TW201400522A - 聚對苯二甲酸丁二酯樹脂組成物及成形體 - Google Patents
聚對苯二甲酸丁二酯樹脂組成物及成形體 Download PDFInfo
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- TW201400522A TW201400522A TW102111083A TW102111083A TW201400522A TW 201400522 A TW201400522 A TW 201400522A TW 102111083 A TW102111083 A TW 102111083A TW 102111083 A TW102111083 A TW 102111083A TW 201400522 A TW201400522 A TW 201400522A
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- Prior art keywords
- polybutylene terephthalate
- terephthalate resin
- resin composition
- voc
- amount
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- -1 Polybutylene terephthalate Polymers 0.000 title claims abstract description 106
- 229920001707 polybutylene terephthalate Polymers 0.000 title claims abstract description 93
- 239000011342 resin composition Substances 0.000 title claims abstract description 44
- 229920005989 resin Polymers 0.000 claims abstract description 62
- 239000011347 resin Substances 0.000 claims abstract description 62
- 238000000034 method Methods 0.000 claims abstract description 31
- 150000001875 compounds Chemical class 0.000 claims abstract description 28
- 238000005886 esterification reaction Methods 0.000 claims abstract description 18
- 238000000465 moulding Methods 0.000 claims abstract description 18
- 230000032050 esterification Effects 0.000 claims abstract description 15
- 238000000691 measurement method Methods 0.000 claims abstract description 6
- 239000003513 alkali Substances 0.000 claims description 26
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 16
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 14
- 235000011056 potassium acetate Nutrition 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 1
- 239000012855 volatile organic compound Substances 0.000 abstract description 41
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 16
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 14
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- 238000004898 kneading Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 235000002639 sodium chloride Nutrition 0.000 description 6
- 238000005809 transesterification reaction Methods 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 229960003563 calcium carbonate Drugs 0.000 description 4
- 235000010216 calcium carbonate Nutrition 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- WSQZNZLOZXSBHA-UHFFFAOYSA-N 3,8-dioxabicyclo[8.2.2]tetradeca-1(12),10,13-triene-2,9-dione Chemical compound O=C1OCCCCOC(=O)C2=CC=C1C=C2 WSQZNZLOZXSBHA-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000002667 nucleating agent Substances 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- DCTMXCOHGKSXIZ-UHFFFAOYSA-N (R)-1,3-Octanediol Chemical compound CCCCCC(O)CCO DCTMXCOHGKSXIZ-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- QXDMQSPYEZFLGF-UHFFFAOYSA-L calcium oxalate Chemical compound [Ca+2].[O-]C(=O)C([O-])=O QXDMQSPYEZFLGF-UHFFFAOYSA-L 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 229940095672 calcium sulfate Drugs 0.000 description 2
- 235000011132 calcium sulphate Nutrition 0.000 description 2
- PYSZASIZWHHPHJ-UHFFFAOYSA-L calcium;phthalate Chemical compound [Ca+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O PYSZASIZWHHPHJ-UHFFFAOYSA-L 0.000 description 2
- 239000007809 chemical reaction catalyst Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- YNQRWVCLAIUHHI-UHFFFAOYSA-L dilithium;oxalate Chemical compound [Li+].[Li+].[O-]C(=O)C([O-])=O YNQRWVCLAIUHHI-UHFFFAOYSA-L 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 2
- GOMCKELMLXHYHH-UHFFFAOYSA-L dipotassium;phthalate Chemical compound [K+].[K+].[O-]C(=O)C1=CC=CC=C1C([O-])=O GOMCKELMLXHYHH-UHFFFAOYSA-L 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- SNKMVYBWZDHJHE-UHFFFAOYSA-M lithium;dihydrogen phosphate Chemical compound [Li+].OP(O)([O-])=O SNKMVYBWZDHJHE-UHFFFAOYSA-M 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- KYKNRZGSIGMXFH-ZVGUSBNCSA-M potassium bitartrate Chemical compound [K+].OC(=O)[C@H](O)[C@@H](O)C([O-])=O KYKNRZGSIGMXFH-ZVGUSBNCSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 description 2
- 235000011151 potassium sulphates Nutrition 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 150000003304 ruthenium compounds Chemical class 0.000 description 2
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- ZYUVGYBAPZYKSA-UHFFFAOYSA-N 5-(3-hydroxybutan-2-yl)-4-methylbenzene-1,3-diol Chemical compound CC(O)C(C)C1=CC(O)=CC(O)=C1C ZYUVGYBAPZYKSA-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- AZFNGPAYDKGCRB-XCPIVNJJSA-M [(1s,2s)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene Chemical compound [Ru+]Cl.CC(C)C1=CC=C(C)C=C1.C1=CC(C)=CC=C1S(=O)(=O)[N-][C@@H](C=1C=CC=CC=1)[C@@H](N)C1=CC=CC=C1 AZFNGPAYDKGCRB-XCPIVNJJSA-M 0.000 description 1
- KDSSEOIBFVTMNM-UHFFFAOYSA-N [K].[K].[K].P(O)(O)(O)=O Chemical compound [K].[K].[K].P(O)(O)(O)=O KDSSEOIBFVTMNM-UHFFFAOYSA-N 0.000 description 1
- NOJZFGZMTUAHLD-UHFFFAOYSA-N [Li].[Cl] Chemical compound [Li].[Cl] NOJZFGZMTUAHLD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 235000011126 aluminium potassium sulphate Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 239000004301 calcium benzoate Substances 0.000 description 1
- 235000010237 calcium benzoate Nutrition 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229940062672 calcium dihydrogen phosphate Drugs 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000004281 calcium formate Substances 0.000 description 1
- 235000019255 calcium formate Nutrition 0.000 description 1
- 229940044172 calcium formate Drugs 0.000 description 1
- 239000004227 calcium gluconate Substances 0.000 description 1
- 235000013927 calcium gluconate Nutrition 0.000 description 1
- 229960004494 calcium gluconate Drugs 0.000 description 1
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229940095643 calcium hydroxide Drugs 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 239000001362 calcium malate Substances 0.000 description 1
- OLOZVPHKXALCRI-UHFFFAOYSA-L calcium malate Chemical compound [Ca+2].[O-]C(=O)C(O)CC([O-])=O OLOZVPHKXALCRI-UHFFFAOYSA-L 0.000 description 1
- 229940016114 calcium malate Drugs 0.000 description 1
- 235000011038 calcium malates Nutrition 0.000 description 1
- ROPDWRCJTIRLTR-UHFFFAOYSA-L calcium metaphosphate Chemical compound [Ca+2].[O-]P(=O)=O.[O-]P(=O)=O ROPDWRCJTIRLTR-UHFFFAOYSA-L 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229960001714 calcium phosphate Drugs 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 229940078456 calcium stearate Drugs 0.000 description 1
- GUPPESBEIQALOS-UHFFFAOYSA-L calcium tartrate Chemical compound [Ca+2].[O-]C(=O)C(O)C(O)C([O-])=O GUPPESBEIQALOS-UHFFFAOYSA-L 0.000 description 1
- 239000001427 calcium tartrate Substances 0.000 description 1
- 235000011035 calcium tartrate Nutrition 0.000 description 1
- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 description 1
- QXDHJHQRJCJRAU-UHFFFAOYSA-N calcium;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Ca].OC(=O)CC(O)(C(O)=O)CC(O)=O QXDHJHQRJCJRAU-UHFFFAOYSA-N 0.000 description 1
- PBUBJNYXWIDFMU-UHFFFAOYSA-L calcium;butanedioate Chemical compound [Ca+2].[O-]C(=O)CCC([O-])=O PBUBJNYXWIDFMU-UHFFFAOYSA-L 0.000 description 1
- FYPVXEILSNEKOO-UHFFFAOYSA-L calcium;butanoate Chemical compound [Ca+2].CCCC([O-])=O.CCCC([O-])=O FYPVXEILSNEKOO-UHFFFAOYSA-L 0.000 description 1
- HZQXCUSDXIKLGS-UHFFFAOYSA-L calcium;dibenzoate;trihydrate Chemical compound O.O.O.[Ca+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 HZQXCUSDXIKLGS-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- VEIOBOXBGYWJIT-UHFFFAOYSA-N cyclohexane;methanol Chemical compound OC.OC.C1CCCCC1 VEIOBOXBGYWJIT-UHFFFAOYSA-N 0.000 description 1
- NHADDZMCASKINP-HTRCEHHLSA-N decarboxydihydrocitrinin Natural products C1=C(O)C(C)=C2[C@H](C)[C@@H](C)OCC2=C1O NHADDZMCASKINP-HTRCEHHLSA-N 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000019700 dicalcium phosphate Nutrition 0.000 description 1
- ZMRYOLSXRRMRBY-UHFFFAOYSA-L dilithium diformate Chemical compound [Li+].[Li+].[O-]C=O.[O-]C=O ZMRYOLSXRRMRBY-UHFFFAOYSA-L 0.000 description 1
- KPHBXCOBSIAOGG-UHFFFAOYSA-L dilithium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Li+].[Li+].OC(=O)CC(O)(C([O-])=O)CC([O-])=O KPHBXCOBSIAOGG-UHFFFAOYSA-L 0.000 description 1
- JHFZWTMEVGPUTE-UHFFFAOYSA-L dilithium;2-hydroxybutanedioate Chemical compound [Li+].[Li+].[O-]C(=O)C(O)CC([O-])=O JHFZWTMEVGPUTE-UHFFFAOYSA-L 0.000 description 1
- VNSVQJIXVXZDJF-UHFFFAOYSA-L dilithium;phthalate Chemical compound [Li+].[Li+].[O-]C(=O)C1=CC=CC=C1C([O-])=O VNSVQJIXVXZDJF-UHFFFAOYSA-L 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- UZLGHNUASUZUOR-UHFFFAOYSA-L dipotassium;3-carboxy-3-hydroxypentanedioate Chemical compound [K+].[K+].OC(=O)CC(O)(C([O-])=O)CC([O-])=O UZLGHNUASUZUOR-UHFFFAOYSA-L 0.000 description 1
- CVOQYKPWIVSMDC-UHFFFAOYSA-L dipotassium;butanedioate Chemical compound [K+].[K+].[O-]C(=O)CCC([O-])=O CVOQYKPWIVSMDC-UHFFFAOYSA-L 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- WPUMTJGUQUYPIV-JIZZDEOASA-L disodium (S)-malate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)CC([O-])=O WPUMTJGUQUYPIV-JIZZDEOASA-L 0.000 description 1
- 239000002526 disodium citrate Substances 0.000 description 1
- 235000019262 disodium citrate Nutrition 0.000 description 1
- 229940079896 disodium hydrogen citrate Drugs 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 1
- HQWKKEIVHQXCPI-UHFFFAOYSA-L disodium;phthalate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C([O-])=O HQWKKEIVHQXCPI-UHFFFAOYSA-L 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229940044170 formate Drugs 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229950006191 gluconic acid Drugs 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 1
- 229940031993 lithium benzoate Drugs 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- WJSIUCDMWSDDCE-UHFFFAOYSA-K lithium citrate (anhydrous) Chemical compound [Li+].[Li+].[Li+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WJSIUCDMWSDDCE-UHFFFAOYSA-K 0.000 description 1
- 229940071260 lithium gluconate Drugs 0.000 description 1
- 229910000032 lithium hydrogen carbonate Inorganic materials 0.000 description 1
- MRVHOJHOBHYHQL-UHFFFAOYSA-M lithium metaphosphate Chemical compound [Li+].[O-]P(=O)=O MRVHOJHOBHYHQL-UHFFFAOYSA-M 0.000 description 1
- IDNHOWMYUQKKTI-UHFFFAOYSA-M lithium nitrite Chemical compound [Li+].[O-]N=O IDNHOWMYUQKKTI-UHFFFAOYSA-M 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- WAHQBNXSPALNEA-UHFFFAOYSA-L lithium succinate Chemical compound [Li+].[Li+].[O-]C(=O)CCC([O-])=O WAHQBNXSPALNEA-UHFFFAOYSA-L 0.000 description 1
- 229960004254 lithium succinate Drugs 0.000 description 1
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
- ZPPPLBXXTCVBNC-ZVGUSBNCSA-M lithium;(2r,3r)-2,3,4-trihydroxy-4-oxobutanoate Chemical compound [Li+].OC(=O)[C@H](O)[C@@H](O)C([O-])=O ZPPPLBXXTCVBNC-ZVGUSBNCSA-M 0.000 description 1
- ZOTSUVWAEYHZRI-JJKGCWMISA-M lithium;(2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Li+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O ZOTSUVWAEYHZRI-JJKGCWMISA-M 0.000 description 1
- LJURPJZOPVZKTQ-UHFFFAOYSA-M lithium;2-carboxybenzoate Chemical compound [Li+].OC(=O)C1=CC=CC=C1C([O-])=O LJURPJZOPVZKTQ-UHFFFAOYSA-M 0.000 description 1
- GKQWYZBANWAFMQ-UHFFFAOYSA-M lithium;2-hydroxypropanoate Chemical compound [Li+].CC(O)C([O-])=O GKQWYZBANWAFMQ-UHFFFAOYSA-M 0.000 description 1
- WNCZOFYWLAPNSS-UHFFFAOYSA-M lithium;3-carboxy-3,5-dihydroxy-5-oxopentanoate Chemical compound [Li+].OC(=O)CC(O)(C(O)=O)CC([O-])=O WNCZOFYWLAPNSS-UHFFFAOYSA-M 0.000 description 1
- LDJNSLOKTFFLSL-UHFFFAOYSA-M lithium;benzoate Chemical compound [Li+].[O-]C(=O)C1=CC=CC=C1 LDJNSLOKTFFLSL-UHFFFAOYSA-M 0.000 description 1
- WIAVVDGWLCNNGT-UHFFFAOYSA-M lithium;butanoate Chemical compound [Li+].CCCC([O-])=O WIAVVDGWLCNNGT-UHFFFAOYSA-M 0.000 description 1
- XKPJKVVZOOEMPK-UHFFFAOYSA-M lithium;formate Chemical compound [Li+].[O-]C=O XKPJKVVZOOEMPK-UHFFFAOYSA-M 0.000 description 1
- HQRPHMAXFVUBJX-UHFFFAOYSA-M lithium;hydrogen carbonate Chemical compound [Li+].OC([O-])=O HQRPHMAXFVUBJX-UHFFFAOYSA-M 0.000 description 1
- HPCCWDVOHHFCKM-UHFFFAOYSA-M lithium;hydrogen sulfate Chemical compound [Li+].OS([O-])(=O)=O HPCCWDVOHHFCKM-UHFFFAOYSA-M 0.000 description 1
- DXUUIDJNCBRHDV-UHFFFAOYSA-M lithium;hydron;oxalate Chemical compound [Li+].OC(=O)C([O-])=O DXUUIDJNCBRHDV-UHFFFAOYSA-M 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002697 manganese compounds Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000019691 monocalcium phosphate Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 235000016337 monopotassium tartrate Nutrition 0.000 description 1
- HWPKGOGLCKPRLZ-UHFFFAOYSA-M monosodium citrate Chemical compound [Na+].OC(=O)CC(O)(C([O-])=O)CC(O)=O HWPKGOGLCKPRLZ-UHFFFAOYSA-M 0.000 description 1
- 239000002524 monosodium citrate Substances 0.000 description 1
- 235000018342 monosodium citrate Nutrition 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- WCGOOOYCJYHLRW-UHFFFAOYSA-I pentalithium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Li+].[Li+].[Li+].[Li+].[Li+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O WCGOOOYCJYHLRW-UHFFFAOYSA-I 0.000 description 1
- RAFRTSDUWORDLA-UHFFFAOYSA-N phenyl 3-chloropropanoate Chemical compound ClCCC(=O)OC1=CC=CC=C1 RAFRTSDUWORDLA-UHFFFAOYSA-N 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229940050271 potassium alum Drugs 0.000 description 1
- GNHOJBNSNUXZQA-UHFFFAOYSA-J potassium aluminium sulfate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GNHOJBNSNUXZQA-UHFFFAOYSA-J 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000004300 potassium benzoate Substances 0.000 description 1
- 235000010235 potassium benzoate Nutrition 0.000 description 1
- 229940103091 potassium benzoate Drugs 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 description 1
- 229910000343 potassium bisulfate Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229960002816 potassium chloride Drugs 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
- JMTCDHVHZSGGJA-UHFFFAOYSA-M potassium hydrogenoxalate Chemical compound [K+].OC(=O)C([O-])=O JMTCDHVHZSGGJA-UHFFFAOYSA-M 0.000 description 1
- 229940086065 potassium hydrogentartrate Drugs 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- PHZLMBHDXVLRIX-UHFFFAOYSA-M potassium lactate Chemical compound [K+].CC(O)C([O-])=O PHZLMBHDXVLRIX-UHFFFAOYSA-M 0.000 description 1
- 239000001521 potassium lactate Substances 0.000 description 1
- 235000011085 potassium lactate Nutrition 0.000 description 1
- 229960001304 potassium lactate Drugs 0.000 description 1
- SVICABYXKQIXBM-UHFFFAOYSA-L potassium malate Chemical compound [K+].[K+].[O-]C(=O)C(O)CC([O-])=O SVICABYXKQIXBM-UHFFFAOYSA-L 0.000 description 1
- 239000001415 potassium malate Substances 0.000 description 1
- 235000011033 potassium malate Nutrition 0.000 description 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
- 229940099402 potassium metaphosphate Drugs 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004304 potassium nitrite Substances 0.000 description 1
- 235000010289 potassium nitrite Nutrition 0.000 description 1
- 229940064218 potassium nitrite Drugs 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- 229940093914 potassium sulfate Drugs 0.000 description 1
- 239000001120 potassium sulphate Substances 0.000 description 1
- 239000001472 potassium tartrate Substances 0.000 description 1
- 229940111695 potassium tartrate Drugs 0.000 description 1
- 235000011005 potassium tartrates Nutrition 0.000 description 1
- RWMKSKOZLCXHOK-UHFFFAOYSA-M potassium;butanoate Chemical compound [K+].CCCC([O-])=O RWMKSKOZLCXHOK-UHFFFAOYSA-M 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- VLYFRFHWUBBLRR-UHFFFAOYSA-L potassium;sodium;carbonate Chemical compound [Na+].[K+].[O-]C([O-])=O VLYFRFHWUBBLRR-UHFFFAOYSA-L 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 235000019265 sodium DL-malate Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- MFBOGIVSZKQAPD-UHFFFAOYSA-M sodium butyrate Chemical compound [Na+].CCCC([O-])=O MFBOGIVSZKQAPD-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- UPMFZISCCZSDND-JJKGCWMISA-M sodium gluconate Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O UPMFZISCCZSDND-JJKGCWMISA-M 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 239000001394 sodium malate Substances 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- UJRAXLUXHBUNDO-UHFFFAOYSA-M sodium;hydron;oxalate Chemical compound [Na+].OC(=O)C([O-])=O UJRAXLUXHBUNDO-UHFFFAOYSA-M 0.000 description 1
- IZUPJOYPPLEPGM-UHFFFAOYSA-M sodium;hydron;phthalate Chemical compound [Na+].OC(=O)C1=CC=CC=C1C([O-])=O IZUPJOYPPLEPGM-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- DQVQCMPCHFOVKK-UHFFFAOYSA-J tetrasodium phthalate Chemical compound C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Na+].[Na+].[Na+].[Na+] DQVQCMPCHFOVKK-UHFFFAOYSA-J 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 235000015870 tripotassium citrate Nutrition 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 235000019263 trisodium citrate Nutrition 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
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Abstract
本發明提供使從也包括THF以外的VOC的聚對苯二甲酸丁二酯樹脂組成物成形而成的成形體不易釋出VOC之技術。係使用包含以直接酯化法製造的聚對苯二甲酸丁二酯樹脂與鹼化合物的聚對苯二甲酸丁二酯樹脂組成物，將聚對苯二甲酸丁二酯樹脂組成物予以成形而成的成形體依德國汽車工業會VDA277規定的VOC測定法測得的VOC排放量為50μgC/g以下。
Description
本發明係關於聚對苯二甲酸丁二酯樹脂組成物、及將該樹脂組成物成形而成的成形體。
聚酯樹脂由於有優良的機械特性、耐熱性、成形性，因此廣泛使用在汽車零件、薄膜、電氣電子零件等。其中，為一種聚酯樹脂的聚對苯二甲酸丁二酯樹脂由於利用無機強化材所獲致之補強效果高、耐藥品性也優良，所以廣泛使用於作為製造汽車或電氣電子設備的連接器、中繼器、開關等的工業用成形體的原料。
但是，上述聚對苯二甲酸丁二酯樹脂在使用成形體時會觀察到由於成形時之樹脂分解等所產生的氣體釋出的現象。產生的氣體當中，又以即使為常溫仍容易揮發的低分子量有機化合物(揮發性有機化合物(VOC))的釋出成為問題。
近年來，汽車製造商針對從汽車的內裝零件釋出的VOC量制定了基準，各汽車製造商設定了各種測定方法、規定。德國汽車工業協會已定出所謂VDA277的檢測揮發性有機化合物的試驗方法。
具體而言，例如非專利文獻1的第26頁所示，依VDA277規定的VOC測定法所測得的VOC排放量須為50μgC/g
以下。
在揮發性有機化合物當中，有四氫呋喃(THF)，專利文獻1中記載：當聚對苯二甲酸丁二酯樹脂的末端羥基量多的情形，成形時的THF產生量會增多，並揭示使用末端羥基濃度低的聚對苯二甲酸丁二酯樹脂。並且，揭示：藉由於聚對苯二甲酸丁二酯樹脂中添加鹼金屬鹽，能使得聚對苯二甲酸丁二酯樹脂的末端羥基安定化。惟，亦如專利文獻1中所記載，「末端羥基濃度係從總末端數減去COOH末端數來求取」，所以，「末端羥基濃度低」也就是指「COOH末端多」，如此的聚對苯二甲酸丁二酯樹脂的耐水解性不利。
專利文獻2中揭示：將聚對苯二甲酸丁二酯樹脂進行聚合時，藉由添加鈦觸媒與磷化合物及鹼金屬或鹼土類金屬，來防止產生THF。但是此方法會有由於使用之鹼性金屬化合物的種類及添加量造成聚合速度減慢等的問題。
又，專利文獻3中揭示：在將聚對苯二甲酸丁二酯樹脂進行聚合時，藉由分次添加有機鈦化合物或鹼金屬鹽，來抑制聚合速度的延遲且同時減少異物或末端羧基濃度的方法。但是，此方法係將添加有機鈦化合物或鹼金屬鹽的階段加以分割，所以管理變得煩雜。而且，此方法尚須要追加添加裝置，難以轉用現有的設備，所以須要進一步投資，於經濟上不利。
[先前技術文獻]
[專利文獻]
[專利文獻1]日本特開平06-9858號公報
[專利文獻2]日本特開平10-30054號公報
[專利文獻3]日本特開2010-100668號公報
[非專利文獻]
[非專利文獻1]C. Henneuse and T. Pacary(2003) Emissions from Plastics, Rapra Review Reports, Vol. 14, No.1
在含有聚對苯二甲酸丁二酯樹脂之聚對苯二甲酸丁二酯樹脂組成物進行成形時若產生VOC，在使用將上述樹脂組成物予以成形而成的成形體時容易從成形體釋出VOC。
本發明係為了解決上述問題而生，其目的在於提供使得不易從將聚對苯二甲酸丁二酯樹脂組成物予以成形而成的成形體釋出包括THF以外的VOC等的VOC的技術。
本案發明人等為了解決上述問題而努力探討，結果發現：若使用如在專利文獻1中使用的以酯交換法製造的聚對苯二甲酸丁二酯樹脂，則從係副產物的醇而來的醛會成為在成形時發生的VOC量增大的原因，並且，若使用含有以直接酯化法製造的聚對苯二甲酸丁二酯樹脂、及鹼化合物的聚對苯二甲酸丁二酯樹脂組成物，能夠抑制上述醛導致的問題，而且也能減少使用成形體時釋放的VOC量，乃完成了本發明。更具體而言，本發明係提供以下者。
(1)一種聚對苯二甲酸丁二酯樹脂組成物，其係包含以直接酯化法製造之聚對苯二甲酸丁二酯樹脂、與鹼化合物，將該聚對苯二甲酸丁二酯樹脂組成物予以成形而成的成形體依前述德國汽車工業會VDA277規定的VOC測定法所測得的VOC排放量為50μgC/g以下。
(2)如(1)之聚對苯二甲酸丁二酯樹脂組成物，其中，在聚對苯二甲酸丁二酯樹脂組成物中的該鹼化合物的添加量，相對於該聚對苯二甲酸丁二酯樹脂100質量份，為0.01質量份以上0.1質量份以下。
(3)如(1)或(2)之聚對苯二甲酸丁二酯樹脂組成物，其中，該鹼化合物為乙酸鉀。
(4)如(1)至(3)中任一項之聚對苯二甲酸丁二酯樹脂組成物，其中，該聚對苯二甲酸丁二酯樹脂的末端羧基量為40meq/kg以下。
(5)一種成形體，其係將如(1)至(4)中任一項之聚對苯二甲酸丁二酯樹脂組成物予以成形而成。
(6)如(5)之成形體，其中，該成形體係汽車內裝零件。
將本發明之聚對苯二甲酸丁二酯樹脂組成物予以成形而成的成形體，在使用時從成形體釋出的VOC量少。
以下針對本發明之實施形態說明。又，本發明不限定於以下的實施形態。
<聚對苯二甲酸丁二酯樹脂組成物>
本發明之聚對苯二甲酸丁二酯樹脂組成物包含聚對苯二甲酸丁二酯樹脂及鹼化合物。
[聚對苯二甲酸丁二酯樹脂]
本發明使用的聚對苯二甲酸丁二酯樹脂，係一般的聚對苯二甲酸丁二酯樹脂，包含至少來自於對苯二甲酸的重複單元、及至少來自碳數4之伸烷基二醇(1,4-丁二醇)的重複單元。
本發明使用之聚對苯二甲酸丁二酯樹脂，係以直接酯化法製造的聚對苯二甲酸丁二酯樹脂。作為聚對苯二甲酸丁二酯樹脂之製造方法，已知有直接酯化法與酯交換法，本發明係以直接酯化法製造聚對苯二甲酸丁二酯樹脂，所以如下所述，能減少從成形體產生的VOC量。
直接酯化法，係使用對苯二甲酸與1,4-丁二醇作為主原料，將對苯二甲酸與1,4-丁二醇於酯化反應觸媒存在下反應的方法。另一方面，酯交換法係使用對苯二甲酸二烷酯與1,4-丁二醇作為主原料，將對苯二甲酸與1,4-丁二醇於酯交換反應觸媒的存在下反應的方法。
直接酯化法在酯化反應時會生成水，不過，酯交換法的情形則生成醇。例如，當使用對苯二甲酸二甲酯製造聚對苯二甲酸丁二酯樹脂時，會生成甲醇。甲醇會變化為甲醛，所以造成從成形體產生的VOC量增加。若以此方式以酯交換法製造聚對苯二甲酸丁二酯樹脂，會產生為副產物的醇。並
且，此醇會變化為醛而使得從成形體產生的VOC量增大。直接酯化法中，不會生成為副產物的醇，因此不會從成形體釋出從此副產物的醇而來的醛。
本發明中，聚對苯二甲酸丁二酯樹脂只要是以直接酯化法製造者即可，製造條件不特別限定。酯化反應觸媒例如可使用銻化合物、鍺化合物、鈦化合物、錫化合物、鹼土類金屬化合物、錳化合物、鋅化合物等。又，觸媒的使用量也不特別限定，適當設定即可。
又，反應溫度、反應壓力、反應時間等反應條件也不特別限定，可因應理想的分子量等適當設定即可。
依此方式製造的聚對苯二甲酸丁二酯樹脂，具有來自於對苯二甲酸的重複單元、及來自於1,4-丁二醇的重複單元。又，本發明之聚對苯二甲酸丁二酯樹脂不限定於由對苯二甲酸丁二酯重複單元構成的均聚對苯二甲酸丁二酯樹脂，也可為含有60莫耳%以上的(特別是75莫耳%以上95莫耳%以下)的對苯二甲酸丁二酯單元的共聚物。
作為對苯二甲酸以外的二羧酸成分(共聚物成分)，例如：間苯二甲酸、鄰苯二甲酸、2,6-萘二羧酸、4,4-二羧基二苯醚等C8-14的芳香族二羧酸；琥珀酸、己二酸、壬二酸、癸二酸等C4-16的烷二羧酸；環己烷二羧酸等C5-10之環烷二羧酸。此等二羧酸成分可以單獨使用或組合使用2種以上。
作為1,4-丁二醇以外的二醇成分(共聚物成分)，例如乙二醇、丙二醇、三亞甲基二醇、1,3-丁二醇、六亞甲基二醇、新戊二醇、1,3-辛二醇等C2-10之伸烷基二醇；二乙二醇、
三乙二醇、二丙二醇等聚氧基伸烷基二醇；環己烷二甲醇、氫化雙酚A等脂環族二醇；雙酚A、4,4’-二羥基聯苯等芳香族二醇；雙酚之環氧乙烷2莫耳加成體、雙酚A之環氧丙烷3莫耳加成體等雙酚A的C2-4的環氧烷加成體。此等二醇成分可以單獨使用也可組合使用2種以上。
本發明使用的聚對苯二甲酸丁二酯樹脂的末端羧基量不特別限制，本發明即使使用末端羧基量少，亦即末端羥基量多的聚對苯二甲酸丁二酯樹脂，仍能減少從成形體產生的VOC量。
於聚對苯二甲酸丁二酯樹脂的末端有羥基的情形，末端羥基及鍵結於末端羥基的伸丁基會生成四氫呋喃(THF)。TFH為一種VOC，所以若使用末端羥基量多的聚對苯二甲酸丁二酯樹脂製作成形體，會於成形時產生THF，因而造成從成形體釋出的VOC量增加。然而，藉由以直接酯化法製造聚對苯二甲酸丁二酯樹脂且同時併用聚對苯二甲酸丁二酯樹脂與鹼化合物，則即使使用末端羥基量多的聚對苯二甲酸丁二酯樹脂仍能抑制上述VOC釋放量。
又，末端羧基量少的聚對苯二甲酸丁二酯樹脂，耐水解性優異。因此，使用本發明之聚對苯二甲酸丁二酯樹脂組成物製造的成形體，耐水解性優良且同時VOC的釋出量也少。
在此，末端羧基量少，係指40meq/kg以下。從更提高耐水解性的觀點，末端羧基量宜為25meq/kg以下更佳。依此方式，設定聚對苯二甲酸丁二酯樹脂之末端羧基量為
25meq/kg以下，而使成形體不易因為在濕熱環境下的水解而造成強度降低，也能利用本發明使從成形體產生的VOC量大幅減少。又，末端羧基量，可藉由將聚對苯二甲酸丁二酯的粉碎試樣於苯甲醇中於215℃溶解10分鐘後，以0.01N的氫氧化鈉水溶解液進行滴定並測定以求得。
本發明使用的聚對苯二甲酸丁二酯樹脂的固有黏度，在不妨礙本發明目的之範圍內不特別限定。聚對苯二甲酸丁二酯樹脂之固有黏度(IV)宜為0.65dL/g以上1.4dL/g以下。當使用具有該範圍之固有黏度的聚對苯二甲酸丁二酯樹脂的情形，獲得之聚對苯二甲酸丁二酯樹脂組成物的成形性特別優良。又，也可摻混具有不同的固有黏度的聚對苯二甲酸丁二酯樹脂來調整固有黏度。例如，藉由摻混固有黏度1.0dL/g的聚對苯二甲酸丁二酯樹脂與固有黏度0.7dL/g的聚對苯二甲酸丁二酯樹脂，可製備固有黏度為0.9dL/g的聚對苯二甲酸丁二酯樹脂。聚對苯二甲酸丁二酯樹脂的固有黏度(IV)，可於鄰氯苯酚中於溫度35℃的條件測定。
本發明之聚對苯二甲酸丁二酯樹脂組成物中的聚對苯二甲酸丁二酯樹脂的含量不特別限定，宜為10質量%以上、小於99.99質量%較理想。又，上述含量若為30質量%以上，則由於含有聚對苯二甲酸丁二酯樹脂所獲致之物性提升會於成形體中顯現，為特別理想。更理想的上述含量為50質量%以上、未達99.99質量%。
[鹼化合物]
本發明之聚對苯二甲酸丁二酯樹脂組成物含有鹼化合
物。藉由含有鹼化合物，能壓抑從將本發明之樹脂組成物予以成形而成的成形體釋放的VOC量。
本發明能使用的鹼化合物的種類不特別限定，例如：鹼金屬鹽及鹼土金屬鹽，具體可列舉：氯化鉀、鉀明礬、甲酸鉀、檸檬酸三鉀、檸檬酸氫二鉀、檸檬酸二氫鉀、葡萄糖酸、琥珀酸鉀、丁酸鉀、草酸二鉀、草酸氫鉀、硬脂酸鉀、鄰苯二甲酸鉀、鄰苯二甲酸氫鉀、偏磷酸鉀、蘋果酸鉀、磷酸三鉀、磷酸氫二鉀、磷酸二氫鉀、亞硝酸鉀、苯甲酸鉀、酒石酸氫鉀、重草酸鉀、重鄰苯二甲酸鉀、重酒石酸鉀、重硫酸鉀、硝酸鉀、乙酸鉀、氫氧化鉀、碳酸鉀、碳酸鉀鈉、碳酸氫鉀、乳酸鉀、硫酸鉀、硫酸氫鉀、氯化鈉、甲酸鈉、檸檬酸三鈉、檸檬酸氫二鈉、檸檬酸二氫鈉、葡萄糖酸鈉、琥珀酸鈉、丁酸鈉、草酸二鈉、草酸氫鈉、硬脂酸鈉、鄰苯二甲酸鈉、鄰苯二甲酸氫鈉、偏磷酸鈉、蘋果酸鈉、磷酸三鈉、磷酸氫二鈉、磷酸二氫鈉、亞硝酸鈉、苯甲酸鈉、酒石酸氫鈉、重草酸鈉、重鄰苯二甲酸鈉、重酒石酸鈉、重硫酸鈉、硝酸鈉、乙酸鈉、氫氧化鈉、碳酸鈉、碳酸氫鈉、乳酸鈉、硫酸鈉、硫酸氫鈉、氯化鋰、甲酸鋰、檸檬酸三鋰、檸檬酸氫二鋰、檸檬酸二氫鋰、葡萄糖酸鋰、琥珀酸鋰、丁酸鋰、草酸二鋰、草酸氫鋰、硬脂酸鋰、鄰苯二甲酸鋰、鄰苯二甲酸氫鋰、偏磷酸鋰、蘋果酸鋰、磷酸三鋰、磷酸氫二鋰、磷酸二氫鋰、亞硝酸鋰、苯甲酸鋰、酒石酸氫鋰、重草酸鋰、重鄰苯二甲酸鋰、重酒石酸鋰、重硫酸鋰、硝酸鋰、乙酸鋰、氫氧化鋰、碳酸鋰、碳酸氫鋰、乳酸鋰、硫酸鋰、硫酸氫鋰、氯化鈣、甲酸鈣、檸檬酸鈣、葡萄糖酸鈣、琥珀酸鈣、
丁酸鈣、草酸鈣、硬脂酸鈣、鄰苯二甲酸鈣、偏磷酸鈣、蘋果酸鈣、磷酸鈣、磷酸氫鈣、磷酸二氫鈣、亞硝酸鈣、苯甲酸鈣、酒石酸鈣、重草酸鈣、重鄰苯二甲酸鈣、重酒石酸鈣、重硫酸鈣、硝酸鈣、乙酸鈣、氫氧化鈣、碳酸鈣、乳酸鈣、硫酸鈣等。此等之鹼化合物中，宜為乙酸鉀、碳酸鈣，尤佳為乙酸鉀。
本發明之聚對苯二甲酸丁二酯樹脂組成物中所含的鹼化合物的含量，依理想的VOC排放量等設定即可，不特別限定，但相對於聚對苯二甲酸丁二酯樹脂100質量份宜為0.01質量份以上0.1質量份以下。從充分抑制來自於單體成分的VOC生成的理由，上述含量為0.01質量份以上較理想，而上述含量為0.1質量份以下能抑制鹼化合物分解聚對苯二甲酸丁二酯樹脂而引起的VOC產生，故較理想。更理想的上述含量為0.01質量份以上0.05質量份以下。又，上述理想範圍外，若聚對苯二甲酸丁二酯樹脂的種類不同(例如分子量、末端羧基量、含有的共聚合成分不同的情形)，也有VOC排放量會落入理想範圍內的情況，此種的情況也在本發明的範圍內。
[其他成分]
本發明之聚對苯二甲酸丁二酯樹脂組成物中也可含有上述必要成分以外的其他成分。作為其他成分，例如填充劑(無機填充劑等)、核劑、顏料、抗氧化劑、安定劑、塑化劑、潤滑劑、脫模劑及阻燃劑等添加劑、其他樹脂等。
[聚對苯二甲酸丁二酯樹脂組成物之製造方法]
本發明之聚對苯二甲酸丁二酯樹脂組成物之製造方法不特別限定。可利用一般作為樹脂組成物之調製法的公知的設備
與方法，來製備樹脂組成物。例如，混合必要成分並使用單軸或雙軸的擠製機或其他熔融混練裝置進行混練，製備為成形用丸粒。又，也可使用多數的擠製機或其他的熔融混練裝置。又，可從料斗同時投入全部成分，也可從側饋料口投入一部分的成分。
鹼化合物宜以溶於水的狀態投入到擠製機等熔融混練裝置較佳。原因為鹼化合物會更均勻地分散於樹脂組成物中。再者，當以固體形式添加鹼化合物的情形，有時鹼化合物會作用為核劑，但是當將鹼化合物以溶於水的狀態添加的情形，能夠抑制鹼化合物作用為核劑，所以對於韌性等的影響可能性小，從此觀點為較理想。此水溶液的鹼化合物的濃度宜為1mol/L以上100mol/L以下較理想。原因為：若鹼化合物的濃度低於1mol/L的情形，水分量增多，容易促進聚對苯二甲酸丁二酯的水解，而鹼化合物的濃度超過100mol/L的情形，鹼化合物不易均勻分散。
[成形體之製造方法]
可利用射出成形等以往公知的成形方法，將以上述方式製作的聚對苯二甲酸丁二酯樹脂組成物丸粒作為原料，來製造成形體。又，由於不必先製成樹脂組成物丸粒，也可以將各成分直接供給到擠製機等熔融混練裝置並製造成形體。
以上述方式獲得的成形體，利用德國汽車工業會VDA277規定的VOC測定法測得的VOC排放量為50μgC/g以下。因此，將本發明之聚對苯二甲酸丁二酯樹脂組成物予以成形而成的成形體，使用時釋出的VOC量減少。使用時釋出的
VOC，當成形體使用於作為汽車內裝零件等車內或室內使用的情形特別成為問題。若為本發明之成形體，在車內或室內均能理想地使用。
以下舉實施例更詳細說明本發明，但本發明不限定於此等實施例。
<材料>
以直接酯化法製造的聚對苯二甲酸丁二酯樹脂：WINTECH POLYMER公司製、「DURANEX(註冊商標)」、IV=0.69dL/g、末端羧基量為23meq/kg
乙酸鉀：和光純藥工業(股)公司、乙酸鉀
碳酸鈣：TOYO FINE CHEMICAL(股)公司、WHITON P-30
<樹脂組成物之製造方法>
將在以直接酯化法製造的聚對苯二甲酸丁二酯樹脂中以表1所示比例混合乙酸鉀或碳酸鈣而得者作為原料，將此原料投入雙軸擠製機(JSW製，TEX-30)，進行熔融混練而製造聚對苯二甲酸丁二酯樹脂丸粒。又，冷卻時間以外的條件如下所述。
(熔融混練條件)
缸筒溫度：260℃
螺桿轉速：130rpm
擠出量：12kg/hr
<成形體的製造>
將實施例及比較例的樹脂丸粒對於射出成形機(JSW公司製，「J75EP」供給，以下列成形條件製造成形體
(100mm×40mm×2mm)。
(成形條件)
成形條件：缸筒溫度：250℃
射出壓力：60(MPa)
射出速度：1.0(m/min)
模具溫度：60(℃)
<VOC排放量的測定>
將實施例、比較例的成形體切成10~25mg而得的樣本約2g分別放入22ml的小玻璃瓶中，精秤樣本重量後，密封並以HS-GC於120℃進行5小時的加熱處理。然後，計算氣相層析儀檢測到的揮發有機成物成分的峰部積分面積，以丙酮為標準，作為重量換算值，求取成形體單位重量的揮發性有機化合物量(μgC/g)。結果如表1所示。
由表1可確認，若將以直接酯化法製造的聚對苯二甲酸丁二酯樹脂與鹼化合物組合，從成形體釋出的VOC量會變得非常低。
Claims (6)
- 一種聚對苯二甲酸丁二酯樹脂組成物，包含以直接酯化法製造之聚對苯二甲酸丁二酯樹脂與鹼化合物，將該聚對苯二甲酸丁二酯樹脂組成物予以成形而成的成形體依德國汽車工業會VDA277規定的VOC測定法測得的VOC排放量為50μgC/g以下。
- 如申請專利範圍第1項之聚對苯二甲酸丁二酯樹脂組成物，其中，聚對苯二甲酸丁二酯樹脂組成物中的該鹼化合物的添加量，相對於該聚對苯二甲酸丁二酯樹脂100質量份為0.01質量份以上0.1質量份以下。
- 如申請專利範圍第1或2項之聚對苯二甲酸丁二酯樹脂組成物，其中，該鹼化合物為乙酸鉀。
- 如申請專利範圍第1或2項之聚對苯二甲酸丁二酯樹脂組成物，其中，該聚對苯二甲酸丁二酯樹脂的末端羧基量為40meq/kg以下。
- 一種成形體，將如申請專利範圍第1或2項之聚對苯二甲酸丁二酯樹脂組成物予以成形而成。
- 如申請專利範圍第5項之成形體，其中，該成形體為汽車內裝零件。
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| DE112014002214T5 (de) * | 2013-04-30 | 2016-01-28 | Wintech Polymer Ltd. | Polybutylenterephthalat-Harz-Zusammensetzung und Formgegenstand |
| HUE050817T2 (hu) * | 2015-07-22 | 2021-01-28 | Polyplastics Co | Eljárás polibutilén tereftalát gyanta kompozíció gyártására, és eljárás polibutilén tereftalát gyanta fröccsöntött cikk gyártására |
| US11001705B2 (en) * | 2015-12-25 | 2021-05-11 | Toyobo Co., Ltd. | Polyester resin composition, light-reflector component containing same, light reflector, and method for producing polyester resin composition |
| JP6769290B2 (ja) * | 2015-12-25 | 2020-10-14 | 東洋紡株式会社 | ポリエステル樹脂組成物、これを含む光反射体用部品および光反射体 |
| CN110249002B (zh) | 2017-02-02 | 2021-06-25 | 东洋纺株式会社 | 聚酯树脂组合物、含该聚酯树脂组合物的光反射体用部件和光反射体 |
| WO2018143099A1 (ja) | 2017-02-02 | 2018-08-09 | 東洋紡株式会社 | ポリエステル樹脂組成物、これを含む光反射体用部品および光反射体 |
| KR102290954B1 (ko) * | 2017-07-25 | 2021-08-19 | 주식회사 엘지화학 | 염화비닐계 중합체 및 이의 제조방법 |
| US11795298B2 (en) | 2018-03-26 | 2023-10-24 | Toyobo Mc Corporation | Polyester resin composition, light-reflector component containing same, and light reflector |
| US20220251291A1 (en) * | 2019-07-29 | 2022-08-11 | Lanxess Deutschland Gmbh | Polybutylene Terephthalate With Low THF Content |
| CN114538880B (zh) * | 2022-01-27 | 2024-04-12 | 环秀(青岛)建材科技有限公司 | 一种无机耐磨地坪涂层的制备与施工方法 |
| CN120548342A (zh) * | 2022-10-26 | 2025-08-26 | 杜邦中国集团有限公司上海分公司 | 具有低voc排放的聚合物复合材料 |
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| JP3366780B2 (ja) * | 1995-07-27 | 2003-01-14 | 帝人株式会社 | 光ファイバールースチューブ用樹脂組成物及び製造方法 |
| JPH1030054A (ja) | 1996-07-12 | 1998-02-03 | Mitsubishi Rayon Co Ltd | ポリエステル系樹脂組成物 |
| JP2001114880A (ja) * | 1999-10-15 | 2001-04-24 | Toray Ind Inc | ポリエステルの製造法 |
| JP2005179604A (ja) * | 2003-12-22 | 2005-07-07 | Polyplastics Co | 研磨材及び成形機金属部品の再生方法 |
| US20090264611A1 (en) * | 2004-04-01 | 2009-10-22 | Toshiyuki Hamano | Polybutylene terephthalate |
| JP2006104363A (ja) * | 2004-10-07 | 2006-04-20 | Wintech Polymer Ltd | ポリブチレンテレフタレート樹脂組成物 |
| JP3974915B2 (ja) * | 2004-12-21 | 2007-09-12 | 株式会社アルファ・オイコス | 基板加熱装置 |
| JP2007204650A (ja) * | 2006-02-03 | 2007-08-16 | Mitsubishi Chemicals Corp | 熱可塑性樹脂組成物および樹脂成形品 |
| JP2010100668A (ja) | 2008-10-21 | 2010-05-06 | Toray Ind Inc | ポリブチレンテレフタレートの製造方法 |
| CN101759966A (zh) * | 2008-11-24 | 2010-06-30 | 东丽纤维研究所（中国）有限公司 | 聚酯组合物及其用途 |
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| JP6054946B2 (ja) | 2016-12-27 |
| EP2832794A4 (en) | 2015-11-11 |
| WO2013146281A1 (ja) | 2013-10-03 |
| EP2832794B1 (en) | 2018-08-22 |
| EP2832794A1 (en) | 2015-02-04 |
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| JPWO2013146281A1 (ja) | 2015-12-10 |
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