SK41693A3 - Adsorptive removal of sulfur compounds from fatty materials - Google Patents
Adsorptive removal of sulfur compounds from fatty materials Download PDFInfo
- Publication number
- SK41693A3 SK41693A3 SK416-93A SK41693A SK41693A3 SK 41693 A3 SK41693 A3 SK 41693A3 SK 41693 A SK41693 A SK 41693A SK 41693 A3 SK41693 A3 SK 41693A3
- Authority
- SK
- Slovakia
- Prior art keywords
- sulfur
- oil
- silica hydrogel
- fatty
- fatty material
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 65
- 150000003464 sulfur compounds Chemical class 0.000 title claims description 20
- 230000000274 adsorptive effect Effects 0.000 title abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 107
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 59
- 239000011593 sulfur Substances 0.000 claims abstract description 59
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 59
- 239000000017 hydrogel Substances 0.000 claims abstract description 51
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 47
- 238000000034 method Methods 0.000 claims abstract description 43
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 33
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 230000008569 process Effects 0.000 claims abstract description 17
- 239000003921 oil Substances 0.000 claims description 33
- 235000019198 oils Nutrition 0.000 claims description 33
- 239000003463 adsorbent Substances 0.000 claims description 32
- 239000003054 catalyst Substances 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 13
- 125000005456 glyceride group Chemical group 0.000 claims description 11
- -1 fatty acid compounds Chemical class 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 238000007670 refining Methods 0.000 claims description 8
- 235000019519 canola oil Nutrition 0.000 claims description 7
- 238000004061 bleaching Methods 0.000 claims description 6
- 239000000828 canola oil Substances 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 244000188595 Brassica sinapistrum Species 0.000 claims description 5
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 5
- 150000002540 isothiocyanates Chemical class 0.000 claims description 5
- 235000021243 milk fat Nutrition 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 239000004164 Wax ester Substances 0.000 claims description 4
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- 150000007522 mineralic acids Chemical class 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 150000003904 phospholipids Chemical class 0.000 claims description 4
- 235000019386 wax ester Nutrition 0.000 claims description 4
- 229930002875 chlorophyll Natural products 0.000 claims description 3
- 235000019804 chlorophyll Nutrition 0.000 claims description 3
- 239000002285 corn oil Substances 0.000 claims description 3
- 235000005687 corn oil Nutrition 0.000 claims description 3
- 230000002255 enzymatic effect Effects 0.000 claims description 3
- 235000021323 fish oil Nutrition 0.000 claims description 3
- 235000005985 organic acids Nutrition 0.000 claims description 3
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 claims description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 claims description 2
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 claims description 2
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 150000001413 amino acids Chemical class 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 150000003553 thiiranes Chemical class 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 1
- 239000007844 bleaching agent Substances 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 claims 1
- 238000004332 deodorization Methods 0.000 claims 1
- 239000010499 rapseed oil Substances 0.000 claims 1
- 230000007423 decrease Effects 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 description 14
- 238000012545 processing Methods 0.000 description 7
- 239000000356 contaminant Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 5
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 229940013317 fish oils Drugs 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- 230000000607 poisoning effect Effects 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 150000003567 thiocyanates Chemical class 0.000 description 3
- 101100006272 Dictyostelium discoideum ChlA gene Proteins 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004993 emission spectroscopy Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011573 trace mineral Substances 0.000 description 2
- 235000013619 trace mineral Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000001238 wet grinding Methods 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000001543 Corylus americana Nutrition 0.000 description 1
- 240000007582 Corylus avellana Species 0.000 description 1
- 235000007466 Corylus avellana Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
- LEVWYRKDKASIDU-IMJSIDKUSA-N L-cystine Chemical compound [O-]C(=O)[C@@H]([NH3+])CSSC[C@H]([NH3+])C([O-])=O LEVWYRKDKASIDU-IMJSIDKUSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000269821 Scombridae Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229930002868 chlorophyll a Natural products 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 230000007515 enzymatic degradation Effects 0.000 description 1
- 230000007071 enzymatic hydrolysis Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 235000020640 mackerel Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013310 margarine Nutrition 0.000 description 1
- 239000003264 margarine Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000011403 purification operation Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/10—Refining fats or fatty oils by adsorption
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/878,944 US5298638A (en) | 1992-05-05 | 1992-05-05 | Adsorptive removal of sulfur compounds from fatty materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK41693A3 true SK41693A3 (en) | 1994-01-12 |
Family
ID=25373132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK416-93A SK41693A3 (en) | 1992-05-05 | 1993-04-29 | Adsorptive removal of sulfur compounds from fatty materials |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5298638A (cs) |
| EP (1) | EP0569110A1 (cs) |
| JP (1) | JPH0633086A (cs) |
| KR (1) | KR930023447A (cs) |
| AU (1) | AU3511593A (cs) |
| CA (1) | CA2094988A1 (cs) |
| CO (1) | CO4180404A1 (cs) |
| CZ (1) | CZ73493A3 (cs) |
| EC (1) | ECSP930925A (cs) |
| HU (1) | HUT67458A (cs) |
| NZ (1) | NZ247051A (cs) |
| PL (1) | PL298814A1 (cs) |
| SK (1) | SK41693A3 (cs) |
| TR (1) | TR27056A (cs) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2260397A1 (en) * | 1999-01-29 | 2000-07-29 | Atlantis Marine Inc. | Method of converting rendered triglyceride oil from marine sources into bland, stable food oil |
| JP4278910B2 (ja) | 2002-03-13 | 2009-06-17 | 花王株式会社 | エステルの製造法 |
| US7585990B2 (en) * | 2003-07-31 | 2009-09-08 | Cargill, Incorporated | Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils |
| WO2005012471A2 (en) * | 2003-07-31 | 2005-02-10 | Cargill, Incorporated | Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils |
| CA2619318C (en) * | 2005-08-15 | 2011-11-01 | Arizona Chemical Company | Low sulfur tall oil fatty acid |
| EP2183205A4 (en) * | 2007-08-09 | 2013-10-02 | Elevance Renewable Sciences | CHEMICAL PROCESSES FOR TREATING METATHESIS RAW MATERIAL |
| US9284515B2 (en) | 2007-08-09 | 2016-03-15 | Elevance Renewable Sciences, Inc. | Thermal methods for treating a metathesis feedstock |
| CN101821218A (zh) | 2007-08-09 | 2010-09-01 | 埃莱文斯可更新科学公司 | 用于处理复分解原料的热方法 |
| US20090077862A1 (en) * | 2007-09-25 | 2009-03-26 | Schwab Scott D | Lubricity additives and methods of producing lubricity additives |
| US8507703B2 (en) * | 2007-11-27 | 2013-08-13 | Grace Gmbh & Co. Kg. | Purification of fatty materials such as oils |
| EP2238220A2 (en) * | 2007-12-21 | 2010-10-13 | Grace GmbH & Co. KG | Treatment of biofuels |
| RU2565057C2 (ru) | 2009-10-12 | 2015-10-20 | Елевансе Реневабле Сайенсез, Инк. | Способы очистки и производства топлива из натурального масляного исходного сырья |
| US9051519B2 (en) | 2009-10-12 | 2015-06-09 | Elevance Renewable Sciences, Inc. | Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters |
| US9365487B2 (en) | 2009-10-12 | 2016-06-14 | Elevance Renewable Sciences, Inc. | Methods of refining and producing dibasic esters and acids from natural oil feedstocks |
| KR101331413B1 (ko) * | 2011-10-18 | 2013-11-21 | 에스케이이노베이션 주식회사 | 황산화물 흡착을 위한 산 처리된 실리카 기반 흡착제 및 그 산 처리 방법 |
| CN104508099A (zh) | 2012-04-26 | 2015-04-08 | 美国达拉斯集团公司 | 用硅酸镁和有机酸纯化未精炼的食用油和食用脂肪 |
| CN110548480A (zh) * | 2019-10-14 | 2019-12-10 | 广汉市迈德乐食品有限公司 | 一种用于火锅牛油的脱胶吸附剂及其应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1214746A1 (ru) * | 1984-04-25 | 1986-02-28 | Научно-производственное объединение "Масложирпром" | Способ рафинации серосодержащих растительных масел |
| US4880574A (en) * | 1984-12-07 | 1989-11-14 | W. R. Grace & Co.-Conn. | Method for refining glyceride oils using partially dried amorphous silica hydrogels |
| US4629588A (en) * | 1984-12-07 | 1986-12-16 | W. R. Grace & Co. | Method for refining glyceride oils using amorphous silica |
| US4734226A (en) * | 1986-01-28 | 1988-03-29 | W. R. Grace & Co. | Method for refining glyceride oils using acid-treated amorphous silica |
| US4939115A (en) * | 1986-01-28 | 1990-07-03 | W. R. Grace & Co.-Conn. | Organic acid-treated amorphous silicas for refining glyceride oils |
| ATE69975T1 (de) * | 1986-11-24 | 1991-12-15 | Unilever Nv | Metall-oxid-siliziumdioxid enthaltendes sorbentmittel und dessen verwendung zur oelraffinierung. |
| US4781864A (en) * | 1987-05-15 | 1988-11-01 | W. R. Grace & Co.-Conn. | Process for the removal of chlorophyll, color bodies and phospholipids from glyceride oils using acid-treated silica adsorbents |
| US4877765A (en) * | 1987-05-15 | 1989-10-31 | W. R. Grace & Co. | Adsorptive material for the removal of chlorophyll, color bodies and phospholipids from glyceride oils |
| GB8906443D0 (en) * | 1989-03-21 | 1989-05-04 | Unilever Plc | Process for refining glyceride oil using silica hydrogel |
| SU1687597A1 (ru) * | 1989-07-05 | 1991-10-30 | Ташкентский Политехнический Институт Им.А.Р.Бируни | Способ рафинации рапсового масла |
-
1992
- 1992-05-05 US US07/878,944 patent/US5298638A/en not_active Expired - Fee Related
-
1993
- 1993-03-03 NZ NZ247051A patent/NZ247051A/en unknown
- 1993-03-10 AU AU35115/93A patent/AU3511593A/en not_active Abandoned
- 1993-04-15 EC EC1993000925A patent/ECSP930925A/es unknown
- 1993-04-16 KR KR1019930006382A patent/KR930023447A/ko not_active Withdrawn
- 1993-04-21 CO CO93383317A patent/CO4180404A1/es unknown
- 1993-04-26 CZ CZ93734A patent/CZ73493A3/cs unknown
- 1993-04-27 CA CA002094988A patent/CA2094988A1/en not_active Abandoned
- 1993-04-27 JP JP5122125A patent/JPH0633086A/ja active Pending
- 1993-04-29 SK SK416-93A patent/SK41693A3/sk unknown
- 1993-05-04 PL PL29881493A patent/PL298814A1/xx unknown
- 1993-05-04 HU HU9301292A patent/HUT67458A/hu unknown
- 1993-05-04 EP EP93250125A patent/EP0569110A1/en not_active Withdrawn
- 1993-05-04 TR TR00450/93A patent/TR27056A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2094988A1 (en) | 1993-11-06 |
| NZ247051A (en) | 1994-09-27 |
| US5298638A (en) | 1994-03-29 |
| ECSP930925A (es) | 1994-03-07 |
| TR27056A (tr) | 1994-10-11 |
| CZ73493A3 (en) | 1994-03-16 |
| HU9301292D0 (en) | 1993-07-28 |
| EP0569110A1 (en) | 1993-11-10 |
| PL298814A1 (en) | 1994-02-07 |
| KR930023447A (ko) | 1993-12-18 |
| JPH0633086A (ja) | 1994-02-08 |
| CO4180404A1 (es) | 1995-06-07 |
| HUT67458A (en) | 1995-04-28 |
| AU3511593A (en) | 1993-11-11 |
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| Publication | Publication Date | Title |
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