1998-03-18
JP3955933B2 (ja)	2007-08-08
BR9701780A (pt)	1998-11-10
EP0801154A1 (fr)	1997-10-15
RU2177857C2 (ru)	2002-01-10
CA2201448A1 (fr)	1997-10-12
DK0801154T3 (da)	2000-03-20
US5788824A (en)	1998-08-04
TR199700291A2 (xx)	1997-10-21
SK45797A3 (en)	1998-04-08
AU707062B2 (en)	1999-07-01
PL319470A1 (en)	1997-10-13
AU1776097A (en)	1997-10-16
CZ292537B6 (cs)	2003-10-15
FR2747400A1 (fr)	1997-10-17
ES2137041T3 (es)	1999-12-01
CA2201448C (fr)	2004-06-22
ZA973094B (en)	1997-11-18
DE69700420T2 (de)	2000-04-13
CN1170781A (zh)	1998-01-21
DE69700420D1 (de)	1999-09-23
ATE183559T1 (de)	1999-09-15

Legal Events

Date	Code	Title	Description
2013-01-02	MM4A	Patent lapsed due to non-payment of maintenance fees	Effective date: 20120409

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US3420760A (en)	1969-01-07	Process for descaling steel strip in an aqueous organic chelating bath using alternating current
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MXPA97002662A (en)	1998-10-30	Procedure for the conditioning of external copper or copper alloy surgery of an element of a metal collapsing machine of the type including a nickel-plated stage and a stage of nickel
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JPH0220720B2 (fr)	1990-05-10
CA1235670A (fr)	1988-04-26	Procede de production de bande d'acier lamine a froid facile a traiter par conversion
Willing et al.	2001	Salt bath technology--a better way to clean metals
KR20050079969A (ko)	2005-08-11	알루미늄 용융도금을 위한 전처리방법
Lindsay et al.	1994	Decorative Chromium Plating
JPS5849637B2 (ja)	1983-11-05	ロ−ルに付着するスケ−ルを防止する方法