SU799672A3 - Способ получени винилгалоид-НыХ пОлиМЕРОВ - Google Patents

Способ получени винилгалоид-НыХ пОлиМЕРОВ Download PDF

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Publication number: SU799672A3
Authority: SU; USSR - Soviet Union
Prior art keywords: monomer; polymer; polymerization; vinyl; reaction
Prior art date: 1976-11-30

Application number

SU772444853A

Other languages

English (en)

Russian (ru)

Inventor

Е.Уолкер Лейг

Original Assignee

Хукер Кемикалз Энд Пластикс Корп., (Фирма)

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-11-30

Filing date

1977-01-26

Publication date

1981-01-23

1976-11-30 Priority claimed from US05/746,048 external-priority patent/US4067928A/en

1977-01-26 Application filed by Хукер Кемикалз Энд Пластикс Корп., (Фирма) filed Critical Хукер Кемикалз Энд Пластикс Корп., (Фирма)

1981-01-23 Application granted granted Critical

1981-01-23 Publication of SU799672A3 publication Critical patent/SU799672A3/ru

Links

-1 vinyl halide Chemical class 0.000 title claims abstract description 82
229920000642 polymer Polymers 0.000 title claims abstract description 80
229920002554 vinyl polymer Polymers 0.000 title claims abstract description 64
238000000034 method Methods 0.000 title claims description 42
238000006243 chemical reaction Methods 0.000 claims abstract description 84
239000000178 monomer Substances 0.000 claims abstract description 82
238000006116 polymerization reaction Methods 0.000 claims abstract description 64
229920000098 polyolefin Polymers 0.000 claims abstract description 56
239000000203 mixture Substances 0.000 claims abstract description 15
230000008569 process Effects 0.000 claims description 19
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
239000005977 Ethylene Substances 0.000 claims description 10
239000000843 powder Substances 0.000 claims description 7
238000010526 radical polymerization reaction Methods 0.000 claims description 3
238000004519 manufacturing process Methods 0.000 claims 1
239000002245 particle Substances 0.000 abstract description 36
238000012545 processing Methods 0.000 abstract description 10
238000002844 melting Methods 0.000 abstract description 8
230000008018 melting Effects 0.000 abstract description 8
238000010438 heat treatment Methods 0.000 abstract description 4
238000012662 bulk polymerization Methods 0.000 abstract 1
238000002485 combustion reaction Methods 0.000 abstract 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 56
239000000047 product Substances 0.000 description 54
229920001577 copolymer Polymers 0.000 description 20
230000015572 biosynthetic process Effects 0.000 description 17
239000011541 reaction mixture Substances 0.000 description 17
239000003999 initiator Substances 0.000 description 14
238000003756 stirring Methods 0.000 description 12
229920000578 graft copolymer Polymers 0.000 description 11
239000012467 final product Substances 0.000 description 10
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 10
238000011068 loading method Methods 0.000 description 9
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 7
229920001519 homopolymer Polymers 0.000 description 7
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
230000007423 decrease Effects 0.000 description 6
238000005530 etching Methods 0.000 description 6
150000001993 dienes Chemical class 0.000 description 5
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
238000002156 mixing Methods 0.000 description 5
229920001897 terpolymer Polymers 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
229920001651 Cyanoacrylate Polymers 0.000 description 4
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
230000008901 benefit Effects 0.000 description 4
230000000740 bleeding effect Effects 0.000 description 4
230000008859 change Effects 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
229920001112 grafted polyolefin Polymers 0.000 description 4
239000008187 granular material Substances 0.000 description 4
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000003153 chemical reaction reagent Substances 0.000 description 3
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238000004090 dissolution Methods 0.000 description 3
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239000000126 substance Substances 0.000 description 3
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LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 2
YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
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239000002253 acid Substances 0.000 description 2
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SJNALLRHIVGIBI-UHFFFAOYSA-N allyl cyanide Chemical compound C=CCC#N SJNALLRHIVGIBI-UHFFFAOYSA-N 0.000 description 2
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229910052799 carbon Inorganic materials 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000012954 diazonium Substances 0.000 description 2
239000011521 glass Substances 0.000 description 2
KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 2
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ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
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YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
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239000004800 polyvinyl chloride Substances 0.000 description 2
229920001291 polyvinyl halide Polymers 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
239000012429 reaction media Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
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WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 1
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AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
LIFLRQVHKGGNSG-UHFFFAOYSA-N 2,3-dichlorobuta-1,3-diene Chemical compound ClC(=C)C(Cl)=C LIFLRQVHKGGNSG-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
VXVUDUCBEZFQGY-UHFFFAOYSA-N 4,4-dimethylpentanenitrile Chemical compound CC(C)(C)CCC#N VXVUDUCBEZFQGY-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
ZMFWTUBNIJBJDB-UHFFFAOYSA-N 6-hydroxy-2-methylquinoline-4-carboxylic acid Chemical compound C1=C(O)C=CC2=NC(C)=CC(C(O)=O)=C21 ZMFWTUBNIJBJDB-UHFFFAOYSA-N 0.000 description 1
VNPRJHMMOKDEDZ-UHFFFAOYSA-L 6-methylheptyl 2-[dibutyl-[2-(6-methylheptoxy)-2-oxoethyl]sulfanylstannyl]sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](CCCC)(CCCC)SCC(=O)OCCCCCC(C)C VNPRJHMMOKDEDZ-UHFFFAOYSA-L 0.000 description 1
RZBBHEJLECUBJT-UHFFFAOYSA-N 6-methylheptyl 2-sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS RZBBHEJLECUBJT-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
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OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
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241000132179 Eurotium medium Species 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
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101150046432 Tril gene Proteins 0.000 description 1
239000012963 UV stabilizer Substances 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000005250 alkyl acrylate group Chemical group 0.000 description 1
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239000003963 antioxidant agent Substances 0.000 description 1
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125000004429 atom Chemical group 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
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125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
FPXFMRRAVFDHMN-UHFFFAOYSA-N carboxy hydrogen carbonate;cyclohexylperoxycyclohexane Chemical compound OC(=O)OC(O)=O.C1CCCCC1OOC1CCCCC1 FPXFMRRAVFDHMN-UHFFFAOYSA-N 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
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125000004122 cyclic group Chemical group 0.000 description 1
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MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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150000004820 halides Chemical class 0.000 description 1
239000012760 heat stabilizer Substances 0.000 description 1
239000008236 heating water Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
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239000012535 impurity Substances 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
GHXZPUGJZVBLGC-UHFFFAOYSA-N iodoethene Chemical compound IC=C GHXZPUGJZVBLGC-UHFFFAOYSA-N 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
239000004611 light stabiliser Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000000155 melt Substances 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
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229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
239000011859 microparticle Substances 0.000 description 1
VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
UIAMCVSNZQYIQS-KTKRTIGZSA-N oleonitrile Chemical compound CCCCCCCC\C=C/CCCCCCCC#N UIAMCVSNZQYIQS-KTKRTIGZSA-N 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
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JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
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239000012985 polymerization agent Substances 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
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150000003077 polyols Chemical class 0.000 description 1
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CAEWJEXPFKNBQL-UHFFFAOYSA-N prop-2-enyl carbonochloridate Chemical compound ClC(=O)OCC=C CAEWJEXPFKNBQL-UHFFFAOYSA-N 0.000 description 1
OTRMXXQNSIVZNR-UHFFFAOYSA-N prop-2-enyl nitrate Chemical compound [O-][N+](=O)OCC=C OTRMXXQNSIVZNR-UHFFFAOYSA-N 0.000 description 1
BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
238000005086 pumping Methods 0.000 description 1
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DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
238000010186 staining Methods 0.000 description 1
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
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Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Graft Or Block Polymers (AREA)
Polymerisation Methods In General (AREA)

SU772444853A 1976-11-30 1977-01-26 Способ получени винилгалоид-НыХ пОлиМЕРОВ SU799672A3 (ru)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/746,048 US4067928A (en)	1975-01-15	1976-11-30	Method of preparing vinyl halide polymers and copolymers with polyolefins

Publications (1)

Publication Number	Publication Date
SU799672A3 true SU799672A3 (ru)	1981-01-23

Family

ID=24999283

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU772444853A SU799672A3 (ru)	1976-11-30	1977-01-26	Способ получени винилгалоид-НыХ пОлиМЕРОВ

Country Status (11)

Country	Link
JP (1)	JPS6031848B2 (fr)
BE (1)	BE850890A (fr)
BR (1)	BR7700207A (fr)
CA (1)	CA1111176A (fr)
DE (1)	DE2701680A1 (fr)
ES (1)	ES455205A1 (fr)
FR (1)	FR2372180A1 (fr)
GB (1)	GB1568632A (fr)
IT (1)	IT1084901B (fr)
NL (1)	NL7701001A (fr)
SU (1)	SU799672A3 (fr)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT987193B (it) *	1972-05-08	1975-02-20	Hooker Chemical Corp	Procedimento di polimerizzazione di cloruro vinilico con polimeri e copolimeri olefinici e loro composizioni

1977
- 1977-01-07 GB GB446479A patent/GB1568632A/en not_active Expired
- 1977-01-12 BR BR7700207A patent/BR7700207A/pt unknown
- 1977-01-17 DE DE19772701680 patent/DE2701680A1/de not_active Ceased
- 1977-01-19 IT IT1942977A patent/IT1084901B/it active
- 1977-01-20 ES ES455205A patent/ES455205A1/es not_active Expired
- 1977-01-25 CA CA270,387A patent/CA1111176A/fr not_active Expired
- 1977-01-25 JP JP762277A patent/JPS6031848B2/ja not_active Expired
- 1977-01-26 SU SU772444853A patent/SU799672A3/ru active
- 1977-01-28 BE BE174499A patent/BE850890A/fr not_active IP Right Cessation
- 1977-01-28 FR FR7702429A patent/FR2372180A1/fr active Granted
- 1977-01-31 NL NL7701001A patent/NL7701001A/xx not_active Application Discontinuation

Also Published As

Publication number	Publication date
IT1084901B (it)	1985-05-28
FR2372180A1 (fr)	1978-06-23
NL7701001A (nl)	1978-06-01
ES455205A1 (es)	1978-03-16
GB1568632A (en)	1980-06-04
JPS5369294A (en)	1978-06-20
FR2372180B1 (fr)	1983-08-19
DE2701680A1 (de)	1978-06-01
BE850890A (fr)	1977-07-28
JPS6031848B2 (ja)	1985-07-24
BR7700207A (pt)	1978-06-06
CA1111176A (fr)	1981-10-20

Publication	Publication Date	Title
EP0301532A2 (fr)	1989-02-01	Agent épaississant de type acide acrylique sans solvant et procédé de leur préparation
US4195137A (en)	1980-03-25	Method of preparing vinyl halide polymers and copolymers with polyolefins
US4028329A (en)	1977-06-07	Process for the bulk polymerization of vinyl halide polymers showing reduced reactor scale formation
US4798869A (en)	1989-01-17	Process for the production of thermoplastic compositions and compositions produced thereby
US3789083A (en)	1974-01-29	Process for the preparation of vinyl chloride polymers grafted on polymers of ethylene
US4067928A (en)	1978-01-10	Method of preparing vinyl halide polymers and copolymers with polyolefins
CA2050192C (fr)	2001-07-24	Preparation d'un copolymere greffe polyacryalate/chlorure de vinyle resistant aux impacts
US4749757A (en)	1988-06-07	High bulk density PVC resin suspension polymerization with inhibitor
EP0647663A1 (fr)	1995-04-12	Elastomères thermoplastiques à base de copolymères greffés de chlorure de vinyle
US4155899A (en)	1979-05-22	Post bulk polymerization process for polyvinyl halide and composition thereof
CA1252930A (fr)	1989-04-18	Polymeres de greffe de monomeres polymerisables et de polymeres olefiniques
SU799672A3 (ru)	1981-01-23	Способ получени винилгалоид-НыХ пОлиМЕРОВ
GB1565626A (en)	1980-04-23	Process for the manufacture of vinyl chloride polymers
EP0847405A1 (fr)	1998-06-17	Emulsifiants polymeres destines a une polymerisation de chlorure de vinyle
SU471725A3 (ru)	1975-05-25	Способ получени полимеров или сополимеров винилхлорида
US4137216A (en)	1979-01-30	Post bulk polymerization process for polyvinyl halide and composition thereof
EP0195522B1 (fr)	1991-12-27	Composition polymère de chlorure de vinyle
DE3003778A1 (de)	1981-08-13	Verfahren zur polymerisation von vinylchlorid in waessiger phase
KR100278167B1 (ko)	2001-01-15	분절 공중합체들의 제조방법
US5908905A (en)	1999-06-01	Polymerization of vinyl chloride with t-butyl peroxyneoheptanoate and perester peroxide
US3810958A (en)	1974-05-14	Method of obtaining small particle size polymers and copolymers of vinyl chloride by bulk polymerization
GB1568631A (en)	1980-06-04	Method of preparing vinyl or vinylidene halide polymer products
CA1102046A (fr)	1981-05-26	Traduction non-disponible
US5235012A (en)	1993-08-10	Method for polymerizing vinyl chloride with controlled water addition
CA1109181A (fr)	1981-09-15	Methode de polymerisation d'halogenure vinylique avec des polymeres et des copolymeres olefiniques; composes a base de ces produits