SK9772001A3 - Aqueous peroxide emulsions, use thereof and polyvinylchloride - Google Patents

Aqueous peroxide emulsions, use thereof and polyvinylchloride Download PDF

Info

Publication number: SK9772001A3
Authority: SK; Slovakia
Prior art keywords: peroxide; emulsion; weight; emulsion according; amount
Prior art date: 1999-01-12

Application number

SK977-2001A

Other languages

English (en)

Slovak (sk)

Inventor

Hans Westmijze

Boen Ho O

Original Assignee

Akzo Nobel Nv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-01-12

Filing date

2000-01-06

Publication date

2001-12-03

2000-01-06 Application filed by Akzo Nobel Nv filed Critical Akzo Nobel Nv

2001-12-03 Publication of SK9772001A3 publication Critical patent/SK9772001A3/sk

Links

239000000839 emulsion Substances 0.000 title claims abstract description 95
150000002978 peroxides Chemical class 0.000 title claims abstract description 66
229920000915 polyvinyl chloride Polymers 0.000 title claims description 6
239000004800 polyvinyl chloride Substances 0.000 title claims description 6
229920001577 copolymer Polymers 0.000 claims abstract description 20
150000002191 fatty alcohols Chemical class 0.000 claims abstract description 20
230000002528 anti-freeze Effects 0.000 claims abstract description 19
150000001298 alcohols Chemical class 0.000 claims abstract description 12
238000007046 ethoxylation reaction Methods 0.000 claims abstract description 10
239000000654 additive Substances 0.000 claims abstract description 9
239000004711 α-olefin Substances 0.000 claims abstract description 9
239000002253 acid Substances 0.000 claims abstract description 6
239000003995 emulsifying agent Substances 0.000 claims abstract description 5
150000001990 dicarboxylic acid derivatives Chemical class 0.000 claims abstract 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 36
238000006116 polymerization reaction Methods 0.000 claims description 25
239000000178 monomer Substances 0.000 claims description 22
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 16
238000000034 method Methods 0.000 claims description 15
230000001804 emulsifying effect Effects 0.000 claims description 11
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
238000007710 freezing Methods 0.000 claims description 10
230000008014 freezing Effects 0.000 claims description 10
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
239000007798 antifreeze agent Substances 0.000 claims description 7
238000006243 chemical reaction Methods 0.000 claims description 7
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
239000000126 substance Substances 0.000 claims description 5
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
150000004978 peroxycarbonates Chemical class 0.000 claims description 3
239000012933 diacyl peroxide Substances 0.000 claims description 2
125000005634 peroxydicarbonate group Chemical group 0.000 claims description 2
108010053481 Antifreeze Proteins Proteins 0.000 abstract 1
239000000203 mixture Substances 0.000 description 21
-1 di-sec-butyl dicarbonate -methylpentylperoxypivalate Chemical compound 0.000 description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
229920000642 polymer Polymers 0.000 description 12
ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 10
239000003505 polymerization initiator Substances 0.000 description 7
230000000052 comparative effect Effects 0.000 description 6
230000000694 effects Effects 0.000 description 5
238000003860 storage Methods 0.000 description 5
239000004094 surface-active agent Substances 0.000 description 5
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
238000000354 decomposition reaction Methods 0.000 description 4
239000002736 nonionic surfactant Substances 0.000 description 4
QFMDFTQOJHFVNR-UHFFFAOYSA-N 1-[2,2-dichloro-1-(4-ethylphenyl)ethyl]-4-ethylbenzene Chemical compound C1=CC(CC)=CC=C1C(C(Cl)Cl)C1=CC=C(CC)C=C1 QFMDFTQOJHFVNR-UHFFFAOYSA-N 0.000 description 3
ZACVGCNKGYYQHA-UHFFFAOYSA-N 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate Chemical compound CCCCC(CC)COC(=O)OOC(=O)OCC(CC)CCCC ZACVGCNKGYYQHA-UHFFFAOYSA-N 0.000 description 3
239000004743 Polypropylene Substances 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
150000001991 dicarboxylic acids Chemical class 0.000 description 3
238000009826 distribution Methods 0.000 description 3
239000003999 initiator Substances 0.000 description 3
239000002245 particle Substances 0.000 description 3
229920001155 polypropylene Polymers 0.000 description 3
WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 3
HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 2
ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical class CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
RAWISQFSQWIXCW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethyloctaneperoxoate Chemical compound CCCCCCC(C)(C)C(=O)OOC(C)(C)CC RAWISQFSQWIXCW-UHFFFAOYSA-N 0.000 description 2
AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 description 2
SGVYKUFIHHTIFL-UHFFFAOYSA-N 2-methylnonane Chemical compound CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 2
RPBWMJBZQXCSFW-UHFFFAOYSA-N 2-methylpropanoyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(=O)C(C)C RPBWMJBZQXCSFW-UHFFFAOYSA-N 0.000 description 2
NUIZZJWNNGJSGL-UHFFFAOYSA-N 2-phenylpropan-2-yl 2,2-dimethyloctaneperoxoate Chemical compound CCCCCCC(C)(C)C(=O)OOC(C)(C)c1ccccc1 NUIZZJWNNGJSGL-UHFFFAOYSA-N 0.000 description 2
AVXWWBFBRTXBRM-UHFFFAOYSA-N 3-bromopyridine-4-carboxylic acid Chemical compound OC(=O)C1=CC=NC=C1Br AVXWWBFBRTXBRM-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
JUIBLDFFVYKUAC-UHFFFAOYSA-N [5-(2-ethylhexanoylperoxy)-2,5-dimethylhexan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C(CC)CCCC JUIBLDFFVYKUAC-UHFFFAOYSA-N 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
239000012986 chain transfer agent Substances 0.000 description 2
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
238000010790 dilution Methods 0.000 description 2
239000012895 dilution Substances 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical class CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
150000004965 peroxy acids Chemical class 0.000 description 2
238000005191 phase separation Methods 0.000 description 2
239000008363 phosphate buffer Substances 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000000725 suspension Substances 0.000 description 2
KXYJPVZMZBJJBZ-UHFFFAOYSA-N tert-butyl 2-ethylbutaneperoxoate Chemical compound CCC(CC)C(=O)OOC(C)(C)C KXYJPVZMZBJJBZ-UHFFFAOYSA-N 0.000 description 2
PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 2
238000012360 testing method Methods 0.000 description 2
KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
150000000218 1-tetradecanols Chemical class 0.000 description 1
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
FIYMNUNPPYABMU-UHFFFAOYSA-N 2-benzyl-5-chloro-1h-indole Chemical compound C=1C2=CC(Cl)=CC=C2NC=1CC1=CC=CC=C1 FIYMNUNPPYABMU-UHFFFAOYSA-N 0.000 description 1
WECIKJKLCDCIMY-UHFFFAOYSA-N 2-chloro-n-(2-cyanoethyl)acetamide Chemical compound ClCC(=O)NCCC#N WECIKJKLCDCIMY-UHFFFAOYSA-N 0.000 description 1
AEPWOCLBLLCOGZ-UHFFFAOYSA-N 2-cyanoethyl prop-2-enoate Chemical compound C=CC(=O)OCCC#N AEPWOCLBLLCOGZ-UHFFFAOYSA-N 0.000 description 1
WDIXVQTZULGQNI-UHFFFAOYSA-N 2-ethyl-2-(2-methylbutan-2-ylperoxy)hexanoic acid Chemical compound CCCCC(CC)(C(O)=O)OOC(C)(C)CC WDIXVQTZULGQNI-UHFFFAOYSA-N 0.000 description 1
OCRKPZNWPPYOSD-UHFFFAOYSA-N 2-ethyl-2-(4-hydroxy-2-methylpentyl)peroxyhexanoic acid Chemical compound CCCCC(CC)(C(O)=O)OOCC(C)CC(C)O OCRKPZNWPPYOSD-UHFFFAOYSA-N 0.000 description 1
HTCRKQHJUYBQTK-UHFFFAOYSA-N 2-ethylhexyl 2-methylbutan-2-yloxy carbonate Chemical compound CCCCC(CC)COC(=O)OOC(C)(C)CC HTCRKQHJUYBQTK-UHFFFAOYSA-N 0.000 description 1
WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
IFXDUNDBQDXPQZ-UHFFFAOYSA-N 2-methylbutan-2-yl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)CC IFXDUNDBQDXPQZ-UHFFFAOYSA-N 0.000 description 1
XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical class CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
241000251468 Actinopterygii Species 0.000 description 1
BGNPWOBJYXRDIZ-UHFFFAOYSA-N C(CCCCCC(C)(C)C)(=O)OOCC(CCCC)CC Chemical compound C(CCCCCC(C)(C)C)(=O)OOCC(CCCC)CC BGNPWOBJYXRDIZ-UHFFFAOYSA-N 0.000 description 1
XLKNLTBGXDXASO-UHFFFAOYSA-N CC(CC(C)O)COOC(C)(C)OC(=O)O Chemical compound CC(CC(C)O)COOC(C)(C)OC(=O)O XLKNLTBGXDXASO-UHFFFAOYSA-N 0.000 description 1
IPQRSDVFKPZICL-UHFFFAOYSA-N CC(CC1=CC=CC=C1C(=O)OO)CC(C)O Chemical compound CC(CC1=CC=CC=C1C(=O)OO)CC(C)O IPQRSDVFKPZICL-UHFFFAOYSA-N 0.000 description 1
ZSPRXICRVVBGRT-UHFFFAOYSA-N CC(O)CC(C)CC(C(=O)OO)CCCCC(C)(C)C Chemical compound CC(O)CC(C)CC(C(=O)OO)CCCCC(C)(C)C ZSPRXICRVVBGRT-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
235000021314 Palmitic acid Nutrition 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
IQARRNIZJJVLPF-UHFFFAOYSA-N [2-(2,2-dimethylpropanoylperoxy)-4-methylpentan-2-yl] 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)C(=O)OOC(C)(CC(C)C)OOC(=O)C(C)(C)C IQARRNIZJJVLPF-UHFFFAOYSA-N 0.000 description 1
JHJSICJSIOGNMW-UHFFFAOYSA-N [2-(2,2-dimethylpropanoylperoxy)-4-methylpentan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(CC(C)C)OOC(=O)C(C)(C)C JHJSICJSIOGNMW-UHFFFAOYSA-N 0.000 description 1
KJOAQLRBQUDXQG-UHFFFAOYSA-N [2-(2-ethylhexanoylperoxy)-4-methylpentan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(CC(C)C)OOC(=O)C(CC)CCCC KJOAQLRBQUDXQG-UHFFFAOYSA-N 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
239000003139 biocide Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
PRUGMAWKMXYGFZ-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyl carbonate Chemical compound CCC(C)OC(=O)OC(=O)OC(C)CC PRUGMAWKMXYGFZ-UHFFFAOYSA-N 0.000 description 1
NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 1
ZGPBOPXFOJBLIV-UHFFFAOYSA-N butoxycarbonyloxy butyl carbonate Chemical compound CCCCOC(=O)OOC(=O)OCCCC ZGPBOPXFOJBLIV-UHFFFAOYSA-N 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
210000004534 cecum Anatomy 0.000 description 1
229960000541 cetyl alcohol Drugs 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
238000003776 cleavage reaction Methods 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
QZHHCYAWCUAHGY-UHFFFAOYSA-N ethanol methanol Chemical compound CO.CO.CCO.CCO QZHHCYAWCUAHGY-UHFFFAOYSA-N 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000000417 fungicide Substances 0.000 description 1
125000005456 glyceride group Chemical group 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
231100001261 hazardous Toxicity 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
125000005397 methacrylic acid ester group Chemical group 0.000 description 1
SYBYTAAJFKOIEJ-UHFFFAOYSA-N methyl iso-propyl ketone Natural products CC(C)C(C)=O SYBYTAAJFKOIEJ-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
229940065472 octyl acrylate Drugs 0.000 description 1
ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
229940055577 oleyl alcohol Drugs 0.000 description 1
XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
XWYPMOYTTQTLRE-UHFFFAOYSA-N pentyl benzenecarboperoxoate Chemical compound CCCCCOOC(=O)C1=CC=CC=C1 XWYPMOYTTQTLRE-UHFFFAOYSA-N 0.000 description 1
150000002976 peresters Chemical class 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
239000003760 tallow Substances 0.000 description 1
NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000012546 transfer Methods 0.000 description 1
229920006337 unsaturated polyester resin Polymers 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Polymerisation Methods In General (AREA)
Compositions Of Macromolecular Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

SK977-2001A 1999-01-12 2000-01-06 Aqueous peroxide emulsions, use thereof and polyvinylchloride SK9772001A3 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP99200066		1999-01-12
PCT/EP2000/000003 WO2000042078A1 (en)	1999-01-12	2000-01-06	Aqueous peroxide emulsions

Publications (1)

Publication Number	Publication Date
SK9772001A3 true SK9772001A3 (en)	2001-12-03

Family

ID=8239797

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK977-2001A SK9772001A3 (en)	1999-01-12	2000-01-06	Aqueous peroxide emulsions, use thereof and polyvinylchloride

Country Status (23)

Country	Link
EP (1)	EP1144461B1 (de)
JP (1)	JP2002534567A (de)
KR (1)	KR100560897B1 (de)
CN (1)	CN1137141C (de)
AT (1)	ATE263191T1 (de)
AU (1)	AU762463B2 (de)
BR (1)	BR0007450A (de)
CA (1)	CA2359065A1 (de)
CZ (1)	CZ20012543A3 (de)
DE (1)	DE60009448T2 (de)
ES (1)	ES2216860T3 (de)
HU (1)	HUP0105010A3 (de)
IL (1)	IL144233A0 (de)
MY (1)	MY119955A (de)
NO (1)	NO20013445L (de)
PL (1)	PL348906A1 (de)
PT (1)	PT1144461E (de)
RU (1)	RU2232776C2 (de)
SK (1)	SK9772001A3 (de)
TR (1)	TR200101999T2 (de)
UA (1)	UA69434C2 (de)
WO (1)	WO2000042078A1 (de)
ZA (1)	ZA200105703B (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2851245B1 (fr) *	2003-02-14	2007-03-23		Emulsion non gelee d'hydroxyperoxyester
FR2995905B1 (fr) *	2012-09-21	2015-10-16	Arkema France	Composition de peroxyde organique sans agent colloide
FR3027236B1 (fr) *	2014-10-17	2020-01-03	Arkema France	Emulsion aqueuse de peroxyde de dialkyle
EP3056531B1 (de)	2015-02-10	2020-12-16	Lummus Novolen Technology Gmbh	Verfahren zur Modifikation der Rheologie von Polymeren
KR102120091B1 (ko)	2016-03-18	2020-06-09	누리온 케미칼즈 인터내셔널 비.브이.	저장 안정한 수성 유기 퍼옥사이드 에멀젼
DE102019110214A1 (de) *	2019-04-17	2020-10-22	Pergan Hilfsstoffe für industrielle Prozesse GmbH	Organische Peroxidemulsion, Verfahren zu deren Herstellung und deren Verwendung
US20230167054A1 (en) *	2020-05-20	2023-06-01	Arkema France	Di-sec-butyl peroxydicarbonate emulsion
MX2022014081A (es)	2020-05-20	2022-12-07	Arkema France	Emulsion de peroxido organico con etanol.
EP4541788A1 (de) *	2023-10-20	2025-04-23	Nouryon Chemicals International B.V.	Kontinuierliche herstellung von wässrigen emulsionen organischer peroxide

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4530913A (en) *	1980-01-16	1985-07-23	Chemplex Company	Polymerization catalyst and method
SE435843B (sv) *	1980-01-28	1984-10-22	Kenogard Ab	Sett vid polymerisation av vinylklorid och vattendispersion for anvendning vid polymerisation av vinylklorid
DE3136931A1 (de) *	1981-09-17	1983-04-07	Akzo Gmbh, 5600 Wuppertal	Copolymere aus (alpha)-(beta)-ungesaettigten dicarbonsaeureestern, verfahren zu deren herstellung sowie deren verwendung als gleitmittel fuer die kunststoffverarbeitung
EP0492712A1 (de) *	1990-12-24	1992-07-01	Akzo Nobel N.V.	Peroxyd-Zusammensetzungen mit ethoxylierten wasserlöslichen Polymeren
SE9101674L (sv) *	1991-05-31	1992-12-01	Berol Nobel Ab	Dispersion
CA2270229A1 (en) *	1996-10-30	1998-05-07	Akzo Nobel Nv	Process to make initiator compositions comprising polyvinyl alcohol and surfactant

2000
- 2000-01-06 TR TR2001/01999T patent/TR200101999T2/xx unknown
- 2000-01-06 PL PL00348906A patent/PL348906A1/xx not_active Application Discontinuation
- 2000-01-06 WO PCT/EP2000/000003 patent/WO2000042078A1/en not_active Ceased
- 2000-01-06 CA CA002359065A patent/CA2359065A1/en not_active Abandoned
- 2000-01-06 DE DE60009448T patent/DE60009448T2/de not_active Expired - Fee Related
- 2000-01-06 AU AU26617/00A patent/AU762463B2/en not_active Ceased
- 2000-01-06 PT PT00904870T patent/PT1144461E/pt unknown
- 2000-01-06 BR BR0007450-0A patent/BR0007450A/pt active Search and Examination
- 2000-01-06 ES ES00904870T patent/ES2216860T3/es not_active Expired - Lifetime
- 2000-01-06 KR KR1020017008701A patent/KR100560897B1/ko not_active Expired - Fee Related
- 2000-01-06 HU HU0105010A patent/HUP0105010A3/hu unknown
- 2000-01-06 EP EP00904870A patent/EP1144461B1/de not_active Expired - Lifetime
- 2000-01-06 CN CNB008025878A patent/CN1137141C/zh not_active Expired - Fee Related
- 2000-01-06 AT AT00904870T patent/ATE263191T1/de not_active IP Right Cessation
- 2000-01-06 SK SK977-2001A patent/SK9772001A3/sk unknown
- 2000-01-06 JP JP2000593644A patent/JP2002534567A/ja active Pending
- 2000-01-06 RU RU2001122594/04A patent/RU2232776C2/ru not_active IP Right Cessation
- 2000-01-06 IL IL14423300A patent/IL144233A0/xx unknown
- 2000-01-06 CZ CZ20012543A patent/CZ20012543A3/cs unknown
- 2000-01-11 MY MYPI20000076A patent/MY119955A/en unknown
- 2000-06-01 UA UA2001085699A patent/UA69434C2/uk unknown
2001
- 2001-07-11 NO NO20013445A patent/NO20013445L/no not_active Application Discontinuation
- 2001-07-11 ZA ZA200105703A patent/ZA200105703B/en unknown

Also Published As

Publication number	Publication date
CN1137141C (zh)	2004-02-04
CN1335859A (zh)	2002-02-13
CZ20012543A3 (cs)	2001-10-17
NO20013445L (no)	2001-09-11
NO20013445D0 (no)	2001-07-11
IL144233A0 (en)	2002-05-23
AU2661700A (en)	2000-08-01
ZA200105703B (en)	2002-10-11
RU2232776C2 (ru)	2004-07-20
BR0007450A (pt)	2001-10-16
KR100560897B1 (ko)	2006-03-13
UA69434C2 (uk)	2004-09-15
ES2216860T3 (es)	2004-11-01
AU762463B2 (en)	2003-06-26
MY119955A (en)	2005-08-30
KR20010089802A (ko)	2001-10-08
CA2359065A1 (en)	2000-07-20
HUP0105010A3 (en)	2003-08-28
HUP0105010A2 (hu)	2002-04-29
DE60009448D1 (de)	2004-05-06
EP1144461A1 (de)	2001-10-17
TR200101999T2 (tr)	2001-11-21
PT1144461E (pt)	2004-08-31
WO2000042078A1 (en)	2000-07-20
DE60009448T2 (de)	2005-01-20
ATE263191T1 (de)	2004-04-15
PL348906A1 (en)	2002-06-17
EP1144461B1 (de)	2004-03-31
JP2002534567A (ja)	2002-10-15

Publication	Publication Date	Title
KR100984714B1 (ko)	2010-10-01	낮은 화학적 산소 요구량 값을 가지며 안정하고 안전한 고농도의 디아실 퍼옥시드와 퍼옥시디카르보네이트 유탁액
SK9772001A3 (en)	2001-12-03	Aqueous peroxide emulsions, use thereof and polyvinylchloride
US6350835B1 (en)	2002-02-26	Emulsions of peroxyesters
KR100501969B1 (ko)	2005-07-20	폴리비닐알콜 및 계면활성제로 구성된 개시제 조성물의 제조방법
JPH0588252B2 (de)	1993-12-21
MXPA01007075A (en)	2002-03-05	Aqueous peroxide emulsions
EP4545573A1 (de)	2025-04-30	Wässrige organische peroxidemulsionen
JPH0565524B2 (de)	1993-09-17