SK286309B6 - Method for electrochemical production of Ni(0) phosphite and diphosphite complexes and method of olefin hydrocyanation or alkene nitrite isomerization - Google Patents

Method for electrochemical production of Ni(0) phosphite and diphosphite complexes and method of olefin hydrocyanation or alkene nitrite isomerization Download PDF

Info

Publication number: SK286309B6
Authority: SK; Slovakia
Prior art keywords: nickel; anode; cathode; phosphite; mmol
Prior art date: 1999-08-20

Application number

SK218-2002A

Other languages

English (en)

Slovak (sk)

Other versions

SK2182002A3 (en

Inventor

Andrei Aleksandrovich Stepanov

Vitali Arjadevich Grinberg

Scott Christopher Jackson

Cynthia Anne Lundgren

Tatjana Lvovna Kulova

Original Assignee

Du Pont

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-08-20

Filing date

2000-08-17

Publication date

2008-07-07

2000-08-17 Application filed by Du Pont filed Critical Du Pont

2002-06-04 Publication of SK2182002A3 publication Critical patent/SK2182002A3/sk

2008-07-07 Publication of SK286309B6 publication Critical patent/SK286309B6/sk

Links

238000000034 method Methods 0.000 title claims abstract description 49
ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 title claims abstract description 34
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 title claims abstract description 31
238000005669 hydrocyanation reaction Methods 0.000 title claims abstract description 10
238000004519 manufacturing process Methods 0.000 title claims abstract description 10
150000001336 alkenes Chemical class 0.000 title claims abstract description 9
238000006317 isomerization reaction Methods 0.000 title claims abstract description 8
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 8
-1 alkene nitrite Chemical class 0.000 title claims abstract description 7
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 236
239000003446 ligand Substances 0.000 claims abstract description 109
229910052759 nickel Inorganic materials 0.000 claims abstract description 62
229910052751 metal Inorganic materials 0.000 claims abstract description 18
239000002184 metal Substances 0.000 claims abstract description 18
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 15
229910052698 phosphorus Inorganic materials 0.000 claims abstract description 15
239000011574 phosphorus Substances 0.000 claims abstract description 15
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims abstract description 14
239000003054 catalyst Substances 0.000 claims abstract description 14
229910001453 nickel ion Inorganic materials 0.000 claims abstract description 14
239000000010 aprotic solvent Substances 0.000 claims abstract description 7
238000000151 deposition Methods 0.000 claims abstract description 5
238000005868 electrolysis reaction Methods 0.000 claims description 72
UVKXJAUUKPDDNW-NSCUHMNNSA-N (e)-pent-3-enenitrile Chemical compound C\C=C\CC#N UVKXJAUUKPDDNW-NSCUHMNNSA-N 0.000 claims description 42
CFEYBLWMNFZOPB-UHFFFAOYSA-N Allylacetonitrile Natural products C=CCCC#N CFEYBLWMNFZOPB-UHFFFAOYSA-N 0.000 claims description 42
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 30
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 27
239000011701 zinc Substances 0.000 claims description 25
230000008569 process Effects 0.000 claims description 18
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 16
125000000217 alkyl group Chemical group 0.000 claims description 15
229910052725 zinc Inorganic materials 0.000 claims description 12
238000004090 dissolution Methods 0.000 claims description 10
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
239000002904 solvent Substances 0.000 claims description 7
YCIMNLLNPGFGHC-UHFFFAOYSA-N o-dihydroxy-benzene Natural products OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 6
150000002500 ions Chemical class 0.000 claims description 5
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 5
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
125000003118 aryl group Chemical group 0.000 claims description 4
229910052742 iron Inorganic materials 0.000 claims description 4
150000002739 metals Chemical class 0.000 claims description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
229910017052 cobalt Inorganic materials 0.000 claims description 2
239000010941 cobalt Substances 0.000 claims description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
229910052737 gold Inorganic materials 0.000 claims description 2
239000010931 gold Substances 0.000 claims description 2
125000001183 hydrocarbyl group Chemical group 0.000 claims description 2
229910052741 iridium Inorganic materials 0.000 claims description 2
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
239000011733 molybdenum Substances 0.000 claims description 2
229910052763 palladium Inorganic materials 0.000 claims description 2
229910052697 platinum Inorganic materials 0.000 claims description 2
229910052707 ruthenium Inorganic materials 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims 2
150000005206 1,2-dihydroxybenzenes Chemical class 0.000 claims 1
KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 claims 1
230000000737 periodic effect Effects 0.000 claims 1
239000011521 glass Substances 0.000 description 28
239000000126 substance Substances 0.000 description 16
229910052739 hydrogen Inorganic materials 0.000 description 15
CUJRVFIICFDLGR-UHFFFAOYSA-N acetylacetonate Chemical compound CC(=O)[CH-]C(C)=O CUJRVFIICFDLGR-UHFFFAOYSA-N 0.000 description 13
229910052799 carbon Inorganic materials 0.000 description 12
239000003792 electrolyte Substances 0.000 description 12
125000004642 (C1-C12) alkoxy group Chemical group 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
238000002955 isolation Methods 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
125000003545 alkoxy group Chemical group 0.000 description 4
230000008901 benefit Effects 0.000 description 4
125000004400 (C1-C12) alkyl group Chemical group 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
239000002841 Lewis acid Substances 0.000 description 3
BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 description 3
229910052802 copper Inorganic materials 0.000 description 3
239000010949 copper Substances 0.000 description 3
230000008021 deposition Effects 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
150000007517 lewis acids Chemical class 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 3
WBAXCOMEMKANRN-UHFFFAOYSA-N 2-methylbut-3-enenitrile Chemical compound C=CC(C)C#N WBAXCOMEMKANRN-UHFFFAOYSA-N 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
230000005611 electricity Effects 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
229910021645 metal ion Inorganic materials 0.000 description 2
125000001624 naphthyl group Chemical group 0.000 description 2
BMGNSKKZFQMGDH-FDGPNNRMSA-L nickel(2+);(z)-4-oxopent-2-en-2-olate Chemical compound [Ni+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O BMGNSKKZFQMGDH-FDGPNNRMSA-L 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
125000005538 phosphinite group Chemical group 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
230000009467 reduction Effects 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
229910052776 Thorium Inorganic materials 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
239000012300 argon atmosphere Substances 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000010406 cathode material Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
238000002484 cyclic voltammetry Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000000840 electrochemical analysis Methods 0.000 description 1
238000002848 electrochemical method Methods 0.000 description 1
238000009713 electroplating Methods 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
230000029142 excretion Effects 0.000 description 1
239000006260 foam Substances 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
239000002815 homogeneous catalyst Substances 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000011835 investigation Methods 0.000 description 1
238000011005 laboratory method Methods 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000011068 loading method Methods 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
LSQSZWHJXWRJID-UHFFFAOYSA-N mercury nickel Chemical compound [Ni].[Hg] LSQSZWHJXWRJID-UHFFFAOYSA-N 0.000 description 1
150000004780 naphthols Chemical class 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
229910000319 transition metal phosphate Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
238000004832 voltammetry Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/52—Isomerisation reactions
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Electrochemistry (AREA)
Inorganic Chemistry (AREA)
Physics & Mathematics (AREA)
Health & Medical Sciences (AREA)
Plasma & Fusion (AREA)
Toxicology (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Catalysts (AREA)

SK218-2002A 1999-08-20 2000-08-17 Method for electrochemical production of Ni(0) phosphite and diphosphite complexes and method of olefin hydrocyanation or alkene nitrite isomerization SK286309B6 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
RU99118171/04A RU2226228C2 (ru)	1999-08-20	1999-08-20	Способ электрохимического получения ni(о) фосфитных и дифосфитных комплексов
PCT/US2000/022527 WO2001014392A1 (en)	1999-08-20	2000-08-17	METHOD FOR ELECTROCHEMICAL PRODUCTION OF Ni(0) PHOSPHITE AND DIPHOSPHITE COMPLEXES

Publications (2)

Publication Number	Publication Date
SK2182002A3 SK2182002A3 (en)	2002-06-04
SK286309B6 true SK286309B6 (en)	2008-07-07

Family

ID=20224153

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK218-2002A SK286309B6 (en)	1999-08-20	2000-08-17	Method for electrochemical production of Ni(0) phosphite and diphosphite complexes and method of olefin hydrocyanation or alkene nitrite isomerization

Country Status (14)

Country	Link
EP (1)	EP1218389B1 (cs)
JP (1)	JP2003507582A (cs)
KR (1)	KR100760788B1 (cs)
CN (1)	CN1211393C (cs)
AU (1)	AU6779000A (cs)
BR (1)	BR0013556A (cs)
CA (1)	CA2376294A1 (cs)
CZ (1)	CZ2002501A3 (cs)
DE (1)	DE60006144T2 (cs)
MX (1)	MXPA02001756A (cs)
PL (1)	PL202487B1 (cs)
RU (1)	RU2226228C2 (cs)
SK (1)	SK286309B6 (cs)
WO (1)	WO2001014392A1 (cs)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE10136488A1 (de)	2001-07-27	2003-02-06	Basf Ag	Ni(O) enthaltendes Katalysatorsystem
AR038161A1 (es)	2002-01-24	2004-12-29	Basf Ag	Procedimiento para separar acidos de mezclas de reaccion quimicas con la ayuda de liquidos ionicos
FR2842197A1 (fr)	2002-07-15	2004-01-16	Rhodia Polyamide Intermediates	Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US7253298B2 (en)	2002-07-15	2007-08-07	Rhodia Polyamide Intermediates	Process for preparing nitrile compounds from ethylenically unsaturated compounds
US6897329B2 (en)	2003-01-14	2005-05-24	Invista North America S.A.R.L.	Process for the preparation of nickel/phosphorous ligand catalyst for olefin hydrocyanation
CN1313641C (zh) *	2003-12-09	2007-05-02	南开大学	化学镀镍磷合金的方法
DE102004004718A1 (de)	2004-01-29	2005-08-18	Basf Ag	Verfahren zur Hydrocyanierung
EP1825914A1 (de) *	2006-02-22	2007-08-29	Basf Aktiengesellschaft	Verbessertes Verfahren zur Herstellung von Nickel(0)-Phophorligand-Komplexen
RU2396375C1 (ru) *	2009-04-09	2010-08-10	Учреждение Российской академии наук Институт органической и физической химии им. А.Е. Арбузова Казанского научного центра Российской академии наук (ИОФХ им. А.Е. Арбузова КазНЦ РАН)	Электрохимический способ получения никельорганических сигма-комплексов
WO2012033555A1 (en)	2010-09-07	2012-03-15	Invista Technologies S.A.R.L.	Nickel compositions for preparing nickel metal and nickel complexes

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
SU166339A (cs) *
US3887441A (en) *	1971-12-29	1975-06-03	Phillips Petroleum Co	Electro-chemical synthesis of organonickel compounds
US4312717A (en) *	1979-06-19	1982-01-26	Sumitomo Chemical Company, Limited	Process for producing 2-(2'-methyl-1'-propenyl)-4-methyltetrahydropyran
US5512695A (en)	1994-04-14	1996-04-30	E. I. Du Pont De Nemours And Company	Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins
FR2727637B1 (fr) *	1994-12-06	1997-01-03	Rhone Poulenc Chimie	Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine
US5602228A (en)	1995-06-06	1997-02-11	Maxdem Incorporated	Nickel phosphate catalysts
FR2743011B1 (fr) *	1995-12-29	1998-02-20	Rhone Poulenc Fibres	Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine
DE19740180A1 (de) *	1997-09-12	1999-03-18	Basf Ag	Katalysator, umfassend wenigstens einen Nickel(0)Komplex auf Basis eines Phosphonitliganden und Verfahren zur Herstellung von Nitrilen
DE19809532C1 (de) *	1998-03-05	1999-04-15	Karlsruhe Forschzent	Verfahren zur Carboxylierung von terminalen Alkinen

1999
- 1999-08-20 RU RU99118171/04A patent/RU2226228C2/ru not_active IP Right Cessation
2000
- 2000-08-17 MX MXPA02001756A patent/MXPA02001756A/es active IP Right Grant
- 2000-08-17 PL PL353637A patent/PL202487B1/pl not_active IP Right Cessation
- 2000-08-17 BR BR0013556-9A patent/BR0013556A/pt not_active Application Discontinuation
- 2000-08-17 DE DE60006144T patent/DE60006144T2/de not_active Expired - Lifetime
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- 2000-08-17 JP JP2001518722A patent/JP2003507582A/ja active Pending
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PL353637A1 (en)	2003-12-01
EP1218389A1 (en)	2002-07-03
DE60006144D1 (de)	2003-11-27
SK2182002A3 (en)	2002-06-04
MXPA02001756A (es)	2002-10-23
AU6779000A (en)	2001-03-19
KR20020023423A (ko)	2002-03-28
WO2001014392A1 (en)	2001-03-01
KR100760788B1 (ko)	2007-10-04
PL202487B1 (pl)	2009-06-30
CA2376294A1 (en)	2001-03-01
EP1218389B1 (en)	2003-10-22
CN1211393C (zh)	2005-07-20
DE60006144T2 (de)	2004-07-22
BR0013556A (pt)	2002-04-09
JP2003507582A (ja)	2003-02-25
RU2226228C2 (ru)	2004-03-27
CZ2002501A3 (cs)	2002-06-12
CN1370177A (zh)	2002-09-18

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