SU452101A3 - Способ получени полимеров и сополимеров ненасыщенных соединений - Google Patents

Способ получени полимеров и сополимеров ненасыщенных соединений

Info

Publication number: SU452101A3
Authority: SU; USSR - Soviet Union
Prior art keywords: copolymers; polymerization; unsaturated compounds; tert; polymers
Prior art date: 1970-12-31

Application number

SU1732501A

Other languages

English (en)

Russian (ru)

Inventor

Жак Дезиллес

Original Assignee

Акитэн Тоталь-Органико (Фирма)

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1970-12-31

Filing date

1971-12-31

Publication date

1974-11-30

1971-12-31 Application filed by Акитэн Тоталь-Органико (Фирма) filed Critical Акитэн Тоталь-Органико (Фирма)

1974-11-30 Application granted granted Critical

1974-11-30 Publication of SU452101A3 publication Critical patent/SU452101A3/ru

Links

238000000034 method Methods 0.000 title description 10
229920000642 polymer Polymers 0.000 title description 8
150000001875 compounds Chemical class 0.000 title description 5
229920001577 copolymer Polymers 0.000 title description 5
238000006116 polymerization reaction Methods 0.000 description 10
239000000178 monomer Substances 0.000 description 8
-1 chlorides Chemical class 0.000 description 7
239000000203 mixture Substances 0.000 description 7
239000003999 initiator Substances 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
239000000725 suspension Substances 0.000 description 6
239000002244 precipitate Substances 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
239000000375 suspending agent Substances 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
229910019142 PO4 Inorganic materials 0.000 description 4
235000021317 phosphate Nutrition 0.000 description 4
239000004094 surface-active agent Substances 0.000 description 4
239000008346 aqueous phase Substances 0.000 description 3
239000007900 aqueous suspension Substances 0.000 description 3
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
239000001110 calcium chloride Substances 0.000 description 2
229910001628 calcium chloride Inorganic materials 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
230000007423 decrease Effects 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910001629 magnesium chloride Inorganic materials 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
230000001376 precipitating effect Effects 0.000 description 2
239000001488 sodium phosphate Substances 0.000 description 2
229910000162 sodium phosphate Inorganic materials 0.000 description 2
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
JMYZLRSSLFFUQN-UHFFFAOYSA-N (2-chlorobenzoyl) 2-chlorobenzenecarboperoxoate Chemical compound ClC1=CC=CC=C1C(=O)OOC(=O)C1=CC=CC=C1Cl JMYZLRSSLFFUQN-UHFFFAOYSA-N 0.000 description 1
IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
229920000459 Nitrile rubber Polymers 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
239000013543 active substance Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
239000001506 calcium phosphate Substances 0.000 description 1
229910000389 calcium phosphate Inorganic materials 0.000 description 1
235000011010 calcium phosphates Nutrition 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
229920005556 chlorobutyl Polymers 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910021432 inorganic complex Inorganic materials 0.000 description 1
239000000787 lecithin Substances 0.000 description 1
229940067606 lecithin Drugs 0.000 description 1
235000010445 lecithin Nutrition 0.000 description 1
229910001463 metal phosphate Inorganic materials 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
239000012074 organic phase Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
239000012071 phase Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000001294 propane Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
239000013049 sediment Substances 0.000 description 1
229960005480 sodium caprylate Drugs 0.000 description 1
UDWXLZLRRVQONG-UHFFFAOYSA-M sodium hexanoate Chemical compound [Na+].CCCCCC([O-])=O UDWXLZLRRVQONG-UHFFFAOYSA-M 0.000 description 1
BYKRNSHANADUFY-UHFFFAOYSA-M sodium octanoate Chemical compound [Na+].CCCCCCCC([O-])=O BYKRNSHANADUFY-UHFFFAOYSA-M 0.000 description 1
FVEFRICMTUKAML-UHFFFAOYSA-M sodium tetradecyl sulfate Chemical compound [Na+].CCCCC(CC)CCC(CC(C)C)OS([O-])(=O)=O FVEFRICMTUKAML-UHFFFAOYSA-M 0.000 description 1
HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
WFRKJMRGXGWHBM-UHFFFAOYSA-M sodium;octyl sulfate Chemical compound [Na+].CCCCCCCCOS([O-])(=O)=O WFRKJMRGXGWHBM-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)

SU1732501A 1970-12-31 1971-12-31 Способ получени полимеров и сополимеров ненасыщенных соединений SU452101A3 (ru)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR7047503A FR2123578A5 (2)	1970-12-31	1970-12-31

Publications (1)

Publication Number	Publication Date
SU452101A3 true SU452101A3 (ru)	1974-11-30

Family

ID=9066673

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU1732501A SU452101A3 (ru)	1970-12-31	1971-12-31	Способ получени полимеров и сополимеров ненасыщенных соединений

Country Status (12)

Country	Link
BE (1)	BE777579A (2)
CA (1)	CA965200A (2)
DE (1)	DE2165368A1 (2)
DK (1)	DK136077B (2)
ES (1)	ES398439A1 (2)
FI (1)	FI54319C (2)
FR (1)	FR2123578A5 (2)
GB (1)	GB1334193A (2)
IT (1)	IT944619B (2)
LU (1)	LU64523A1 (2)
NL (1)	NL7118192A (2)
SU (1)	SU452101A3 (2)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2912571A1 (de) *	1979-03-29	1980-10-09	Basf Ag	Verfahren zur polymerisation von vinylchlorid

1970
- 1970-12-31 FR FR7047503A patent/FR2123578A5/fr not_active Expired
1971
- 1971-12-28 LU LU64523D patent/LU64523A1/xx unknown
- 1971-12-29 ES ES398439A patent/ES398439A1/es not_active Expired
- 1971-12-29 FI FI373171A patent/FI54319C/fi active
- 1971-12-29 DE DE19712165368 patent/DE2165368A1/de active Pending
- 1971-12-29 DK DK641771A patent/DK136077B/da unknown
- 1971-12-30 BE BE777579A patent/BE777579A/xx unknown
- 1971-12-31 SU SU1732501A patent/SU452101A3/ru active
- 1971-12-31 IT IT3318771A patent/IT944619B/it active
- 1971-12-31 NL NL7118192A patent/NL7118192A/xx unknown
- 1971-12-31 CA CA131,539A patent/CA965200A/en not_active Expired
- 1971-12-31 GB GB6094871A patent/GB1334193A/en not_active Expired

Also Published As

Publication number	Publication date
BE777579A (fr)	1972-04-17
ES398439A1 (es)	1974-10-01
CA965200A (en)	1975-03-25
IT944619B (it)	1973-04-20
LU64523A1 (2)	1972-06-20
DE2165368A1 (de)	1972-07-27
DK136077B (da)	1977-08-08
DK136077C (2)	1978-01-09
GB1334193A (en)	1973-10-17
FI54319C (fi)	1978-11-10
FR2123578A5 (2)	1972-09-15
FI54319B (fi)	1978-07-31
NL7118192A (2)	1972-07-04

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US4839417A (en)	1989-06-13	Method for making odorless aqueous solutions of water soluble polymers or copolymers
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US3509114A (en)	1970-04-28	Process for polymerization of water-soluble acrylic monomers
US3249595A (en)	1966-05-03	Aqueous emulsion polymerization process employing water-soluble peroxides
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US3442880A (en)	1969-05-06	Suspension polymerization process wherein a soluble hydrocarbon phosphate is used with a difficultly soluble phosphate
US3681310A (en)	1972-08-01	Process for suspension polymerization of vinyl-type monomers
US3222340A (en)	1965-12-07	Process for preparing bead polymers in aqueous medium containing calcium phosphate and an amino polyacetic acid compound
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