SU802429A1 - Method of water- and grease-proofing treatment of hodroxyl- and amine-containing fibrous materials - Google Patents
Method of water- and grease-proofing treatment of hodroxyl- and amine-containing fibrous materials Download PDFInfo
- Publication number
- SU802429A1 SU802429A1 SU762397564A SU2397564A SU802429A1 SU 802429 A1 SU802429 A1 SU 802429A1 SU 762397564 A SU762397564 A SU 762397564A SU 2397564 A SU2397564 A SU 2397564A SU 802429 A1 SU802429 A1 SU 802429A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- water
- hodroxyl
- grease
- amine
- fibrous materials
- Prior art date
Links
- 238000011282 treatment Methods 0.000 title description 4
- 238000000034 method Methods 0.000 title description 2
- 150000001412 amines Chemical class 0.000 title 1
- 239000002657 fibrous material Substances 0.000 title 1
- 239000004744 fabric Substances 0.000 description 6
- 229920004936 Lavsan® Polymers 0.000 description 4
- 229920000297 Rayon Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 210000005053 lamin Anatomy 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Поли-(1,3,5,7,9,11,13-гептафторметил-3 ,5,7,9,11,13-гексаоксиперфтормиристиноиламиноэтилоксиметил )2-метил-5-винилпири;5Н ий хлорид (4)/Poly- (1,3,5,7,9,11,13-heptafluoromethyl-3, 5,7,9,11,13-hexa-oxyperfluoromeristoyl-amino-ethyloxymethyl) 2-methyl-5-vinylpyri; 5N and 1 chloride (4) /
или их смесь в соотношении 0,5:or their mixture in the ratio of 0.5:
R(( CHjO f НС1-- -Квв«Я{СН|)20в%С1 }R ((CHjO f HC1-- -Kvv “I {CH |) 20c% C1}
P- JH-CHj 5 4CH-(Jll2-|io P-JH-CHj 5 4CH- (Jll2- | io
« 3FjCF2CF20-tCB-Cft2-0-)CF ,"3FjCF2CF20-tCB-Cft2-0-) CF,
Выход солей составл ет 65-80%. Соли представл ют собой слегка окрашенные кристаллические продукты, растворил«ле в воде..The salt yield is 65-80%. Salts are slightly colored crystalline products, dissolved in water.
Водозащитные свойства модифицированных текстильных материалов определ ют на пенетрометре по ГОСТ 3816-61. Маслозащитные свойства определ ют по методике 3 М, заключающейс в нанесении на ткань капель различных жидкостей , отличающихс величиной порерхностного нат жени , и наблюдении за их поведением на поверхности материала . Мыльно-содовые обработки провод т по ГОСТ 3816-61.The waterproof properties of the modified textile materials are determined on a penetrometer according to GOST 3816-61. The oil barrier properties are determined by the 3 M method, which consists in applying to the fabric droplets of various fluids differing in the magnitude of the surface tension, and observing their behavior on the surface of the material. Soap and soda treatments are conducted according to GOST 3816-61.
Изобретение иллюстрируетс следующими примерами.The invention is illustrated by the following examples.
Пример 1. Хлопчатобумажную, вискозную штапельную, шерст ную, поликапро 1мидную , смешанные хлопко-лавсановую и вискозно-лавсановую ткани обрабатывают 2,5%-ным водным раствором соединений (1) - С) при 20°СExample 1. Cotton, viscose staple, wool, polycapro 1midny, mixed lavsan and viscose lavsan fabrics are treated with a 2.5% aqueous solution of compounds (1) - C) at 20 ° С
0,5:1:1 - 1:1:0,5:0,5, соответственно .0.5: 1: 1 - 1: 1: 0.5: 0.5, respectively.
Указанные соединени получают по следующей схеме: тСОЯН{СН2)20СН23Г VClThese compounds are obtained according to the following scheme: tSOYAN {CH2) 20CH23G VCl
в течение 1 мин, отжимгшт между ва. Q лами до 100% привеса, высушивают при в течение 5 мин до влгикности 4% и прогревают в течение 12,5 мин при 1550с.within 1 min, wringing between wa. Q lamines to 100% weight gain, dried at 5 minutes to a moisture content of 4% and heated for 12.5 minutes at 1550s.
Содержаниефтора на ткани после указанной обработки, масло стойкость и водоупорность приведены в табл. 1.The content of fluoride on the fabric after this treatment, oil resistance and water resistance are given in table. one.
Пример 2. Смешанную вискозно-лавсановую ткань (67% вискозы, 33% лавсана ) обрабатывают 2,5%-ным водным раствором смеси соединений (1) - С) в соотношении (1} : (2}: 0)гС4) 0,5: 0,5:1:1 в услови х, указанных впримере 1. Содержание фтора на ткани после модификации, маслостойкость и водоупорность приведены в табл. 2.Example 2. Mixed viscose lavsan fabric (67% viscose, 33% lavsan) is treated with a 2.5% aqueous solution of a mixture of compounds (1) - C in the ratio (1}: (2}: 0) gS4) 0, 5: 0.5: 1: 1 under the conditions indicated in Example 1. The fluorine content on the fabric after modification, oil resistance and water resistance are listed in Table. 2
Таким образом, насто щее изобретеиие обеспечивает получение тканей с высокими и устойчивыми к мокрым обработкам масло-,водоотталкивающими свойствами.Thus, the present invention provides fabrics with high and resistant to wet treatments with oil-, water-repellent properties.
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Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU762397564A SU802429A1 (en) | 1976-08-23 | 1976-08-23 | Method of water- and grease-proofing treatment of hodroxyl- and amine-containing fibrous materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU762397564A SU802429A1 (en) | 1976-08-23 | 1976-08-23 | Method of water- and grease-proofing treatment of hodroxyl- and amine-containing fibrous materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU802429A1 true SU802429A1 (en) | 1981-02-07 |
Family
ID=20674565
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU762397564A SU802429A1 (en) | 1976-08-23 | 1976-08-23 | Method of water- and grease-proofing treatment of hodroxyl- and amine-containing fibrous materials |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU802429A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6740413B2 (en) | 2001-11-05 | 2004-05-25 | 3M Innovative Properties Company | Antistatic compositions |
| US7678941B2 (en) | 2001-05-10 | 2010-03-16 | 3M Innovative Properties Company | Polyoxyalkylene ammonium salts and their use as antistatic agents |
| RU2467112C1 (en) * | 2011-03-05 | 2012-11-20 | Общество с ограниченной ответственностью "Текстиль-АС" | Method of obtaining oil-water-repellent textile fabric of aramid fibers |
-
1976
- 1976-08-23 SU SU762397564A patent/SU802429A1/en active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7678941B2 (en) | 2001-05-10 | 2010-03-16 | 3M Innovative Properties Company | Polyoxyalkylene ammonium salts and their use as antistatic agents |
| US7893144B2 (en) | 2001-05-10 | 2011-02-22 | 3M Innovative Properties Company | Polyoxyalkylene ammonium salts and their use as antistatic agents |
| US6740413B2 (en) | 2001-11-05 | 2004-05-25 | 3M Innovative Properties Company | Antistatic compositions |
| RU2467112C1 (en) * | 2011-03-05 | 2012-11-20 | Общество с ограниченной ответственностью "Текстиль-АС" | Method of obtaining oil-water-repellent textile fabric of aramid fibers |
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