TW201329B - - Google Patents

Description

^ 01329 A6 B6 V. Description of the invention (1) The present invention relates to a liquid and solidified surface active composition with a high content of active substances, which includes a mixture of ethoxylated alcohol and I-oxysulfuric alcohol-β containing ion and The synthesis and cleaning of synthetic laundry detergents and their use in Lou ionic surfactant mixtures are disclosed in the special-to literature. Liquid ft surface active thorn compositions are well known in the field of surface cleaning and cleaning, regardless of the family or industry; all available formulations on the world are one or more surface active substances (surfactants) in Water and organic solvents C). These H-regulated substances usually contain only about 10% by weight of dry matter to 45% by weight of active substance. In the use of quite dilute 'conjugates', some problems are involved, such as the difficulty and high cost of transporting the preparations from the place of manufacture to the place of sale. Because most of the formulations are Smilax, it is often advantageous to prepare concentrated formulations in terms of transportation costs. Μ Department of Economics * Printed by the Bureau

{Please read the back .. < Precautions before filling in this I. As it can provide good cleaning and foaming, I have found that I-oxysulfate has been used more in household laundry detergents and liquids as a mixed activity table. Part of the two active agent system. However, the disadvantage of using oxosulfate in the formulation is that when it is diluted into a formulation with a concentration greater than 30%, there is a strong tendency to form coagulation. The formation of condensate can be reduced by about 14% of alcohol in the active substance solution of ethyl alcohol sulfate. This relatively high active substance solution can reduce the cost of delivery, but the ethoxylated sulfuric acid alcohol solution contains G alcohol so that it can not be used in spray-dried or dry-mixed laundry powder, because of the flammability and medium burning of L alcohol There is a significant risk of processing. In addition, when the surfactant concentrate is blended with the water-soluble detergent powder particles, the amount of water contained will inhibit free flow. Therefore, one object of the present invention is to include debt formation. Oxygenated alcohols with less than 15% Qin grits and essentially free of any organic solvents are listed in Table A 4 (210X297 public) ^ 01329

Λ, Description of the invention (2) Μ Jizhong central wiping quasi-bureau printing active composition. In the two active compositions of the present invention, from the table H (H) H Qian (Non-ion) ^ active oxidation = the combination, each table rain active system used as a mutual solubilizer, so that the liquid can contain at least 85% Active substance. The present invention-another object is to provide a single phase that can be poured at a relatively low a, for example, about 50 ° C. or Ti ^ Qing, and a simple W phase crossing. Another object of the present invention is to use the continuous waves of the I trunk. The present invention relates to a kind of eastern active composition, which is liquid or dried green powder. ', Which includes: ") 15% by weight to gg% by weight. Rolled pheasant, with the formula, where n has ^ to 2 Broken atom · Hyun group or, with 8 to! Aromatic aryl group with 2 broken atoms, n table represents the average number of L times per molecule of the oxygen group and is in the range from i to the design garden,] weight% to 80 weight oxygen Salt of sulfuric acid alcohol, with the formula: -〇-CCH2CH2〇), -S〇iM, where R, is a Hyun group having 8 to 18 K atoms or a Hyun aryl group having 8 to! 2 atoms of this group, m It is-cation 'filtered from catfish metal ions, according to the ions and their mixtures, the average number of L radicals per molecule oxygen in the art table and M to the Pan Fanyuan, and ⑻. Include at least ®% by weight of ingredients Ca), ⑻ and (c), and if necessary, and a kind of suction step shoulder 1 ingredient. This month also about the use of this empty surface active composition to make fen-like cleaning The product and its preparation method β The composition does not contain organic soluble, especially low-molecular-weight organic guest, special low-alcohol with 1 to 5 zizi, especially I Alcohol and ί Please listen to the notes on the back of the product first and then fill in " this Ϊ .Wo-Dai 4- 〒4 (210Χ29Ϋ Public Broadcasting) 01329 A6 .______ B6 V. Description of the invention (3) 肀 醇 〇 Used in this article "Liquid spoon" means a material that can be indignant, and its repair technique and ^ coagulation ^ used in this article "the quality is not included," refers to the amount of organic thorns (if any) is lower than the quality of the goods. -An amount that changes the properties of the composition. The composition typically contains less than 3% by weight of an organic solvent. Formula-RP-CCH2-CH, 0) aH CI) where R is an alkyl group having 8 to 18 broken atoms or an alkyl aryl group having 8 to ^ broken atoms, n represents radon times per molecule I The average number of radicals is in the range of 1 to 12, preferably 2 to 9, and more preferably 2 · to 5. The alkyl group may be an iT or branch broken chain, and the I oxygen component may be a chain or branch The combination of molecules < »Preferably, the R group in the composition—about 10% of the fat is linear. It should be understood that R can be replaced by any precise substituent (such as a letter group). L oxidation in this category Things It is prepared from a series of Luojiao 1 alkylene oxide in the presence of a catalyst in the corresponding enzyme (CHOH). The I radon alcohol component of the present invention is preferably derived from G-oxidized primary or secondary potash chain or branched alcohol. The most common G oxides in this class and particularly useful in the present invention are I-rolled primary alcohols, in formula I, r is an alkyl group and -G-CCH2-GIU0) nH ether substituent is connected to the first level of the alkyl group The compound on the base. The alcohol that is oxidized to form the G-like alcohol component of the present invention includes coconut in the gallbladder (please read the precautions on the back before filling in the main text) • Install · • Hit · Line · 201329 A6 B6 Five 2. Description of the invention (4} Fatty alcohol, bovine hide lipase, Fangfang _ compound, such as k can be obtained on the synthesis of Changjian Zhifang alcohol strain f. Please read the note on the back of this item before filling this page.} s alcohol complex can be obtained from NEODOL _25 · yeast f

Shell Chemical Com-n

Pany's registrar for the manufacture and sale of products Λ), C: 2 to C_J4. Alcohol vibrator from 7- put two decoctions 4 can be obtained from Tergit〇1 24L (this ion We C〇rp〇rat such as Ladders for selling and selling products), and Cr2 to ej3 alcohol complexes are available from NE_C Shell, for example). 3 ^ All together. Violet of oxidized alcohol can be calculated by adding the alcohol or alcohol ice to be oxidized, the amount of which is from 0% to 0.6% by weight, preferably from 0.1% to 0.4% by weight (calculated from the total alcohol content of the jacket) strong base , Typically alkali metal or J earth metal argon radon compounds such as sodium hydrogenated potassium or potassium hydroxide, which is used. Oxidation catalyst. The resulting mixture is dried, such as by removing the existing water, and then epoxy G Xuan is calculated to provide 1 to 12 per ear of ethylene glycol in the amount of ethylene oxide, so that the resulting mixture reacts to Until the consumption of epoxy I alkylene-, the reaction process is detected by the reduction of the reaction pressure work.- The oxidation of G printed by the Ministry of Economic Affairs of the Ministry of Economic Affairs is typically carried out at elevated temperature and pressure. The response of Tonghe is from i2〇 * c to 22〇.c, preferably from ho.c to 160 C. The general reaction power is achieved by adding the desired amount of epoxy resin with a high vapor pressure at the desired anti-It temperature to the reactor. For the safety of the Kaoheng method, the splitting of the epoxy G-hyun reactant is preferably limited to, for example, less than 4 bar, and / or the reactant is preferably sentimental gas plant (such as nitrogen). Dilute to, for example, the vapor phase of the roll The degree is 50% or less. However, the reaction can be safely completed at a greater concentration of Central East I Hyun, a greater total pressure and a greater partial pressure of epoxy G-alkane. If this 7 T 4 (210X297 common eaves) is adopted ^ 01329 ^ 01329 Ά Bureau Printed A6 B6 V. Description of the invention (5) Known precautions in the technique # to deal with the danger of explosion The total pressure is between 3 and 8 barg with epoxy oxygen content between 1 and 4 gage The dagger is better, and the total force is between 3.5 and 7.5 gauge bar and the partial pressure of alkylene oxide is between 1.5 and 3.5 gauge bar. Pressure is used to measure the degree of reaction-response, and the reaction is considered to be substantially completed when the sign force is no longer reduced at any time. It should be understood that the ethylation process is used to oxidize alcohol per ear. Add the desired average number and set the unit to the unit. For example, _ treatment of alcohol mixtures with 3 epoxides per alkyl alcohol can be used to oxidize the alcohol molecules with an average of 3 cycloradonyl groups per alkyl alcohol group, although the proportion of alkanol groups is Combine more than three epoxy I alkyl groups, and approximately equal to less than three combinations. There is also a small proportion of unreacted alcohol in the heterogeneous ethoxylation product mixture. Particular ion-active detergent active compounds that can be used in the compositions of the present invention include lipid oxide I, preferably having {to a primary or secondary monohydric alcohol of Ce to (preferably Ci 2 to hO alkyl and each Ottool on average from 0 to 10% (preferably 2 to 9% of earrings epikane; l alkylene oxide, with k to ^ Hyun group, preferably meaning to ^ Hyun group, and 12 to 12 ears of epoxy resin per ear Alkane. The preferred type of compound is composed of a broken alcohol and 2 to 9 mols per mole of fatty alcohol, plus a table .... Oxides ... The type includes the epoxide of the substituted oxal. The condensed product of Hyun; Narrow starting portion 2 "epi-alcohol and 7-alcohol ... the product of the earrings table ^; narrow ears: may month" fatty C oxygen) alcohol and 6 12 13 d per mole of fatty alcohol, the indentation of the table C alkanes It is known that fatty epi-alcohol is a straight salt, but it depends on the processing conditions. It has a certain degree of branching. In the range of 5% by weight to M ·, depending on it, it can also be in the range of ---- 50% by weight.内 分 分 古 山 ▼ 4 (210X297 Gongai) '-8 ---- 201329 A6 B6 Fifth, the invention of research (6) found in commercially available oxygen alcohol. The weight of the composition of the present invention , Preferably from 25% by weight to: the amount of alcohol can be from 15% by weight to 66% by weight.-75% by weight, more than 28% by weight of the composition of component (b) is dangerous The general species of glucosene from surfactants or oxythiosulfonate are characterized by the following chemical formula ^ -〇-CCH2-CH2〇)

SOsM (please read "Notes on the back and fill in the ears first"). The Central Committee of the Ministry of Economics and Trademarks prints-where Zhuang 'is "or support for Xu Xuanji, with ... broken atoms, compared with 2 to 18 broken atoms" Or a aryl group having 8 to 12 Angstrom atoms is a cation, selected from metal detectors, according to ions and their mixtures, the average number of 1 group per molecule of oxygen in the z table ... to the general range, preferably 5 to 12 'is more preferably 9il2 < > R, preferably large colony is a cross-chain alkyl, at least 50%, preferably about 85% of the Hyun. R in the composition is $ 鐽. It should be understood that R , Can be any inert substituent (for example, substituted by Keith. In one of the "goods", 1 rolled citric acid alcohol is a derivative of a first or second grade alcohol in the range of 8 to 18. The radon sulfate alcohol The precursor of the enzyme is spinosad or it has a supportive structure. In general, the oxidation of I to form i-oxidized alcohol and then the acidic taste sequence can be broken to form the alcohol of the present invention. Aim at fatty alcohols, and commercially available synthetic long-chain fatty alcohol mixtures, such as C "alcohol admixtures can be obtained from NEODOL 25 alcohol C Shell Chemical Con ^ any), to alcohol Compounds can be obtained from Tergitol 24L (Union Carbide Corporation), and. Ordered. • Green. A 4 (210X297 public release) 9 Α6 Β6 V. Description of invention (7) c " To alcohol mixtures can be obtained from NE. DOL 23 alcohol c Shell). The G-oxythiol composition is typically made by reacting the alcohol with the alcohol from each ear to the earrings to form the oxygen-oxidizing agricultural products. After teaching, the alcohol oxidation product will be disproportionated with a decomposing agent,-the resulting acid decomposing product will be neutralized with an aqueous solution of metal, and the β-generalization procedure includes sulfuric acid trioxide decomposition , • Gassylic acid C C1S03H) sulfated and sulfanilic acid (he s〇) sulfated, it is better to break the hair with trioxide. The typical tri-oxidation breaking acidification process includes the liquid H oxidation of alcohol and the gaseous tri-dongdong destruction at about atmospheric force, in the water-cooled reaction zone of the drop-touch breaking acidifier, at 3, c to π, cs Contact within a range of degrees to produce sulfur oxides. The sulfuric acid sulfate of the ethoxylated alcohol is then discharged from the falling film column, and it is neutralized with a metal solution such as hydrogenated sodium or potassium to form I-like sulfuric acid alkoxide. Specific sulfated 1 oxidized cleanser active compounds that can be used in the compositions of the present invention include sulfated fatty alcohols, preferably straight money with ^ to Cu ('than Gui 2 to cz j) dazzling base, Grade or secondary alcohol, and the average 1 to 12 C of alcohol per ear is preferably 5 to! 2 Talk about epoxide L-alkanes, and have k to

Cu alkyl (preferably Ce to alkyl) is deacidified and alkyl oxide is oxidized, and the average molecular weight per mole of alkyl alcohol is to pan-mole ethylene oxide. The preferred type of G-oxygen sulfate is sulfated straight-chain alcohol, such as alcohol with an average of 5 to 100%. It is printed by the Central Department of Economic Affairs of the Ministry of Economy. The best ethoxylated sulfuric alcohol is prepared by sulfation of Cw-C: 3 alcohol oxidized by 65 oxirane ethylene oxide I. In the preferred embodiment, the thin I-sulfated component has a higher average number of table-based g-units per molecule than the U-oxidized fit. . Oxysulfuryl alcohol_The average teaching code of the parent molecular oxygen sub-c base element is also in I $ 19 Fan ▼ 4 (210X297 «) 10 years Π IjH --- 1¾¾] A6 -___ B6 V. The invention says that (8) to 12 * It is better to be 9 to 1 ?, 7 4yfJ »& lSA, divided into the rolling times B M_,-two points to 12, 1 oxidation cup injury from the average number of 25 Wu typical In the range of 1 to 12, from 2 to 9, more preferably from 2 to 5. The amount of I-oxo-acid alcohol present in the composition in the left ## of Zhongjin is within 1% by weight to 10% by weight, preferably 25% by weight to 75% by weight. ! 2, # '公 ； * ·· __ 12-more preferably from 9 to 12, each in the alcohol composition. Preferably, the amount of & I oxybromic acid-alcohol is in the range of [% by weight to such a weight < Preferably for -5 g,... Β weighs 1% to 75% by weight, more preferably 28%

Main 66% by weight 9 Fruit I: 缶 C a) The ethoxylated alcohol can vary widely on the component (upper) sulfur, the weight ratio "l ^ kt weight I is better than the range of 3: i JLi: 3 preferably 2: 1 To i: 2. The component (C) of the Tic surfactant composition is taken as water. The amount of water used in the composition is less than κ weight% of the composition, preferably less than 10 weight = preferably less than 7% by weight, most preferably less than 5% by weight. When there is no water, such as: dagger alcohol shortage or ―. Alcohol amine is used to neutralize the wound, the amount of water can be controlled most effectively. Strong, by dry-dry or by adding water-, too very ten Shen # &… 'Mizuki X can also be controlled in the system using alkali-metal neutralizing agent'. The desired amount of water can be light-easy by the general proficiency in this technique. It can be determined with a minimum amount of slave test. The dish of the liquid surface-active composition of the present invention can be completed by mixing together using any of the cosmetics. However, it is generally preferred to add the unneutralized ethoxylated alcohol product (printed by the sulfation reaction of organic sulfur) to the Ministry of Economy to knead the bureau to print the alcohol and concentrated alkali. 50% argon sodium hydroxide dissolved in water) fully stirred and mixed ^ inside. Other remote bases include potassium hydroxide, ammonium hydroxide, diethanol and monoethanol. . The content of the surface active substance typically possessed by the liquid ancestor compound of the present invention, please print on the back of the first page, and then write on the back side of the item. * A / 4 (210X297) Provincial Ministry of Economics and Trademark Outfit

201329 V. Description of the invention (9 to half and half. The percent of the acid-rolled alcohol is the second of the composition =, preferably to W, more preferably to "% by weight. It is preferably alcohol-soluble, more preferably It has a type of less than 3% by weight, and more preferably has 1 to 5 angstroms of low Sf solvent. The compound can be used in various cleaning conditions, and the composition can be in a relatively low C.C or other quality state. ^ The active agent composition can also be added to water to form a liquid cleaning agent with lower activity: refolding. ^ The body is illustrated in the following yellow. The example is shown below, it is for illustration, and should not be construed as limiting the invention. .

It Example 1 Mistake of thorn composition

iAji # 剌 组 厶 铷 A has a -Cjj alkyl group and contains an average of 65 earrings of ethane / cohol. Radon alcohol C is commercially available from NEODOL 23_65 alcohol) wheat s〇3 in a laboratory-scale falling film reactor reacted and sulfated to form [oxyacid alcohol alcohol and its ear M w, reactor The temperature is that the acid product is prepared at a rate of 8 g / min. It is directly contained in a table containing 16.1 g of a 50% sodium oxyhydroxide date solution and a table with _Ch alkyl mesh containing an average of 5 g of epoxide G alkanol / gear Pre-mixed solution of alcohol (commercially available from NEODOL 23.5 alcohol)-neutralized. The surface-active spiny mixture is fully stirred by using a magnetic stirring method, and the temperature of the mixture is outside water: {please first "Continue the note on the back side and then fill in this booklet] • Pack. • Hit the line • 201329 A6 B6 V. Description of the invention (丨 〇)-· * · Keep at 55'C. In the whole process of this method, no formation of condensate was found in this process. Add about 〇grams of acid * from the tax acidifier, and wait until the pH 8 is measured with wet PH paper. The final product is a clear and tangible liquid ritual at .20 .C, which has the following analytical composition: * • 48% by weight I • Dong · Sulfate (sodium salt) • 46% by weight. Rolling alcohol-5% by weight of water.-1 weight of sodium sulfate and trace by-product table two compatibility agent combination • Field A sticky seat at 50, c-and the rate of 〇. 〇 second use Brookfield LVTD type The viscosity meter measured 0.2 Pa. Table I shows the viscosity of the surfactant composition A and the viscosity of the ethoxylated alcohol / water composition (containing the same amount of ethoxylated alcohol as the surfactant composition A and the remaining composition is water) and the ethoxylated sulfuric acid fermentation / water composition (Contains the same amount of table two active agent composition A table l sulfate fermentation and the rest of the group. Become water> Comparison of the catfish degree. As shown in Table I, containing 94% by weight of surfactant composition containing surfactant The viscosity of A is lower than the viscosity of c-oxygenated alcohol / water composition and i-epi-acid alcohol / water composition. F Please rest on the back first < Precautions then «. Write this page 0 • St. • tr .Line · «Jibuzhong. Central Central Bureau of Printing and Printing T 4 (210X297 common eaves) 13 ^ 013 £ 9 A6 B6 V. Description of invention (11) Table G Oxidation of alcohol_ethoxybrokenol viscosity% by weight% by weight % By weight (C Pa.s) Surfactant composition A 46 48 5 0.2 Alcohol / H20-a single surface active composition] Composition 46 0 5 4 > 4 0 1 Oxygen sparse alcohol / h2o Surfactant composition 0 48 52 > 4 0 Surfactant composition B 1 (please read the precautions on the back before filling in the ear) • Pack · • Order. • Line · Ministry of Economic Affairs For printing, mix 10g of Surfactant Composition A with 4kl of NEODOL 23-5 alcohol, and use it to make a liquid fluid with a residue of 20, which has the following composition: -34% by weight I oxygen Alcohol sulfate C sodium salt) -62% by weight I oxidized alcohol-3% by weight water 4 (210X297 Koji) 14 «£ Printed by the Central Kneading Bureau of the Ministry of Economy ^ 01-329 A6 .______ B6_ V. Description of the invention (12) .-< 1% by weight of sodium sulfate and the amount of product composition of the product | i degree in _50 Ct aromatic years 〇.42 Miao-* * down to Ze or 〇1 Pa · S 〇 Table Π display surface 涪Viscosity of sexual erythrochrome β and c-oxidized alcohol / water composition (containing the same amount of I-oxidized alcohol as surfactant composition B, and the remaining composition is the viscosity of water D and I-oxyacidase / water composition (containing Comparing the standpoint of the equivalent amount of hexoxysulfate JL with the surface active agent composition B and the rest of the composition as water). As shown in Table II, the degree of the surface active composition B containing SS wt% total surfactant The merchandise is lower than the catfish degree of the oxidized alcohol / water composition and the L-oxyacid alcohol / hydrino compound. —Table _I Resolve the dwelling rate of the alcohol. Recheck% 'wt% wt% C Pa 4) {Please first Notes on the back of Xian Jing will write the ear again) • Installed • • Played. Surfactant is composition B 62 34 3 0.1 k ML 稃 / Η, Ο Surfactant composition 62 0 38 31 m 無 alcohol / Ha〇 Table rain active thorn composition 0 34 66 > 40 »A 4 (210X297 Koji) --15-201329 A6 B6 V. Description of the invention (13

For the multi-surfactant group, rubidium C uses the procedure described in Table A for the combination of the two active agents, but 145-gram acid form of I-oxysulfuric acid alcohol contains 24 grams of 50% aqueous solution of sodium argon radon and M free NE〇D. L 23-5 Mang's premixed solution is neutralized. "The last 20 grams of product is masked with 0.7 grams of NEODOL 23-5 ephemera, with« prepared at 35.C as a slag clear flowable fluid ft composition, which has the following composition: --61% by weight 1 oxysulfate alcohol ( ; Sodium salt)-32% by weight of oxidized alcohol '6% by weight of water-1% by weight of sulfuric acid system and trace by-product composition viscosity at 50. C and slowness of 0.42 seconds to Xun 2

Pa.S 〇Table H shows the viscosity of the two active agent composition C and the i-oxidized alcohol / water combination (containing the same amount of ethoxylated alcohol as the surfactant composition C and the remaining composition is water) ^ Comparison of the drillability of G oxysulfate alcohol / water composition (containing the same amount of ethoxythiol alcohol as surfactant composition C and the remaining groups: becoming water). As shown in Table m, the degree of the two active creative compounds c containing f 3% by weight of the total active agents on the table is lower than that of the alcohol / water combination poplar and l-oxyfiscerol / water combination The viscosity of the substance. {Please first «read the notes on the back and then fill out the Hundred). Installed and hit the edge of the Ministry of Economic Affairs. Printed by the Central Bureau of Accreditation 16 A 4 (210X297 Gongshou) ^ 01329 A6 B6

V. Description of the invention (14) Table I Alcohol 1 Dongbaol H20 Viscosity-. Wt% wt% wt% C Pa .s Table two active thorns 32 61 6 0 Button: Compound C-1 like alcohol / h2o Surface active thorn composition 32 0 6S 23 1 Toshinol / Η, ο 0 61 39 > 4 0 {Please first read the precautions on the back side and then fill out this Ϊ · «... Dozen. Table rain active agent composition --Example 2 Pearbee Cleansing Composition of Cleaner Composition '1 Heat 34g of neutralized surface active composition A to 50 * C and add 125g of low density 2/1 C at a rate of 2.2ml / min Weight ratio) acid-acid sodium / hydrogen sodium / sodium citrate mixture. During the addition of the two-acting agent in the table, use the double flag or Yingjia 4 (210X297 Gongai) at the B0 turn per minute in the Bra bender viscometer V-3A. • Line. Printed by the Central Bureau of Economic Development of the Ministry of Economic Affairs 17 The surname of the Ministry of Economic Affairs and Central Bureau of Printing and Printing 201329 A6 ._____ B6 V. Description of the invention (15) The device is mixed. Get free-flowing non-blocky costumes. The powder flow properties are measured using the quasi-funnel funnel flow test, which even measures the time required for the 50 gram powder sample to pass through the test funnel. The average flow rate can then be measured. In this test, the typical small holes in the laundry detergent container are simulated. The typical commercial laundry has a flow rate of between 5 g / sec and 9 g / sec. . After an aging time of one week, the average flow rate of detergent progenitor 1 is 6.3 g / sec. By comparison, the feed was prepared in a similar manner-however, the powder containing 35 grams of NEODOL 23-5 alcohol as the sole surfactant did not flow through the funnel. …-The cleaning properties of the cleaning agent composition 1 are evaluated using the standard so-called earth-edge cleaning test procedure, which is described in many technical balances-such as Chemical Times & Trends · Vol. 8, p. 31 and Journal tha American Oil Chemists ^ Society, Vol. 45 p. 537 · ό Detergent composition 1 has a concentration of 0.07 _% by weight, washing 3 »degree 38 C» water attack degree 15 0 ppm- Breaking sour (C a / M g = 3/2, • calculated in moles). 65/35 Polyurethane / Cotton fabric removed from the durable treatment to remove the dirt, obtained the following results: dirt removal unit 30 49 32 (please read the precautions on the back before filling this page.).

Jf Dilute Petroleum Synthetic Support S Clay Armor 4 (210X297 Koji) ^ 01329 ^ 01329 «Jebu Central Central Bureau of Printing and Printing A6 B6 V. Description of the invention (16) In the same test, the commercially available cleaning agents are in the same concentration Use Xunxun to shift the amount. Cleaning composition 7. Use the procedure described in Detergent Composition 1, but add 32 grams of surface-active composition A to make it have a hair keto acid argon platinum / hip acid rate mud compound and Perk low-density dimerization Fill in the mixture of endless acid rates. The resulting detergent powder had an average flow rate of 5.0 g / sec in the quasi-funnel flow test after one week of aging. Use the procedures and conditions described in the cleaning agent compound i. The amount of dirt transfer applied to this cleaning compound is as follows: Dirt removal% stone oil 28 Synthetic mooring 60 Clay 34 Example 3 Living compound

The main product D has a C, 2-Ci3 alkyl group and a C radon alcohol C containing an average of 6.5 earrings and alkane / molol. Commercially available from NEODOL 23-6. 5 alcohol) and s〇a in the laboratory The scale of the falling film reactor reacts and sulfates / to form I oxyacid alcohol ° S〇s / I compound has an ear ratio of 1.05, the reactor a degree is 65C 'acid product at a speed of 8 g / min. Prepare and directly contain {please read the precautions on the back before filling out this page_) • Install · -Green-

101329 A6 B6 V. Description of the invention (17) Printed by the Central Bureau of Eel Economy, 9.9 grams of 50% aqueous sodium oxyhydroxide solution and 15 gram of ο "-Hyunji and containing an average of 5 earrings on the table. Neutralize the pre-mixed solution of its U-alcohol (commercially available from NEODOL 23-5 alcohol). The surface-active mixture is fully mixed by using magnetic stirring method. The temperature of the mixture should be at 55 * C. No condensate formation was found throughout the process. Add: 佂 得. From the pit acidifier: about go grams of acid product, until the pIi 8 is measured with wet pH paper. The final product is a clear and flowable liquid at 20 * C, with the following analytical composition-:-.-28% by weight of 1 sodium oxysulfate salt)-67% by weight of ethoxylated alcohol-4% by weight of water-1% by weight of 碇Sodium sulfate and trace by-products are listed in Table 2. Two active agents are used in each surfactant. The procedure described in Surfactant Composition D is used. NEODOL 23 -5 alcohol is pre-mixed and neutralized. The final product is Qiao 40 · (: clear and flowable liquid gift, which has the following sub-composition:-© wt% ethoxylated sulfuric acid alcohol C sodium salt)-22 wt-rolled fresh--7 wt% water • 2 wt% Rates and trace by-products of sulphur, please firstly listen to #Notes on the back and then fill out this page). Install. • Hit ·. Line. A 4 (210X297 public issue) -20 ^ 01329

Fifth, the invention of 寨 (zhao) Example 4 tL Tong Qing Lian Ru Ji He Yang i3 prepared by Qinghanbeiya 34 g of neutralizing and expressing activity W technical cooperation field D was heated to 50.c, 2.2 ml / min At the rate of 125, the low density 2/1 (weight ratio) breaks the argon #! / 璩 ether for Λ Ϋ in the table. During the addition of the two active systems in the table, Matsushita is included in the Bz ^ bender privacy meter V-3¾ In every minute, you can use double flags or stirrers to stir. Get free-flowing Pak bulk powder. The endless flow-free congratulation system uses the quasi-funnel and dynamic test of trousers, in which a sample of 50 grams of Fenmo is passed through the test funnel. After the game's time, you can go to Liangping for the record year. In this test, the typical small rolls with a “clean detergent capacity” are used. Typical commercially available powders have an average flow rate of 5 g / sec to 9 g〆sec. Higher flow rates are more ideal. 。 Qing_Jie system combination for 3 years * fi ip initial <average dry flow rate is 6.9 g / s, so it is a medium commodity. By comparison, with phase ^,-not like sound Tan but contains 35 grams of NEODOL 23 fly alcohol as The only negative-acting agent is pink powder. The catching speed is 5.9 g / s, and the NEODOL 23-5 r S7 * λ ^ 67 g). The endless benefits of the Xunxun can not stop the funnel. {Please read the back side first Pay attention to tf and then call for this tile) • outfit. • hit, • line • pheasant central bureau quasi-bureau printed armor 4 (210X297 public hair) 21

Claims (1)

01329, Guang? Min Zunli asked Feng to apply for the revised version of Winter Arrival (November 1981) A table two active composition. It is a liquid technology or dried bee powder, which includes: U) 20% by weight to TO weight H epi-alcohol, with the formula * f surprised first notice the precautions on the back of the sticks before they can be « ) R-〇-CCH, CHaO) aH, where R is a strontium group with 8 to 12 broken atoms or a strontium group with 8 to -12 broken atoms, 〇 represents the oxygen G group of each child The average number and within the range of Wei to Pan Fan, (b) 70% to 20% by weight of 1 table-sulfate alcohol ||, Yi You Shi Pian -〇-CCH, CH2〇), -S〇, M , Where R, is an alkyl group having 8 to 15 atoms or an alkylaryl group having 8 to 12 carbon atoms, and M is a citric acid, selected from the group consisting of metal ions, ammonium ions, and mixtures thereof, each The 'average number of the I group in the molecular table is within the range, and ⑷ · 〇. "Wt% to 15wt% water, in which the component" ... b) includes at least the secret weight% Cheng _, _e), if necessary, and- This kind of adsorbed secret powder_agent ingredients, the amount of the adsorbent Fenmo cleanser is 2 to 5 times of the skill of the liquid to be adsorbed. 2. The surface-active composition according to item i of the patent application garden, which includes an amount of 5% to 1% by weight of the alcohol, which has the formula -ΙΙ-〇-(: ί: Η2 (: Η, 〇) β Η, where R is an alkyl group having 8 to 8 broken atoms or an alkylaryl group having 8 to 12 carbon atoms, and the average number of oxyethylene groups per molecule of the horse table is in the range of 1 to 12, (B) 66 weights. / To 28 weights: salt of oxoic acid alcohol, having the formula 〇CCHaCH ^ O), -s〇3M, where R, is a bright group with 8 to 18 K atoms or has 8 magic 2 shattered aryl radicals, M is-cation 'is selected from metal detectors, according to the heteros and their mixtures, X table is the number of sub-oxygen sub-groups and is in the range of 1 to general range Time, and Cc) 0 · 01 weight: £% to 15 weights of water, of which component u) and (b) to ^ 01329 A7 B7 C7 D7 6. Applying for a patent Fan Ming The central economic center rubs the quasi-Jh printing compound at 85% by weight, and the weight ratio of ... to ... is 1.1 to 1: 2.申 靖 专 _The scope of the surface active composition of item 1 or 2 of the benefit range r '--resembling Liuding (ς c) includes 0.01% by weight to 10% by weight of water, and the components-a) and C b) account for at least 90 % By weight into your weight 4 a), rh, π Cc) ^ C rattan and ^ According to the first compound of the patent scope of Shenjing, where the component ⑷ becomes C b) by weight (dagger in 3 &gt; i to 1: 3 Fan 囷 内. .5. 1According to the patent application, Fan Li No. lil2㉖'s surface active composition 'wherein the composition does not contain organic solvents on the goods. The surface active group mouthpiece, wherein the group composition does not substantially contain a low alcohol solvent. IS root I * please patent range, the liquid surface active combination R-〇- C CH CH 2 including t at least 1 Moer three gasification sulphur gas ceremony and every mole has a complete ... with ... alcohol (where R is 8 to 18 from the alkyl group or 8 to 12 20 to the heart # 度 ^ atomic synthesis "Yuan aryl group" is neutralized under the mixed pressure condition of the obtained reaction of Wei and argon oxidation, as well as the preparation of alcohols and concentrated argon-rolled sodium oxidation bells or gas oxidation solutions Ren Pi. T-shirt and &amp; According to the method of patent application item 7_, which includes the method of matching 1 profit range 7 item T Yanzi; cleansing ingredients ..... composition and-or more The end of Qing Jia 4 (210X297 public) ................................................ ............. St .............................. * r ... ...... 一 ..................... End (please read the precautions on the back before filling in the Luan page)