SK283468B6 - Spôsob izolácie katalyzátora pomocou membránovej elektrodialýzy - Google Patents

Spôsob izolácie katalyzátora pomocou membránovej elektrodialýzy Download PDF

Info

Publication number: SK283468B6
Authority: SK; Slovakia
Prior art keywords: solution; catalyst; electrodialysis; mol; cobalt
Prior art date: 1996-04-02

Application number

SK1358-98A

Other languages

English (en)

Slovak (sk)

Other versions

SK135898A3 (en

Inventor

Eric Fache

Dominique Horbez

Philippe Leconte

Original Assignee

Rhodia Fiber And Resin Intermediates

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-04-02

Filing date

1997-03-27

Publication date

2003-08-05

1997-03-27 Application filed by Rhodia Fiber And Resin Intermediates filed Critical Rhodia Fiber And Resin Intermediates

1999-04-13 Publication of SK135898A3 publication Critical patent/SK135898A3/sk

2003-08-05 Publication of SK283468B6 publication Critical patent/SK283468B6/sk

Links

238000000034 method Methods 0.000 title claims abstract description 45
239000012528 membrane Substances 0.000 title claims abstract description 38
238000000909 electrodialysis Methods 0.000 title claims abstract description 35
239000003054 catalyst Substances 0.000 title claims abstract description 34
238000007254 oxidation reaction Methods 0.000 claims abstract description 21
239000010941 cobalt Substances 0.000 claims abstract description 20
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 20
229910017052 cobalt Inorganic materials 0.000 claims abstract description 19
239000002815 homogeneous catalyst Substances 0.000 claims abstract description 8
125000001931 aliphatic group Chemical group 0.000 claims abstract description 4
239000000243 solution Substances 0.000 claims description 71
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 38
239000001361 adipic acid Substances 0.000 claims description 19
235000011037 adipic acid Nutrition 0.000 claims description 19
239000000203 mixture Substances 0.000 claims description 18
230000003647 oxidation Effects 0.000 claims description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
229910052751 metal Inorganic materials 0.000 claims description 14
239000002184 metal Substances 0.000 claims description 14
150000001875 compounds Chemical class 0.000 claims description 13
238000002955 isolation Methods 0.000 claims description 11
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 10
-1 hydroxides Chemical class 0.000 claims description 9
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 8
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 8
125000000129 anionic group Chemical group 0.000 claims description 8
125000002091 cationic group Chemical group 0.000 claims description 8
150000001924 cycloalkanes Chemical class 0.000 claims description 8
239000011541 reaction mixture Substances 0.000 claims description 8
150000003839 salts Chemical class 0.000 claims description 8
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
229910052802 copper Inorganic materials 0.000 claims description 6
239000010949 copper Substances 0.000 claims description 6
150000002739 metals Chemical class 0.000 claims description 6
125000001453 quaternary ammonium group Chemical group 0.000 claims description 5
239000002904 solvent Substances 0.000 claims description 5
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 5
229910052684 Cerium Inorganic materials 0.000 claims description 4
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 4
229910052742 iron Inorganic materials 0.000 claims description 4
239000011877 solvent mixture Substances 0.000 claims description 4
239000001384 succinic acid Substances 0.000 claims description 4
229910052720 vanadium Inorganic materials 0.000 claims description 4
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 4
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
239000006227 byproduct Substances 0.000 claims description 3
229910052748 manganese Inorganic materials 0.000 claims description 3
239000011572 manganese Substances 0.000 claims description 3
238000011282 treatment Methods 0.000 claims description 3
125000000524 functional group Chemical group 0.000 claims description 2
150000004679 hydroxides Chemical class 0.000 claims description 2
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
238000002360 preparation method Methods 0.000 claims description 2
238000010790 dilution Methods 0.000 claims 1
239000012895 dilution Substances 0.000 claims 1
239000011159 matrix material Substances 0.000 claims 1
238000000926 separation method Methods 0.000 abstract description 6
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 23
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 12
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 12
239000002253 acid Substances 0.000 description 9
239000003792 electrolyte Substances 0.000 description 9
238000012360 testing method Methods 0.000 description 9
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 8
239000012527 feed solution Substances 0.000 description 8
239000007788 liquid Substances 0.000 description 8
229910017604 nitric acid Inorganic materials 0.000 description 8
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
239000001301 oxygen Substances 0.000 description 7
229910052760 oxygen Inorganic materials 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
150000001868 cobalt Chemical class 0.000 description 6
HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 6
239000012071 phase Substances 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
230000000694 effects Effects 0.000 description 5
239000008151 electrolyte solution Substances 0.000 description 5
YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 4
ZBYYWKJVSFHYJL-UHFFFAOYSA-L cobalt(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Co+2].CC([O-])=O.CC([O-])=O ZBYYWKJVSFHYJL-UHFFFAOYSA-L 0.000 description 4
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 4
150000002894 organic compounds Chemical class 0.000 description 4
239000012085 test solution Substances 0.000 description 4
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
229940011182 cobalt acetate Drugs 0.000 description 3
QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 3
230000005684 electric field Effects 0.000 description 3
239000007789 gas Substances 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
229910021645 metal ion Inorganic materials 0.000 description 3
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000010936 titanium Substances 0.000 description 3
229910052719 titanium Inorganic materials 0.000 description 3
OTTXIFWBPRRYOG-UHFFFAOYSA-N 2-hydroxyadipic acid Chemical compound OC(=O)C(O)CCCC(O)=O OTTXIFWBPRRYOG-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
YYLLIJHXUHJATK-UHFFFAOYSA-N Cyclohexyl acetate Chemical compound CC(=O)OC1CCCCC1 YYLLIJHXUHJATK-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
239000003011 anion exchange membrane Substances 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
229930188620 butyrolactone Natural products 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
238000005341 cation exchange Methods 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
238000001311 chemical methods and process Methods 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000004587 chromatography analysis Methods 0.000 description 2
239000003426 co-catalyst Substances 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
229910002804 graphite Inorganic materials 0.000 description 2
239000010439 graphite Substances 0.000 description 2
239000004816 latex Substances 0.000 description 2
229920000126 latex Polymers 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
238000005259 measurement Methods 0.000 description 2
150000002736 metal compounds Chemical class 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
230000010287 polarization Effects 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
239000010970 precious metal Substances 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
238000012545 processing Methods 0.000 description 2
238000004064 recycling Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000003681 vanadium Chemical class 0.000 description 2
CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 description 1
NYHNVHGFPZAZGA-UHFFFAOYSA-N 2-hydroxyhexanoic acid Chemical compound CCCCC(O)C(O)=O NYHNVHGFPZAZGA-UHFFFAOYSA-N 0.000 description 1
YDCRNMJQROAWFT-UHFFFAOYSA-N 5-hydroxyhexanoic acid Chemical compound CC(O)CCCC(O)=O YDCRNMJQROAWFT-UHFFFAOYSA-N 0.000 description 1
IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Natural products CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
SVMCDCBHSKARBQ-UHFFFAOYSA-N acetic acid;cobalt Chemical compound [Co].CC(O)=O SVMCDCBHSKARBQ-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
XENHXPKUQLUHCZ-UHFFFAOYSA-L butanedioate;cobalt(2+) Chemical compound [Co+2].[O-]C(=O)CCC([O-])=O XENHXPKUQLUHCZ-UHFFFAOYSA-L 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
150000007942 carboxylates Chemical group 0.000 description 1
239000012295 chemical reaction liquid Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
229910001429 cobalt ion Inorganic materials 0.000 description 1
229910001981 cobalt nitrate Inorganic materials 0.000 description 1
ATFHQVJTPHERNM-UHFFFAOYSA-L cobalt(2+);hexanedioate Chemical compound [Co+2].[O-]C(=O)CCCCC([O-])=O ATFHQVJTPHERNM-UHFFFAOYSA-L 0.000 description 1
ZAGFOYIWAMLQGA-UHFFFAOYSA-L cobalt(2+);pentanedioate Chemical compound [Co+2].[O-]C(=O)CCCC([O-])=O ZAGFOYIWAMLQGA-UHFFFAOYSA-L 0.000 description 1
TZWGXFOSKIHUPW-UHFFFAOYSA-L cobalt(2+);propanoate Chemical compound [Co+2].CCC([O-])=O.CCC([O-])=O TZWGXFOSKIHUPW-UHFFFAOYSA-L 0.000 description 1
BZRRQSJJPUGBAA-UHFFFAOYSA-L cobalt(ii) bromide Chemical compound Br[Co]Br BZRRQSJJPUGBAA-UHFFFAOYSA-L 0.000 description 1
238000011437 continuous method Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000010494 dissociation reaction Methods 0.000 description 1
230000005593 dissociations Effects 0.000 description 1
239000004744 fabric Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
238000007172 homogeneous catalysis Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000012535 impurity Substances 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
229910001437 manganese ion Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
238000013508 migration Methods 0.000 description 1
230000005012 migration Effects 0.000 description 1
239000012452 mother liquor Substances 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
230000036284 oxygen consumption Effects 0.000 description 1
239000002245 particle Substances 0.000 description 1
125000005496 phosphonium group Chemical group 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000001953 recrystallisation Methods 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000000052 vinegar Substances 0.000 description 1
235000021419 vinegar Nutrition 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Water Supply & Treatment (AREA)
Materials Engineering (AREA)
Health & Medical Sciences (AREA)
Urology & Nephrology (AREA)
Oil, Petroleum & Natural Gas (AREA)
Separation Using Semi-Permeable Membranes (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Water Treatment By Electricity Or Magnetism (AREA)

SK1358-98A 1996-04-02 1997-03-27 Spôsob izolácie katalyzátora pomocou membránovej elektrodialýzy SK283468B6 (sk)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR9604379A FR2746671B1 (fr)	1996-04-02	1996-04-02	Procede de separation d'un catalyseur par electrodialyse membranaire
PCT/FR1997/000559 WO1997036673A1 (fr)	1996-04-02	1997-03-27	Procede de separation d'un catalyseur par electrodialyse membranaire

Publications (2)

Publication Number	Publication Date
SK135898A3 SK135898A3 (en)	1999-04-13
SK283468B6 true SK283468B6 (sk)	2003-08-05

Family

ID=9491013

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK1358-98A SK283468B6 (sk)	1996-04-02	1997-03-27	Spôsob izolácie katalyzátora pomocou membránovej elektrodialýzy

Country Status (18)

Country	Link
US (1)	US6214190B1 (de)
EP (1)	EP0914195B1 (de)
JP (1)	JP3770620B2 (de)
CN (1)	CN1126587C (de)
AR (1)	AR006476A1 (de)
BR (1)	BR9708416A (de)
CA (1)	CA2250801C (de)
CZ (1)	CZ291840B6 (de)
DE (1)	DE69713334T2 (de)
ES (1)	ES2177975T3 (de)
FR (1)	FR2746671B1 (de)
ID (1)	ID16798A (de)
PL (1)	PL183407B1 (de)
RU (1)	RU2181303C2 (de)
SK (1)	SK283468B6 (de)
TW (1)	TW515726B (de)
UA (1)	UA46099C2 (de)
WO (1)	WO1997036673A1 (de)

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FR2775685B1 (fr) *	1998-03-05	2000-12-29	Rhone Poulenc Fibres	Procede de separation et de purification de l'acide adipique
US6340420B1 (en) *	1998-07-06	2002-01-22	Rpc Inc.	Methods of treating the oxidation mixture of hydrocarbons to respective dibasic acids
GB0406141D0 (en) *	2004-03-18	2004-04-21	Boc Group Plc	Electromembrane process and apparatus
RU2268085C2 (ru) *	2004-03-22	2006-01-20	Тамбовский государственный технический университет (ТГТУ)	Электробаромембранный аппарат рулонного типа
US7255798B2 (en) *	2004-03-26	2007-08-14	Ion Power, Inc.	Recycling of used perfluorosulfonic acid membranes
US7541489B2 (en)	2004-06-30	2009-06-02	Sabic Innovative Plastics Ip B.V.	Method of making halophthalic acids and halophthalic anhydrides
CN101468836A (zh) *	2007-12-25	2009-07-01	通用电气公司	电渗析装置和方法
DE102013205508A1 (de) *	2013-03-27	2014-10-02	Siemens Aktiengesellschaft	Anlage und Verfahren zum Separieren von Metallen
CN105132005A (zh) *	2015-07-28	2015-12-09	昆明理工大学	一种制备生物柴油的方法
SG11201803576SA (en) *	2015-10-30	2018-05-30	China Petroleum & Chem Corp	Method for wastewater treatment and the treatment system thereof, and method for the preparation of a molecular sieve and the preparation system
CN114164460B (zh) *	2020-08-19	2023-05-02	中国石油化工股份有限公司	环己烷直接氧化制己二酸合成液的处理方法
CN112939765B (zh)	2021-02-22	2022-08-09	湘潭大学	一种由环己烷联产己二酸和环己酮肟的方法
US20230264989A1 (en) *	2022-02-22	2023-08-24	John J. Gresens	Portable Replenishable Capacitive Deionization Device

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1591176A (de) *	1968-10-30	1970-04-27
US3673068A (en) *	1968-12-16	1972-06-27	Asahi Chemical Ind	Process for recovering waste acids and metals by electrodialysis
US4680098A (en) *	1985-03-18	1987-07-14	Amoco Corporation	Aqueous recovery of cobalt or cobalt and manganese from solution also containing oxygenated aromatic compounds
IT1197007B (it) *	1986-07-28	1988-11-25	Oronzio De Nora Impianti	Catodo incollato alla superficie di una membrana a scambio ionico, per l'impiego in un elettrolizzatore per processi elettrochimici e relativo metodo di elettrolisi
US5282939A (en) *	1988-09-20	1994-02-01	Basf Aktiengesellschaft	Removal of salts by electrodialysis
FR2722783B1 (fr) *	1994-07-21	1996-08-30	Rhone Poulenc Chimie	Procede de preparation d'acide adipique par oxydattion directe du cyclohexane et recyclage du catalyseur

1996
- 1996-04-02 FR FR9604379A patent/FR2746671B1/fr not_active Expired - Fee Related
1997
- 1997-03-26 TW TW086103856A patent/TW515726B/zh not_active IP Right Cessation
- 1997-03-27 BR BR9708416A patent/BR9708416A/pt not_active IP Right Cessation
- 1997-03-27 SK SK1358-98A patent/SK283468B6/sk unknown
- 1997-03-27 CA CA002250801A patent/CA2250801C/fr not_active Expired - Fee Related
- 1997-03-27 PL PL97329130A patent/PL183407B1/pl not_active IP Right Cessation
- 1997-03-27 EP EP97919434A patent/EP0914195B1/de not_active Expired - Lifetime
- 1997-03-27 WO PCT/FR1997/000559 patent/WO1997036673A1/fr not_active Ceased
- 1997-03-27 UA UA98095065A patent/UA46099C2/uk unknown
- 1997-03-27 DE DE69713334T patent/DE69713334T2/de not_active Expired - Lifetime
- 1997-03-27 JP JP53498497A patent/JP3770620B2/ja not_active Expired - Fee Related
- 1997-03-27 ES ES97919434T patent/ES2177975T3/es not_active Expired - Lifetime
- 1997-03-27 RU RU98119719/28A patent/RU2181303C2/ru not_active IP Right Cessation
- 1997-03-27 CZ CZ19983156A patent/CZ291840B6/cs not_active IP Right Cessation
- 1997-03-27 US US09/155,597 patent/US6214190B1/en not_active Expired - Fee Related
- 1997-03-27 CN CN97193591A patent/CN1126587C/zh not_active Expired - Fee Related
- 1997-04-01 ID IDP971093A patent/ID16798A/id unknown
- 1997-04-02 AR ARP970101306A patent/AR006476A1/es unknown

Also Published As

Publication number	Publication date
CN1126587C (zh)	2003-11-05
FR2746671B1 (fr)	1998-09-25
DE69713334T2 (de)	2003-01-02
UA46099C2 (uk)	2002-05-15
PL183407B1 (pl)	2002-06-28
TW515726B (en)	2003-01-01
DE69713334D1 (de)	2002-07-18
ES2177975T3 (es)	2002-12-16
CA2250801C (fr)	2001-12-25
EP0914195A1 (de)	1999-05-12
CN1215350A (zh)	1999-04-28
SK135898A3 (en)	1999-04-13
CZ315698A3 (cs)	1999-03-17
US6214190B1 (en)	2001-04-10
BR9708416A (pt)	1999-08-03
WO1997036673A1 (fr)	1997-10-09
PL329130A1 (en)	1999-03-15
JP2000508227A (ja)	2000-07-04
RU2181303C2 (ru)	2002-04-20
CZ291840B6 (cs)	2003-06-18
ID16798A (id)	1997-11-13
CA2250801A1 (fr)	1997-10-09
JP3770620B2 (ja)	2006-04-26
AR006476A1 (es)	1999-08-25
EP0914195B1 (de)	2002-06-12
FR2746671A1 (fr)	1997-10-03

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US20020189950A1 (en)	2002-12-19	Electrodialysis of multivalent metal salts
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CA2227398A1 (en)	1998-07-23	Apparatus and process for electrodialysis of salts
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