TW200933019A - Process and apparatus for generating hydrogen enriched fuel - Google Patents

Process and apparatus for generating hydrogen enriched fuel Download PDF

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Publication number
TW200933019A
TW200933019A TW097103689A TW97103689A TW200933019A TW 200933019 A TW200933019 A TW 200933019A TW 097103689 A TW097103689 A TW 097103689A TW 97103689 A TW97103689 A TW 97103689A TW 200933019 A TW200933019 A TW 200933019A
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Taiwan
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hydrogen
fuel
tank
aqueous solution
water
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TW097103689A
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Chinese (zh)
Inventor
Sesinando Allas Bautista
Cheng Hock Mike A Chia Chia
Krishna Kumar Sharma
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Niche Vision Sdn Bhd
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Priority to TW097103689A priority Critical patent/TW200933019A/en
Publication of TW200933019A publication Critical patent/TW200933019A/en

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Output Control And Ontrol Of Special Type Engine (AREA)

Abstract

A process (10) and apparatus (50) for generating hydrogen enriched fuel for an internal combustion engine is provided. Tap water is softened with industrial salts in a water softening chamber (55) and passes into a solution chamber (60) and thereafter into an electrolysis chamber (65). In the electrolysis chamber (65) the water solution is broken down into hydrogen and oxygen molecules by application of a pulsating direct current. The generated hydrogen molecules are purified and stored in a hydrogen collector (75). The dissociated oxygen molecules are saturated in and re-circulated with the water solution from the electrolysis chamber to the solution chamber (60). A primary fossil fuel from a vehicle fuel tank is sent to a frothing cylinder where it is passed through a perforated tube (81) so as to create turbulence. Thereafter, the frothed fuel is mixed with the collected pure hydrogen in a mixing cylinder (80) thereby forming a hydrogen saturated fuel. The hydrogen enriched fuel may be delivered directly to an internal combustion engine, or may be stored prior to such a delivery.

Description

200933019 九、發明說明: 【發明所屬之技術領域】 本發明係有關於一改良之燃料源之製造,尤其是一種 用於内燃機之富氫燃料之製造。 5 Ο 10 15 ❹ 20 【先前技術】 目前’内燃機之主要是藉由石化燃料及特定之石油衍 生物而產生動力,其包括汽油、柴油及天然氣。許多内燃 機之動力之替代已提出,包括太陽能及乙醇。然而,至今 並無可實行之可代替石化燃料之產品。再者,近來石化燃 料之衍生燃料的價格顯著地增加。因此,内燃機的效率變 得更加重要。 本發明尋求改善内燃機之燃料效率。 【發明内容】 根據本發明之第一態樣,提供一產生内燃機用之富氫 燃料之製程,包括以下步驟: 1. 提供一水溶液; 2. 由該水溶液分離及移除氫; 3. 提供一主要石化燃料源; 4. 將該燃料起泡;以及 5. 混合所移除之氫與該起泡的燃料。 因此’本發明提供一製程,其轉換主要燃料(如汽油、 柴油、天然氣、重油(bunker)或煤)為更有效率之燃料。 5 200933019 在混合燃料與釋放的氳之前,為了改善後續之混合步 驟之效率,此燃料藉由將其導入紊流而起泡。 當本發明之氫飽和燃料形成後,將其導入一燃燒腔體 後,可發生兩程序: 5 ❹ 10 15 ❿ 20 1. 燃料之正常燃燒程序;以及 2. 氳與導入腔體之環境空氣中受熱之氮的互相融合。 藉由飽和於燃料中之氫,每一燃燒循環所產生之動力 增加’並因此達成在相同動力輸出下,燃燒腔體内所需之 燃料相較於傳統燃料源是降低的。 用以產生氫分子之水溶液可以包括自來水β這表示, 水可以由居家或商業用水直接地取得。 在萃取風步驟之前’可將水先軟化。水可以用任何可 降低其硬度之物質加以處理,通常藉由沈澱或吸收鈣及鎂 離子。例如’硫酸鎂可使用為軟化水之化合物。 當水分子(HA)被分解而產生氫時,氧原子在2η2〇 ► 2Η2+〇2反應中一起被製造出。在一些實施例中,反應中所 釋放之氧被與水溶液一起回收,且再被產生氫之反應所利 用0 產生氳步驟可包括一電解步驟,其中雙原子之氫分子 由氧分子中分離。此可經由將一脈動直流電流導入至一浸 於水溶液中之陰極與陽極中而達成。 主要燃料對氫的比率是重要的,且其會影響混合之效 率及飽和程度。一實施例中,氫混合於燃料之比率為每公 升 5 ppm。 6 200933019 在製造富氫燃料之後,它可以直接輸入一内燃機,或 是,該富氫燃料在輸入一内燃機之前,可以先被儲存。 根據本發明之第二態樣,提供一產生用於内燃機之富 氫燃料之裝置,包括: 5 —溶液槽,用以儲存一水溶液; 一氫產生槽,用以接收由該溶液槽之水,並將氫分子 由氧分子中分離及移除; 一燃料起泡裝置,用以在主要石化燃料中製造紊流; © 以及 10 —混合槽,用以接收分離之氫與該起泡的燃料而產生 富氫燃料。 該燃料起泡裝置是在混合被分離之氫之前,用以在燃 料中製造紊流。在一實施例中,混合槽包括一具排孔之管 結構。當燃料經由此具排孔之結構而被置於紊流之中,則 15 因此改善後續之混合。 該氫產生槽可以包括一電解槽。在此例中,由溶液槽 ^ 所收集之水被施以脈衝電流,而分解水為氫及氧分子。此 ❹ 反應之速度及氣體產生之速率可藉由改變施加於電解裝 置之電壓而獲得控制。 20 本裝置可更包括有一水軟化槽,用以處理水而形成一 水溶液。因此,水在傳輸到溶液槽之前,可以先導入此水 軟化槽。 本裝置可更包括有用以將由電解槽而來之氧分子與 水溶液再循環使一起回到該溶液槽之裝置。當氫由水溶液 7 200933019 被分離與移除,剩餘之水溶液與共生成之氧分子可以被運 送回到溶液槽/腔體。 本裝置可更包括有一觸媒出口槽,用以允許氫排出該 氫產生槽’但避免氧通過。 本裝置可更包括有一氫收集器,在輸送到混合槽之 前,純化氫及儲存它。 本裝置可更包括有一儲存槽,其用以儲存由該混合槽 而來之富氫燃料。因此,由混合槽排出之富氫燃料可以直 © 接被輸送到一内燃機,或是於其被輸送到内燃機之前,輸 10 送到該用以儲存之儲存槽。 本裝置可更包括有一旁通管配置,若產生氫失敗時, 可用以將燃料繞過該混合槽。若偵測到產生氫之錯誤時, 燃料可不被輸送到該混合槽,而直接輸送到該内燃機,在 此例中,引擎將在它正常的燃料消耗速率下運轉。 15 根據本發明之第三態樣係提供一内燃機燃料供應系 統’其包括在此所述之產生富氫燃料之裝置。 Q 根據本發明之第四態樣係提供一内燃機配置,其包括 一如所述之燃料供應系統。 20 【實施方式】 首先請先參考圖1,其係一般產生富氫燃料之製程, 標示為10。一水供給端12提供自來水,其被一硫酸鎂之 工業鹽14軟化而產生一水溶液16。 在步驟18中,水溶液16藉由一可調式12伏特之電 8 200933019 5 ❹ 10 15 ❹ 20 源供應器22施加一脈衝直流電20而被電解。 電解步驟18係用以分離氫氣24與氧氣26。 氧氣26經由循環後回到水溶液16。 氫氣24係由水溶液16分離出,且在步驟28與一石 化燃料源30混合。 混合步驟28產生富氫燃料32。燃料32可以被輸送到 儲存單元34或直接供給到引擎36。 請參見圖2,其係一般之燃料轉換裝置,標示為50。 一般裝置50係包括: 一水軟化槽55 一水溶液槽60; 一電解槽65 ; 一觸媒出口槽70; 一氳氣收集槽75;以及 一混合槽80。 水軟化槽55具有一水輸入口 56,用以接收一定量之 家用自來水。水軟化槽55包括一定量之硫酸鎂用以軟化 由入口 56而來之水。經軟化之水由出口 57排出水軟化槽 55 ° 水軟化槽出口 57輸出軟化水,並使其進入已準備好 之水溶液槽60。一供料泵61經由一單向閥62將軟化水由 水溶液槽60輸送進入電解槽65。 在電解槽65内,水溶液被施加一提供至沈浸在槽65 中之陽極與陰極板66之脈衝直流(DC)電流。一液面偵測 9 200933019 器67監控電解槽65内之皮、文、为县 w 水溶液量,並利用水溶液供料发200933019 IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to the manufacture of an improved fuel source, and more particularly to the manufacture of a hydrogen-rich fuel for an internal combustion engine. 5 Ο 10 15 ❹ 20 [Prior Art] At present, the internal combustion engine is mainly powered by fossil fuels and specific petroleum derivatives, including gasoline, diesel and natural gas. Alternatives to the power of many internal combustion engines have been proposed, including solar and ethanol. However, there are no viable products to replace fossil fuels to date. Moreover, the price of derivative fuels for petrochemical fuels has increased significantly recently. Therefore, the efficiency of the internal combustion engine becomes more important. The present invention seeks to improve the fuel efficiency of internal combustion engines. SUMMARY OF THE INVENTION According to a first aspect of the present invention, a process for producing a hydrogen-rich fuel for an internal combustion engine is provided, comprising the steps of: 1. providing an aqueous solution; 2. separating and removing hydrogen from the aqueous solution; a source of primary fossil fuel; 4. foaming the fuel; and 5. mixing the removed hydrogen with the foamed fuel. Thus, the present invention provides a process for converting a primary fuel such as gasoline, diesel, natural gas, bunker or coal to a more efficient fuel. 5 200933019 Before mixing the fuel with the released helium, in order to improve the efficiency of the subsequent mixing step, the fuel is foamed by introducing it into the turbulent flow. When the hydrogen-saturated fuel of the present invention is formed and introduced into a combustion chamber, two procedures can occur: 5 ❹ 10 15 ❿ 20 1. Normal combustion procedure of the fuel; and 2. 环境 and ambient air introduced into the chamber The nitrogen of heat is fused to each other. By saturating the hydrogen in the fuel, the power generated by each combustion cycle is increased' and thus at the same power output, the fuel required in the combustion chamber is reduced compared to conventional fuel sources. The aqueous solution used to generate hydrogen molecules can include tap water, which means that water can be taken directly from domestic or commercial water. The water can be softened first before the extraction of the wind step. Water can be treated with any substance that reduces its hardness, usually by precipitation or absorption of calcium and magnesium ions. For example, 'magnesium sulfate can be used as a compound that softens water. When water molecules (HA) are decomposed to generate hydrogen, oxygen atoms are produced together in a 2η2〇 ► 2Η2+〇2 reaction. In some embodiments, the oxygen released in the reaction is recovered with the aqueous solution and is again produced by the reaction to produce hydrogen. The step of generating hydrazine may include an electrolysis step in which hydrogen molecules of the diatomic atoms are separated from the oxygen molecules. This can be achieved by introducing a pulsating direct current into a cathode and anode immersed in the aqueous solution. The ratio of primary fuel to hydrogen is important and affects the efficiency and saturation of the mixing. In one embodiment, the ratio of hydrogen mixed to fuel is 5 ppm per liter. 6 200933019 After manufacturing a hydrogen-rich fuel, it can be directly input into an internal combustion engine, or the hydrogen-rich fuel can be stored before being input to an internal combustion engine. According to a second aspect of the present invention, there is provided a device for producing a hydrogen-rich fuel for an internal combustion engine, comprising: a solution tank for storing an aqueous solution; and a hydrogen generating tank for receiving water from the solution tank, And separating and removing hydrogen molecules from oxygen molecules; a fuel bubbling device for creating turbulence in the primary fossil fuel; and a 10 - mixing tank for receiving separated hydrogen and the foamed fuel Produce hydrogen-rich fuel. The fuel frothing device is used to create turbulent flow in the fuel prior to mixing the separated hydrogen. In one embodiment, the mixing tank includes a tube structure with a row of holes. When the fuel is placed in the turbulent flow through the structure with the rows of holes, then the subsequent mixing is improved. The hydrogen generating tank may include an electrolytic tank. In this case, the water collected by the solution tank is subjected to a pulse current, and the decomposition water is hydrogen and oxygen molecules. The rate of this reaction and the rate at which the gas is produced can be controlled by varying the voltage applied to the electrolysis device. 20 The apparatus may further comprise a water softening tank for treating the water to form an aqueous solution. Therefore, the water can be introduced into the water softening tank before being transferred to the solution tank. The apparatus may further comprise means for recycling the oxygen molecules from the electrolysis cell with the aqueous solution for return to the solution tank. When hydrogen is separated and removed from aqueous solution 7 200933019, the remaining aqueous solution and co-generated oxygen molecules can be transported back to the solution tank/cavity. The apparatus may further include a catalyst outlet tank for allowing hydrogen to exit the hydrogen generating tank' but avoiding the passage of oxygen. The apparatus may further include a hydrogen collector for purifying hydrogen and storing it prior to delivery to the mixing tank. The apparatus may further include a storage tank for storing hydrogen-rich fuel from the mixing tank. Therefore, the hydrogen-rich fuel discharged from the mixing tank can be sent directly to an internal combustion engine, or sent to the storage tank for storage before being sent to the internal combustion engine. The apparatus may further include a bypass configuration for bypassing the mixing tank if hydrogen fails. If an error in hydrogen generation is detected, fuel may not be delivered to the mixing tank and delivered directly to the internal combustion engine, in which case the engine will operate at its normal fuel consumption rate. The third aspect of the present invention provides an internal combustion engine fuel supply system' which includes the apparatus for producing a hydrogen rich fuel as described herein. Q According to a fourth aspect of the present invention, an internal combustion engine configuration is provided which includes a fuel supply system as described. [Embodiment] First, please refer to FIG. 1 first, which is a process for generally producing a hydrogen-rich fuel, which is indicated as 10. A water supply end 12 provides tap water which is softened by a magnesium sulfate industrial salt 14 to produce an aqueous solution 16. In step 18, the aqueous solution 16 is electrolyzed by applying a pulsed direct current 20 to the source supply 22 of an adjustable 12 volt power supply. Electrolysis step 18 is used to separate hydrogen 24 from oxygen 26. Oxygen 26 is returned to aqueous solution 16 via circulation. Hydrogen 24 is separated from aqueous solution 16 and mixed with a source of refractory fuel 30 at step 28. Mixing step 28 produces a hydrogen rich fuel 32. Fuel 32 may be delivered to storage unit 34 or directly to engine 36. Please refer to FIG. 2, which is a general fuel conversion device, designated 50. The general apparatus 50 includes: a water softening tank 55 - an aqueous solution tank 60; an electrolytic tank 65; a catalyst outlet tank 70; a helium gas collecting tank 75; and a mixing tank 80. The water softening tank 55 has a water inlet 56 for receiving a certain amount of domestic tap water. The water softening tank 55 includes a quantity of magnesium sulfate to soften the water from the inlet 56. The softened water exits the water softening tank from the outlet 57. 55 ° The water softening tank outlet 57 outputs demineralized water and enters the prepared aqueous tank 60. A feed pump 61 delivers demineralized water from the aqueous solution tank 60 to the electrolytic cell 65 via a check valve 62. Within electrolytic cell 65, the aqueous solution is applied with a pulsed direct current (DC) current supplied to the anode and cathode plates 66 immersed in tank 65. A liquid level detection 9 200933019 The device 67 monitors the amount of the skin, the text, the county w aqueous solution in the electrolytic cell 65, and uses the aqueous solution to supply the material.

61維持液面。 K 槽65内水溶液之電解造成軟化水中之水分子分解為 氫及氧。由觸媒出口槽7G通人氫及氧。槽7q只允許氣通 5 ❹ 10 15 ❹ 過並避免氧由槽70脫離。接著,氧被送回電解槽Μ並混 合回到水溶液令,再藉由回饋泵72與單向閥71而被輸送 回水溶液槽60中。 以氣艘泵73將氫由觸媒出口槽7〇送到氮氣收集槽 75。氫氣收集槽75將任何其他經電解槽65輸送之殘留氣 體中分離出氫。一壓力偵測器76監控氩氣收集槽75内氫 之壓力,並由一壓力指示器76a顯示氫的壓力。一壓力釋 放閥75a係用以作為一安全裝置而設置於氫收集槽中。 純氫氣於壓力約為34.47 kPa(5psi)時,由氫氣收集槽 75經單向閥84供給進入混合圓柱筒80。 燃料由燃料入口 85經槽80内之一穿孔管81而供給 進入混合槽80,所以燃料於進入混合槽8〇之同時間被起 泡。富氫燃料由燃料出口 86排出混合槽8〇β 燃料之入口 /出口配置包括一旁通閥87 ,在氫氣產生 發生錯誤時’其允許燃料繞過混合槽8(^ 燃料由燃料出口 86供給到燃燒引擎杲並進入燃料注 射系統。 請參見圓3’其係圖2之燃料轉換器50之電性方塊圖。 以下說明電性元件: 一電源供給線90 ; 20 200933019 5 ❹ 10 15 ❹ 20 一電壓調整器91 ; 一微控器92 ; 水溶液供給與回饋泵93 ; 水溶液供給與回饋螺線管94 ; 壓力開關95 ; 氣體偵測開關96 ; 溫度計97 ; 電解槽電源供給卡98 ; 電解槽電源供給99 ; 電能變換器100 ; 電解槽液面偵測器101 ; 氣體脈衝泵電源供給102 ;以及 旁通開關電源供給103。 請參見圖4’其係為水軟化槽55之詳細結構。槽55 包括一普遍的平行六面體55a,其在相同之頂面上包括有 一進水口 56及一出水口 57。槽55a大致之尺寸如圖所示。 請參見圖5 ’其係為水溶液槽60之詳細結構。槽6〇 包括一普通的平行六面鱧60a。槽60具有一軟化水入口 63 於其一側壁,及一軟化水出口於其相對之侧壁上。 請參見圖6’其詳細地呈現電解槽槽65包括— 般平行六面體65a,在本實施例中是由一硬質塑膠殼體所 形成。本體65以移除外殼之方式呈現,以顯示出内部元 件。本體65容置有一由兩矩形板66a、66b所形成之陰極 及一由兩矩形板66c、66d所形成之陽極。一軟化水溶液入 11 200933019 口 68及一溶液回饋出口 69配置於本體65a之一側壁之相 對端。一氣體出口 69配置於本體65a之頂面。 5 〇 10 15 20 請參見圖7a及7b,其係為觸媒出口槽之詳細結構。 此槽包括一圓柱形銅殼體74a,其容置有一鋁製網線之圓 柱體74b。槽70之一端連到電解槽65之氣體出口 69,另 一端連到單向閥84。 請參見圖8,其係為氫氣收集槽75之詳細結構。槽 75包括一 一般之圓柱體75a。本體容置有一鎂薄膜78,其 接收由觸媒出口槽經入口 77a而來之氣體。純化後之氫氣 經由出口 77b而由槽75排出。槽75a包括一閥79,其同 時具有壓力釋放閥及水分散閥之功能。 請參見圖9a及9b,其係為混合槽80之詳細結構。槽 80包括一一般之帽-型本體8〇a,其被一蓋子83覆蓋。蓋 子83具有一氣體入口 82、一燃料入口 85及一燃料出口 86。燃料入口 85連接管狀的燃料導管81,其包括有複數 個孔81a’孔81a可允許燃料流經管81而進入可與氫混合 之槽80的内部。蓋子83更包括一對鑲嵌孔83a。 請參見圖1 〇,其係為一燃料供給系統,標示為i 5〇。 系統150包括一微控器192用以控制系統之運作。一水溶 液槽160利用供給泵161供給軟化水進入電解槽165。電 解槽165所分離之氫經由觸媒供給管線(未圖示)被送進氫 氣收集槽175»收集槽供給純氫進入混合槽18〇〇燃料由 一載具燃料槽供給進入一起泡圓柱筒181,其在本實施例 中是與混合槽180分離且置於外部的。在氫化燃料送進载 12 200933019 ' 具燃料泵之前,起泡的燃料被送進混合槽180並在此與純 氫混合。 根據本發明之製程與裝置之燃料供給系統之測試結 果,顯現燃料效率明顯增加,如下表1及2所示。61 maintain the liquid level. The electrolysis of the aqueous solution in the K tank 65 causes the water molecules in the demineralized water to decompose into hydrogen and oxygen. Hydrogen and oxygen are supplied from the catalyst outlet tank 7G. The tank 7q only allows the gas to pass through 5 ❹ 10 15 并 and prevents oxygen from being detached from the tank 70. Next, the oxygen is sent back to the electrolytic cell and mixed back into the aqueous solution, and then returned to the aqueous solution tank 60 by the feedback pump 72 and the check valve 71. Hydrogen is pumped from the catalyst outlet tank 7 to the nitrogen collection tank 75 by the gas pump 73. The hydrogen collection tank 75 separates hydrogen from any other residual gas transported through the electrolytic cell 65. A pressure detector 76 monitors the pressure of hydrogen in the argon collecting tank 75 and displays the pressure of hydrogen by a pressure indicator 76a. A pressure relief valve 75a is provided as a safety device in the hydrogen collection tank. Pure hydrogen is supplied from the hydrogen collection tank 75 through the check valve 84 to the mixing cylinder 80 at a pressure of about 34.47 kPa (5 psi). The fuel is supplied from the fuel inlet 85 through the perforated pipe 81 in the tank 80 into the mixing tank 80, so that the fuel is bubbled while entering the mixing tank 8〇. The hydrogen-rich fuel exits the mixing tank 8 from the fuel outlet 86. The inlet/outlet configuration of the fuel includes a bypass valve 87 that allows the fuel to bypass the mixing tank 8 when the hydrogen generation error occurs (the fuel is supplied to the combustion by the fuel outlet 86) The engine slams into the fuel injection system. See circle 3' for the electrical block diagram of fuel converter 50. Figure 2 shows the electrical components: a power supply line 90; 20 200933019 5 ❹ 10 15 ❹ 20 a voltage Regulator 91; a micro-controller 92; aqueous solution supply and feedback pump 93; aqueous solution supply and feedback solenoid 94; pressure switch 95; gas detection switch 96; thermometer 97; electrolyzer power supply card 98; 99; power converter 100; electrolytic bath level detector 101; gas pulse pump power supply 102; and bypass switching power supply 103. See Figure 4' for the detailed structure of water softening tank 55. A universal parallelepiped 55a includes a water inlet 56 and a water outlet 57 on the same top surface. The groove 55a is substantially sized as shown in the drawing. See Figure 5 for details of the aqueous solution tank 60. The groove 6A includes a common parallel hexahedron 60a. The groove 60 has a softened water inlet 63 on one side wall thereof and a softened water outlet on the opposite side wall. See Figure 6' for a detailed presentation. The electrolytic cell slot 65 includes a generally parallelepiped 65a, which in this embodiment is formed by a rigid plastic housing. The body 65 is presented in a manner to remove the outer casing to reveal internal components. The body 65 houses a The cathode formed by the two rectangular plates 66a, 66b and the anode formed by the two rectangular plates 66c, 66d. A softened aqueous solution into the 11 200933019 port 68 and a solution feedback outlet 69 are disposed at opposite ends of one of the side walls of the body 65a. The gas outlet 69 is disposed on the top surface of the body 65a. 5 〇10 15 20 See Figures 7a and 7b, which are detailed structures of the catalyst outlet groove. The groove includes a cylindrical copper casing 74a that houses an aluminum. The cylindrical body 74b of the wire mesh. One end of the groove 70 is connected to the gas outlet 69 of the electrolytic cell 65, and the other end is connected to the check valve 84. Referring to Fig. 8, it is a detailed structure of the hydrogen collecting tank 75. The groove 75 includes A general cylinder 75a. Body housing A magnesium film 78 receives the gas from the catalyst outlet tank through the inlet 77a. The purified hydrogen is discharged from the tank 75 via the outlet 77b. The tank 75a includes a valve 79 having a pressure relief valve and a water dispersion valve. Referring to Figures 9a and 9b, which are the detailed construction of the mixing tank 80. The tank 80 includes a general cap-type body 8A, which is covered by a cover 83. The lid 83 has a gas inlet 82, a A fuel inlet 85 and a fuel outlet 86. The fuel inlet 85 is connected to a tubular fuel conduit 81 which includes a plurality of holes 81a'. The holes 81a allow fuel to flow through the tube 81 into the interior of the tank 80 which is miscible with hydrogen. The cover 83 further includes a pair of inlaid holes 83a. See Figure 1 〇, which is a fuel supply system, labeled i 5〇. System 150 includes a microcontroller 192 for controlling the operation of the system. The aqueous solution tank 160 supplies the demineralized water to the electrolytic cell 165 by the supply pump 161. The hydrogen separated by the electrolytic cell 165 is sent to the hydrogen collecting tank 175 through a catalyst supply line (not shown). The collecting tank supplies pure hydrogen into the mixing tank 18. The fuel is supplied from a carrier fuel tank into the bubble cylinder 181. It is separated from the mixing tank 180 and placed outside in this embodiment. Before the hydrogenated fuel is fed into the load 12 200933019 'with the fuel pump, the foamed fuel is sent to the mixing tank 180 where it is mixed with pure hydrogen. According to the test results of the fuel supply system of the process and apparatus of the present invention, the fuel efficiency is significantly increased as shown in Tables 1 and 2 below.

❹ 13 200933019❹ 13 200933019

表1 氫飽和測試結果 測試週期 每曰燃剩 -消耗 燃料種類 2006年4月 正常 Nh2 柴油 汽油 第一曰 25公升 17.40 X 第二曰 25公升 20.00 X 第三曰 25公升 16.50 X 第四曰 25公升 18.50 X 第五曰 25公升 16.70 X 第六曰 25公升 17.00 X 平均 16.90 X 平均 18.50 X 2006年5月4日 第一曰 本 16.80 X 第二曰 本 16.50 X 第三曰 木 17.00 X 第四曰 * 16.50 X 第五曰 本 17.20 X 第六曰 氺 16.90 X 平均 16.83 2006年5月14曰 第一曰 氺 16.00 X 第二曰 * 16.40 X 第三曰 本 16.00 X 第四曰 氺 16.50 X 第五曰 * 16.20 X 第六曰 本 16.50 X 平均 16.30 3系列測試平均 16.68 X 25 16.68 燃料使用減少 33% 8.32 33% 16.70 X 14 200933019 表2 氮飽和測試結果 氫氣體積 34.47 kPa (5psi)/ 5ppm 測試週期 每曰燃料消耗 燃料種類 2006年6月1日 正常 Nh2 柴油45% 汽油30% 第一曰 25公升 17.60 33% 第二曰 25公升 15.40 第三曰 25公升 14.50 第四曰 25公升 13.70 第五曰 25公升 13.00 第六曰 25公升 13.00 43.3% 平均 本 平均 本 2006年6月8日 第一曰 本氺 12.80 49% 第二曰 *木 12.50 木 第三曰 本氺 12.60 本 第四曰 氺本 12.60 幸 第五曰 本木 12.50 本 第六曰 氺木 12.40 50.1 平均 2006年6月14曰 第一曰 氺本 14.20 45% 第二曰 14.00 本 第三曰 13.90 木 第四曰 ** 14.20 本 第五曰 氺本 14.00 * 第六曰 冰本 14.00 45% 平均 3系列測試平均 本 附註 50.10% 臨界點高引擎變動 45% 理想設定最低引擎變動 **正常燃料消耗值 15 200933019 取決於評估資料Table 1 Hydrogen saturation test results Test cycle per smoldering-consumption fuel type April 2006 Normal Nh2 Diesel gasoline First 曰25 liters 17.40 X Second 曰25 liters 20.00 X Third 曰25 liters 16.50 X Fourth 曰25 liters 18.50 X Fifth 曰25 liters 16.70 X Sixth 曰25 liters 17.00 X Average 16.90 X Average 18.50 X May 4, 2006 First 1616.80 X Second 16 16.50 X Third 曰木17.00 X Fourth 曰* 16.50 X Fifth Sample 17.20 X Sixth Level 16.90 X Average 16.83 May 14, 2006 First Level 16.00 X Second Level* 16.40 X Third Version 16.00 X Fourth Level 16.50 X Fifth Page* 16.20 X Sixth sample 16.50 X Average 16.30 3 series test average 16.68 X 25 16.68 Fuel use reduced by 33% 8.32 33% 16.70 X 14 200933019 Table 2 Nitrogen saturation test results Hydrogen volume 34.47 kPa (5 psi) / 5 ppm Test cycle per 曰 fuel Fuel consumption type June 1, 2006 Normal Nh2 Diesel 45% Gasoline 30% First 曰25 liters 17.60 33%曰25 liters 15.40 Third 曰25 liters 14.50 Fourth 曰25 liters 13.70 Fifth 曰25 liters 13.00 Sixth 曰25 liters 13.00 43.3% Average this average June 8, 2006 First 氺本氺 12.80 49% Second曰*木12.50 木三曰本氺12.60 The fourth 曰氺12.60 幸五曰本木12.50 The sixth 曰氺木12.40 50.1 Average June 14, 2006 first book 14.20 45% Second曰14.00 This third 曰13.90 木四曰** 14.20 The fifth 1414.00 * The sixth 曰冰本14.00 45% The average 3 series test average this note 50.10% The critical point height engine change 45% The ideal setting minimum engine Change** Normal fuel consumption value 15 200933019 Depends on assessment data

Nh2 -根據本發明之燃料供給系統 本發明可以輕易地在不脫離本發明之範疇或基本特 徵下以其他特定之形式被製造,其對本發明技術領域之技 術人士顯而易見的。因此,本實施例應被認為是只為說明 5 10 20 之目的而非限制,本發明之範疇為申請專利範圍所指出, 而非上述之敘述,且因此其範圍内之所有改變是包含在本 發明之内的。 ❺ 【圓式簡單說明】 本發明將以實施例之方式,配合附圖為更具體之描 述,其中: 圖1係根據本發明之產生富氫燃料之製程流程圖。 圖2係根據本發明形成之燃料轉換器之示意圖。 15 ❹ 圖3係為圖2之轉換器操作的電性元件示意圖。 圖4係為圖2之轉換器之水軟化槽部分之立體圖。 囷5係為圖2之轉換器之溶液槽部分之立體圖 圓6係為圖2之轉換器之電解槽部分之立趙圖:以移除外 圓7a係為圖2之轉換器之觸媒出口槽部分之縱向剖面圖 圓7b係圖7a之槽沿X-X線之剖面圖。 圖8係為圖2之轉換器之氫收集器部分之剖面 圖9a係為圖2之轉換器之混合槽部分 ® Λ t β 1刀义縱向剖面圖。 圖9 b係圏9a之混合槽之平面圖。 16 200933019 • 圖10係根據本發明所形成之一内燃機燃料供應系統。 【主要元件符號說明】 10富氫燃料之製程 12水供給端 14工業鹽 16水溶液 18步驟 20脈衝直流電 22電源供應器 24氫氣 26氧氣 28混合步驟 30石化燃料源 32富氫燃料 34儲存單元 36引擎 50燃料轉換裝置 55水軟化槽 55a平行六面體 56入口 57出口 60水溶液槽Nh2 - Fuel Supply System According to the Invention The present invention can be easily manufactured in other specific forms without departing from the scope of the invention, as will be apparent to those skilled in the art. Therefore, the present embodiments are to be considered as illustrative only and not limiting, and the scope of the invention is the scope of the claims, rather than the above description, and therefore all changes within the scope thereof are included Within the invention. BRIEF DESCRIPTION OF THE DRAWINGS [Brief Description of the Invention] The present invention will be described in more detail with reference to the accompanying drawings, in which: FIG. 1 is a process flow diagram for producing a hydrogen-rich fuel according to the present invention. 2 is a schematic illustration of a fuel converter formed in accordance with the present invention. 15 ❹ Figure 3 is a schematic diagram of the electrical components operated by the converter of Figure 2. Figure 4 is a perspective view of the water softening tank portion of the converter of Figure 2.囷5 is a perspective view of the solution tank portion of the converter of Fig. 2. The circle 6 is the vertical diagram of the electrolytic cell portion of the converter of Fig. 2: the outer ring 7a is removed as the catalyst outlet of the converter of Fig. 2. The longitudinal section circle 7b of the groove portion is a sectional view of the groove of Fig. 7a along the line XX. Figure 8 is a cross section of the hydrogen collector portion of the converter of Figure 2. Figure 9a is a longitudinal cross-sectional view of the mixing tank portion of the converter of Figure 2 ® Λ t β 1 . Figure 9b is a plan view of the mixing tank of the crucible 9a. 16 200933019 • Figure 10 is a fuel supply system for an internal combustion engine formed in accordance with the present invention. [Main component symbol description] 10 hydrogen-rich fuel process 12 water supply terminal 14 industrial salt 16 aqueous solution 18 step 20 pulse direct current 22 power supply 24 hydrogen 26 oxygen 28 mixing step 30 petrochemical fuel source 32 hydrogen-rich fuel 34 storage unit 36 engine 50 fuel conversion device 55 water softening tank 55a parallelepiped 56 inlet 57 outlet 60 aqueous solution tank

76壓力偵測器 76a壓力指示器 77a 入口 77b 出口 78鎂薄膜 79閥 80混合槽 80a帽-型本體 81穿孔管 81 a孔 83蓋子 83a鑲嵌孔 84單向閥 85燃料入口 86燃料出口 87旁通閥 90電源供給線 91電壓調整器 92微控器 93水溶液供給與回饋泵 17 200933019 60a 平行六面體 94水溶液供給與回饋螺線管 61 供料泵 95壓力開關 62 單向閥 96氣體偵測開關 63 軟化水入口 97溫度計 65 電解槽 98電解槽電源供給卡 65a 平行六面體 99電解槽電源供給 66 陽極與陰極板 100電能變換器 66a、66b、 66c、66d 矩形板 101電解槽液面偵測器 67 液面偵測器 102氣體脈衝泵電源供給 68 軟化水溶液入口 103旁通開關電源供給 69 溶液回馈出口 150系統 70 觸媒出口槽 160槽 71 單向閥 161供給泵 72 回饋泵 165電解槽 73 氣體泵 175槽 74a 圓柱形銅殼體 180混合槽 74b 圓柱體 181圓柱筒 75 氫氣收集槽 192微控器 75a壓力釋放閥 1876 pressure detector 76a pressure indicator 77a inlet 77b outlet 78 magnesium film 79 valve 80 mixing tank 80a cap-type body 81 perforated tube 81 a hole 83 cover 83a inlay hole 84 check valve 85 fuel inlet 86 fuel outlet 87 bypass Valve 90 power supply line 91 voltage regulator 92 micro-controller 93 aqueous solution supply and feedback pump 17 200933019 60a parallelepiped 94 aqueous solution supply and feedback solenoid 61 supply pump 95 pressure switch 62 check valve 96 gas detection switch 63 softened water inlet 97 thermometer 65 electrolytic cell 98 electrolytic cell power supply card 65a parallelepiped 99 electrolytic cell power supply 66 anode and cathode plate 100 power converter 66a, 66b, 66c, 66d rectangular plate 101 electrolytic cell level detection 67 liquid level detector 102 gas pulse pump power supply 68 softened aqueous solution inlet 103 bypass switching power supply 69 solution feedback outlet 150 system 70 catalyst outlet tank 160 tank 71 check valve 161 supply pump 72 feedback pump 165 electrolytic tank 73 Gas pump 175 tank 74a cylindrical copper housing 180 mixing tank 74b cylinder 181 cylinder 75 hydrogen collecting tank 192 micro controller 75a pressure relief valve 18

Claims (1)

200933019 十、申請專利範圍: 1. 一種產生内燃機用富氫燃料之製程,包括以 驟: 卜步 i) 提供一水溶液; 5 ❹ 10 15 ❹ ii) 由該水溶液將氫分離及移除; iii) 提供一主要石化燃料源; iv) 將該燃料起泡;以及 V)混合所移徐之氫與該起泡之燃料。 2. 如f請專利範圍第i項所述之製程,其中該水溶液 包括自來水。 3. 如申請專利範圍第!項或第2項所述之製程,其中 在步驟ii)之前,進行一軟化水步驟。 4. 如申請專利範圍第丨項或第2項所述之製程,其中 當氫於步驟ii)分離時,所產生之氧與該水溶液一起被回 收。 5·如申請專利範圍第1項所述之製程,其中步驟u) 包括一電解步驟(18),其中雙原子之氫分子由氧分子中分 離。 6. 如申請專利範圍第丨項所述之製程,其中步驟iv) 包括經由一穿孔管(81)傳遞該燃料。 7. 如申請專利範圍第1項所述之製程,其中於步驟 v)中,混合氫與該起泡的燃料之比例為每公升5卯瓜。 8. 如申請專利範圍第1項所述之製程,其中於步驟 v)之後’該富氫燃料直接輸入一内燃機。 20 200933019 9. 如申請專利範圍第丨項或第2項所述之製程,其中 於步驟v)之後,該富氫燃料於輸入一内燃機之前先被儲 存。 10. —種產生内燃機用之富氫燃料之裝置,包括: 5 一 /谷液槽(60),用以儲存一水溶液(16); 一氮產生槽(65),用以接收由該溶液槽而來之水,且 由氧分子中分離及移除氫分子; 一燃料起泡裝置(81),用以在主要石化燃料(3〇)中製造 ❹ 紊流;以及 1〇 混σ槽(8〇),用以接收分離之氫與該起泡的燃料而 產生富氫燃料(32)。 11. 如申請專利範圍第1〇項所述之裝置,其中該氫產 生槽包括一電解槽(65)。 12. 如申請專利範圍第1〇項或第u項所述之裝置, 15其更包括有-水軟化槽(55),用以處理水*形成—水溶液 (16) 〇 13·如申請專利範圍第1〇項或第u項之任一項所述 之裝置,其中該燃料起泡裝置(81)是位於該混合槽⑽中。 14.如_請專利範圍第W項或第11項之任-項所述 20之裝置,其中該起泡裝置包括―穿孔管(8in㈣㈣ 過該穿孔管。 K如中請專㈣圍第1G項或第u項之卜項所述 之裝置’更包括有一儲存槽(34),其用以儲存由該混合槽 (80)而來之富氫燃料。 25 16.如申請專利範圍帛10項或帛U項之任一項所述 20 200933019 之裝置,更包括有一用 水溶液再循環進人該溶來之氧分子與 17如㈣奎 ()之裝置(71,72)。 產生綱排出,並避免氧出通:。(7〇),…許氣由該氣 18.如申請專利範圍第1〇項或第u項之任 之裝置,更包括有一氫氣收隼器门” a 項所述 風軋收集器(75),用以在與該起泡的 燃料混合前儲存被移除之氫。 ❹ 10 19.如申請專利範圍第10項或第丨丨項之任一項所述 之裝置’更包括有-旁通單元(87),若產生氫之過程失敗 時’用以將燃料繞過該混合槽(80)。 20· —種内燃機燃料供應系統,其包括如申請專利範 圍第10項或第11項之任一項所述之用以產生富氫燃料之 裝置。 15 ❹ 21200933019 X. Patent application scope: 1. A process for producing a hydrogen-rich fuel for an internal combustion engine, comprising: providing an aqueous solution according to step: i); 5 ❹ 10 15 ❹ ii) separating and removing hydrogen from the aqueous solution; iii) Providing a primary source of fossil fuel; iv) foaming the fuel; and V) mixing the displaced hydrogen with the foamed fuel. 2. The process described in item i of the patent scope, wherein the aqueous solution comprises tap water. 3. If you apply for a patent scope! The process of item 2 or 2, wherein prior to step ii), a demineralized water step is performed. 4. The process of claim 2 or 2, wherein when hydrogen is separated in step ii), the oxygen produced is recovered together with the aqueous solution. 5. The process of claim 1, wherein step u) comprises an electrolysis step (18) wherein the diatomic hydrogen molecules are separated from the oxygen molecules. 6. The process of claim 2, wherein step iv) comprises delivering the fuel via a perforated tube (81). 7. The process of claim 1, wherein in step v), the ratio of mixed hydrogen to the foamed fuel is 5 ounces per liter. 8. The process of claim 1, wherein the hydrogen-rich fuel is directly input to an internal combustion engine after step v). 20 200933019 9. The process of claim 2 or 2, wherein after the step v), the hydrogen-rich fuel is stored prior to input to an internal combustion engine. 10. A device for producing a hydrogen-rich fuel for an internal combustion engine, comprising: a 1-cell tank (60) for storing an aqueous solution (16); a nitrogen generating tank (65) for receiving a solution tank And the water is separated and removed from the oxygen molecules; a fuel bubbling device (81) for producing turbulent flow in the main fossil fuel (3〇); and 1〇 mixed σ groove (8 〇) for receiving separated hydrogen and the foamed fuel to produce a hydrogen-rich fuel (32). 11. The device of claim 1, wherein the hydrogen generating tank comprises an electrolytic cell (65). 12. If the device described in claim 1 or item u, 15 further comprises a water-softening tank (55) for treating water* forming-water solution (16) 〇13. The device of any of the preceding claims, wherein the fuel frothing device (81) is located in the mixing tank (10). 14. The device of claim 20, wherein the foaming device comprises a perforated tube (8 in (four) (four) through the perforated tube. K is in the middle of the special (four) circumference 1G item Or the device of item [i] further includes a storage tank (34) for storing hydrogen-rich fuel from the mixing tank (80). 25 16. If the patent application scope is 10 items or The apparatus of any of the above-mentioned 20 200933019, further comprising a device (71, 72) for recycling the dissolved oxygen molecules with an aqueous solution such as (four) quinone (71, 72) with an aqueous solution. Oxygen outlet: (7〇), ... Xu gas from the gas 18. As claimed in the scope of the application of the scope of the first or the second item, including a hydrogen gas collector door "a" a collector (75) for storing the removed hydrogen prior to mixing with the foamed fuel. ❹ 10 19. The device of any one of claim 10 or claim Including a bypass unit (87), if the process of generating hydrogen fails, 'to bypass the mixing tank (80). 20· A supply system comprising the apparatus for producing a hydrogen-rich fuel as described in any one of claims 10 or 11 of the patent application. 15 ❹ 21
TW097103689A 2008-01-31 2008-01-31 Process and apparatus for generating hydrogen enriched fuel TW200933019A (en)

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