TR201713191A2 - A SOAP-BASED NATURAL LIQUID DETERGENT METHOD AND A NATURAL SOAP-BASED LIQUID DETERGENT OBTAINED BY THIS METHOD - Google Patents

A SOAP-BASED NATURAL LIQUID DETERGENT METHOD AND A NATURAL SOAP-BASED LIQUID DETERGENT OBTAINED BY THIS METHOD Download PDF

Info

Publication number
TR201713191A2
TR201713191A2 TR2017/13191A TR201713191A TR201713191A2 TR 201713191 A2 TR201713191 A2 TR 201713191A2 TR 2017/13191 A TR2017/13191 A TR 2017/13191A TR 201713191 A TR201713191 A TR 201713191A TR 201713191 A2 TR201713191 A2 TR 201713191A2
Authority
TR
Turkey
Prior art keywords
soap
liquid detergent
obtaining
based natural
natural liquid
Prior art date
Application number
TR2017/13191A
Other languages
Turkish (tr)
Inventor
Esen Özlem
Özge Avci Tuna Asli
Ünal Si̇nem
Original Assignee
Evyap Sabun Yag Gliserin Sanayi Ve Ticaret A S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evyap Sabun Yag Gliserin Sanayi Ve Ticaret A S filed Critical Evyap Sabun Yag Gliserin Sanayi Ve Ticaret A S
Priority to TR2017/13191A priority Critical patent/TR201713191A2/en
Publication of TR201713191A2 publication Critical patent/TR201713191A2/en
Priority to PCT/TR2018/050469 priority patent/WO2019125336A2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08Liquid soap, e.g. for dispensers; capsuled
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/08Water-soluble compounds
    • C11D9/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/225Polymers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/30Organic compounds, e.g. vitamins containing nitrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

Bu buluş ile, bitkisel yağ asitlerinin yüksek pH?da bir zayıf ve/veya kuvvetli bir baz ile sabunlaştırılmasından sonra oluşan doğal sabun formunun kıvamlaştırıcı, şelatlayıcı hammaddeler, parfüm, boya ve ekstrakt gibi diğer bileşenlerin ilavesi ile sentetik sıvı deterjanların yerine çamaşır temizliğinde elde veya makinada kullanılabilecek, düşük ve yüksek sıcaklıklarda fiziksel olarak kararlı, viskozite ve jelleşme problemi gözlenmeyen, yıkama ve temizleme performansı yüksek, insan ve çevre dostu olan, doğal bitkisel sabun bazlı sıvı deterjan formülü geliştirilmiştir.With the present invention, the natural soap form formed after saponification of vegetable fatty acids with a weak and / or strong base at high pH, with the addition of other components such as thickener, chelating raw materials, perfume, paint and extract, instead of synthetic liquid detergents in laundry or machine cleaning. A natural vegetable soap based liquid detergent formula that can be used at low and high temperatures is physically stable, has no viscosity and gelling problems, has high washing and cleaning performance, and is human and environmentally friendly.

Description

TARIFNAME SABUN BAZLI DOGAL BIR SIVI DETERJAN ELDE EDILMESI YÖNTEMI VE BU YÖNTEMLE ELDE EDILEN SABUN BAZLI DOGAL BIR SIVI DETERJAN Teknik Alan Bu bulus, klasik kati/Sivi deterjanlarin insan ve çevre sagligina karsi potansiyel tüm olumsuz etkilerini ortadan kaldirabilmek amaciyla dogal ve bitkisel olan sabun bazli sivi deterjan ile ilgilidir. Önceki Teknik Yakin geçmiste ham petrolden sentetik yolla elde edilen deterjanlar temizleyici olarak kullanilmaya baslanmistir. Ancak bu temizleyici maddelerin gelisigüzel üretilmesi ve bilinçsizce çevreye yayilmasi nedeniyle insan ve diger canlilarin yasam ortami olan su, hava ve toprak kirliliginde ciddi bir artis görülmüstür. DESCRIPTION OBTAINING A NATURAL SOAP BASED LIQUID DETERGENT METHOD AND SOAP BASED NATURAL OBTAINED BY THIS METHOD A LIQUID DETERGENT Technical Area This invention shows the potential of conventional solid/liquid detergents against human and environmental health. natural and herbal products in order to eliminate all the negative effects of relates to soap-based liquid detergent. Prior Art In the recent past, detergents obtained synthetically from crude oil have been used as cleaners. has been used as. However, these cleaning agents are indiscriminate. human and other living things due to its production and unconsciously spreading to the environment. There has been a serious increase in water, air and soil pollution, which is the living environment.

Warwick, C., Guerreiro, A. ve Soares, A., tarafindan 2013 yilinda Biosens. Biosens in 2013 by Warwick, C., Guerreiro, A., and Soares, A.,.

Bioelectron. 41, 1-11 yayinlanan “Sensing and analysis of soluble phosphates in environmental samples” baslikli makalede, mevcut deterjanlarin performansinin artmasi için içerisine ilave edilen selatlayici ajanlarin çevre açisindan ciddi problemlere neden oldugundan bahsedilmektedir. Örnegin selatlama amaciyla kullanilan fosfatlar suda yasayan canlilar tarafindan besin olarak kullanildigi için fosfat fazlasi ekosistemde alg vb. canli popülasyonunda normalden fazla artisa sebep olmaktadir. Bu artis nedeniyle de su yüzeyinde biriken algler, suyun alt kismina oksijen ve isik girmesini engellemekte, dolayisi ile diger canlilarin yasamini olumsuz etkilemektedir. Cai, Z. ve Hakkinen,P.J., tarafindan, 2005 yilinda, “Encylopedia of Toxicology, Ikinci Baski, sayfa 739 -742,de yayinlanan, Avusturya, Belçika, Irlanda ve Italya) su kirliligini azaltmak için deterjanlara ilave edilen fosfat miktarinin kontrolünü esas alan bir mevzuat gelistirildigi belirtilmektedir. bioelectron. 41, 1-11 published “Sensing and analysis of soluble phosphates in In the article titled “environmental samples”, the performance of existing detergents The chelating agents added to increase the are said to cause problems. For example, for the purpose of chelating Since the phosphates used are used as food by aquatic organisms, Excess phosphate algae etc. in the ecosystem. more than normal increase in the living population causes. Due to this increase, algae accumulated on the water surface, It prevents oxygen and light from entering the negatively affects their lives. by Cai, Z. and Hakkinen,P.J., 2005 Published in “Encyclopedia of Toxicology, Second Edition, pp. 739 -742, Austria, Belgium, Ireland and Italy) added to detergents to reduce water pollution. A legislation has been developed based on the control of the amount of phosphate produced. is indicated.

Ayrica, yüzey aktif maddelerinin yüksek maliyetlerini düsürmek amaci ile mevcut deterjan formüllerinin içerisine kaolin, bentonit, asit ve silikatlar gibi suda az çözünen maddelerin katilmasi nedeniyle de dogada biyobozunurlugu olmayan maddelerin çevreye salinimi söz konusu olmustur. Bir ürünün içerigindeki biyobozunur olmayan madde miktari ne kadar fazla ise 0 ürün çevre kirliligine etkisi 0 kadar fazladir denebilir. Çünkü, su ve toprakta bozulmayan ürünler akarsulara ve deniz suyuna karistiginda denizdeki canlilarin ölümüne, topraga karistiginda ise bitkilerin ve toprakta yasayan canli varliklarin zarar görmelerine sebep olmakta, böylece ekolojik sistemi de tehdit etmektedir. In addition, in order to reduce the high costs of surfactants, water such as kaolin, bentonite, acid and silicates are included in existing detergent formulas. non-biodegradable in nature due to the addition of less soluble substances substances have been released into the environment. content of a product The higher the amount of non-biodegradable material, the less the product will be subject to environmental pollution. It can be said that the effect is as high as 0. Because products that do not degrade in water and soil When it mixes with streams and sea water, it causes death of sea creatures, soil When mixed, it causes damage to plants and living creatures living in the soil. thus threatening the ecological system.

Yukarida sayilan tüm olumsuz etkilere ilave olarak deterjanlarda kullanilan beyazlatici, parlatici, köpürtücü, köpük kesici vb. gibi birçok madde de yüzey aktif maddeler gibi canli vücudundaki dokularda iritasyona ve hatta kansere neden olabilmektedir. Dolayisiyla son yillarda kullanilan sentetik deterjanlarin çevre kirliligindeki önemli etkisi göze çarpmaya baslamis ve bu konuda önlem alma zorunlulugu gündeme gelmistir. Istanbul Üniversitesi Yayinlari: 4747, Cerrahpasa Tip Fakültesi Yayinlari: 261, Köksal, S., tarafindan 2008 yilinda, Halk Sagligi Ders Kitabi “Altinci Bölüm ÇEVRE SAGLIGI” s.605-650,de belirtilmis olan bilgiler isiginda, Türkiye”de insan vücuduna giren deterjan yüzey aktif madde miktari en çok 1 mg/L olacak sekilde limit belirlenmistir. Ancak ülkemizde yapilan çalismalar içme sularinda bile çok yüksek miktarda yüzey aktif madde miktari bulundugunu göstermistir. Bu nedenle ülkemizde biyobozunur deterjanlarin kullanimi oldukça önem arz etmektedir. In addition to all the above-mentioned negative effects, the detergents used in bleach, brightener, foamer, defoamer etc. surface of many substances, such as As active substances, it can cause irritation and even cancer in the tissues of the living body. can happen. Therefore, the environmental impact of synthetic detergents used in recent years. pollution has started to stand out, and it is necessary to take precautions in this regard. necessity came to the fore. Istanbul University Publications: 4747, Cerrahpasa Faculty of Medicine Publications: 261, by Köksal, S., in 2008, Public Health The ones mentioned in the Textbook “Chapter Six ENVIRONMENTAL HEALTH” pp.605-650 In the light of information, detergent surfactant entering the human body in Turkey The limit has been determined as the amount of which will be 1 mg/L at the most. However, in our country Studies have shown that a very high amount of surfactant even in drinking water showed that the amount was present. Therefore, it is biodegradable in our country. The use of detergents is very important.

Deterjanlarin içeriginde bulunan sabun ve yüzey aktif maddeler yikama islemi esnasinda yüzey gerilimini azaltarak, köpük olusturma ve temizleme islemini gerçeklestirirler. Temizleme islemi kisaca; i) Yikanacak maddenin ve kir yüzeyinin yikama çözeltisi (sabun veya deterjan) ile islatilmasi, ii) Kirlerin yüzeyden uzaklastirilmasi, iii) Kirin yikama çözeltisi içerisinde tutulmasi adimlarindan olusur. Washing process of soap and surfactants in detergents It reduces the surface tension during the foaming and cleaning process. they perform. The cleaning process is briefly; i) Washing solution (soap or with detergent), ii) Removal of dirt from the surface, iii) It consists of the steps of keeping the dirt in the washing solution.

Yikama çözeltisini olusturan moleküller hem hidrofilik (suyu seven) hem de hidrofobik (suyu sevmeyen/kiri seven) yapiya sahiptir. Molekülün hidrofobik ucu kir parçacigina yönelerek kiri çepeçevre sararken, hidrofilik olan ucu kir parçacigini kumastan uzaklastirarak yikama çözeltisi içerisine tasir ve kumasa tekrar yapismasini önler. Böylelikle kumas kirlerden tamamen arinmis olur. The molecules that make up the washing solution are both hydrophilic (water-loving) and It has a hydrophobic (water-loving/dirt-loving) structure. hydrophobic end of the molecule while it wraps the dirt all around by aiming at the dirt particle, the hydrophilic end move the particle away from the fabric into the washing solution and prevents it from sticking again. Thus, the fabric is completely free from dirt.

Sabun bazli likit deterjanlarda bazi fiziksel problemler ile karsilasilabilmektedir. Örnegin: fiziksel olarak kararli, uygun viskoziteye sahip veya jellesmeyen bir sivi bilesim hazirlamak oldukça zordur. Bilinen teknikte yer alan, EP1689843B1 referans numarali Avrupa patent dokümaninda, sabun olmayan yüzey aktif madde, yag asidinden elde edilen sabun, parfüm, boya, enzim ve antioksidan maddeden olusan bir likit deterjan formülü beyan edilmistir. Ancak bu teknikte elde edilen likit deterjan formülünde iki haftalik (37°C,de) stabilite süreci sonunda az da olsa faz ayrimi gözlendigi, dolayisiyla formülün kararli olmadigi sonucuna varilmistir. Some physical problems may be encountered in soap-based liquid detergents. For example: a liquid that is physically stable, has the appropriate viscosity, or does not gel It is quite difficult to prepare the composition. prior art, EP1689843B1 non-soap surfactant in the European patent document ref. substance, soap, perfume, dye, enzyme and antioxidant obtained from fatty acids. A liquid detergent formula consisting of substance has been declared. However, in this technique Two-week stability period (at 37°C) in the liquid detergent formula obtained At the end of the study, a little phase separation was observed, so the formula was not stable. conclusion has been reached.

Teknikte yer alan, US9150818B2 referans numarali Birlesik Devletler patent dokümaninda ise çamasir temizleme özelligine sahip olan ve hem sivi hem de kati formda kararli olabilen konsantre bir deterjan formülü gelistirilmistir. Bu bilesimde bor içeren anyonik dolgu maddesi, karbonat ve perkarbonat içeren dolgu maddesi, C6 - C20 karbon sayisina sahip olan karboksilik asitlerden olusan sabun, emulgatör ve enzim kullanilmistir. Dolayisiyla elde edilen nihai ürün katki malzemeleri ve diger ilave bilesenlerle olusturulan bir formülasyona sahip oldugundan, bitkisel ve dogal olan bir ürün degildir. United States patent reference number US9150818B2 on the art In the document, it has laundry cleaning feature and is used for both liquid and solid A concentrated detergent formula that can be stable in form has been developed. This boron-containing anionic filler, carbonate and percarbonate-containing filler, consisting of carboxylic acids having carbon numbers C6 - C20 soap, emulsifier and enzyme were used. Therefore, the final product obtained is additive. It has a formulation created with ingredients and other additional ingredients. It is not a herbal and natural product.

Bulusun Kisa Açiklamasi Bu bulus ile birlikte yikama ve temizleme performansi yüksek, viskozite (300 - 3000 cp) ve jellesme problemi gözlenmeyen, düsük ve yüksek sicakliklarda (5°C - 50°C) fiziksel olarak kararli sabun bazli likit bir deterjan formülü gelistirilmistir. Brief Description of the Invention With this invention, washing and cleaning performance is high, viscosity (300 - 3000 cp) and at low and high temperatures (5°C - 50°C) physically stable soap-based liquid detergent formula has been developed.

Bulusumuz bitkisel yag ve/veya yag asitlerinin kuvvetli ve/veya zayif bir baz ile yüksek pH'da sabunlastirilmasindan sonra olusan dogal sabun formunun kivamlastirici ve selatlayici hammaddeler eklenerek çamasirlarda yikama ve temizlik amaçli kullanilabilen dogal bitkisel sabun bazli sivi deterjan üretilmesi ile Bulus ile elde ve çamasir makinelerinde kullanilabilen mevcut sentetik sivi deterjanlarin yerine kimyasal reaksiyon ile elde edilen sabunun formu sivilastirilarak biyobozunur olan, 5°C - 50°C sicaklik araliklarinda fiziksel olarak kararli olan, 7 - 32 Fransiz Sertligi gibi farkli su sertliklerinde yüksek yikama performansina sahip, bitkisel ve ve dogal olan bir deterjan formülü gelistirilmistir. Our invention is a mixture of vegetable oil and/or fatty acids with a strong and/or weak base. of the natural soap form formed after saponification at high pH. By adding thickening and chelating raw materials, washing and with the production of natural herbal soap-based liquid detergents that can be used for cleaning purposes. With the invention, the existing synthetic liquid that can be used in hand and washing machines the form of soap obtained by chemical reaction instead of detergents biodegradable by liquefying, physically in the temperature range of 5°C to 50°C high wash in different water hardnesses such as 7 - 32 French Hardness, which is stable A herbal and natural detergent formula has been developed.

Bulusun Ayrintili Açiklamasi Bulus konusu sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi, biyobozunur olan, 5°C - 50°C sicaklik araliklarinda fiziksel olarak kararli olan, 7 - 32 Fransiz Sertliginde yüksek yikama performansina sahip, bitkisel olan ve i. bitkisel yag asidi çözeltisi, baz çözeltisi/bazik materyal ve tuz çözeltisinin hazirlanmasi, ii. sabunlasma reaksiyonunun gerçeklestirilmesi için bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin 80°C,de karistirilmasi, iii. bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin karistirilmasiyla olusan çözeltiye kivamlastirici ve selatlayici eklenmesi, iv. ortaya çikan ürünün 35°C,nin altindki sicakliga sogutulmasi adimlarini içermektedir. Detailed Description of the Invention The method of obtaining a soap-based natural liquid detergent, which is the subject of the invention, biodegradable, physically stable in the temperature range of 5°C to 50°C, 7 - 32 French Hardness with high washing performance, herbal and I. vegetable fatty acid solution, base solution/basic material and salt preparation of the solution ii. vegetable fatty acid to carry out the saponification reaction mixing the solution with the base and salt solution at 80°C, iii. vegetable fatty acid solution and base and salt solution thickener and chelator to the solution formed by mixing adding, iv. cooling the resulting product to a temperature below 35°C contains the steps.

Bulusun bir uygulamasinda bitkisel yag asidi çözeltisinde yer alan yag asidi olarak; C8 - C18 arasindaki bitkisel yag asidi zincirlerinin kullanilmaktadir. In one embodiment of the invention, the fatty acid in the vegetable fatty acid solution aspect; Vegetable fatty acid chains between C8 - C18 are used.

Tercihen bu araliktaki yag asitlerinden C12 - C18 arasindaki bitkisel yag asidi zincirlerinin kullanilmaktadir. Bu baglamda, kullanilabilecek olan yag asitleri asitlerinden olusan bir gruptan seçilen en az bir yag asidi bulus kapsaminda kullanilmaktadir. Bunlarin arasindan tercihen bitkisel doymus yag asitlerinden bunlarin karisimlarindan olusan bir gruptan seçilen yag asidi kullanilanilmaktadir. karisiminda kütlece karisim oranlari, sirasiyla: %1,0 - 50,0 araliginda, %1,0 - Kullanilan bir diger karisim olan laun'k asit ve miristik asit karisiminda kütlece olmaktadir. Kullanilan bir diger karisim olan laurik asit ve palmitik asit karisiminda kütlece karisim oranlari, sirasiyla: %10,0 - 30,0 araliginda ve %3,0 - ,0 araliginda olmaktadir. Vegetable fatty acid between C12 - C18, preferably one of the fatty acids in this range chains are used. In this context, the fatty acids that can be used at least one fatty acid selected from a group consisting of acids is used. Among them, preferably vegetable saturated fatty acids fatty acid selected from a group consisting of mixtures of these is used. Mixture ratios by mass in the mixture, respectively: 1.0% - 50.0%, 1.0% - In the mixture of laun'k acid and myristic acid, which is another mixture used, the mass is happening. Lauric acid and palmitic acid, another mixture used Mixture ratios by mass in the mixture, respectively: 10.0% - 30.0% and 3.0% - It is in the range of 0.

Bulusun bir uygulamasinda, potasyum hidroksit (KOH), sodyum hidroksit (NaOH), monoetanolamin (HZNCHZCHZOH), dietanolamin (HN(CH2CH20H)2), trietanolamin (N(CH2CH20H)3), amonyak (NH3) ve bunlarin karisimlarindan olusan bir gruptan seçilen en az biri baz çözeltisi/bazik materyal olarak kullanilmaktadir. tercihen bu bazik materyal olarak potasyum hidroksitin (KOH) kullanilmaktadir. Kullanilan bazik materyal miktariin toplam karisima göre orani Bulusun bir uygulamasinda, tuz çözeltisi olarak, sodyum klorür (NaCl), sodyum sülfat (NaSO4) ve potasyum klorür (KCl) tuzlannin çözeltilerinden en az biri tuz çözeltisi olarak kul]anilmaktadir.Tercihen tuz çözeltisi olarak sodyum klorür (NaCl) kullanilmaktadir. In one embodiment of the invention, potassium hydroxide (KOH), sodium hydroxide (NaOH), monoethanolamine (HZNCHZCHZOH), diethanolamine (HN(CH2CH2OH)2), triethanolamine (N(CH2CH2OH)3), ammonia (NH3) and their mixtures as a base solution/basic material selected from a group consisting of is used. preferably potassium hydroxide (KOH) as this basic material is used. The ratio of the amount of basic material used to the total mixture In one embodiment of the invention, sodium chloride (NaCl) is used as salt solution. At least one of the solutions of sulfate (NaSO4) and potassium chloride (KCl) salts It is used as a solution. Preferably sodium chloride as a salt solution. (NaCl) is used.

Bulusun bir uygulamasinda, kivamlastirici olarak; hidroksietil selüloz, hidroksimetil selüloz, hidroksietilmetil selüloz, hidroksipropil selüloz, hidroksipropil metil selüloz, akrilat kopolimer emülsiyonlari ve diger tüm kivamlastiricilardan arasindan en az biri kullanilmaktadir. Bunlarin arasindan tercihen hidroksietil selüloz kullanilmaktadir. Kivamlastiricinin toplam karisima olmaktadir. In one embodiment of the invention, as a thickener; hydroxyethyl cellulose, hydroxymethyl cellulose, hydroxyethylmethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, acrylate copolymer emulsions and all other At least one of the thickeners is used. Among them preferably hydroxyethyl cellulose is used. Total mixture of thickener is happening.

Bulusun bir uygulamasinda, selatlayici olarak, EDTA türevleri veya tetrasodyum glutamate diasetat selatlayicilarindan en az biri kullanilmaktadir. Tercihen bir EDTA türevi olan tetrasodyum EDTA kullanilmaktadir. In one embodiment of the invention, EDTA derivatives or tetrasodium are used as chelators. At least one of the glutamate diacetate chelators is used. Preferably a Tetrasodium EDTA, which is an EDTA derivative, is used.

Bulusun bir uygulamasinda, “ortaya çikan ürünün sogutulmasi” adimindan sonra, sogutulmus ürüne parfüm ilavesi edilmektedir. Bulusun bir uygulamasinda, renklendirici ilavesi edilmektedir. Bulusun bir uygulamasinda, “ortaya çikan ürünün sogutulmasi” adimindan sonra sogutulmus ürüne ekstrakt ilavesi edilmektedir. In one embodiment of the invention, after the "cooling of the resulting product" step, Perfume is added to the cooled product. In one embodiment of the invention, colorant is added. In one embodiment of the invention, "emerging Addition of extract to the cooled product after the “cooling the product” step is being done.

Bu bulus, amacina ulasmak için gerçeklestirilen sabun bazli dogal sivi deterjan - Kaprilik asit (CgHiöog), kaprik asit (CioHZOOZ), laurik asit (C12H2402), (C13H3002) yag asitlerinin en az biri kullanilarak bir bitkisel yag asidi çözeltisinin ve potasyum hidroksit (KOH), sodyum hidroksit (NaOH), monoetanolamin (H2NCH2CH20H), dietanolamin (HN(CH2CH20H)2), trietanolamin (N(CH2CH20H)3) veya amonyak (NH3) bazlan arasindan seçilen en az biri ile, sodyum klorür (NaCl), sodyum sülfat (NaSO4) ve potasyum klorür (KCl) tuzlarindan en az biri seçilerek bir baz ve tuz sulu çözeltisinin hazirlanmasi, sabunlasma reaksiyonunun gerçeklestirilmesi için bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin 80°C°de karistirilmasi, karistirilan çözeltiye kivamlastirici olarak hidroksietil selüloz, hidroksimetil selüloz, hidroksietilmetil selüloz, hidroksipropil selüloz, hidroksipropil metil selüloz, akrilat kopolimer emülsiyonlari ve diger tüm kivamlastiricilar arasindan seçilen bir veya birkaçi ile, selatlayici olarak EDTA türevleri veya Tetrasodyum Glutamat Diasetat eklenmesi, elde edilen nihai ürünün 35°C,nin altina sogutulmasi, sogutulmus ürün içerisine tercihen parfüm, renklendirici veya ekstrakt gibi bilesenlerin ilavesi edilmesi adimlari ile üretilmektedir. This invention is a soap-based natural liquid detergent realized to achieve its purpose. - Caprylic acid (CgHiog), capric acid (CioHZOOZ), lauric acid (C12H2402), A vegetable fatty acid using at least one of the (C13H3002) fatty acids solution and potassium hydroxide (KOH), sodium hydroxide (NaOH), monoethanolamine (H2NCH2CH2OH), diethanolamine (HN(CH2CH2OH)2), between triethanolamine (N(CH2CH2OH)3) or ammonia (NH3) bases with at least one selected, sodium chloride (NaCl), sodium sulfate (NaSO4) and a base and salt aqueous solution by choosing at least one of the potassium chloride (KCl) salts. preparation of the solution vegetable fatty acid to carry out the saponification reaction mixing the solution of base and salt at 80°C, hydroxyethyl cellulose as a thickener to the stirred solution, hydroxymethyl cellulose, hydroxyethylmethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, acrylate copolymer emulsions and all other with one or more selected among the thickeners, as a chelator Addition of EDTA derivatives or Tetrasodium Glutamate Diacetate, cooling the final product below 35°C, Preferably perfume, colorant or extract into the cooled product. It is produced by the steps of adding components.

Bitkisel yaglarin ve/veya yag asitlerinin yüksek pH degerlerinde (pH 8,0 - 11,0) zayif ve/veya kuvvetli bir haz ile sabunlastinlmasindan sonra olusan dogal sabun formunun kivamlastirici, selatlayici, parfüm, boya ve ekstrakt gibi diger bilesenlerin ilavesi ile çamasir temizliginde elde veya makinada kullanilabilecek dogal bitkisel sabun bazli sivi deterjan üretilmistir. At high pH values of vegetable oils and/or fatty acids (pH 8.0 - 11,0) natural soap formed after saponification with a weak and/or strong taste other forms such as thickener, chelator, perfume, dye and extract. With the addition of components, it can be used by hand or machine for washing laundry. liquid detergent based on natural herbal soap has been produced.

Bulus konusu üretim yöntemi sirasi ile asagidaki basamaklardan olusmaktadir: Bitkisel yag asidi çözeltisinin hazirlanmasi. The production method which is the subject of the invention consists of the following steps, respectively: Preparation of vegetable fatty acid solution.

Ilk adimda belirtilen bitkisel yag asileri tercihen Kaprilik asit (C8H1602), Baz ve tuz çözeltisinin hazirlanmasi. Üçüncü adimda belirtilen baz çözeltisi tercihen Potasyum Hidroksit (KOH), Sodyum Hidroksit (NaOH), Monoethanolamin (H2NCH2CH20H), Diethanolamin (HN(CH2CH20H)2), Triethanolamin (N(CH2CH20H)3), Amonyak (NH3),dir. Tuz çözeltisi tercihen: Sodyum Klorür (NaCl), Sodyum Sülfat (NaSO4), Potasyum Klorür (KCl),dir. Vegetable oil vaccines mentioned in the first step preferably Caprylic acid (C8H1602), Preparation of base and salt solution. The base solution specified in the third step is preferably Potassium Hydroxide (KOH), Sodium Hydroxide (NaOH), Monoethanolamine (H2NCH2CH2OH), Diethanolamine (HN(CH2CH2OH)2), Triethanolamine (N(CH2CH2OH)3), Ammonia (NH3). Salt solution preferably: Sodium Chloride (NaCl), Sodium Sulphate (NaSO4), Potassium Chloride (KCl).

Bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin 80°C,de karistirilmasi ile sabunlasma reaksiyonunun gerçeklestirilmesi. Mixing the vegetable fatty acid solution with the base and salt solution at 80°C carrying out the saponification reaction with

Kivamlastirici ve selatlayici ajanlarin ilavesi. Addition of thickening and chelating agents.

Altinci adimda belirtilen kivamlastincilar tercihen Hidroksietil Selüloz, Hidroksimetil Selüloz, Hidroksietilmetil Selüloz, Hidroksipropil Selüloz, Hidroksipropil Metil Selüloz, Akrilat Kopolimer Emülsiyonlari ve diger tüm kivamlastiricilardir. Selatlayici olarak tercihen EDTA türevleri, Tetrasodyum Glutamat Diasetafdir. The thickeners mentioned in the sixth step are preferably Hydroxyethyl Cellulose, Hydroxymethyl Cellulose, Hydroxyethylmethyl Cellulose, Hydroxypropyl Cellulose, Hydroxypropyl Methyl Cellulose, Acrylate Copolymer Emulsions and other all thickeners. Preferably EDTA derivatives as chelators, Tetrasodium Glutamate Diacetaph.

Bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisi kansimina kivamlastirici ve selatlayici ajanlarin ilave edilmesi. Thickening of the mixture of vegetable fatty acid solution and base and salt solution and adding chelating agents.

Nihai formülün sogutularak içerisine parfüm, boya, ekstrakt gibi diger SABUN BAZLI DOGAL BIR SIVI DETERJAN ELDE EDILMESI YÖNTEMI VE BU YÖNTEMLE ELDE EDILEN SABUN BAZLI DOGAL BIR SIVI DETERJAN Bu bulus ile, bitkisel yag asitlerinin yüksek leda bir zayif ve/veya kuvvetli bir baz ile sabunlastirilmasindan sonra olusan dogal sabun formunun kivamlastirici, selatlayici hammaddeler, parfüm, boya ve ekstrakt gibi diger bilesenlerin ilavesi ile sentetik sivi deterjanlarin yerine çamasir temizliginde elde veya makinada kullanilabilecek, düsük ve yüksek sicakliklarda fiziksel olarak kararli, viskozite ve jellesme problemi gözlenmeyen, yikama ve temizleme performansi yüksek, insan ve çevre dostu olan, dogal bitkisel sabun bazli sivi deterjan formülü gelistirilmistir. The final formula is cooled and mixed with other substances such as perfume, paint, extract. OBTAINING A NATURAL SOAP BASED LIQUID DETERGENT METHOD AND SOAP BASED NATURAL OBTAINED BY THIS METHOD A LIQUID DETERGENT With this invention, it has been determined that vegetable fatty acids have a weak and/or strong thickener of the natural soap form formed after saponification with a base, Addition of other ingredients such as chelating raw materials, perfume, dye and extract It can be used for washing laundry by hand or in the machine instead of synthetic liquid detergents. Physically stable at low and high temperatures, viscosity and no gelling problem, high washing and cleaning performance, and environmentally friendly, natural herbal soap-based liquid detergent formula developed.

Claims (2)

ISTEMLER 1. Biyobozunur olan, 5°C - 50°C sicaklik araliklarinda fiziksel olarak kararli olan, 7 - 32 Fransiz Sertliginde yüksek yikama performansina sahip, bitkisel olan ve i. bitkisel yag asidi çözeltisi, baz çözeltisi/bazik materyal ve tuz çözeltisinin hazirlanmasi, ii. sabunlasma reaksiyonunun gerçeklestirilmesi için bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin 80°C7de karistirilmasi, iii. bitkisel yag asidi çözeltisi ile baz ve tuz çözeltisinin karistirilmasiyla olusan çözeltiye kivamlastirici ve selatlayici eklenmesi iv. ortaya çikan ürünün 35°C5nin altindki sicakliga sogutulmasi adimlari ile sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. REQUIREMENTS 1. Biodegradable, physically stable in the temperature range of 5°C - 50°C, having high washing performance at 7 - 32 French Hardness, vegetal and i. preparation of vegetable fatty acid solution, base solution/basic material and salt solution, ii. mixing the vegetable fatty acid solution with the base and salt solution at 80°C to carry out the saponification reaction, iii. Adding a thickener and chelator to the solution formed by mixing the vegetable fatty acid solution with the base and salt solution iv. The method of obtaining a soap-based natural liquid detergent by the steps of cooling the resulting product to a temperature below 35°C. 2. Bitkisel yag asidi çözeltisinde yer alan yag asidi olarak; C8 - C18 arasindaki bitkisel yag asidi zincirlerinin kullanildigi Istem l,deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. . Bitkisel yag asidi çözeltisinde yer alan yag asidi olarak; Cl2 - C18 arasindaki bitkisel yag asidi zincirlerinin kullanildigi Istem 2,deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. . Bitkisel yag asidi çözeltisinde yer alan yag asidi olarak; kaprilik asit (C, miristik asit asitlerinden ve bunlarin kansimlarindan olusan bir gruptan seçilen en az bir yag asidinin kullanildigi Istem 1 ve 2adeki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Bitkisel yag asidi çözeltisinde yer alan yag asidi olarak; bitkisel doymus asit (C16H3202) ve bunlarin karisismindan olusan bir gruptan seçilen en az biri yag asidinin kullanildigi Istem 43deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Bitkisel doymus yag asitlerinden laurik asit oraninin kütlece %1,0 - 50,0 araliginda, miristik asit oraninin kütlece %l,0 - 20,0 araliginda ve palmitik asit oraninin kütlece %1,0 - 20,0 araliginda oldugu bir karisimin kullanildigi Istem 5°teki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Bitkisel doymus yag asitlerinden laurik asit oraninin kütlece %5,0 - 40,0 araliginda, miristik asit oraninin kütlece %3,0 - 15,0 araliginda ve palmitik asit oraninin kütlece %3,0 - 10,0 araliginda oldugu bir karisimin kullanildigi Istem 6,daki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Bitkisel doymus yag asitlerinden laurik asit oraninin kütlece %10,0 - 30,0 araliginda, miristik asit oraninin kütlece %3,0 - 10,0 araliginda ve palmitik asit oraninin kütlece %4,0 - 8,0 araliginda oldugu bir karisimin kullanildigi Istem 7,deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Bitkisel doymus yag asitlerinden laurik asit oraninin kütlece %10,0 - 30,0 araliginda, miristik asit oraninin kütlece %3,0 - 10,0 araliginda oldugu Istem 5,teki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Bitkisel doymus yag asitlerinden laurik asit oraninin kütlece %10,0 - 30,0 araliginda, palmitik asit oraninin kütlece %3,0 - 10,0 araliginda oldugu Istem 5,teki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Potasyum hidroksit (KOH), sodyum hidroksit (NaOH), monoetanolamin (H2NCH2CH20H), dietanolamin (HN(CH2CH20H)2), trietanolamin (N(CH2CH20H)3) veya amonyak (NH3) bazlari arasindan seçilen en az birinin baz çözeltisi/balik materyal olarak kullanildigi Istem 1,deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Bazik materyal olarak potasyum hidroksitin (KOH) kullanildigi Istem ”deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Bazik materyal miktarinin kütlece %l,0 - 30,0 oranlari araliginda oldugu Istem 1 veya 12,deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Bazik materyal miktarinin kütlece %5,0 - 20,0 oranlari araliginda oldugu Istem 13,deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Bazik materyal miktarinin kütlece %7,0 - 10,0 oranlari araliginda oldugu Istem l4”deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Sodyum klorür (NaCl), sodyum sülfat (NaSO4) ve potasyum klorür (KCl) tuz çözeltileri arasindan en az birinin tuz çözeltisi olarak kullanildigi Istem l,deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Tuz çözeltisi olarak sodyum klorür (NaCl) tuz çözeltisinin kullanildigi Istem 165daki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Kivamlastirici olarak; hidroksietil selüloz, hidroksimetil selüloz, hidroksietilmetil selüloz, hidroksipropil selüloz, hidroksipropil metil selüloz, akrilat kopolimer emülsiyonlari ve diger tüm kivamlastiricilar arasindan en az birinin kullanildigi Istem l”deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Kivamlastirici olarak hidroksietil selülozun kullanildigi Istem l8'deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Kivamlastirici miktarinin kütlece %0,001 - 10,0 araliginda oldugu Istem 1 ve Istem 19,daki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Kivamlastirici miktarinin kütlece %0,01 - 5,0 araliginda oldugu Istem 20,deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. EDTA türevleri veya tetrasodyum glutamate diasetat selatlayicilarindan en az birinin selatlayici olarak kullanildigi Istem l”deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. Selatlayici olarak tetrasodyum EDTA°nin kullanildigi Istem 22ldeki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. parfüm ilavesi edilmesi adimini içeren Istem lldeki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. renklendirici ilavesi edilmesi adimini içeren Istem 1,deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. 26. “ortaya çikan ürünün sogutulmasi” adimindan sonra sogutulmus ürüne ekstrakt ilavesi edilmesi adimini içeren Istem 1,deki gibi sabun bazli dogal bir sivi deterjan elde edilmesi yöntemi. 5 27. Yukaridaki istemlerden herhangi birindeki gibi bir yöntemle elde edilen ve biyobozunur, 5°C - 50°C sicaklik araliklarinda fiziksel olarak kararli olan ve 7 - 32 Fransiz Sertliginde yüksek yikama performansina sahip bir sabun bazli dogal bir sivi deterjan.2. As the fatty acid in the vegetable fatty acid solution; The method of obtaining a soap-based natural liquid detergent as in claim 1, in which vegetable fatty acid chains between C8 - C18 are used. . As the fatty acid in the vegetable fatty acid solution; The method of obtaining a soap-based natural liquid detergent as in Claim 2, in which vegetable fatty acid chains between Cl2 - C18 are used. . As the fatty acid in the vegetable fatty acid solution; Caprylic acid (C, method of obtaining a soap-based natural liquid detergent as in Claims 1 and 2, in which at least one fatty acid selected from a group consisting of myristic acid acids and their mixtures is used. As the fatty acid in the vegetable fatty acid solution; vegetable saturated acid ( C16H3202) and at least one fatty acid selected from a mixture of these, is used as a method of obtaining a soap-based natural liquid detergent as in claim 43. The ratio of lauric acid, by mass, of vegetable saturated fatty acids, is between 1.0 - 50.0 by mass, the ratio of myristic acid by mass Method of obtaining a soap-based natural liquid detergent as in claim 5, using a mixture in the range of 1.0 - 20.0% and palmitic acid in the range of 1.0 - 20.0% by mass. A mixture in which the ratio of myristic acid is between 3.0% and 15.0% by mass, and the ratio of palmitic acid is between 3.0% and 10.0% by mass. The method of obtaining a soap-based natural liquid detergent as in Claim 6, where it is used. Claim that a mixture of vegetable saturated fatty acids with a ratio of lauric acid in the range of 10.0 - 30.0 mass%, myristic acid ratio in the range of 3.0 - 10.0% by mass and palmitic acid ratio in the range of 4.0 - 8.0% by mass is used. Method of obtaining a soap-based natural liquid detergent as in Figure 7. The method of obtaining a soap-based natural liquid detergent as in Claim 5, where the ratio of lauric acid from vegetable saturated fatty acids is between 10.0 - 30.0% by mass, and the ratio of myristic acid is between 3.0 - 10.0% by mass. The method of obtaining a soap-based natural liquid detergent as in Claim 5, where the ratio of lauric acid from vegetable saturated fatty acids is between 10.0 - 30.0% by mass, and the ratio of palmitic acid is between 3.0 - 10.0% by mass. Base solution/fish material of at least one selected from potassium hydroxide (KOH), sodium hydroxide (NaOH), monoethanolamine (H2NCH2CH2OH), diethanolamine (HN(CH2CH2OH)2), triethanolamine (N(CH2CH20H)3) or ammonia (NH3) bases The method of obtaining a soap-based natural liquid detergent as in Claim 1, where it is used as The method of obtaining a soap-based natural liquid detergent as in Claim where potassium hydroxide (KOH) is used as the basic material. The method of obtaining a soap-based natural liquid detergent as in claim 1 or 12, where the amount of basic material is between 1.0% and 30.0% by mass. The method of obtaining a soap-based natural liquid detergent as in Claim 13, where the amount of basic material is in the range of 5.0% - 20.0% by mass. The method of obtaining a soap-based natural liquid detergent as in Claim 14, where the amount of basic material is in the range of 7.0 - 10.0% by mass. The method of obtaining a soap-based natural liquid detergent as in Claim 1, where at least one of the sodium chloride (NaCl), sodium sulfate (NaSO4) and potassium chloride (KCl) salt solutions is used as the salt solution. The method of obtaining a soap-based natural liquid detergent as in Claim 165, in which sodium chloride (NaCl) salt solution is used as the salt solution. As a thickener; The method of obtaining a soap-based natural liquid detergent as in Claim 1, where at least one of hydroxyethyl cellulose, hydroxymethyl cellulose, hydroxyethylmethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, acrylate copolymer emulsions and all other thickeners is used. The method of obtaining a soap-based natural liquid detergent as in claim 18, in which hydroxyethyl cellulose is used as the thickener. The method of obtaining a soap-based natural liquid detergent as in Claim 1 and Claim 19, where the amount of thickener is in the range of 0.001% - 10.0% by mass. The method of obtaining a soap-based natural liquid detergent as in Claim 20, where the amount of thickener is in the range of 0.01 - 5.0% by mass. The method of obtaining a soap-based natural liquid detergent as in claim 1, in which at least one of EDTA derivatives or tetrasodium glutamate diacetate chelators is used as a chelator. The method of obtaining a soap-based natural liquid detergent as in claim 22, in which tetrasodium EDTA is used as a chelator. The method of obtaining a soap-based natural liquid detergent as in claim 11, which includes the step of adding perfume. The method of obtaining a soap-based natural liquid detergent as in Claim 1, which includes the step of adding colorant. 26. The method of obtaining a soap-based natural liquid detergent as in Claim 1, which includes the step of adding the extract to the cooled product after the step of “cooling the resulting product”. 5 27. A soap-based natural liquid detergent obtained by a method according to any one of the above claims, which is biodegradable, physically stable in the temperature range of 5°C to 50°C, and has high washing performance at a French Hardness of 7 - 32.
TR2017/13191A 2017-09-07 2017-09-07 A SOAP-BASED NATURAL LIQUID DETERGENT METHOD AND A NATURAL SOAP-BASED LIQUID DETERGENT OBTAINED BY THIS METHOD TR201713191A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
TR2017/13191A TR201713191A2 (en) 2017-09-07 2017-09-07 A SOAP-BASED NATURAL LIQUID DETERGENT METHOD AND A NATURAL SOAP-BASED LIQUID DETERGENT OBTAINED BY THIS METHOD
PCT/TR2018/050469 WO2019125336A2 (en) 2017-09-07 2018-09-06 A method for obtaining a soap based natural liquid detergent and a soap based natural liquid detergent obtained with thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TR2017/13191A TR201713191A2 (en) 2017-09-07 2017-09-07 A SOAP-BASED NATURAL LIQUID DETERGENT METHOD AND A NATURAL SOAP-BASED LIQUID DETERGENT OBTAINED BY THIS METHOD

Publications (1)

Publication Number Publication Date
TR201713191A2 true TR201713191A2 (en) 2017-12-21

Family

ID=66992764

Family Applications (1)

Application Number Title Priority Date Filing Date
TR2017/13191A TR201713191A2 (en) 2017-09-07 2017-09-07 A SOAP-BASED NATURAL LIQUID DETERGENT METHOD AND A NATURAL SOAP-BASED LIQUID DETERGENT OBTAINED BY THIS METHOD

Country Status (2)

Country Link
TR (1) TR201713191A2 (en)
WO (1) WO2019125336A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112708645A (en) * 2020-11-04 2021-04-27 呼伦贝尔东北阜丰生物科技有限公司 Method for efficiently producing monosodium glutamate

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3910974A1 (en) * 1989-04-05 1990-10-11 Henkel Kgaa Liquid detergent
GB9216570D0 (en) * 1992-08-01 1992-09-16 Cussons Int Ltd Liquid detergent composition
DE102004040849A1 (en) * 2004-08-23 2006-03-02 Henkel Kgaa Clear washing and cleaning agent with yield point
JP2011521083A (en) * 2008-05-28 2011-07-21 ザ プロクター アンド ギャンブル カンパニー Fabric softening laundry detergent with good stability
KR20130058531A (en) * 2011-11-25 2013-06-04 애경산업(주) Dishwashing liquid detergent composition
JP6612528B2 (en) * 2015-05-27 2019-11-27 関西酵素株式会社 Liquid cleaning fee

Also Published As

Publication number Publication date
WO2019125336A3 (en) 2019-07-25
WO2019125336A2 (en) 2019-06-27

Similar Documents

Publication Publication Date Title
CN101517060B (en) Structured surfactant system
JP6956346B2 (en) Gel-like cleaning agent
CN106047505A (en) Natural-formulation multi-effect cleaning composition and application thereof
CN105802757B (en) Assign the detergent composition method that viscosity small range changes within the scope of extensive temperature and detergent composition
CN101035889A (en) Low pH structured surfactant compositions
US10793808B2 (en) Potassium soaps that can be thickened with chloride salts
CN108471742A (en) Treatment compositions providing antimicrobial benefits
CN103202781A (en) Cream body bath composition and application thereof
CN105368598A (en) Tea saponin washing powder
JP6564365B2 (en) Hair treatment composition
TR201713191A2 (en) A SOAP-BASED NATURAL LIQUID DETERGENT METHOD AND A NATURAL SOAP-BASED LIQUID DETERGENT OBTAINED BY THIS METHOD
PL178798B1 (en) Intensely foaming detergent agent based on a non-ionic surfactant
CN111690471B (en) High-concentration laundry detergent without gel and precipitation and preparation method thereof
JP2019073571A (en) Liquid detergent composition for garments
CN103232097A (en) Composite preparation for increasing dissolved oxygen content in pond culture water body
WO2017046285A1 (en) Water-soluble receptacle comprising a coating
PT101540B (en) LIQUID DETERGENT BASED ON A HIGH-SPEED POWER MAO ION-ACTIVE AGENT.
WO2019199255A2 (en) Developing natural soap based antibacterial liquid soap formula
WO2017050821A1 (en) Surfactant-containing composition for the treatment of textiles with a dye
CN102827702A (en) Washing agent
WO2018081430A1 (en) Amino acid based amphoteric surfactant
CN107855073A (en) Biological environmental production surfactant and preparation method thereof
CN113355175A (en) Trace efficient laundry detergent and preparation method thereof
JP4150918B2 (en) Liquid detergent composition
CN108441340B (en) A kind of green environmental protection household cleaning agent and preparation method thereof