TR201901305T4 - Bir metalosen katalizli polietilen reçinesi içeren boru. - Google Patents

Bir metalosen katalizli polietilen reçinesi içeren boru. Download PDF

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Publication number
TR201901305T4
TR201901305T4 TR2019/01305T TR201901305T TR201901305T4 TR 201901305 T4 TR201901305 T4 TR 201901305T4 TR 2019/01305 T TR2019/01305 T TR 2019/01305T TR 201901305 T TR201901305 T TR 201901305T TR 201901305 T4 TR201901305 T4 TR 201901305T4
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Turkey
Prior art keywords
polyethylene resin
fraction
metallocene catalyzed
iso
load
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TR2019/01305T
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English (en)
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Lhost Olivier
Michel Jacques
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Total Res & Technology Feluy
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Application filed by Total Res & Technology Feluy filed Critical Total Res & Technology Feluy
Publication of TR201901305T4 publication Critical patent/TR201901305T4/tr

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/12Rigid pipes of plastics with or without reinforcement
    • F16L9/127Rigid pipes of plastics with or without reinforcement the walls consisting of a single layer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/05Bimodal or multimodal molecular weight distribution
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18Bulk density
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00Chemical blending or stepwise polymerisation process with the same catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

Mevcut buluş, en az bir metalosen katalizli polietilen reçinesi içeren bir boru ile ilgili olup, burada polietilen reçinesi, bir multimodal molekül ağırlığı dağılımına sahiptir ve en az iki metalosen katalizli polietilen fraksiyonları A ve B'yi içerir, burada A ve B fraksiyonları, en az iki seri bağlantılı reaktörlü farklı reaktörlerde hazırlanır, burada polietilen reçinesi şunları ihtiva eder: polietilen reçinesinin toplam ağırlığına göre, ağırlıkça en az %30 ve ağırlıkça en fazla %50 polietilen fraksiyonu A, tercihen burada A fraksiyonu, ISO 1133:1997, şart D'ye uygun olarak fraksiyon A'nın döküntüsü üzerinde 190 °C'lik bir sıcaklıkta ve 2,16 kg'lık bir yük altında belirlenen şekilde en az 50 g/10 dk'lık bir MI2 erime endeksine sahiptir; burada B fraksiyonu, en fazla 0,9210 g/cm3'lük bir yoğunluğa sahiptir; ve burada polietilen reçinesi, 190 °C'de ve 5 kg'lık bir yük altında, ISO 1133:1997, şart T'ye uygun olarak belirlenen şekilde en az 0,10 g/10 dk ve en fazla 1,0 g/10 dk'lık bir MI5 erime endeksine sahiptir; burada polietilen reçinesi, 190 °C'lik bir sıcaklıkta ve 21,6 kg'lık bir yük ile ISO 1133:1997, şart G'nin prosedürüne uygun olarak ölçülen şekilde en az 4,0 g/10 dk ve en fazla 14,0 g/10 dk'lık bir HLMI'ye; ve 23 °C'lik bir sıcaklıkta ASTM D-1505'in prosedürüne göre belirlenen şekilde en az 0,9420 g/cm3 ve en fazla 0,9460 g/cm3'lük bir yoğunluğa sahiptir.
TR2019/01305T 2014-04-23 2015-04-23 Bir metalosen katalizli polietilen reçinesi içeren boru. TR201901305T4 (tr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP14165701 2014-04-23

Publications (1)

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TR201901305T4 true TR201901305T4 (tr) 2019-02-21

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ID=50687258

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TR2019/01305T TR201901305T4 (tr) 2014-04-23 2015-04-23 Bir metalosen katalizli polietilen reçinesi içeren boru.

Country Status (18)

Country Link
US (1) US9932427B2 (tr)
EP (1) EP3077714B1 (tr)
JP (1) JP6517837B2 (tr)
KR (1) KR102350401B1 (tr)
CN (1) CN106459289B (tr)
AU (1) AU2015250852B2 (tr)
BR (1) BR112016024693B1 (tr)
CA (1) CA2946458A1 (tr)
EA (1) EA031372B1 (tr)
ES (1) ES2710671T3 (tr)
MX (1) MX2016013874A (tr)
MY (1) MY175713A (tr)
PH (1) PH12016502069B1 (tr)
PL (1) PL3077714T3 (tr)
SA (1) SA516380121B1 (tr)
SG (1) SG11201608689SA (tr)
TR (1) TR201901305T4 (tr)
WO (1) WO2015162212A1 (tr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2640045C1 (ru) 2014-10-13 2017-12-26 ЭлДжи КЕМ, ЛТД. Сополимер этилен/1-гексен или этилен/1-бутен, обладающий отличными технологическими свойствами и сопротивлением разрастанию трещин под действием факторов окружающей среды
GB2533770B (en) 2014-12-22 2021-02-10 Norner Verdandi As Polyethylene for pipes
JP6702731B2 (ja) * 2016-01-20 2020-06-03 旭化成株式会社 エチレン−α−オレフィン共重合体
KR20180137002A (ko) * 2016-04-26 2018-12-26 토탈 리서치 앤드 테크놀로지 펠루이 나노입자를 포함하는 폴리올레핀 조성물
WO2019068882A1 (en) * 2017-10-06 2019-04-11 Total Research & Technology Feluy POLYETHYLENE CONDUCTIVE MULTILAYER PIPES AND PROCESS FOR PRODUCING THE SAME
KR102203007B1 (ko) * 2019-06-05 2021-01-14 대림산업 주식회사 다단계 연속 중합 방법을 이용한 멀티모달 폴리올레핀 제조방법
US12612473B2 (en) 2019-10-07 2026-04-28 Lg Chem, Ltd. Polyethylene and its chlorinated polyethylene
EP4063451A4 (en) * 2020-08-19 2023-11-22 Lg Chem, Ltd. PELLET-TYPE POLYETHYLENE RESIN COMPOSITION, AND PREPARATION METHOD THEREFOR
CN116789882A (zh) * 2023-05-19 2023-09-22 中沙(天津)石化有限公司 一种基于双环管淤浆相聚乙烯工艺生产茂金属树脂的生产方法
WO2025104234A1 (en) * 2023-11-15 2025-05-22 Borealis Ag Polyethylene compositions

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Also Published As

Publication number Publication date
PH12016502069A1 (en) 2017-01-09
KR102350401B1 (ko) 2022-01-11
MX2016013874A (es) 2017-05-12
CN106459289B (zh) 2019-08-02
EA031372B1 (ru) 2018-12-28
EA201691948A1 (ru) 2017-02-28
JP6517837B2 (ja) 2019-05-22
KR20160147888A (ko) 2016-12-23
US20170058063A1 (en) 2017-03-02
CA2946458A1 (en) 2015-10-29
EP3077714B1 (en) 2018-11-14
PH12016502069B1 (en) 2017-01-09
CN106459289A (zh) 2017-02-22
MY175713A (en) 2020-07-06
BR112016024693A2 (pt) 2017-08-15
EP3077714A1 (en) 2016-10-12
US9932427B2 (en) 2018-04-03
JP2017519946A (ja) 2017-07-20
AU2015250852B2 (en) 2017-12-07
ES2710671T3 (es) 2019-04-26
SA516380121B1 (ar) 2021-03-11
WO2015162212A1 (en) 2015-10-29
SG11201608689SA (en) 2016-11-29
PL3077714T3 (pl) 2019-04-30
BR112016024693B1 (pt) 2021-05-25
AU2015250852A1 (en) 2016-11-17

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