TR199902670T2 - Çözeltiyle boyanmis naylon elyaf. - Google Patents
Çözeltiyle boyanmis naylon elyaf.Info
- Publication number
- TR199902670T2 TR199902670T2 TR1999/02670T TR9902670T TR199902670T2 TR 199902670 T2 TR199902670 T2 TR 199902670T2 TR 1999/02670 T TR1999/02670 T TR 1999/02670T TR 9902670 T TR9902670 T TR 9902670T TR 199902670 T2 TR199902670 T2 TR 199902670T2
- Authority
- TR
- Turkey
- Prior art keywords
- nylon fiber
- light
- solution dyed
- dyed nylon
- color
- Prior art date
Links
- 229920001778 nylon Polymers 0.000 title 1
- 239000000835 fiber Substances 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- -1 piperidine compound Chemical class 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 238000009987 spinning Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 238000010998 test method Methods 0.000 abstract 1
- NQRYJNQNLNOLGT-UHFFFAOYSA-N tetrahydropyridine hydrochloride Natural products C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052724 xenon Inorganic materials 0.000 abstract 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/04—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/28—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/06—Dyes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2973—Particular cross section
- Y10T428/2976—Longitudinally varying
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Coloring (AREA)
- Hydrogenated Pyridines (AREA)
- Polyamides (AREA)
Abstract
En azindan bir adet mono ya da dikarboksilik asit düzenleyicisinin ve en azindan bir adet engellenmis piperidin bilesiminin varliginda polimerize edilmis amid monomerleri olan bir po1iamidin eritilmesi, eritilen poliamidin renklendirilmesi ve renklendirilmis poliamidin AATCC Test Yöntemi 16-1993 "Isiga Karsi Renk Dayanikligi" E Seçenegi uyarinca 2125 kJ ksenon ark radyasyonuna tabi tutulduktan sonra % 40 ya da daha üstündeki bir oranda korunmus saglamliga sahip olan elyaflar halinde egrilmesi yoluyla yapilan stabilize edilmis çözeltiyle boyanmis elyaf. Bakir stabilize ediciler gereksizdir.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4526997P | 1997-05-01 | 1997-05-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TR199902670T2 true TR199902670T2 (tr) | 2000-06-21 |
Family
ID=21936927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TR1999/02670T TR199902670T2 (tr) | 1997-05-01 | 1998-04-23 | Çözeltiyle boyanmis naylon elyaf. |
Country Status (24)
| Country | Link |
|---|---|
| US (2) | US6136433A (tr) |
| EP (1) | EP0979320B1 (tr) |
| JP (1) | JP2001522418A (tr) |
| KR (1) | KR100487469B1 (tr) |
| CN (1) | CN1104512C (tr) |
| AR (1) | AR015627A1 (tr) |
| BG (1) | BG63574B1 (tr) |
| BR (1) | BR9809015A (tr) |
| CA (1) | CA2232359C (tr) |
| CZ (1) | CZ9903872A3 (tr) |
| DE (1) | DE69804440T2 (tr) |
| ES (1) | ES2175721T3 (tr) |
| HU (1) | HU224834B1 (tr) |
| ID (1) | ID22804A (tr) |
| IL (1) | IL132339A (tr) |
| IN (1) | IN208586B (tr) |
| MX (1) | MX229777B (tr) |
| MY (1) | MY119153A (tr) |
| PL (1) | PL190983B1 (tr) |
| SK (1) | SK140399A3 (tr) |
| TR (1) | TR199902670T2 (tr) |
| TW (1) | TW538152B (tr) |
| WO (1) | WO1998050610A1 (tr) |
| ZA (1) | ZA983642B (tr) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2249005A1 (en) * | 1998-03-09 | 1999-09-09 | Basf Corporation | Light and thermally stable polyamide |
| DE19812135A1 (de) * | 1998-03-20 | 1999-09-23 | Basf Ag | Inhärent licht- und hitzestabilisierte Polyamide mit verbesserter Naßechtheit |
| DE10058291A1 (de) * | 2000-11-23 | 2002-05-29 | Basf Ag | Mehrkomponenten-Faser |
| GB2373256B (en) * | 2001-03-14 | 2005-03-30 | Du Pont | Fabrics comprising melt spun yarns having high lustre |
| US6620208B2 (en) | 2001-03-30 | 2003-09-16 | Honeywell International Inc. | Wetfast polyamide fiber with high amino end group content |
| EP1399506A1 (en) * | 2001-05-14 | 2004-03-24 | Ciba SC Holding AG | New pigmentary compositions |
| HUP0303984A2 (hu) * | 2001-05-15 | 2004-03-01 | Basf Ag | Poliamidból és egy 2,6-diamino-piridin-származékból álló rendszer és eljárás előállítására |
| MXPA03009911A (es) | 2001-06-06 | 2004-01-29 | Basf Corp | METODO PARA LA OBTENCIoN DE UN POLIMERO A PARTIR DE UNA COMPOSICIoN DE PRECURSOR DE POLIMERO. |
| PL366777A1 (en) * | 2001-06-14 | 2005-02-07 | Basf Corporation | Light-stabilized polymers comprising light-stabilizing moieties, articles therefrom and a method of making the same |
| US20050113512A1 (en) * | 2002-06-04 | 2005-05-26 | Otto Ilg | Method of making a polymer from a polymer precursor composition |
| WO2004083270A2 (en) * | 2003-03-18 | 2004-09-30 | Ciba Specialty Chemicals Holding Inc. | Colored polymeric articles having high melt temperatures |
| DE102004028825B4 (de) | 2004-06-15 | 2022-07-14 | Coroplast Fritz Müller Gmbh & Co. Kg | Kabelbaum und Verwendung eines technischen Klebebandes |
| US20090246448A1 (en) * | 2006-02-14 | 2009-10-01 | Francoise Henrio | Thermoplastic polymer/colorant tow and flocked articles prepared therefrom |
| DE102008038099A1 (de) | 2008-08-18 | 2010-02-25 | Teijin Monofilament Germany Gmbh | Gefärbte Fäden und deren Verwendung |
| EP3263639A1 (en) * | 2016-06-27 | 2018-01-03 | Clariant International Ltd | Use of an additive composition for the preparation of polycondensation polymers |
| TWI641732B (zh) * | 2017-09-11 | 2018-11-21 | 展頌股份有限公司 | 除臭尼龍6纖維及其製造方法 |
| CN111979591B (zh) * | 2020-07-30 | 2023-01-24 | 神马实业股份有限公司 | 一种高强度高耐热细单纤尼龙66纤维及其制备方法 |
| WO2025129268A1 (en) * | 2023-12-21 | 2025-06-26 | Gale Pacific Limited | Yarn for fabric and fabric |
| CN118994563A (zh) * | 2024-09-05 | 2024-11-22 | 湘潭大学 | 一种本征彩色尼龙及其制备方法 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3947424A (en) * | 1974-07-31 | 1976-03-30 | E. I. Du Pont De Nemours And Company | Polyamidation process |
| US3929725A (en) * | 1974-07-31 | 1975-12-30 | Du Pont | Process for stabilizing polyamides |
| DE2642461A1 (de) * | 1976-09-21 | 1978-03-30 | Bayer Ag | Permanent stabilisierte polymere |
| SU670588A1 (ru) * | 1978-02-14 | 1979-06-30 | Предприятие П/Я А-3324 | Полимерна композици |
| US4374641A (en) * | 1979-08-01 | 1983-02-22 | Badische Corporation | Polymeric color concentrates for thermoplastic polymeric materials |
| US4756947A (en) * | 1984-06-19 | 1988-07-12 | Toray Industries, Inc. | Grained artificial leather having good color fastness of ultrafine polyamide fibers |
| US5280088A (en) * | 1986-02-28 | 1994-01-18 | General Electric Company | Thermoplastic blends of a polyamide having low amine end-group concentration and a polymer containing carbonate linkages |
| US4874391A (en) * | 1986-07-29 | 1989-10-17 | Ciba-Geigy Corporation | Process for photochemical stabilization of polyamide fiber material and mixtures thereof with other fibers: water-soluble copper complex dye and light-stabilizer |
| DE3816699A1 (de) * | 1988-05-17 | 1989-11-30 | Bayer Ag | Verfahren zur nachbehandlung von gefaerbten textilmaterialien |
| DE3920029C2 (de) * | 1988-06-30 | 1999-05-20 | Clariant Finance Bvi Ltd | Farbstoffe zum Färben von Kunststoffen |
| DE3823112A1 (de) * | 1988-07-08 | 1990-01-11 | Basf Ag | 2,6-polyalkyl-piperidin-4-amide, deren verwendung als stabilisatoren, insbesondere fuer kunststoffe, sowie diese amide enthaltendes organisches material |
| US5108684B1 (en) * | 1988-12-14 | 1994-05-10 | Du Pont | Process for producing stain-resistant, pigmented nylon fibers |
| DE3901717A1 (de) * | 1989-01-21 | 1990-07-26 | Sandoz Ag | Synthetische polyamide mit verbesserter anfaerbbarkeit |
| FR2642764B1 (fr) * | 1989-02-03 | 1993-05-28 | Rhone Poulenc Chimie | Nouveaux composes a fonction piperidinyle et leur application dans la photostabilisation des polymeres |
| EP0516192A3 (en) * | 1989-02-13 | 1992-12-23 | Atochem North America, Inc. | Reactive hindered amine light stabilizers |
| JPH03504984A (ja) * | 1989-02-13 | 1991-10-31 | アトケム ノース アメリカ,インコーポレイテッド | 反応性ヒンダードアミンによる光安定剤 |
| ATE130882T1 (de) * | 1990-07-12 | 1995-12-15 | Ciba Geigy Ag | Verfahren zur photochemischen und thermischen stabilisierung von polyamid-fasermaterialien. |
| EP0546993A1 (de) * | 1991-12-09 | 1993-06-16 | Ciba-Geigy Ag | Wasserlöschliche Triazinderivate zur photochemischen und thermischen Stabilisierung von Polyamidfasermaterialien |
| US5466761A (en) * | 1993-10-29 | 1995-11-14 | Dsm N.V. | Nylon alloys |
| US5736468A (en) * | 1994-02-02 | 1998-04-07 | Trichromatic Carpet Inc. | Stain resistant polyamide substrate treated with sulfonated phosphated resol resin |
| US5756407A (en) * | 1994-02-02 | 1998-05-26 | Trichromatic Carpet Inc. | Stain resistant polyamide substrate treated with sulfonated phosphated resol resin |
| DE59502905D1 (de) * | 1994-04-15 | 1998-08-27 | Basf Ag | Inhärent licht- und hitzestabilisierte polyamide |
| ES2128024T3 (es) * | 1994-09-30 | 1999-05-01 | Ciba Geigy Ag | Estabilizacion de fibra pigmentada con una mezcla sinergistica de amina impedida y absorbedor de uv. |
| US5618909A (en) * | 1995-07-27 | 1997-04-08 | Alliedsignal Inc. | Light stabilized polyamide substrate and process for making |
| JPH0941218A (ja) * | 1995-07-31 | 1997-02-10 | Teijin Ltd | 粗面化ポリアミド繊維の製造方法 |
| JPH0941217A (ja) * | 1995-07-31 | 1997-02-10 | Teijin Ltd | 粗面化ポリアミド繊維の製造方法 |
| DE19537614C3 (de) * | 1995-10-09 | 2003-10-02 | Inventa Ag | Polycaprolactam mit neuartiger Kettenregelung |
| US5851238A (en) * | 1996-07-31 | 1998-12-22 | Basf Corporation | Photochemically stabilized polyamide compositions |
-
1998
- 1998-03-11 US US09/041,031 patent/US6136433A/en not_active Expired - Lifetime
- 1998-04-23 KR KR10-1999-7010066A patent/KR100487469B1/ko not_active Expired - Fee Related
- 1998-04-23 WO PCT/EP1998/002411 patent/WO1998050610A1/en not_active Ceased
- 1998-04-23 CZ CZ19993872A patent/CZ9903872A3/cs unknown
- 1998-04-23 BR BR9809015-1A patent/BR9809015A/pt not_active Application Discontinuation
- 1998-04-23 EP EP98928218A patent/EP0979320B1/en not_active Revoked
- 1998-04-23 PL PL336573A patent/PL190983B1/pl not_active IP Right Cessation
- 1998-04-23 SK SK1403-99A patent/SK140399A3/sk unknown
- 1998-04-23 HU HU0002967A patent/HU224834B1/hu not_active IP Right Cessation
- 1998-04-23 CN CN98804639A patent/CN1104512C/zh not_active Expired - Fee Related
- 1998-04-23 ID IDW991272A patent/ID22804A/id unknown
- 1998-04-23 TR TR1999/02670T patent/TR199902670T2/tr unknown
- 1998-04-23 JP JP54767098A patent/JP2001522418A/ja not_active Withdrawn
- 1998-04-23 DE DE69804440T patent/DE69804440T2/de not_active Expired - Lifetime
- 1998-04-23 ES ES98928218T patent/ES2175721T3/es not_active Expired - Lifetime
- 1998-04-23 IL IL13233998A patent/IL132339A/xx not_active IP Right Cessation
- 1998-04-24 CA CA002232359A patent/CA2232359C/en not_active Expired - Fee Related
- 1998-04-28 IN IN917CH1998 patent/IN208586B/en unknown
- 1998-04-29 MX MX9803374A patent/MX229777B/es not_active IP Right Cessation
- 1998-04-30 MY MYPI98001952A patent/MY119153A/en unknown
- 1998-04-30 TW TW087106655A patent/TW538152B/zh not_active IP Right Cessation
- 1998-04-30 ZA ZA9803642A patent/ZA983642B/xx unknown
- 1998-04-30 AR ARP980102049A patent/AR015627A1/es unknown
-
1999
- 1999-11-09 BG BG103868A patent/BG63574B1/bg unknown
- 1999-11-11 US US09/438,728 patent/US6358458B1/en not_active Expired - Fee Related
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