SU772479A3 - Способ стабилизации перкарбоната натри - Google Patents
Способ стабилизации перкарбоната натри Download PDFInfo
- Publication number
- SU772479A3 SU772479A3 SU782632851A SU2632851A SU772479A3 SU 772479 A3 SU772479 A3 SU 772479A3 SU 782632851 A SU782632851 A SU 782632851A SU 2632851 A SU2632851 A SU 2632851A SU 772479 A3 SU772479 A3 SU 772479A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- sodium percarbonate
- product
- active oxygen
- loss
- stabilizing
- Prior art date
Links
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 title claims abstract description 8
- 229940045872 sodium percarbonate Drugs 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title claims 2
- 230000000087 stabilizing effect Effects 0.000 title claims 2
- 239000002245 particle Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 6
- 239000000377 silicon dioxide Substances 0.000 abstract 3
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 230000007423 decrease Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
- C01B15/10—Peroxyhydrates; Peroxyacids or salts thereof containing carbon
- C01B15/106—Stabilisation of the solid compounds, subsequent to the preparation or to the crystallisation, by additives or by coating
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Glanulating (AREA)
Description
высокодисперсной кремниевой кислоты (средний размер первичных частиц 12 нм), Продукт сушат при 58°С в течение 30 мин в сушильном шкафу.
Полученный продукт имеет сйедующие результаты анализа: активный кислород 13,26, StOg 0,99, COg 26,53, FejO 0,003%, насыпной вес 1,030 кг/л хранении при 30°С, относительнойвлажности 92,9% спуст 4 дн потери активного кислорода составл ют 1,6%, спуст 7 дней - 6,8% и 10 дней8 ,4%.
При использовании перкарбоната натри с содержанием воды меньше 1% потери активного кислорода в течение 10 дней при 30°С и относительной влажности воздуха 92,9% достигают 23,8%, при содержании воды больше 10% потери активного кислорода снижаютс незначительно, но при этом по вл етс слабое комкование продукта. При размере частиц кремниевой кислоты более 100 нм потери активного кислорода возрастают более, чем на 20%,
при размере частиц ниже 2 нм не наблюдаетс снижени потерь.активного кислорода, получение кремниевой кислоты с размером частиц ниже 2 нм затруднительно .
Claims (1)
- Формула изобретениСпособ стабилизации перкарбоната натри путем смешени перкарбоната натри с соединением, содержащим крений ,, с последукнцей сушкой продукта, -отличающийс тем, что, с целью снижени потерь активного кислорода в продукте при его хранении , в качестве соединени , содержащего кремний, используют кремниевую кислоту с размером частиц 2-100 нм и на смешение подают перкарбонат натри с содержанием воды 1-10 вес.%.Источники информации, прин тые во внимание при зкспертизе1, Патент США № 3773678, кл. 252-186, опублик. 1973.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2748783A DE2748783C3 (de) | 1977-10-31 | 1977-10-31 | Verfahren zum Stabilisieren von Natriumpercarbonat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU772479A3 true SU772479A3 (ru) | 1980-10-15 |
Family
ID=6022715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU782632851A SU772479A3 (ru) | 1977-10-31 | 1978-06-27 | Способ стабилизации перкарбоната натри |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US4178351A (ru) |
| JP (1) | JPS5484898A (ru) |
| AT (1) | AT375057B (ru) |
| BE (1) | BE871633A (ru) |
| CA (1) | CA1118295A (ru) |
| CH (1) | CH638463A5 (ru) |
| DD (1) | DD138967A5 (ru) |
| DE (1) | DE2748783C3 (ru) |
| ES (1) | ES471589A1 (ru) |
| FR (1) | FR2407172A1 (ru) |
| GB (1) | GB2006738B (ru) |
| IL (1) | IL54466A (ru) |
| IT (1) | IT1111417B (ru) |
| PL (1) | PL111289B1 (ru) |
| PT (1) | PT68236A (ru) |
| SE (1) | SE435611B (ru) |
| SU (1) | SU772479A3 (ru) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0003248A1 (en) * | 1977-11-09 | 1979-08-08 | Animark Products Limited | Composition and method for bleaching hair or keratinous fibre |
| US4416606A (en) * | 1980-10-22 | 1983-11-22 | Mitsubishi Gas Chemical Company, Inc. | Apparatus for granulating sodium percarbonate |
| US4410444A (en) * | 1981-03-24 | 1983-10-18 | Degussa Aktiengesellschaft | Process for the production of a stable per salt |
| US4867902A (en) * | 1988-03-23 | 1989-09-19 | Z-Gard, Inc. | Microencapsulated oxygen generators |
| WO1991015423A1 (en) * | 1990-04-06 | 1991-10-17 | Fmc Corporation | Peroxygen laundry bleach |
| US5194176A (en) * | 1990-04-06 | 1993-03-16 | Fmc Corporation | Peroxygen laundry bleach |
| US5332518A (en) * | 1992-04-23 | 1994-07-26 | Kao Corporation | Stable slurry-coated sodium percarbonate, process for producing the same and bleach detergent composition containing the same |
| US5328721A (en) * | 1992-07-30 | 1994-07-12 | Fmc Corporation | Process for manufacturing sodium carbonate perhydrate particles and coating them with sodium borosilicate |
| EP0708855A4 (en) * | 1993-07-14 | 1996-07-17 | Procter & Gamble | DETERGENTS CONTAINING PERCARBONATE AND METHOD FOR THE PRODUCTION THEREOF |
| US5780410A (en) * | 1993-07-14 | 1998-07-14 | The Procter & Gamble Company | Detergent compositions containing percarbonate and making processes thereof |
| PL173175B1 (pl) * | 1994-02-25 | 1998-02-27 | Inst Chemii Nieorganicznej | Sposób otrzymywania środka zmiękczająco-wybielającego, stosowanego jako składnik środków piorących, myjących i czyszczących |
| US6017867A (en) * | 1998-06-05 | 2000-01-25 | The Procter & Gamble Company | Detergent compositions containing percarbonate and making processes thereof |
| DE19830946A1 (de) * | 1998-07-10 | 2000-01-13 | Degussa | Verfahren zur Herstellung von beschichteten Persauerstoffverbindungen |
| US20050031530A1 (en) * | 2003-08-07 | 2005-02-10 | Martin Perry L. | Method and apparatus for producing a peroxyacid solution |
| RU2253610C1 (ru) * | 2004-01-20 | 2005-06-10 | Гайтанов Юрий Яковлевич | Способ стабилизации пероксосолей щелочных металлов и устройство для осуществления способа |
| US20060013750A1 (en) * | 2004-07-16 | 2006-01-19 | Martin Perry L | Solvent-activated reactor |
| US20060014872A1 (en) * | 2004-07-16 | 2006-01-19 | Martin Roy W | Protective composition that allows in-situ generation of permeation channels therein |
| US8758631B2 (en) | 2010-05-18 | 2014-06-24 | United Laboratories International, Llc | Process for decontamination of hazardous sulfur compounds in sour water tanks |
| EP3954743A1 (de) | 2020-08-12 | 2022-02-16 | Evonik Operations GmbH | Verwendung von siliziumdioxid zur verbesserung der leitfähigkeit von beschichtungen |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB174891A (en) * | 1920-07-26 | 1922-01-26 | Adolf Welter | Process for producing finely granulated compounds |
| DE870092C (de) * | 1944-06-22 | 1953-03-09 | Degussa | Verfahren zum Stabilisieren von Percarbonaten |
| BE492338A (ru) * | 1948-11-23 | |||
| US3640885A (en) * | 1968-09-24 | 1972-02-08 | Ken Mcgee Chemical Corp | Dry free flowing peroxygen composition with an organic acid anhydride and alkali metal hydrate |
| BE791037A (fr) * | 1971-11-09 | 1973-05-07 | Fmc Corp | Procede pour agglomerer le peroxohydrate de carbonate de sodium |
| US3951838A (en) * | 1973-10-10 | 1976-04-20 | E. I. Du Pont De Nemours And Company | Silica sol stabilizers for improving the stability of sodium percarbonate in solid bleaches and detergents |
-
1977
- 1977-10-31 DE DE2748783A patent/DE2748783C3/de not_active Expired
-
1978
- 1978-04-07 IL IL54466A patent/IL54466A/xx unknown
- 1978-06-27 SU SU782632851A patent/SU772479A3/ru active
- 1978-06-28 PT PT68236A patent/PT68236A/pt unknown
- 1978-06-29 IT IT68531/78A patent/IT1111417B/it active
- 1978-07-10 ES ES471589A patent/ES471589A1/es not_active Expired
- 1978-07-17 CA CA000307560A patent/CA1118295A/en not_active Expired
- 1978-07-27 FR FR7822302A patent/FR2407172A1/fr active Granted
- 1978-09-25 DD DD78208063A patent/DD138967A5/xx unknown
- 1978-10-13 GB GB7840485A patent/GB2006738B/en not_active Expired
- 1978-10-16 US US05/951,461 patent/US4178351A/en not_active Expired - Lifetime
- 1978-10-26 PL PL1978210519A patent/PL111289B1/pl unknown
- 1978-10-27 BE BE6046653A patent/BE871633A/xx not_active IP Right Cessation
- 1978-10-30 CH CH1118378A patent/CH638463A5/de not_active IP Right Cessation
- 1978-10-30 SE SE7811246A patent/SE435611B/sv not_active IP Right Cessation
- 1978-10-30 AT AT0774578A patent/AT375057B/de not_active IP Right Cessation
- 1978-10-31 JP JP13334878A patent/JPS5484898A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| CH638463A5 (de) | 1983-09-30 |
| PL111289B1 (en) | 1980-08-30 |
| AT375057B (de) | 1984-06-25 |
| DE2748783C3 (de) | 1985-07-11 |
| DD138967A5 (de) | 1979-12-05 |
| FR2407172A1 (fr) | 1979-05-25 |
| DE2748783A1 (de) | 1979-05-03 |
| ES471589A1 (es) | 1979-02-01 |
| BE871633A (fr) | 1979-04-27 |
| DE2748783B2 (de) | 1979-08-30 |
| ATA774578A (de) | 1983-11-15 |
| PT68236A (de) | 1978-07-01 |
| SE435611B (sv) | 1984-10-08 |
| IT7868531A0 (it) | 1978-06-29 |
| GB2006738A (en) | 1979-05-10 |
| IT1111417B (it) | 1986-01-13 |
| FR2407172B1 (ru) | 1983-03-18 |
| GB2006738B (en) | 1982-03-31 |
| PL210519A1 (pl) | 1979-07-02 |
| SE7811246L (sv) | 1979-05-01 |
| JPS5732001B2 (ru) | 1982-07-08 |
| US4178351A (en) | 1979-12-11 |
| JPS5484898A (en) | 1979-07-06 |
| IL54466A0 (en) | 1978-07-31 |
| CA1118295A (en) | 1982-02-16 |
| IL54466A (en) | 1981-07-31 |
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