TW200418558A - Process for the production of a porous cellulosic body - Google Patents

Process for the production of a porous cellulosic body Download PDF

Info

Publication number: TW200418558A
Authority: TW; Taiwan
Prior art keywords: cellulose; aqueous medium; porous; patent application; medium
Prior art date: 2003-01-20

Application number

TW093101667A

Other languages

English (en)

Chinese (zh)

Inventor

Heinrich Firgo

Hartmut Ruf

Karl Michael Hainbucher

Hedda Weber

Original Assignee

Chemiefaser Lenzing Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2003-01-20

Filing date

2004-01-20

Publication date

2004-10-01

2004-01-20 Application filed by Chemiefaser Lenzing Ag filed Critical Chemiefaser Lenzing Ag

2004-10-01 Publication of TW200418558A publication Critical patent/TW200418558A/zh

Links

238000000034 method Methods 0.000 title claims abstract description 36
238000004519 manufacturing process Methods 0.000 title abstract description 3
229920002678 cellulose Polymers 0.000 claims abstract description 100
239000001913 cellulose Substances 0.000 claims abstract description 100
239000002904 solvent Substances 0.000 claims abstract description 28
239000012736 aqueous medium Substances 0.000 claims abstract description 26
239000002609 medium Substances 0.000 claims abstract description 13
150000003512 tertiary amines Chemical class 0.000 claims abstract description 13
239000007788 liquid Substances 0.000 claims abstract description 6
238000006116 polymerization reaction Methods 0.000 claims abstract description 5
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 18
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
229910002092 carbon dioxide Inorganic materials 0.000 claims description 12
239000002245 particle Substances 0.000 claims description 11
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
239000001569 carbon dioxide Substances 0.000 claims description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
239000001257 hydrogen Substances 0.000 claims description 4
238000009413 insulation Methods 0.000 claims description 4
239000000463 material Substances 0.000 claims description 4
238000005406 washing Methods 0.000 claims description 4
150000001412 amines Chemical class 0.000 claims description 3
239000007789 gas Substances 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 2
239000003989 dielectric material Substances 0.000 claims description 2
239000007772 electrode material Substances 0.000 claims description 2
239000000446 fuel Substances 0.000 claims description 2
239000000843 powder Substances 0.000 claims description 2
238000000197 pyrolysis Methods 0.000 claims description 2
239000000243 solution Substances 0.000 claims 4
239000000969 carrier Substances 0.000 claims 2
239000000126 substance Substances 0.000 claims 2
239000003054 catalyst Substances 0.000 claims 1
238000010586 diagram Methods 0.000 claims 1
239000011810 insulating material Substances 0.000 claims 1
239000012457 nonaqueous media Substances 0.000 claims 1
238000007254 oxidation reaction Methods 0.000 claims 1
LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 abstract description 5
230000001376 precipitating effect Effects 0.000 abstract description 4
239000011324 bead Substances 0.000 description 16
238000001035 drying Methods 0.000 description 11
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
239000004964 aerogel Substances 0.000 description 10
239000011148 porous material Substances 0.000 description 9
239000000499 gel Substances 0.000 description 8
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000003960 organic solvent Substances 0.000 description 6
229920000297 Rayon Polymers 0.000 description 4
239000012530 fluid Substances 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
238000000352 supercritical drying Methods 0.000 description 4
239000002270 dispersing agent Substances 0.000 description 3
238000005516 engineering process Methods 0.000 description 3
239000000203 mixture Substances 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
239000004966 Carbon aerogel Substances 0.000 description 2
229920002301 cellulose acetate Polymers 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
239000000835 fiber Substances 0.000 description 2
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
239000008188 pellet Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
235000011121 sodium hydroxide Nutrition 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000007711 solidification Methods 0.000 description 2
LHHLBUGXFMVKRO-UHFFFAOYSA-N 4-oxido-4-propylmorpholin-4-ium Chemical compound CCC[N+]1([O-])CCOCC1 LHHLBUGXFMVKRO-UHFFFAOYSA-N 0.000 description 1
GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
238000004026 adhesive bonding Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
GNHQSAUHXKRQMC-UHFFFAOYSA-N benzene;chlorine Chemical compound [Cl].C1=CC=CC=C1 GNHQSAUHXKRQMC-UHFFFAOYSA-N 0.000 description 1
239000002041 carbon nanotube Substances 0.000 description 1
229910021393 carbon nanotube Inorganic materials 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000010411 cooking Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
230000001351 cycling effect Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000003028 elevating effect Effects 0.000 description 1
ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000004880 explosion Methods 0.000 description 1
WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
239000003292 glue Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000011796 hollow space material Substances 0.000 description 1
239000004434 industrial solvent Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000012774 insulation material Substances 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
238000000465 moulding Methods 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
230000005693 optoelectronics Effects 0.000 description 1
229920006122 polyamide resin Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000000746 purification Methods 0.000 description 1
229910052704 radon Inorganic materials 0.000 description 1
SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000010802 sludge Substances 0.000 description 1
230000008023 solidification Effects 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
239000011240 wet gel Substances 0.000 description 1
229920001285 xanthan gum Polymers 0.000 description 1
239000012991 xanthate Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
- C08J2201/054—Precipitating the polymer by adding a non-solvent or a different solvent
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/08—Supercritical fluid
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2301/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Processes Of Treating Macromolecular Substances (AREA)

TW093101667A 2003-01-20 2004-01-20 Process for the production of a porous cellulosic body TW200418558A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
AT0007103A AT412404B (de)	2003-01-20	2003-01-20	Verfahren zur herstellung eines porösen cellulosischen körpers

Publications (1)

Publication Number	Publication Date
TW200418558A true TW200418558A (en)	2004-10-01

Family

ID=32686600

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW093101667A TW200418558A (en)	2003-01-20	2004-01-20	Process for the production of a porous cellulosic body

Country Status (4)

Country	Link
EP (1)	EP1585772A1 (de)
AT (1)	AT412404B (de)
TW (1)	TW200418558A (de)
WO (1)	WO2004065424A1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102006049179B4 (de) *	2006-10-18	2016-07-07	Deutsches Zentrum für Luft- und Raumfahrt e.V.	Aerogelfasern, Verfahren zu deren Herstellung sowie deren Verwendung
DE102010011808A1 (de)	2010-03-18	2011-11-17	Blue Globe Energy Gmbh	Poröser Cellulose-Festkörper, dessen Herstellung und Verwendung als Zellwachstumssubstrat
DE102013111459A1 (de) *	2013-10-17	2015-04-23	Elringklinger Ag	Akustisch wirksame Abschirmteile und Abdeckungen

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3553132A (en) *	1968-02-26	1971-01-05	Celanese Corp	Heat and flame resistant pyrolyzed cellular material and process of making same
SE434848B (sv) *	1976-04-22	1984-08-20	Purdue Research Foundation	Forfaringssett for framstellning av porosa cellulosaperlor
US5169687A (en) *	1988-09-16	1992-12-08	University Of South Florida	Supercritical fluid-aided treatment of porous materials
NZ336994A (en) *	1997-12-14	2001-08-31	Thuringisches Inst Fur Textil	Method for producing regular porous cellulose pearls with particle size 2 and 50 micrometers
DE19755353C1 (de) *	1997-12-14	1999-04-29	Thueringisches Inst Textil	Verfahren zur Herstellung regulärer, poröser Perlcellulosen und ihre Verwendung
DE10102334C2 (de) *	2001-01-19	2003-12-04	Thueringisches Inst Textil	Verfahren zur Herstellung von regulären, monodispersen Celluloseperlen und ihre Verwendung

2003
- 2003-01-20 AT AT0007103A patent/AT412404B/de not_active IP Right Cessation
2004
- 2004-01-19 WO PCT/AT2004/000013 patent/WO2004065424A1/de not_active Ceased
- 2004-01-19 EP EP04703120A patent/EP1585772A1/de not_active Withdrawn
- 2004-01-20 TW TW093101667A patent/TW200418558A/zh unknown

Also Published As

Publication number	Publication date
ATA712003A (de)	2004-07-15
EP1585772A1 (de)	2005-10-19
WO2004065424A1 (de)	2004-08-05
AT412404B (de)	2005-02-25

Publication	Publication Date	Title
Liu et al.	2021	Binder-free 3D printing of covalent organic framework (COF) monoliths for CO2 adsorption
Chen et al.	2019	Anisotropic nanocellulose aerogels with ordered structures fabricated by directional freeze-drying for fast liquid transport
Cheng et al.	2022	General suspended printing strategy toward programmatically spatial Kevlar aerogels
KR101963139B1 (ko)	2019-03-28	탄소 에어로겔의 제조 방법 및 이에 의하여 제조된 탄소 에어로겔
Yu et al.	2016	Polymerization under hypersaline conditions: a robust route to phenolic polymer‐derived carbon aerogels
CN108840656B (zh)	2021-02-09	一种基于静电纺SiO2纳米纤维气凝胶隔热材料及其制备和应用
CN105017555B (zh)	2018-10-02	一种纤维素气凝胶及其杂化气凝胶的制备方法
CN105174246B (zh)	2017-06-27	一种毫米级多级孔碳球的制备方法
CN105289433B (zh)	2017-07-04	一种规模化制备过渡金属氧化物多孔微球的方法
CN102745670B (zh)	2014-10-08	三维有序大孔复合材料的制备方法
CN102417606A (zh)	2012-04-18	一种甲壳素气凝胶的制备方法
WO2014015709A1 (zh)	2014-01-30	高密度高硬度石墨烯多孔炭材料及其制备方法和应用
CN108715444B (zh)	2020-02-04	一种超疏水氧化硅杂化石墨烯气凝胶微粉、制法及其应用
CN104876638B (zh)	2017-03-01	一种纳米级多孔陶瓷用造孔剂及其制备方法和应用
CN106587006B (zh)	2019-01-22	一种基于纤维素纳米晶制备碳纳米棒的方法
CN108686697A (zh)	2018-10-23	一种藻酸盐基复合氮化碳光催化气凝胶材料及其制备方法与应用
CN108190853B (zh)	2021-03-26	一种蜂窝状泡沫壁空心炭球的制备方法
CN107915216A (zh)	2018-04-17	一种孔结构可控的介孔/大孔碳材料3d打印成型的方法
WO2013135100A1 (zh)	2013-09-19	一种纤维素基-硅杂化微球及其制备方法
WO2017155468A1 (en)	2017-09-14	Chemical vapor deposition process to build 3d foam-like structures
CN106750503A (zh)	2017-05-31	一种ZnO/纤维素复合气凝胶的制备方法
Wang et al.	2022	Templated synthesis and assembly with sustainable cellulose nanomaterial for functional nanostructure
CN104549204B (zh)	2017-02-22	一种二氧化钛/碳纳微米球粉体的制备方法及其应用
CN103848413B (zh)	2016-08-10	一种介孔碳球材料的制备方法
TW200418558A (en)	2004-10-01	Process for the production of a porous cellulosic body