SU802430A1 - Composition for water-and grease-proofing theattment of textiles - Google Patents
Composition for water-and grease-proofing theattment of textiles Download PDFInfo
- Publication number
- SU802430A1 SU802430A1 SU762397565A SU2397565A SU802430A1 SU 802430 A1 SU802430 A1 SU 802430A1 SU 762397565 A SU762397565 A SU 762397565A SU 2397565 A SU2397565 A SU 2397565A SU 802430 A1 SU802430 A1 SU 802430A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- water
- composition
- theattment
- proofing
- textiles
- Prior art date
Links
- 239000004753 textile Substances 0.000 title claims description 10
- 239000000203 mixture Substances 0.000 title description 7
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 150000004812 organic fluorine compounds Chemical class 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000000463 material Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000005871 repellent Substances 0.000 description 7
- 229920004936 Lavsan® Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 229920000297 Rayon Polymers 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- -1 ethyl hydroxymethyl Chemical group 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- XTPPAVHDUJMWEX-UHFFFAOYSA-M 1-ethenylpyridin-1-ium;chloride Chemical compound [Cl-].C=C[N+]1=CC=CC=C1 XTPPAVHDUJMWEX-UHFFFAOYSA-M 0.000 description 1
- YUBIBZIJVGDAAE-UHFFFAOYSA-M CCOC[N+]1=C(C)C=CC(C=C)=C1.[Cl-] Chemical compound CCOC[N+]1=C(C)C=CC(C=C)=C1.[Cl-] YUBIBZIJVGDAAE-UHFFFAOYSA-M 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- AOJFQRQNPXYVLM-UHFFFAOYSA-N pyridin-1-ium;chloride Chemical compound [Cl-].C1=CC=[NH+]C=C1 AOJFQRQNPXYVLM-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
1one
Изобретение относитс к области текстильного отделочного производства , в частности к технологии водо- ,маслоотталкива1ощей отделки текстильных материалов. Текстильные материалы с масло-(Водоотталкивающими свойствами примен ютс дл изготовлени защитной спецодежды работников нефтеперерабатывающей промышленности , а также чехол.ных упаковочных материалов, транспортерных лент.The invention relates to the field of textile finishing production, in particular, to the technology of water-, oil-repellent finishing of textile materials. Textile materials with oil- (Water-repellent properties are used to make protective workwear for workers in the oil refining industry, as well as a cover. Packaging materials, conveyor belts.
Известен состав дл придани текстильным материалам масло-,водоотталкивающих свойств на основе фторсодержащих четвертичных аммониевых солей 1 .A known composition for imparting to the textile materials oil-, water-repellent properties based on fluorinated quaternary ammonium salts 1.
Недостатком данного состава вл етс низка устойчивость достигаемого масло-,водоотталкивающего эффекта модифицированных им текстильных материалов к мыльно-содовым стиркам .The disadvantage of this composition is the low resistance of the achieved oil-, water-repellent effect of the textile materials modified by it to soap and soda washes.
Наиболее близким к изобретению вл етс состав, содержащий поли-Ctj Ь--дигидроперфторгептилакрилат и воду (латекс ГФ) 2 .The closest to the invention is a composition containing poly-ctj b - dihydropertorgeptylacrylate and water (GF latex) 2.
Недостатками данного состава вл ютс недостаточно высокий эффект отделки и низка устойчивость масловодоотталкивающих свойств модифицированных латексом ГФ текстильных материалов к мыльно-содовьлм .The disadvantages of this composition are the insufficiently high finishing effect and the low resistance of the oil-water repellent properties of the latex-modified GF textile materials to soap-and-soap.
Целью изобретени вл етс повышение водо-,маслоотталкивающих свойств модифицированных текстильных материалов и увеличение устойчивости указанных свойств к мокрым обработкам в жестких услови х.The aim of the invention is to increase the water-, oil-repellent properties of the modified textile materials and to increase the resistance of these properties to wet treatments under harsh conditions.
00
Поставленна цель достигаетс за счет того, что состав, включакхдий поли-о - сэ -дигидроперфторгептилакрилат и воду, дополнительно содержит поли-|(2-перфторэнантоиламино} этило5 ксиметил -2-метил-5-винилипиридиний хлорид или поли- |(2-перфторпеларгоиламино ) этилоксиметил -2-метил-5-винилпиридиний хлорид при следующем соотношении компонентов, вес. ч.This goal is achieved due to the fact that the composition, including poly-o-se-dihydroperfluorpeptilacrylate and water, additionally contains poly- | ) ethyloxymethyl -2-methyl-5-vinylpyridinium chloride in the following ratio of components, parts by weight
00
Поли-cioi -дигидроперфторгептилакрилат .0,4-1,25Poly-cioi-dihydroperfluorpeptilacrylate .0.4-1.25
Поли-( 2-перфторэнантоэламино ) этил-оксиметил -2-метил-55Poly- (2-perfluoroenanto-elamino) ethyl hydroxymethyl -2-methyl-55
винилпиридиний хлоридvinyl pyridinium chloride
или поли-(2-перфторпеларгоил амино) этилокси . -2метил- 5-виЕжлпиридиний хлорид. 1,25-2,1or poly (2-perfluoroparargoyl amino) ethyloxy. -2methyl-5-viral pyridinium chloride. 1.25-2.1
00
ВодаОстальноеWaterEverything
Изобретение иллюстрируетс следующими примерами.The invention is illustrated by the following examples.
Пример 1. Хлопчатобумажную, вискозную , штапельную,/йГерст ную, смешанные хлопко-лавсановую или вискоэно-лавсановую , поликапроамидную ткани обрабатывают водной дисперсией, содержащей, вес.%: Поли-(уо6,-дигидроперфторгептилакрилатО ,4Example 1. Cotton, viscose, staple, / Thirsty, mixed cotton-lavsan or viscoeno-lavsan, polycaproamide fabrics are treated with an aqueous dispersion containing, in wt.%: Poly- (y-6, -dihydropertorgeptilacrylate O, 4
Поли-СС 2-перфторэ нантоиламино )этилоксиметилД-З-метил5-винилпиридиний хлорид 2,1 ВодаОстальноеPoly-CC 2-perfluoro nantoylamino) ethyloxymethyl-D-3-methyl-5-vinyl pyridinium chloride 2,1 Water Rest
отживают между валами до 100% привеса , высушивают при до относительной влажности 4% в течение 7 мин и прогревают в течение 15 мин при . Затем ткани промывают водой, высушивают и анализируют. Содержание фтора, малостойкость и водостойкость модифицированных тканей приведены в табл. 1.Between shafts, they live up to a 100% gain, dried at a relative humidity of 4% for 7 minutes and heated for 15 minutes at. Then the tissue is washed with water, dried and analyzed. Fluorine content, low resistance and water resistance of modified tissues are given in Table. one.
Пример 2. Хлопчатобумажную, вискозную , штапельную, шерст ную, смешанные хлопко-лавсановую и вискозно-лавсановую , поликапроамидную ткани обрабатывают водной дисперсией, содержащей, вес.%: Поли-С1с.;0б игидроперфторгептилакрилат 1,25Example 2. Cotton, viscose, staple, wool, mixed cotton-lavsan and viscose lavsan, polycaproamide fabrics are treated with an aqueous dispersion containing, in wt.%: Poly-C1c., 0b ihydroperftorgeptilacrylate, 1.25
Поли- С 2-перфторпеларгоиламино ) эти 1оксиметил| -2 -метил-5 винилпйридинийхлорид 1,25 Вода .Остальное,Poly-C 2-perfluoropararoylamino) these 1-oxymethyl | -2-methyl-5 vinylpyridinium chloride 1,25 Water. The rest,
отжимают между валами до 100% привеса , высушивают при 85с до относительной влажности 4% в течение 7 мин и прогревают в Течение 15 мин при . Затем ткани проьвлвают водой, высушивают и анализируют. Содержаниеsqueeze between the shafts to 100% weight gain, dried at 85 s to a relative humidity of 4% for 7 minutes and heated for 15 minutes at. Then the tissues are sprinkled with water, dried and analyzed. Content
фтора, маслостойкость и водостойкость модифицированных тканей приведены в табл. 2.fluorine, oil resistance and water resistance of modified tissues are given in Table. 2
Водозащитные свойства модифицированных текстильных материалов определ ют на пенетрометре по ГОСТThe waterproof properties of the modified textile materials are determined on a penetrometer according to GOST.
3816-61. Маслозащитные свойства определ ют по методике 3 М, заключающейс в нанесении капель на ткань различных жидкостей, отличающихс величиной поверхностного нат жени ,и наблюдении за их поведением на поверхности материала. Мыльно-содовые стирки (мсс) провод т по ГОСТ 3816-61.3816-61. The oil barrier properties are determined by the 3 M method, which consists in applying drops on the fabric of various liquids differing in the value of surface tension, and observing their behavior on the surface of the material. Soap and soda washes (mss) are conducted according to GOST 3816-61.
Таким образом, указанный составThus, the specified composition
обеспечивает придание текстильнымprovides imparting textile
материалам высоких и устойчивых вhigh and resistant materials
процессе мыльно-содовых обработокthe process of soap and soda treatments
масло-,водоотталкивающих свойств.oil-, water-repellent properties.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU762397565A SU802430A1 (en) | 1976-08-23 | 1976-08-23 | Composition for water-and grease-proofing theattment of textiles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU762397565A SU802430A1 (en) | 1976-08-23 | 1976-08-23 | Composition for water-and grease-proofing theattment of textiles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU802430A1 true SU802430A1 (en) | 1981-02-07 |
Family
ID=20674566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU762397565A SU802430A1 (en) | 1976-08-23 | 1976-08-23 | Composition for water-and grease-proofing theattment of textiles |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU802430A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6740413B2 (en) | 2001-11-05 | 2004-05-25 | 3M Innovative Properties Company | Antistatic compositions |
| US7678941B2 (en) | 2001-05-10 | 2010-03-16 | 3M Innovative Properties Company | Polyoxyalkylene ammonium salts and their use as antistatic agents |
-
1976
- 1976-08-23 SU SU762397565A patent/SU802430A1/en active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7678941B2 (en) | 2001-05-10 | 2010-03-16 | 3M Innovative Properties Company | Polyoxyalkylene ammonium salts and their use as antistatic agents |
| US7893144B2 (en) | 2001-05-10 | 2011-02-22 | 3M Innovative Properties Company | Polyoxyalkylene ammonium salts and their use as antistatic agents |
| US6740413B2 (en) | 2001-11-05 | 2004-05-25 | 3M Innovative Properties Company | Antistatic compositions |
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