SU743576A3 - Способ получени 1,2-дихлорэтана - Google Patents

Способ получени 1,2-дихлорэтана Download PDF

Info

Publication number: SU743576A3
Authority: SU; USSR - Soviet Union
Prior art keywords: catalyst; chloride; potassium chloride; zone; copper chloride
Prior art date: 1975-07-14

Application number

SU762378586A

Other languages

English (en)

Russian (ru)

Inventor

Гордон Кэмпбелл Рамсей

Портер Доан Эллиот

Генри Хейнес Майер

Джон Вогт Гарви

Сильвестр Наворски Джозеф

Original Assignee

Стауффер Кемикал Компани (Фирма)

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-07-14

Filing date

1976-07-13

Publication date

1980-06-25

1976-07-13 Application filed by Стауффер Кемикал Компани (Фирма) filed Critical Стауффер Кемикал Компани (Фирма)

1980-06-25 Application granted granted Critical

1980-06-25 Publication of SU743576A3 publication Critical patent/SU743576A3/ru

Links

238000000034 method Methods 0.000 title claims description 28
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 title claims description 10
239000003054 catalyst Substances 0.000 claims abstract description 60
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 50
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims abstract description 27
239000001103 potassium chloride Substances 0.000 claims abstract description 25
235000011164 potassium chloride Nutrition 0.000 claims abstract description 25
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 14
239000005977 Ethylene Substances 0.000 claims abstract description 14
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 4
238000006243 chemical reaction Methods 0.000 claims description 21
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 17
229910000041 hydrogen chloride Inorganic materials 0.000 claims description 17
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 16
239000007789 gas Substances 0.000 claims description 15
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
239000001301 oxygen Substances 0.000 claims description 12
229910052760 oxygen Inorganic materials 0.000 claims description 12
238000002474 experimental method Methods 0.000 claims description 9
238000013021 overheating Methods 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 5
230000000694 effects Effects 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 4
230000003197 catalytic effect Effects 0.000 claims description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
230000033228 biological regulation Effects 0.000 claims description 2
239000000376 reactant Substances 0.000 claims description 2
230000002411 adverse Effects 0.000 claims 1
230000006866 deterioration Effects 0.000 claims 1
238000009434 installation Methods 0.000 claims 1
239000002245 particle Substances 0.000 abstract description 6
229960003280 cupric chloride Drugs 0.000 abstract description 2
239000011148 porous material Substances 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
239000003153 chemical reaction reagent Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
238000011144 upstream manufacturing Methods 0.000 description 3
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
239000008346 aqueous phase Substances 0.000 description 2
229910001882 dioxygen Inorganic materials 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
238000010009 beating Methods 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
230000001186 cumulative effect Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
229960003750 ethyl chloride Drugs 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
230000004807 localization Effects 0.000 description 1
229910000476 molybdenum oxide Inorganic materials 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000012074 organic phase Substances 0.000 description 1
PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000005029 sieve analysis Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
238000004448 titration Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/158—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of halogenated hydrocarbons
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/10—Chlorides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0457—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being placed in separate reactors
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00026—Controlling or regulating the heat exchange system
- B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
- B01J2208/00044—Temperature measurement
- B01J2208/00061—Temperature measurement of the reactants
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

SU762378586A 1975-07-14 1976-07-13 Способ получени 1,2-дихлорэтана SU743576A3 (ru)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US59546575A	1975-07-14	1975-07-14

Publications (1)

Publication Number	Publication Date
SU743576A3 true SU743576A3 (ru)	1980-06-25

Family

ID=24383345

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
SU762378586A SU743576A3 (ru)	1975-07-14	1976-07-13	Способ получени 1,2-дихлорэтана
SU782607604A SU1225473A3 (ru)	1975-07-14	1978-04-27	Катализатор дл оксихлорировани этилена в 1,2-дихлорэтан

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
SU782607604A SU1225473A3 (ru)	1975-07-14	1978-04-27	Катализатор дл оксихлорировани этилена в 1,2-дихлорэтан

Country Status (4)

Country	Link
US (1)	US4123467A (cs)
BE (1)	BE844056A (cs)
CS (1)	CS202554B2 (cs)
SU (2)	SU743576A3 (cs)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1120956A (en) *	1977-09-07	1982-03-30	William Q. Beard, Jr.	Process for the production of perchloroethylene by catalytic oxychlorination
US4849393A (en) *	1986-08-21	1989-07-18	The B.F. Goodrich Company	Catalyst and process for the fluid-bed oxychlorination of ethylene to EDC
US5227548A (en) *	1988-12-20	1993-07-13	Imperial Chemical Industries Plc	Oxychlorination of ethylene to 1,2-dichloroethane
US5202511A (en) *	1989-08-16	1993-04-13	The Dow Chemical Company	Catalyst diluent for oxychlorination process
DE4018512A1 (de) *	1990-06-09	1991-12-12	Wacker Chemie Gmbh	Zylindrisch geformter katalysator und dessen verwendung bei der oxichlorierung von ethylen
GB2294262B (en)	1994-10-20	1998-07-08	Evc Tech Ag	Single stage fixed bed oxychlorination of ethylene
DE69601540T2 (de) *	1995-06-07	1999-10-07	The Dow Chemical Co., Midland	Verfahren zur oxychlorierung
DE10003510A1 (de)	2000-01-27	2001-08-02	Basf Ag	Verfahren zur Herstellung von 1,2-Dichlorethan
US20040151630A1 (en) *	2002-08-26	2004-08-05	Hernandez Herbert A.	Total nitrogen and sulphur analysis using a catalytic combustion gas converter system
CN112358376B (zh) *	2020-11-10	2025-06-17	天津渤化工程有限公司	基于四级反应器的氧氯化反应系统及方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA517009A (en) *		1955-09-27	W. Hearne George	Manufacture of olefin dichlorides
IT713532A (cs) *	1962-02-01
GB1104666A (en) *	1964-05-29	1968-02-28	Stauffer Chemical Co	Oxychlorination of ethylene to ethylenedichloride
DE1668749C3 (de) *	1967-06-23	1974-01-03	Toagosei Chemical Industry Co., Ltd., Tokio	Verfahren zur Herstellung von 1,2-Dichloräthan
US3892816A (en) *	1972-12-19	1975-07-01	Shell Oil Co	Process for oxychlorination of ethylene
DE2356549C2 (de) *	1973-11-13	1975-10-30	Basf Ag, 6700 Ludwigshafen	Verfahren zur Herstellung von 1,2-Dichloräthan durch Oxychlorierung von Xthylen

1976
- 1976-05-14 US US05/686,333 patent/US4123467A/en not_active Expired - Lifetime
- 1976-07-12 BE BE7000846A patent/BE844056A/xx not_active IP Right Cessation
- 1976-07-13 CS CS764636A patent/CS202554B2/cs unknown
- 1976-07-13 SU SU762378586A patent/SU743576A3/ru active
1978
- 1978-04-27 SU SU782607604A patent/SU1225473A3/ru active

Also Published As

Publication number	Publication date
US4123467A (en)	1978-10-31
SU1225473A3 (ru)	1986-04-15
BE844056A (nl)	1977-01-12
CS202554B2 (en)	1981-01-30

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CS202555B2 (cs)	1981-01-30	Katalytická směs pro výrobu chlorovaných uhlovodíků, zejména 1,2-dichlorethanu, oxychlorací ethylenu
DE1468802B2 (de)	1975-03-06	Verfahren zur Oxychlorierung von aliphatischen Kohlenwasserstoffen, die 1 bis 4 Kohlenstoffatome aufweisen, oder ihrer teilweise chlorierten Derivate
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