TW201240121A - CIGS solar cell substrate and cell - Google Patents

CIGS solar cell substrate and cell Download PDF

Info

Publication number: TW201240121A
Authority: TW; Taiwan
Prior art keywords: layer; substrate; solar cell; steel; steel plate
Prior art date: 2010-09-08

Application number

TW100132364A

Other languages

English (en)

Chinese (zh)

Inventor

Shoichi Matsuo

Yoshikatsu Nishida

Yoshikazu Morita

Takahiro Fujii

Original Assignee

Nisshin Steel Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2010-09-08

Filing date

2011-09-08

Publication date

2012-10-01

2011-09-08 Application filed by Nisshin Steel Co Ltd filed Critical Nisshin Steel Co Ltd

2012-10-01 Publication of TW201240121A publication Critical patent/TW201240121A/zh

Links

239000000758 substrate Substances 0.000 title claims abstract description 82
229910000831 Steel Inorganic materials 0.000 claims abstract description 145
239000010959 steel Substances 0.000 claims abstract description 145
239000010410 layer Substances 0.000 claims abstract description 113
239000011247 coating layer Substances 0.000 claims abstract description 44
238000007747 plating Methods 0.000 claims abstract description 27
229910052910 alkali metal silicate Inorganic materials 0.000 claims abstract description 9
239000003513 alkali Substances 0.000 claims description 24
238000000034 method Methods 0.000 claims description 20
239000012535 impurity Substances 0.000 claims description 11
229910052708 sodium Inorganic materials 0.000 claims description 6
229910052757 nitrogen Inorganic materials 0.000 claims description 4
229910052761 rare earth metal Inorganic materials 0.000 claims description 4
229910017612 Cu(In,Ga)Se2 Inorganic materials 0.000 claims description 3
229910052744 lithium Inorganic materials 0.000 claims description 3
229910052700 potassium Inorganic materials 0.000 claims description 3
229910052791 calcium Inorganic materials 0.000 claims description 2
239000000470 constituent Substances 0.000 claims description 2
238000005363 electrowinning Methods 0.000 claims description 2
229910052748 manganese Inorganic materials 0.000 claims description 2
229910052720 vanadium Inorganic materials 0.000 claims description 2
239000003518 caustics Substances 0.000 claims 1
239000011162 core material Substances 0.000 claims 1
229910001220 stainless steel Inorganic materials 0.000 abstract description 9
229910000859 α-Fe Inorganic materials 0.000 abstract description 2
239000010949 copper Substances 0.000 description 77
239000010960 cold rolled steel Substances 0.000 description 30
230000000052 comparative effect Effects 0.000 description 27
239000011734 sodium Substances 0.000 description 24
239000000463 material Substances 0.000 description 18
238000006243 chemical reaction Methods 0.000 description 15
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 15
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 15
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 9
239000011651 chromium Substances 0.000 description 9
229910052751 metal Inorganic materials 0.000 description 9
239000000203 mixture Substances 0.000 description 9
239000005361 soda-lime glass Substances 0.000 description 9
239000002585 base Substances 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 8
239000011248 coating agent Substances 0.000 description 8
238000000576 coating method Methods 0.000 description 8
238000010438 heat treatment Methods 0.000 description 8
239000010935 stainless steel Substances 0.000 description 8
239000010936 titanium Substances 0.000 description 8
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 7
239000002253 acid Substances 0.000 description 7
239000002184 metal Substances 0.000 description 7
150000003839 salts Chemical class 0.000 description 7
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
229910052804 chromium Inorganic materials 0.000 description 6
229910052802 copper Inorganic materials 0.000 description 6
238000012360 testing method Methods 0.000 description 6
239000011888 foil Substances 0.000 description 5
239000011521 glass Substances 0.000 description 5
SITVSCPRJNYAGV-UHFFFAOYSA-L tellurite Chemical compound [O-][Te]([O-])=O SITVSCPRJNYAGV-UHFFFAOYSA-L 0.000 description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
238000009792 diffusion process Methods 0.000 description 4
238000003618 dip coating Methods 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
239000000126 substance Substances 0.000 description 4
229910052717 sulfur Inorganic materials 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 3
238000001354 calcination Methods 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
238000007772 electroless plating Methods 0.000 description 3
238000005516 engineering process Methods 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 3
229920006254 polymer film Polymers 0.000 description 3
229910052719 titanium Inorganic materials 0.000 description 3
239000011787 zinc oxide Substances 0.000 description 3
WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
229910052797 bismuth Inorganic materials 0.000 description 2
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
229910052980 cadmium sulfide Inorganic materials 0.000 description 2
230000000694 effects Effects 0.000 description 2
229910052733 gallium Inorganic materials 0.000 description 2
229910052738 indium Inorganic materials 0.000 description 2
AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000011707 mineral Substances 0.000 description 2
150000002923 oximes Chemical class 0.000 description 2
238000005096 rolling process Methods 0.000 description 2
239000004575 stone Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
241001523681 Dendrobium Species 0.000 description 1
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
239000005864 Sulphur Substances 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
229920001646 UPILEX Polymers 0.000 description 1
VEUACKUBDLVUAC-UHFFFAOYSA-N [Na].[Ca] Chemical compound [Na].[Ca] VEUACKUBDLVUAC-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000010953 base metal Substances 0.000 description 1
229910000416 bismuth oxide Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000005097 cold rolling Methods 0.000 description 1
229910000365 copper sulfate Inorganic materials 0.000 description 1
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
238000000151 deposition Methods 0.000 description 1
TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
238000009713 electroplating Methods 0.000 description 1
239000003337 fertilizer Substances 0.000 description 1
238000005242 forging Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
238000007654 immersion Methods 0.000 description 1
238000007733 ion plating Methods 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000012071 phase Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000003405 preventing effect Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
229910052711 selenium Inorganic materials 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000009628 steelmaking Methods 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
238000007740 vapor deposition Methods 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
239000013585 weight reducing agent Substances 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/16—Material structures, e.g. crystalline structures, film structures or crystal plane orientations
- H10F77/169—Thin semiconductor films on metallic or insulating substrates
- H10F77/1698—Thin semiconductor films on metallic or insulating substrates the metallic or insulating substrates being flexible
- H10F77/1699—Thin semiconductor films on metallic or insulating substrates the metallic or insulating substrates being flexible the films including Group I-III-VI materials, e.g. CIS or CIGS on metal foils or polymer foils
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/541—CuInSe2 material PV cells
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

Photovoltaic Devices (AREA)
Other Surface Treatments For Metallic Materials (AREA)

TW100132364A 2010-09-08 2011-09-08 CIGS solar cell substrate and cell TW201240121A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP2010200493A JP2012059855A (ja)	2010-09-08	2010-09-08	Ｃｉｇｓ太陽電池用基板および電池

Publications (1)

Publication Number	Publication Date
TW201240121A true TW201240121A (en)	2012-10-01

Family

ID=45810634

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW100132364A TW201240121A (en)	2010-09-08	2011-09-08	CIGS solar cell substrate and cell

Country Status (3)

Country	Link
JP (1)	JP2012059855A (ja)
TW (1)	TW201240121A (ja)
WO (1)	WO2012033033A1 (ja)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US9419151B2 (en)	2012-04-25	2016-08-16	Guardian Industries Corp.	High-reflectivity back contact for photovoltaic devices such as copper—indium-diselenide solar cells
US9246025B2 (en)	2012-04-25	2016-01-26	Guardian Industries Corp.	Back contact for photovoltaic devices such as copper-indium-diselenide solar cells
US9935211B2 (en)	2012-04-25	2018-04-03	Guardian Glass, LLC	Back contact structure for photovoltaic devices such as copper-indium-diselenide solar cells
US8809674B2 (en)	2012-04-25	2014-08-19	Guardian Industries Corp.	Back electrode configuration for electroplated CIGS photovoltaic devices and methods of making same
US20150136209A1 (en) *	2012-05-14	2015-05-21	Nippon Steel & Sumikin Chemical Co., Ltd.	Polyimide layer-containing flexible substrate, polyimide layer-containing substrate for flexible solar cell, flexible solar cell, and method for producing same
JP6392501B2 (ja)	2013-05-10	2018-09-19	新日鐵住金ステンレス株式会社	絶縁性に優れた熱膨張係数の小さいステンレス製太陽電池用基板およびその製造方法
EP2887405A1 (de) *	2013-12-23	2015-06-24	Saint-Gobain Glass France	Schichtsystem für Dünnschichtsolarzellen

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2004327849A (ja) *	2003-04-25	2004-11-18	Matsushita Electric Ind Co Ltd	太陽電池およびその製造方法
JP5419160B2 (ja) *	2009-01-07	2014-02-19	国立大学法人鹿児島大学	光発電装置及びその製造方法

2010
- 2010-09-08 JP JP2010200493A patent/JP2012059855A/ja not_active Withdrawn
2011
- 2011-09-05 WO PCT/JP2011/070118 patent/WO2012033033A1/ja not_active Ceased
- 2011-09-08 TW TW100132364A patent/TW201240121A/zh unknown

Also Published As

Publication number	Publication date
JP2012059855A (ja)	2012-03-22
WO2012033033A1 (ja)	2012-03-15

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